共查询到20条相似文献,搜索用时 15 毫秒
1.
2.
有机材料(EDT-DSDTFVO)FeCl_4和(EDT-DSDTFVO)GaCl_4的输送现象 总被引:1,自引:0,他引:1
通过对有机材料(EDT-DSDTFVO)2FeCl4和(EDT-DSDTFVO)2GaCl4的输送测定,对其电阻率的温度依赖性以及压力效果进行了系统的比较,虽然两类盐的电阻率随着温度的变化行为十分相似,但是其压力效果尤其在高压时表现出明显的差异性。认为这种差异性和π-d相互作用密切相关。在这里,用EDT-DSDTFVO表示ethylenedithiodiselenadithiafulvalenothioquinone-1,3-dithiole methide。 相似文献
3.
4.
用轨线法对N(4Su)+CH(0,0)→CN(v′,J′)+H(2Sg)和N(4Su)+CH(0,0)→NH(v′,J′)+C(3Pg)反应进行计算,研究了两个反应的阈能、反应截面、产物散射分析和微观反应机理 相似文献
5.
有机材料(EDT-DSDTFVO)2FeCl4和(EDT-DSDTFVO)2GaCl4的输送实验结果,显示出这两类盐的电阻率对温度的依赖性以及压力效果十分相似,但是两种盐的磁电阻率却表现出很大的不同,FeCl4盐为负磁电阻,而GaCl4盐为正磁电阻.我们认为这种输送现象的差异性起源于π-d相互作用.我们用EDT-DSDTFVO表示ethylenedithiodiselenadithiafulvalenothioquinone-1,3-dithiole methide. 相似文献
6.
Na5Eu(MoO4)4和Na5Eu(WO4)4的荧光光谱和晶场参数 总被引:2,自引:1,他引:1
本文报告了Na5Eu(MoO4)4和Na5Eu(WO4)4粉末样品的荧光光谱。结果表明,在这些化合物中,稀土离子占据S4对称性晶格点,点对称性相当接近D2d。从实验光谱数据,我们导出了D2d对称性下Na5Eu(MoO4)和Na5Eu(WO4)4的晶场参数,这些参数相当好地拟合了从光谱实验中得到的能级。 相似文献
7.
Similarities in the decomposition and dehydrogenation of cyclohexene on (4 × 4)-CMo(110) and Pt(111)
《Surface science》1996,367(3):L102-L110
The decomposition and dehydrogenation of cyclohexene have been used as probing reactions to directly compare the surface reactivities of carbon-modified Mo(110) and Pt(111). By using temperature programmed desorption (TPD) and high-resolution electron energy loss spectroscopy (HREELS), we find that the dominant decomposition pathway of cyclohexene can be converted from complete decomposition to atomic carbon and hydrogen on clean Mo(110) to partial dehydrogenation to benzene and hydrogen on (4 × 4)-CMo(110). The latter reaction mechanism is very similar to that observed on Pt(111). Furthermore, in contrast to the near identical catalytic properties that are commonly observed for bulk molybdenum carbide and nitride powder materials, we find that the reactivities of carbon-modified and nitrogen-modified Mo(110) surfaces are qualitatively different. 相似文献
8.
9.
掺杂晶体(NH4)1-xKxNO3、(NH4)1-xNaxNO3振动模的临界行为王焕茹吴国祯(清华大学物理系北京100084)TheCriticalBehavioursoftheVibrationalModesofDoped(NH4)1-xKxNO... 相似文献
10.
11.
基质发光材料Na5Eu(MoO4)4和NaEu(MoO4)2的制备和发光 总被引:1,自引:0,他引:1
本文研究了化学计量的基质发光材料Na5Eu(MoO4)4和NaEu(MoO4)2.它们都属于四方晶系,空间群为I41/α .NaEu(Mo04)2属于白钨矿(scheelite)结构,一个晶胞中有2个分子式NaEu(MoO4)2(z=2);而Na5Eu(Mo4O)4属于类自钨矿(scheelite-like)结构,一个晶胞中有4个分子式Na5Eu(MoO4)4(z=4).X射线衍射确定的晶胞常数,对Na5Eu(MoO4)4,α=1.1439nm和c=1.1486nm(密度d计算=4.01g/cm3,z=4);对NaEu(MoO4)2,α=0.5236nm和c=1.1439nm(密度d计算=5.24g/cm3,z=2).由差热法和X射线衍射法确定了Na2MoO4-Eu2(MoO4)3的相图.Na5Eu(MoO4)4分解为NaEu(MoO4)2的温度是700℃.本文确定了制备纯 Na5Eu(MoO4)和NaEu(MoO4)2的方法,并研究了上述两种材料的激发光谱和发光光谱.确定了用X射线粉末衍射谱和发光光谱鉴别Na5Eu(MoO4)4和NaEu(MoO4)2的方法.在365nm紫外光激发下,Na5Eu(MoO4)4的发光比Na5Eu(WO4)4的强得多,在室温下,Na5Eu(MoO4)4,NaEu(MoO4)2和Na5Eu(WO4)4的相对发光积分亮度比为3.8:3.2:1.0. 相似文献
12.
本文研究了基质发光材料Na5Eu(MoO4)4和NaEu(MoO4)2的喇曼光谱.用群论方法分析了它们的内、外振动模式,对实验振动模进行了指认.本文还将上述喇曼光谱与Na5Eu(WO4)4、CaWO4、SrWO4、CaMoO4和SrMoO4的喇曼光谱进行了比较,Na5Eu(MoO4)4和NaEu(MoO4)2的喇曼光谱结果表明(MoO4)2-离子团的高能量拉伸内振动是产生Eu3+的5D2→5D1,5D1→5D0-多声子无辐射弛豫的原因,这导致了Eu3+在这类材料中主要产生5DO→7Fj的发光跃迁. 相似文献
13.
采用水热法制备了NaEu(MoO4)2-x(WO4)x固溶体微晶;通过X射线衍射(XRD)、扫描电镜(SEM)和荧光分析(FA)对所制备的微晶进行了表征。XRD结果表明NaEu(MoO4)2-x(WO4)x微晶呈现典型的四方晶相白钨矿结构。SEM分析表明微晶呈米粒状。荧光分析显示,NaEu(MoO4)2-x(WO4)x微晶在370~386 nm之间呈现MO2-4配离子(M=Mo,W)的特征发射峰,发射波长随x的增大而减小;同时,Eu3+在592 nm(5D0→7F1)和614 nm(5D0→7F2)的特征发射峰均明显显现,强度随x的增大而逐渐增大。 相似文献
14.
L. S. Smirnov A. I. Baranov L. A. Shuvalov L. Bobrowicz-Sarga I. Natkaniec S. Waplak 《Physics of the Solid State》2001,43(1):117-126
The (NH4)3H(SO4)2 and [(NH4)0.82Rb0.18]3H(SO4)2 crystals are investigated by dielectric spectroscopy, inelastic incoherent neutron scattering (IINS), and neutron powder diffraction. A comparative analysis of the data obtained is given. It is shown that the phase transitions II ? III, III ? IV, IV ? V, and V ? VII in the (NH4)3H(SO4)2 crystal are accompanied by changes in the orientation ordering of the NH 4 + ions. In the [(NH4)0.82Rb0.18]3H(SO4)2 crystal, these phase transitions are completely suppressed and the long-range order inherent in the II phase is retained over the entire temperature range covered (6–300 K). It is revealed that this crystal at the temperature T g≈70 K undergoes a transition to the dipole glass phase, which is attended by “freezing” the orientation disordering of the ammonium ions. 相似文献
15.
The Euclidean (4)3, model in R3 corresponds to a perturbation by a 4 interaction of a Gaussian measure on scalar fields with a covariance depending on a real parameter in the range 01. For =1 one recovers the covariance of a massless scalar field in R3. For =0, 4 is a marginal interaction. For 0<1 the covariance continues to be Osterwalder-Schrader and pointwise positive. We consider the infinite volume critical theory with a fixed ultraviolet cutoff at the unit length scale and we prove that for >0, sufficiently small, there exists a non-gaussian fixed point (with one unstable direction) of the Renormalization Group iterations. We construct the stable critical manifold near this fixed point and prove that under Renormalization Group iterations the critical theories converge to the fixed point.
Partially supported by NSERC of CanadaLaboratoire Associé au CNRS. UMR 5825Partially supported by CNR, G.N.F.M. and MURST 相似文献
16.
17.
对于盐熔法合成的LiNdP_4O_(12)单晶进行了X射线衍射分析,该晶体属于单斜晶系,空间群为C2/c,z=4,晶胞参数为:α=16.486A,b=7.073A,c=9.775A,β=126.23°,全矩阵最小二乘法修正给出1251个独立反射的R=0.054,R_ω=0.050,经吸收和次级消光校正后,R=0.048,R_ω=0.043,基本的结构单位是(PO_3)_n的螺旋带,它们由共角的四面体构成,十二面体NdO_8不共有任何O原子,从这意义来说是相互分立的。 相似文献
18.
19.
20.
本文讨论了双荷子系统的能谱, 表明双荷子系统哈密顿量HD=1/2M π2-α/r+μ2/2Mr2具有SO(4)对称性. 相似文献