Effects of oxygen partial pressure on optical absorption edge and UV emission energy of ZnO films

ZnO, with a band-gap of 3.37 eV and a large exciton binding energy (about 60 meV) at room temperature, is a promising material for optoelectronic devices, field- emission displays, and gas sensors. Recently, the interest in short wavelength display device is on the increase. In this regard, ZnO is a promising material[1-6]. High quality ZnO films have been prepared by many methods such as sputtering[7], reactive thermal and electron-beam evaporation[8], pulse laser deposition[9], chemical v…     

Effect of substituent on UV–visible absorption and photostability of liquid crystals: DFT study

The electronic transitions in the ultraviolet–visible (UV–Vis) range of two nematogens, namely 4′-cyanophenyl-4-n-pentylbenzoate and 4′-cyanophenyl-4-n-pentoxybenzoate, have been studied. The UV–Vis and circular dichroism spectra of these molecules have been simulated using the TDDFT/B3LYP/6-31+G(d) method. Mulliken atomic charges for each molecule have been compared with Loewdin atomic charges to analyze the molecular charge distribution and phase stability. The highest occupied molecular orbital and lowest unoccupied molecular orbital energies corresponding to the electronic transitions in the UV–Vis range have been reported. The excited states have been calculated via configuration interaction singles with semi-empirical Hamiltonian ZINDO (Zerner's intermediate neglect of differential overlap method). Further, the effect of substituent on ultraviolet absorption and photostability of the molecules has been discussed. The photostability of the molecules has been investigated in order to understand the application and operation with ultraviolet and visible light regions.     

UV–visible,infrared absorption spectra of undoped and TiO2-doped lead phosphate glasses and the effect of gamma irradiation

Undoped and TiO₂-doped lead phosphate glasses were prepared. Ultraviolet (UV)–visible and Fourier transform-infrared (IR) absorption spectra of the prepared samples were measured before and after being subjected to doses of 30 and 60 kGy of gamma irradiation. The parent undoped lead phosphate glass reveals charge transfer UV absorption bands which are attributed to the presence of unavoidable iron impurities contaminated within the raw materials used for the preparation of the glasses and the sharing of divalent lead (Pb²⁺) ions. Experimental spectral data indicate that the doped titanium ions are involved in such glasses in two valences, namely the trivalent and tetravalent states. The predominant trivalent titanium (Ti³⁺) ions are characterized by its purple color and exhibiting two visible absorption bands at about 500–550 and 700–720 nm. The lesser tetravalent titanium (Ti⁴⁺) ions belong to the d⁰ configuration and generally exhibit only an UV absorption band. Spectral data show that gamma irradiation causes noticeable changes in the undoped and TiO₂-doped samples in the UV range while the effects are limited in the visible range. The observed changes in the UV region are attributed to photochemical reactions while TiO₂-doped samples show retardation or shielding toward continuous gamma irradiation together with the sharing of heavy Pb²⁺ ions. IR absorption spectra reveal the vibrations of several phosphate groups including the metaphosphate chains as the main structural building units together with the possible Pb?O vibrations.     

Synthesis,vibrational and UV–visible studies of sodium cadmium orthophosphate

In this paper, NaCdPO₄ orthophosphate was prepared by solid-state reaction technique at high temperature. Structural, vibrational and optical properties have been investigated. X-ray powder diffraction analysis revealed that the titled compound crystallizes in the orthorhombic system with Pmnb space group. Vibrational study by means of Raman and FTIR spectroscopies confirms the existence of the (PO₄)^3? functional group. Optical properties were recorded at room temperature using UV–visible spectroscopy in the spectral range (200–800) nm. The UV–Vis absorption bands are attributed to the charge transfer from the oxygen ligands to the central phosphate atom inside the PO₄ ^3? groups. The optical absorbance was measured also to determinate the optical band gap using Kubelka–Munk function. The dispersion parameters (E₀ and E_d) of this compound were estimated using the Wemple Di-Domenico model.     

Growth and microstructure for visible emission and surface optical phonon mode of Zn–ZnO nanostructure

The Zn–ZnO nanostructured thin films were prepared in carbon matrix using a cost-effective vacuum-carbon arc method. On increasing graphitization with ZnO, the grazing incidence X-ray diffraction pattern showed that the intensity of the ZnO peak increases, whereas that of the Zn peak decreases. X-ray line profile analysis and transmission electron microscopy were employed to investigate the microstructural evolution of Zn–ZnO nanostructure during vacuum arc processing. A growth mechanism is proposed for the Zn–ZnO nanostructure when reaction with carbon-containing gas inside the reactor wall takes place. Detailed studies of photoluminescence bands clearly exhibit the intensity variation of violet and blue-green bands on increasing graphitization ratio. Using the dielectric continuum approach, surface optical phonon modes of the Zn–ZnO nanostructure were studied for different synthesized samples.     

Anomalous infrared and visible light absorption and local structure of Ag–Au core/shell nanoparticles

We measured infrared and visible light absorption spectra and EXAFS for Ag–Au core/shell particles. The shell thickness and core diameter can be evaluated from the EXAFS results, which are almost consistent with those obtained using TEM. The influence of a thinner shell only slightly appeared in the visible absorption spectra, whereas the influence appeared strongly in the infrared absorption spectra. The spectra of the material in the vicinity of the particle surface appear in the infrared spectra. On the other hand, the spectra of the rather more internal material are observed in the visible spectra. It is thought that the influence of the core metal is different in the visible spectra from the infrared spectra. By considering the penetration depth, this phenomenon can be explained.     

Microstructure and optical absorption of Au-MgF2 nanoparticle cermet films

The microstructure and optical absorption of Au-MgF2 nanoparticle cermet films with different Au contents are studied. The microstructural analysis shows that the films are mainly composed of the amorphous MgF2 matrix with embedded fcc Au nanoparticles with a mean size of 9.8-21.4nm. Spectral analysis suggests that the surface plasma resonance （SPR） absorption peak of Au particles appears at λ=492-537nm. With increasing Au content, absorption peak intensity increases, profile narrows and location redshifts. Theoretical absorption spectra are calculated based on Maxwell-Garnett theory and compared with experimental spectra.     

Numerical analysis of absorption–amplification response in an optical fiber

We investigated the transient and steady-state processes of a probe field in an optical fiber. It is found that the nonlinear processes can be easily controlled via the coherent field and incoherent pumping field. The underlying mechanisms are much more practical than those in atomic systems, which may provide some possibilities for technological applications in optical-fiber communication.     

The absorption spectrum of diatomic calcium between 120 and 20 nm

The vacuum ultraviolet absorption spectrum of Ca₂ has been extended down to 20?nm by using the same techniques as those described by Nzohabonayo et al. [2003, Molec. Phys., 101, 2917]. All the new states observed are Rydberg states giving three new ionization limits at 13.76?eV, 17.99?eV and a third one higher than 33?eV.     

PAMELA spectrum of electrons and positrons of cosmic rays in the energy range of 0.05–1.2 TeV

A proprietary method is used to process measurement data from a high-energy particle (protons, electrons, and positrons with Е ≥ 50 GeV) spectrometer in a near-Earth orbit. The data from three detector systems are used: a tracker in a constant magnetic field (TRK), a calorimeter (CAL), and a neutron detector (ND). A relatively simple and efficient way of isolating electrons and positrons from the total charged particle flux entering the PAMELA spectrometer is proposed. A technique for determining the energy of isolated primary particles and retrieving their energy spectra is described. The composite electron and positron spectrum (below, the total electron and positron flux is referred to simply as the electron flux) for energies up to 1.5 TeV is presented.     

On the determination of energy fluxes at plasma–surface processes

A summary is given of different methods for the determination of the energy influx and its influence on the thermal balance and energetic conditions of substrate surfaces during plasma processing. The discussed mechanisms include heat radiation and kinetic and potential energy of charged particles and sputtered neutrals. For a few examples such as magnetron sputtering of a-C:H films, sputter deposition of aluminum on microparticles, and titanium deposition in a hollow-cathode arc evaporation device the energetic balance of substrates during plasma processing is presented. Received: 6 July 2000 / Accepted: 12 December 2000 / Published online: 3 April 2001     

Furi–Martelli–Vignoli spectrum and Feng spectrum of nonlinear block operator matrices

We investigate the Furi-Martelli-Vignoli spectrum and the Feng spectrum of continuous nonlinear block operator matrices,and mainly describe the relationship between the Furi-Martelli-Vignoli spectrum(compared to the Feng spectrum)of the whole operator matrix and that of its entries.In addition,the connection between the Furi-Martelli-Vignoli spectrum of the whole operator matrix and that of its Schur complement is presented by means of Schur decomposition.     

Fundamental absorption of calcium,magnesium, and lithium fluorides in the range of 8–12 μm

The fundamental absorption of calcium, magnesium, and lithium fluorides in the range of 8–12 μm has been studied experimentally by the spectrophotometric method. The known and experimentally obtained values of the absorption coefficients of these materials have been analyzed. It has been shown that the values experimentally measured in the range of 8–12 μm obey the Uhrbach rule and the multiphoton absorption determines the long-wavelength transmission cutoff of pure optical materials. The results presented make it possible to suggest that plates made of LiF and CaF₂ crystals and of optical ceramics based on MgF₂ can be used to fabricate calibrated radiation attenuators in the spectral range of 8–12 μm.     

Models of optical absorption in amorphous semiconductors at the absorption edge — A review and re-evaluation

Davis-Mott and Tauc models of optical absorption at the absorption edge in the high absorption coefficient region (10⁴cm^–1) are carefully reviewed with regard to their theoretical foundations, assumptions, mathematical derivations, and results. The full implications of these models are exploited, and it is found that the Davis-Mott model for negligible matrix elements between localised states could account for the cubic power law behaviour of with photon energy of some amorphous semiconductors such as a-Si. A fractional power law to find the optical band gapE _opt, of the form [ (–E _opt)^r; 2r3] based on Davis-Mott model is proposed in which the indexr can be a function of disorder. The Tauc model has further been extended to the case of negligible matrix elements between localised states, in which the same square power law for vs. with the same meaning of the optical gap as in the original Tauc model has resulted. A consideration of the case of unequal matrix elements for those transitions between localised states and those between extended states is also included. The meaning ofE _opt has been re-assessed and it is emphasized that it is an extrapolation of delocalised states to the zero of the density of states rather than a threshold energy for the onset of some kind of optical transitions.This paper is cordially dedicated to Professor C. A. Hogarth who taught us the Physics of amorphous materials.     

Impurity-modulated Aharonov–Bohm oscillations and intraband optical absorption in quantum dot–ring nanostructures

In this work we study the electronic states in quantum dot–ring complex nanostructures with an on-center hydrogenic impurity. The influence of the impurity on Aharonov–Bohm energy spectra oscillations and intraband optical absorption is investigated. It is shown that in the presence of a hydrogenic donor impurity the Aharonov–Bohm oscillations in quantum dot–ring structures become highly tunable. Furthermore, the presence of the impurity drastically changes the intraband absorption spectra due to the strong controllability of the electron localization type.     

Floquet spectrum and optical behaviors in dynamic Su–Schrieffer–Heeger modeled waveguide array

Floquet topological insulators(FTIs) have been used to study the topological features of a dynamic quantum system within the band structure. However, it is difficult to directly observe the dynamic modulation of band structures in FTIs. Here, we implement the dynamic Su–Schrieffer–Heeger model in periodically curved waveguides to explore new behaviors in FTIs using light field evolutions. Changing the driving frequency produces near-field evolutions of light in the high-frequency curved waveguide array that are equivalent to the behaviors in straight arrays. Furthermore, at modest driving frequencies,the field evolutions in the system show boundary propagation, which are related to topological edge modes. Finally, we believe curved waveguides enable profound possibilities for the further development of Floquet engineering in periodically driven systems, which ranges from condensed matter physics to photonics.