共查询到20条相似文献,搜索用时 437 毫秒
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The effect of sodium borate decahydrate as a nondurable treatment on the flammability of 100% cotton fabric (woven plain 150
g m−2) has been investigated in this paper. The laundered bone-dried massed samples were impregnated with suitable concentrations
of sodium borate decahydrate. Each bunches of fabrics were dipped into individual aqueous solutions of the salt, followed
by means of squeeze rolls and drying at 110°C. By using a ‘vertical flame spread test’ the optimum add-on values to impart
flame-retardancy onto cotton fabric was determined to be as 4.24 g salt per 100 g fabric. The objective of this study is thermogravimetry
(TG) investigation of pure cotton, treated one with the salt at its optimum efficiency. So that outcomes could be compared
and commented, finally the results obtained are in favor of ‘Chemical action theory’, ‘Condensed phase retardation’, ‘Dust
or wall effect theory’ and also ‘Gas dilution theory’. 相似文献
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Johanna S. Knyrim S. Rebecca Römer Wolfgang Schnick Hubert Huppertz 《Solid State Sciences》2009,11(2):336-342
The new orthorhombic barium borate β-BaB4O7 was synthesized under high-pressure/high-temperature conditions in a Walker-type multianvil apparatus at 7.5 GPa and 1100 °C, starting from stoichiometric mixtures of the binary oxides. β-BaB4O7 crystallizes in space group Pmnb with Z = 2 and lattice parameters a = 1099.4(2), b = 901.7(2), c = 430.73(9) pm, R1 = 0.0199, and wR2 = 0.0406 (all data). The network-structure is built up exclusively from BO4-tetrahedra, linked via common corners. Its structural differences to the ambient-pressure phase α-BaB4O7 and structural agreements with the isotypic high-pressure phases β-MB4O7 (M = Ca, Hg, Sn) and the ambient-pressure phases MB4O7 (M = Sr, Pb, Eu) are discussed. β-BaB4O7 and a hypothetical BaB4O7 in the β-MB4O7 (M = Ca, Hg, Sn) structure were studied as high-pressure phases of α-BaB4O7, using density functional calculations. The transition pressure of α-BaB4O7 into the structure of β-BaB4O7 was calculated to 1.5 GPa; the transition pressure of β-BaB4O7 into BaB4O7 in the β-MB4O7 (M = Ca, Hg, Sn) structure to 7.5 GPa. 相似文献
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Yu. A. Ferapontov M. A. Ul’yanova T. V. Sazhneva 《Russian Journal of Inorganic Chemistry》2008,53(10):1635-1640
The decomposition kinetics of peroxide products contained in the liquid phase of the LiOH-H2O2-H2O ternary system were studied, and the applicability of the solubility method to studying this system was demonstrated for hydrogen peroxide concentrations in the liquid phase from 2 to 6 wt % and temperatures of 21–33°C. The stabilizing influence of solid Li2O2 · H2O on hydrogen peroxide decomposition was demonstrated. The temperature and concentration boundaries of existence were determined for the Li2O2 · H2O phase, whose identity was verified by chemical analysis and qualitative X-ray powder diffraction analysis. 相似文献
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Ohne Zusammenfassung 相似文献
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P_2O_5-V_2O_5-TiO_2(简写为P-V-Ti)对芳烃氧化有良好的催化效果.丁烷氧化催化剂P-V体系的体相和表面结构已有一些报道.但P_2O_5对V-Ti的影响文献较少报道.本文用XRD,IR,TPD和ESR考察了P-V-Ti体系. 1.试剂和催化剂:草酸、偏钒酸铵、二氧化钛均为化学纯.将V_2O_5:TiO_2=11:89(重量)样品分别按 P/V原子比为0.1,0.3,0.6,1.0,1.5和2.5制成编号为P-0.1,P-0.3,P-O.6,P-1.0,P-1.5和P-2.5的催化剂. 相似文献
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利用abinitio方法,在UHF,UMP2及不同基组3-21G,6-31G^*,6-311+G^*和UMP2(full)/6-311+G^*水平上,研究了O~2/O~2^.^-自交换电子转移反应。优化了电子转移前后反应物和产物的结构,研究了体系能量的变化,计算了自交换电子转移反应的内重组能。对UHF方法和UMP2方法的计算结果进行了比较,并与实验结果进行了对照。结果表明UHF方法由于没有考虑组态相互作用,计算结果存在较大偏差,UMP2(full)/6-311+G^*水平上的计算结果与实验值吻合较好。在UMP2(full)/6-311+G^*水平上计算了气相自交换电子转移反应速率常数。在优化了电子转移复合物结构的基础上考虑了溶剂效应的影响,计算了水溶液中的溶剂重组能。研究结果表明O~2/O~2^.^-体系电子转移反应的活化能主要来源于溶剂重组能的贡献。最后计算了该反应在水溶液中的反应速率常数。理论计算结果与实验值吻合得很好。 相似文献
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Li2O﹒2B2O3-H2O过饱和溶液20℃结晶动力学研究 总被引:3,自引:1,他引:3
盐水溶液中存在过饱和现象,硼酸盐溶液的过饱和即是一例.其中,镁础酸盐体系过饱和溶液在不同浓度和温度条件下的液固相关系曾有多次报道[‘-’];给出过许多有益的结果,也探讨了镁硼酸盐的结晶反应机理并拟合出相应的结晶动力学方程.这些工作对认识盐水溶液过饱和现象有重要意义.为了更广泛地认识和了解不同棚酸盐水溶液中的过饱和现象,本文采用动力学方法,首先对Li20·2B203-HZO过饱和溶液结晶过程进行了研究.1实验初始反应溶液中Li。O/BZO。(摩尔比)为1/2,按此配比计算并称取需要量的Li0H·H。O(A.R.)、H。… 相似文献
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《Journal of Coordination Chemistry》2012,65(1-2):133-144
Abstract Reactions of Mo(CO)6 with Na2WO4 · 2H2O in refluxing carboxylic anhydride produce the triangular bioxo-capped mixed-metal carboxylate clusters Na[MoW2O2(O2CR)9] (R = Me, 1; Et, 2), the propionate being hydrolyzed in 2M HCl containing ZnCl2 to form [MoW2O2(O2CEt)6(H2O)3]ZnCl4·2H2O (3). Cluster 2 is converted to the incomplete cuboidal tetraanion [MoW2O4(O2CEt)8]4- upon reacting with Cr(CO)6 in propionic anhydride at 120°, the latter species being trapped by Cr3± and Na± ions in the reaction mixture to afford the octanuclear heterometallic chain-like cluster Na2Cr2 [MoW2O4(O2CEt)8]2 (4). Clusters 1, 3 and 4 have been characterized by X-ray crystallography with the following crystal data, for 1: monoclinic, space group P21/c, a = 16.666(8), b = 11.096(3), c = 16.541(7) Å, β = 94.60(4)°, V = 3048.9 Å3, Z = 4, R, Rw = 0.070, 0.079; for 3, monoclinic, space group Cm, a = 10.259(3), b = 15.756(3), c = 10.870(3) Å, β = 96.18(3)°, V = 1746.8 Å3, Z = 2, R, Rw = 0.028, 0.034; for 4, triclinic, space group P-1, a = 13.013(5), b = 14.005(4), c = 12.357(4) Å, α = 109.71(2), β = 117.77(3), γ = 90.41(3)°, V = 1838.9 Å3, Z = 1, R, Rw = 0.037, 0.042. 相似文献
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Alfredo Román-Tejeda Heriberto Pfeiffer 《Journal of Thermal Analysis and Calorimetry》2012,110(2):807-811
CO2 capture and storage are the most important issues to be tackled in the near future. For the last few years, different lithium ceramics have been proposed as possible CO2 captors. In this article, the CO2 chemisorption process on ??-LiBO2, which had not been previously investigated, was studied. ??-LiBO2 was synthesized and characterized by XRD, SEM and N2 adsorption. Its CO2 reactivity was evaluated by dynamic and isothermal thermogravimetric experiments. Results show that ??-LiBO2 is able to react with CO2. Additionally, there is a phase transformation from ??-LiBO2 to ??-LiBO2 during the CO2 absorption. Although the CO2 absorption was not considerably high, the results showed that lithium ceramics, containing boron, absorbed CO2. 相似文献
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Kravchenko E. A. Kargin Yu. F. Egorysheva A. V. Buslaev Yu. A. 《Russian Journal of Coordination Chemistry》2001,27(8):542-547
It was earlier found from nuclear quadrupole resonance (NQR) measurements and computer modeling that -Bi2O3, Bi3O4Br and mixed oxides Bi2O3· 2Al2O3, Bi2O3· 2Ga2O3, Bi2O3· 3GeO2, and 2Bi2O3· 3GeO2exhibit local ordered magnetic fields from 30 to 200 G. It thus follows that these compounds are not diamagnets in a conventional sence of the word. With the aim of revealing previously unknown magnetic properties in bismuth(III) oxide-based Main Group element compounds, the mixed bismuth–boron oxides 2Bi2O3· B2O3, 3Bi2O3· 5B2O3, and Bi2O3· 3B2O3were prepared and studied using 209Bi NQR. The quadrupole interactions of the 209Bi nuclei and their electronic environment were studied, the crystallochemical features of the compounds were discussed, and the conformity of the 209Bi results to the X-ray structure data was verified. The preliminary tests in the field of a permanent magnet showed that the resonance intensities increase in external magnetic fields, indicating that a magnetism of unknown nature develops in the titled compounds. It was found reasonable to continue studies of the magnetic properties of these compounds using single-crystal 209Bi NQR in external magnetic fields. 相似文献
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Zusammenfassung Die Systeme GeO2–Na2O, –K2O und –Rb2O werden röntgenographisch und differentialthermoanalytisch untersucht. Die früher beschriebene Verbindung Na2Ge4O9 (I) erweist sich als identisch mit dem vonJ. F. White und Mitarbeitern angegebenen Na4Ge9O20. Von der dargestellten isotypen Kalium-Verbindung werden die Gitterkonstanten ermittelt. Im analogen Rubidium-System läßt sich ein isotypes Enneagermanat bisher nicht nachweisen. Einkristallaufnahmen von Natriumtetragermanat [Na2Ge4O9 (II)] ergeben eine hexagonale Elementarzelle mit 6 Formeleinheiten Na2Ge4O9. Ebenso werden von den isotypen Kalium-und Rubidiumtetragermanaten die Gitterparameter bestimmt. Im Natrium-System stellt offensichtlich das Enneagermanat die stabile Phase dar, während das Tetragermanat nur durch rasches Abkühlen aus der Schmelze erhalten wird. Bei den Kaliumgermanaten ist dagegen das Tetragermanat die stabile Phase.Mit 2 Abbildungen 相似文献
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Lomonova E. E. Agarkov D. A. Borik M. A. Eliseeva G. M. Kulebyakin A. V. Kuritsyna I. E. Milovich F. O. Myzina V. A. Osiko V. V. Chislov A. S. Tabachkova N. Yu. 《Russian Journal of Electrochemistry》2020,56(2):118-123
Russian Journal of Electrochemistry - The effects of the Y2O3 and Yb2O3 co-doping impurities on the transport characteristics and stabilization of the cubic phase in solid solutions based on... 相似文献