Infrared transitions of C2D6 from v 4 to the interacting system v 4+ v 6, v 4+ v8, v 3+ 2v 4: rotational analysis,and torsional splitting in the v 3+ 2v 4 and v 3+ v 4 states

The hot infrared transitions of C₂D₆ from the υ₄(A_1u ) to the υ₄ + υ₆(A_2g ) and υ₄ + υ₈(E _g ) vibrational states, observed from 960 to 1180 cm^?1, have been rotationally analysed on a high-resolution Fourier transform spectrum (full width at half-maximum about 0·0030 cm^?1). The vibration-rotation interactions affecting the upper vibrational states are very similar to those of the corresponding cold system. A strong x,y Coriolis interaction between υ₄ + υ₆ and υ₄ + υ₈, with K-level crossing, generates large displacements of the rotational components of both vibrational states, tuning them to additional local resonances in several spectral regions. Thus l resonances with Δl = ±2, Δk = ±1 occur within υ₄ + υ₈. A x,y Coriolis-type resonance between υ₄ + υ₈(?l,K ? 1) and υ₃ + 2υ₄(K) occurs at K = 11,12,13, and a further coupling of υ₄ + υ₈(+l,K + 1) and υ₃ + 2υ₄(K + 3) is most effective at K = 11 and 12. These resonances induce torsional splittings on the perturbed levels of υ₄ + υ₈ and allow us to determine the torsional splittings in the υ₃ + 2υ₄ state. The vibration-rotation constants of υ₄ + υ₆, υ₄ + υ₈ and υ₃ + 2υ₄, several interaction parameters and the torsional splitting of υ₃ + 2υ₄ have been determined by least-squares fit of 1391 observed transition wavenumbers, with an overall standard deviation σ = 0·75 × 10^?3 cm^?1. The vibrational wavenumbers found for the four torsional components of (υ₃ + 2υ₄)? υ₄ are υ(E_3d) = 1040·961 82(809)cm^?1, υ(A_3d) = 1041·218 27(865)cm^?1, υ(E_3s) = 1041·225 23(662)cm^?1 and υ(A_1s) = 1041·407 77(633)cm^?1. These are anomalous for both the order of the torsional components and the magnitudes of their separations. We believe that this is mainly due to the interactions of υ₃ + 2υ₄ with the torsional manifolds with υ₃ = 0 and υ₃ = 2, through the vibration-torsion Hamiltonian term (?V ₆/?q ₃)q ₃cos (6γ)]/2. The further observation of a few doublets of υ₈ and υ₃ + υ₄ at resonance provides information on the torsional splitting of the latter state.     

High-resolution FTIR spectroscopy of the v11 and v2 + v7 bands of ethylene-d4

The Fourier transform infrared spectrum of the v₁₁ band of ethylene-d₄ (C₂D₄) has been recorded with an unapodized resolution of 0.006 cm^?1 in the frequency range 2150 to 2250cm^?1. The v₁₁ band, with a band centre of about 2201 cm^?1, was found to be perturbed by the nearby v₂ + v₇ band centred at about 2235 cm^?1 by a b-type Coriolis interaction. By fitting a total of 772 infrared transitions of v₁₁ using a Watson's A-reduced Hamiltonian in the I^r representation with the inclusion of b-type Coriolis interaction term, two sets of constants, up to quartic distortion constants for the v₁₁ = 1 state, and principal rotational constants for the v₂ + v₇ = 1 dark state, were derived. The inertia defect of the v₁₁ state was found to be 0.0693 ± 0.0004u Ų.     

Vibration-rotation analysis of the jet-cooled v12, v7 + v8 and v6 + v10 absorption bands of 12C2H4

A Fourier transform interferometer was used to record the slit-jet cooled absorption spectrum of ¹²C₂H₄ between 700 and 2400 cm^?1I, at a spectral resolution of 0.005 cm^?1. Three bands, v₁₂ at 1442.442 70(1)cm^?1, v₇ + v₈ at 1888.978 23(3)cm^?1 and v₆ + v₁₀ at 2047.775832(2)cm^?1, were rotationally analysed. In the case of 7¹8¹, a known Coriolis perturbation mechanism involving the nearby 4¹8¹ (1958.264cm^?1) and 8¹10¹ (1766.391 cm^?1) states was accounted for in the analysis. The latter fitting procedure included 12 levels from the 4¹8¹ state which are observed because lines from v₄ + v₈ borrow intensity from v₇ + v₈. Compared to the literature, significantly improved vibration-rotation constants were obtained for all upper states reported in the present study.     

Experimental Ro-Vibrational Line Intensities for the v1 + v2 and v2 + v3 Bands of the D234S Molecule

Russian Physics Journal - The study of the absolute line intensities in the high-resolution spectrum of the D234S molecule in the range of 2300–2900 cm–1 has been carried out for the...     

l-Resonance effects in the hot bands 3v 5 ← 2v 5, (v 4 + 2v 5) ← (v 4 + v 5) and (2v 4 + v 5) ← 2v 4 of acetylene

In the infrared spectrum of C₂H₂ around the fundamental v ₅, the hot bands starting from the levels 2v ₅, 2v ₄ and v ₄ + v ₅ have been investigated. From the analysis of about 20 different bands, 40 molecular constants describing the bending modes v ₄ and v ₅ have been derived.     

Anharmonic resonances between the v 1 + v ±1 6, v 3 + v ±1 5 + 2v 0 6 and v 3 + v ∓1 5 + 2v ±2 6 vibrational bands of CH3 79Br

The 22 K sub-bands, belonging to the v ₁ + v ^±1 ₆, v ₃ + v ^± ₅ + 2v ⁰ ₆ and v ₃ + v ^±1 ₅ + 2v ^±2 ₆ rovibrational bands of monoisotopic CH₃ ⁷⁹Br, have been identified. An RMS standard deviation of about 0·020 cm^-1 has been achieved by a least squares fit over 619 lines belonging to these 22 sub-bands. For this purpose, a model taking into account (a) anharmonic resonances between (i) v ₁ + v ^±1 ₆, and v ₃ + v ^±1 ₅ + 2v ⁰ ₆, (ii) v ₁ + v ^±1 ₆ and v ₃ + v ^?1 ₅ + 2v ^±2 ₆ and (iii) v ₃ + v ^±1 ₅ + 2v ⁰ ₆ and v ₂ + 2v ₃ + v ^±1 ₅ and (b) Coriolis resonances between the v ₂ and v ₅ modes, was used.     

The v 1 and v 3 bands of ND3

High resolution (0.004cm^-1 instrumental bandwidth) interferometric Fourier transform infrared spectra of ¹⁴ND₃ were obtained on a BOMEM DA002 spectrometer under essentially Doppler limited conditions. An analysis is reported of the ND₃ stretching fundamentals with band centres at [EQUATION]₁ ⁰ (s ← a) = (2420.056 ± 0.001)cm^?1, [EQUATION]₁ ⁰(a ← s) = (2420.650 ± 0.001)cm^?1, [EQUATION]₃ ⁰(a ← a) = (2563.8840 ± 0:0005)cm^?1 and [EQUATION]₃ ⁰ (s ← s) = (2563.9161 ± 0.0005)cm^?1, with inversion tunnelling splittings Δ[EQUATION]₁ = 0.5412cm^?1 and Δ[EQUATION]₃ = 0.0209cm^?1 in the vibrationally excited levels. About 50 parameters of the effective Hamiltonian for this band system could be determined accurately. Assignments were established with certainty by means of ground state combination differences. The results are important for and are discussed in relation to the mode selective inhibition and promotion of inversion at the nitrogen atom by exciting ND stretching vibrations, and treatments of isotope e? ects on inversion of ammonia by means of effective Hamiltonians and true molecular Hamiltonians on high dimensional potential hypersurfaces.     

The 2v 2, v 1 and v 3 bands of H2 16O

The 2v ₂, v ₁ and v ₃ bands of H₂ ¹⁶O occurring in the region 2930–4255 cm^-1 were studied from a spectrum recorded with a high resolution Fourier transform spectrometer (resolution: 0·005 cm^-1). The set of the observed transitions leads by a least squares method to the determination of very accurate values of the rotational levels belonging to the vibrational states (000), (020), (100), (001). From these levels, using Watson's Hamiltonian, we have obtained respectively 21 and 17 rotational constants for the states (000) and (020).     

O2 broadening of carbon disulphide 12C32S2 in the v 3 and v 3—v 1 bands

Using a tunable diode laser spectrometer, we have measured O₂ broadening coefficients of ¹²C³²S₂ for 31 lines in the v ₃ fundamental band near 6.5 μm and 12 lines in the v ₃—v ₁ band near 11.4 μm. The collisional halfwidths are obtained by fitting the spectral lines with a Voigt and a Rautian profile. The broadening coefficients of ¹²C³²S₂-O₂ are also calculated from semiclassical theory involving, in addition to electrostatic interactions, successively the atom-atom Lennard-Jones model and a simple formulation for the anisotropic dispersion forces, leading to more satisfactory results.     

Measurement of the Σ−→ne −¯v and Σ−→ nμ−¯v rates

The recoilless nuclear resonance absorption of the 90 keVγ-rays of⁹⁹Ru was observed in a variety of chemical compounds of ruthenium in the oxidation states +2 through +8 at 4.2 ° K. For most of the compounds isomer shifts increasing monotonically with the oxidation state of ruthenium were found. This behaviour, which may essentially be attributed to the decreasing number of 4d electrons, and the few exceptions from it are discussed qualitatively on the basis of the molecular orbital theory.     

The rovibrational Raman spectrum of water vapour v 1 and v 3

The OH stretching region in the Raman spectrum of water vapour has been observed and reproduced by computer simulation using rovibrational wave functions derived from the analysis of high-resolution absorption spectra. Relative intensity measurements allow the determination of the depolarization ratio and the ratio of the two non-vanishing second-order irreducible tensor components for v ₁. These quantities have been combined with the literature value for the cross section of this band to calculate the principal cartesian components of the v ₁ derived polarizability tensor. The cross section for the v ₃ vibration was also determined, and these results are considered in terms of the bond polarizability theory.     

The rotational spectrum and molecular parameters of ClO in the v=0 and v=1 states

The $\text{J =}\text{9}\text{2}\text{←}\text{7}\text{2}$, ${}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ and ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, ground vibrational state transitions of ³⁵ClO and ³⁷ClO and the ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, excited vibrational state transitions of ³⁵ClO have been observed in the 164–167 GHz region. Additional measurements have also been made on the $\text{J =}\text{3}\text{2}\text{←}\text{1}\text{2}$ and $\text{J =}\text{5}\text{2}\text{←}\text{3}\text{2}$ transitions of both the ground and excited vibrational states. All measurements were made using millimeter oscillators which were phase locked to harmonics of a Hewlett-Packard microwave spectrometer's X-band source. Λ-doubling splitting of a few ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ transitions was resolved.When magnetic and nuclear quadrupole hyperfine terms off-diagonal in J and $\text{Ω}$ in the Hund's case (a) representation were included in addition to the usual diagonal terms, an excellent fit to all of our observed transitions resulted. The most significant change from previously determined parameters is the centrifugal distortion constant D for which the values, D₀ = 0.03972(26) MHz for ³⁵ClO, D₀ = 0.03888(32) MHz for ³⁷ClO and D₁ = 0.0395(21) MHz for ³⁵ClO are obtained. Values of 1.56959(1) Å for the equilibrium bond length and 854(7) cm^?1 for the equilibrium vibrational frequency are derived from the measured spectra. In addition, values for the Λ-doubling constant β_p and the quadrupole coupling constant eQq₂ were derived from the measured spectra for the first time.     

Collision-induced Raman scattering in CO2 at the frequency of the v 2 and v 3 inactive vibrations

Experimental results on intensities and band shapes of collision-induced Raman scattering at the v ₂ and v ₃ vibrational transitions in gaseous and liquid CO₂ are reported and discussed. The CO₂ results are compared with new data for v ₃ in SF₆.     

用各向异性流v2和v4测试超相对论性重离子碰撞的动力学描述

We present various predictions for the anisotropic collective flow of particles in heavy-ion collisions, in particular scaling laws of the second and fourthharmonics v₂ and v₄, derived within ideal fluid dynamics. We also discuss qualitatively the deviation from the ideal behaviour expected in an out-of-equilibrium scenario.     

High-resolution FTIR spectrum of vinyl chloride: rovibrational analysis of the v 10 and v 11 fundamental bands

The Fourier transform gas-phase infrared spectra of the v ₁₀ and v ₁₁ bands of natural CH₂=CHCl have been measured with a resolution of 0.005 cm^?1 in the frequency range 820–1010 cm^?1. These vibrations of symmetry species A″ give rise to c-type bands and the transitions observed are characterized by δK _a = ±1 and δK _c = 0, ±2. Both J and K structures have been resolved in different subbranches and about 1800 (J ≤ 64, K _a ≤ 13) and 2800 (J ≤ 72, K _a ≤ 14) transitions for the v ₁₀ and v ₁₁ fundamentals, respectively, have been identified for the ³⁵Cl isotopomer. Combined analysis of the assigned data with the available ground state constants allowed the determination of the band origins, rotational and centrifugal distortion parameters for the v ₁₀ = 1 and v ₁₁ = 1 excited states of CH₂=CH³⁵Cl isotopic species. The molecular constants obtained account for slight perturbations in the v ₁₀ vibrational level.     

High resolution FTIR spectroscopy of CH2DF: analysis of the v 3 and v 4 interacting bands

The high resolution (0.004cm^?1) Fourier transform infrared spectrum of the monodeuterated form of methyl fluoride, CH₂DF, has been recorded and analysed in the v ₃ and v ₄ band region around 1420cm^?1. Both bands, coming from A′ symmetry vibrations, have a/b hybrid character, although in v ₃ the b-type component prevails over the a-type. The rotational structure has been analysed using a dyad model including c-type Coriolis coupling and high order vibrational resonance between these states. Accurate upper state molecular parameters and interaction terms have been obtained by fitting about 3270 assigned transitions to Watson's A-reduced Hamiltonian in the I^r representation. In addition, from a simultaneous fit of ground state combination differences coming from this analysis and 42 literature microwave transitions, an improved and more complete set of ground state constants, including three new sextic centrifugal distortion terms (Φ_JK, Φ_KJ and Φ_K), has been derived.     

The v 3 and 2v 3 I.R. bandshapes and dipole correlation functions of compressed gaseous N2O; intensity measurements of the 2v 3 band

The I.R. spectrum of the ν₃ band (4·5 µm) of N₂O has been studied for temperatures varying from 219 to 298 K and densities up to 85 kg m^-3. The 2v ₃ band (2·3 µm) has been analysed at room temperature for densities up to 182 kg m^-3; measurements of the integrated intensities as a function of density show no evidence of pressure induced absorption. This band has also been observed in the vicinity of the critical region.

The dipole moment autocorrelation function is used to assess a collisional model derived from the impact approximation and the Gordon M- and J-diffusion models developed classically as well as the semi-classical M-diffusion model. The M- and J-diffusion models reproduce well the experimental correlation function for the ₃ band; the semi-classical M-diffusion model is better than the classical ones for the overtone 2v ₃ and gives a satisfactory account of the correlation functions. For the collisional model considered which implies uncorrelated rotational levels, a discrepancy between theoretical and experimental correlation functions and bandshapes becomes noticeable from about 40 kg m^-3 and increases with density.     

High-Resolution Fourier Transform Spectra of HDSe: The Interacting States (v(1) v(2) v(3))/(v(1) +/- 1 v(2) -/+ 2 v(3)) with 2v(1) + v(2) = 1, 2, 3, and 4

For the first time, high-resolution Fourier transform spectra of HDSe in the region of the three polyads, nu(1)/2nu(2), nu(1) + nu(2)/3nu(2), and 2nu(1)/nu(1) + 2nu(2)/nu(2) + nu(3), have been recorded and analyzed. Combined with an earlier investigation of the nu(2) band, and including estimates for the unobserved "dark" 4nu(2) band, these levels were subjected to a "Global Fit," which makes use of relations between parameters within the different polyads. Since there are five isotopic species present in natural HD(M)Se (M = 82, 80, 78, 77, 76), altogether 34 vibration-rotation bands have been studied in the present contribution. The parameters determined by the Global Fit reproduce upper vibrational-rotational energies of all these bands with accuracies close to experimental precision. Copyright 2000 Academic Press.     

Bounds on the magnetic moment of the τ-neutrino via the process e+e-→v(v)γ

Using Breit-Wigner resonance relation,bounds on the magnetic moment of the tau-neutrino are calculated through the reaction e+e-→v(v)γ at the neutral boson pole in the framework of a superstringinspired E6 model which has one extra low-energy neutral gauge boson and a LRSM.