Localized self-trapping in the two-dimensional discrete molecular lattice with the interaction between Frenkel excitons and phonons

We investigate the interactions of lattice phonons with Frenkel exciton, which has a small radius in a two-dimensional discrete molecular lattice, by the virtue of the quasi-discreteness approximation and the method of multiple-scale, and obtain that the self-trapping can also appear in the two-dimensional discrete molecular lattice with harmonic and nonlinear potential. The excitons' effect on the molecular lattice does not distort it but only causes it to localize which enables it to react again through phonon coupling to trap the energy and prevent its dispersion.     

Quality factor enhancement of plasmonic surface lattice resonance by using asymmetric periods

We report that using asymmetric lattice periods can enhance the quality factor of plasmonic surface lattice resonances(SLRs)in two-dimensional array of metal-insulator-metal nanopillars in asymmetric dielectric environment.Simulation results show that by adopting appropriate asymmetric lattice periods,the SLR quality factor can be enhanced by 24%compared with the scenario of symmetric periods.We find that the SLR quality factor is optimized when the resonance wavelength is closest to the Rayleigh cutoff wavelength.We also find that the SLRs effect is polarization sensitive in the proposed structure.We expect this work will advance the engineering of SLRs especially in asymmetric dielectric environments,and will promote their applications in sensing.     

An improvement of the lattice theory of dislocation for a two-dimensional triangular crystal

The structure of dislocation in a two-dimensional triangular crystal has been studied theoretically on the basis of atomic interaction and lattice statics. The theory presented in this paper is an improvement to that published previously.Within a reasonable interaction approximation, a new dislocation equation is obtained, which remedies a fault existing in the lattice theory of dislocation. A better simplification of non-diagonal terms of the kernel is given. The solution of the new dislocation equation asymptotically becomes the same as that obtained in the elastic theory, and agrees with experimental data. It is found that the solution is formally identical with that proposed phenomenologically by Foreman et al, where the parameter can be chosen freely, but cannot uniquely determined from theory. Indeed, if the parameter in the expression of the solution is selected suitably, the expression can be well applied to describe the fine structure of the dislocation.     

Bose–Einstein condensates in an eightfold symmetric optical lattice

We investigate the properties of Bose–Einstein condensates(BECs) in a two-dimensional quasi-periodic optical lattice(OL) with eightfold rotational symmetry by numerically solving the Gross–Pitaevskii equation. In a stationary external harmonic trapping potential, we first analyze the evolution of matter-wave interference pattern from periodic to quasiperiodic as the OL is changed continuously from four-fold periodic to eight-fold quasi-periodic. We also investigate the transport properties during this evolution for different interatomic interaction and lattice depth, and find that the BEC crosses over from ballistic diffusion to localization. Finally, we focus on the case of eightfold symmetric lattice and consider a global rotation imposed by the external trapping potential. The BEC shows vortex pattern with eightfold symmetry for slow rotation, becomes unstable for intermediate rotation, and exhibits annular solitons with approximate axial symmetry for fast rotation. These results can be readily demonstrated in experiments using the same configuration as in Phys. Rev.Lett. 122 110404(2019).     

Exciton—Phonon Scattering in CdSe／ZnSe Quantum Dots

A temperature-dependent photoluminescence measurement is performed in CdSe/ZnSe quantum dots with a ZnCdSe quantum well.We deduce the temperature dependence of the exciton linewidth and peak energy of the zero-dimensional exciton in the quantum dots and two-dimensional exciton in the CdSe wetting layer.The experimental data reveal a reduction of homogeneous broadening of the exciton line in the quantum dots in comparison with that in the two-dimensional wetting layer,which indicates the decrease of exciton and optical phonon coupling in the CdSe quantum dots.     

Friction phenomena in a two-dimensional Frenkel-Kontorova model

By using the molecular dynamic simulation method with a fourth-order Runge--Kutta algorithm, a two-dimensional dc- and ac-driven Frenkel--Kontorova (FK) model with a square symmetry substrate potential for a square lattice layer has been investigated in this paper. For this system, the effects of many different parameters on the average velocity and the static friction force have been studied. It is found that not only the amplitude and frequency of ac-driven force, but also the direction of the external driving force and the misfit angle between two layers have some strong influences on the static friction force. It can be concluded that the superlubricity phenomenon appears easily with a larger ac amplitude and lower ac frequency for some special direction of the external force and misfit angle.     

Fabrication of Two-Dimensional Photonic Crystals with Triangular Rods by Single-Exposure Holographic Lithography

We demonstrate a single-exposure holographic fabrication of two-dimensional photonic crystal with round- cornered triangular ＇atoms＇ arranged in a triangular lattice. Simulation results show that double absolute photonic band gaps exist in this structure. Our experimental results show that holographic lithography can be used to fabricate photonic crystals not only with various lattice structures but also with various kinds of structures of the atoms, to obtain absolute band gaps or a particular band gap structure. Furthermore, the single-exposure holographic method not only makes the fabrication process simple and convenient but also makes the structures of the atoms more perfect.     

Lower Exciton Number Strong Light Matter Interaction in Plasmonic Tweezers

The plasmonic nanocavity is an excellent platform for the study of light matter interaction within a sub-diffraction volume under ambient conditions.We design a structure of plasmonic tweezers,which can trap molecular Jaggregates and also serve as a plasmonic cavity with which to investigate strong light matter interaction.The optical response of the cavity is calculated via finite-difference time-domain methods,and the optical force is evaluated based on the Maxwell stress tensor method.With the help of the coupled oscillator model and virtual exciton theory,we investigate the strong coupling progress at the lower level of excitons,finding that a Rabi splitting of 230 meV can be obtained in a single exciton system.We further analyze the relationship between optical force and model volume in the coupling system.The proposed method offers a way to locate molecular J-aggregates in plasmonic tweezers for investigating optical force performance and strong light matter interaction.     

Global phase diagram of a spin–orbit-coupled Kondo lattice model on the honeycomb lattice

Motivated by the growing interest in the novel quantum phases in materials with strong electron correlations and spin–orbit coupling, we study the interplay among the spin–orbit coupling, Kondo interaction, and magnetic frustration of a Kondo lattice model on a two-dimensional honeycomb lattice.We calculate the renormalized electronic structure and correlation functions at the saddle point based on a fermionic representation of the spin operators.We find a global phase diagram of the model at half-filling, which contains a variety of phases due to the competing interactions.In addition to a Kondo insulator, there is a topological insulator with valence bond solid correlations in the spin sector, and two antiferromagnetic phases.Due to the competition between the spin–orbit coupling and Kondo interaction, the direction of the magnetic moments in the antiferromagnetic phases can be either within or perpendicular to the lattice plane.The latter antiferromagnetic state is topologically nontrivial for moderate and strong spin–orbit couplings.     

Discrete gap breathers in a two-dimensional diatomic face-centered square lattice

In this paper we study the existence and stability of two-dimensional discrete gap breathers in a two-dimensional diatomic face-centered square lattice consisting of alternating light and heavy atoms, with on-site potential and coupling potential. This study is focused on two-dimensional breathers with their frequency in the gap that separates the acoustic and optical bands of the phonon spectrum. We demonstrate the possibility of the existence of two-dimensional gap breathers by using a numerical method. Six types of two-dimensional gap breathers are obtained, i.e., symmetric, mirror-symmetric and asymmetric, whether the center of the breather is on a light or a heavy atom. The difference between one-dimensional discrete gap breathers and two-dimensional discrete gap breathers is also discussed. We use Aubry's theory to analyze the stability of discrete gap breathers in the two-dimensional diatomic face-centered square lattice.     

Exciton condensation driving the periodic lattice distortion of 1T-TiSe2

We address the lattice deformation of 1T-TiSe2 within the exciton condensate phase. We show that, at low temperature, condensed excitons influence the lattice through electron-phonon interaction. It is found that at zero temperature, in the exciton condensate phase of 1T-TiSe2, this exciton condensate exerts a force on the lattice generating ionic displacements comparable in amplitude to what is measured in experiment. This is thus the first quantitative estimation of the amplitude of the periodic lattice distortion observed in 1T-TiSe2 as a consequence of the exciton condensate phase.     

Self-trapping dynamics of excitons on a one-dimensional lattice

Lattice relaxation dynamics of one-dimensional excitons coupled with an optical lattice vibration mode is studied using molecular dynamics techniques. By investigating the time-evolution of the wave-function and other physical properties, it is found that not only the wavefunction of the relaxed state, a self-trapped exciton (STE), but also the relaxation dynamics changes by varying the strength of the electron-phonon interaction. Hence we can classify STEs into “large” STEs and “small” STEs by means of the difference in physical properties. Such difference is more enhanced for excitons than for polarons, since both the translational motion and the relative motion of the electron and hole is affected in excitons. Dispersion in the phonon frequency also plays an important role in this classification. Optical properties, the Stokes shift and the peak shift of photoinduced absorption, are also calculated.     

The effect of lattice vibrations on trap-limited exciton lifetimes

The problem of exciton migration and trapping on a linear polymer is treated as a random walk on a one-dimensional lattice. The average number of steps required for a walker to be trapped is calculated when the probability of stepping to adjacent lattice sites is not symmetrical, and is found to be less than that calculated for a symmetrical walk. An asymmetrical stepping probability is shown to result from the thermal vibrations of the lattice. The magnitude of this effect on the exciton lifetime is estimated and found to be significant.This work was partially supported by the US Office of Naval Research, and by the US Air Force Office of Scientific Research (Grant #611-67).     

Wave radiation in lattice fracture

The square and triangular lattices are considered, where the uniform crack growth is accompanied by the wave radiation. The radiation energy and structure are studied. The energy radiated to the bulk of the lattice is found in a direct way. The radiation structure is described based on the crack problem solution and by means of the analysis of two-dimensional dispersion relations for the intact lattice. The mode III problem for square lattice is discussed in detail, whereas, in the case of the plane problem for the triangular lattice, the only those results are derived which follow from the two-dimensional dispersion relations. It is shown that there exists a finite crack-speed-dependent region of wavenumbers corresponding to the waves radiated to the bulk of the lattice. In the case of the triangular-cell lattice, in addition, one or several lattice Rayleigh waves are radiated. For the square lattice a complete solution for the wave field is presented with the crack-speed-dependent far-field asymptote. The latter is characterized by the wave amplitude asymptotically decreasing as the distance from the crack front in power −1/3. The asymptotically significant crack-speed-dependent direction of the radiation is determined. Such asymptotic results are also valid for the triangular lattice.     

Charged Frenkel biexcitons in organic molecular crystals

It is known that the energy of the lowest electronic transition in the neutral molecules of anthracene, tetracene, and other polyacenes is blue-shifted in comparison with the corresponding transition energy in univalent molecular ions. This effect in a molecular crystal may be responsible for the attraction between a molecular (Frenkel) exciton and a charge carrier. Due to this attraction, a bound state of Frenkel exciton and free charge (charged Frenkel exciton) may be formed [5]. As we demonstrate below, the same mechanism can be responsible for the formation of a charged biexciton (bound state of two Frenkel excitons and a charge carrier). A one-dimensional lattice model is used which corresponds to J aggregates and is also a good approximation for quasi-one-dimensional crystals. Calculations are performed for molecular crystals like tetracene, where the exciton band at low temperature is much narrower than the band of the charge carrier.     

Two-dimensional optical lattice solitons

We study various families of two-dimensional discrete or lattice solitons, and show that they are possible only when their power level exceeds a critical threshold. In addition, we show that gap-lattice solitons exist only when the lattice possesses a complete 2D band gap. Our results suggest that these conditions are universally valid, irrespective of the nature of the nonlinearity or the specific structure of the index lattice. The analysis explains fundamental aspects of behavior of two-dimensional discrete solitons that have been very recently observed in photosensitive optical crystals.     

Effective velocity of 2D phononic crystals with rectangular lattice

The effective velocity of elastic waves for two-dimensional (2D) phononic crystals with rectangular lattice in the long-wavelength limit is studied by numerical simulations. It is demonstrated that, for all three propagating modes, not only the modes polarized in-plane (L wave and SV wave), but also the mode polarized out-plane (SH wave), the effective velocities are distinctly anisotropic and the slowness curves exhibit twofold symmetry. The anisotropy increases as the filling fraction increases or as the width to length ratio of the lattice decreases, and high anisotropy can be obtained in phononic crystals with large contrast between material parameters, which is much higher in rectangular lattice than in square lattice with the same material parameters. Owing to these dependences, the effective velocity can be controlled in engineering.     

Effect of the number of defect particles on the structure and dispersion relation of a two-dimensional dust lattice system

The effect of the number of defect particles on the structure and dispersion relations of a two-dimensional (2D) dust lattice is studied by molecular dynamics (MD) simulation. The dust lattice structures are characterized by particle distribution, nearest neighbor configuration and pair correlation function. The current autocorrelation function, the dispersion relation and sound speed are used to represent the wave properties. The wave propagation of the dust lattice closely relates to the lattice structure. It shows that the number of defect particles can affect the dust lattice local structure and then affect the dispersion relations of waves propagating in it. The presence of defect particles has a greater effect on the transverse waves than on the longitudinal waves of the dust lattice. The appropriate number of defect particles can weaken the anisotropy property of the lattice.