共查询到19条相似文献,搜索用时 62 毫秒
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本文采用固相反应法制备了一系列纳米Pr6O11掺杂的MgB2超导块材,掺杂量分别为0,1,3,5,10wt.%.X射线衍射结果表明:随着Pr6O11掺杂量的增加,MgB2的晶格常数也逐渐增大,也就是说Pr原子部分替代了MgB2晶格中的Mg原子.磁测量结果显示,Pr6O11的掺杂对MgB2的超导转变温度(Tc)有很小的抑制.在低含量Pr6O11掺杂(1wt.%)时,MgB2的临界电流密度(Jc)和不可逆场(Hirr)均有明显的提高,但进一步提高Pr6O11的掺杂量时,会损害MgB2在高场下的性能.文中同时也讨论了Pr6O11掺杂影响MgB2的Tc和Jc性能的机理. 相似文献
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采用脉冲激光沉积技术.在单晶SrTiO3基底上外延生长了一系列名义结构为p×(NdBa2Cu3O7-δ(m)/YBazCu3O7-δ(n))的多层膜和准多层膜(单元层NdBa2Cu3O7-δ较厚而YBa2Cu3O7-δ呈非连贯的岛状分布,m,n为激光脉冲数,p为重复周期).样品的超导转变温度在87-91 K范围,具体大小取决于不同的调制结构,多层膜的重复周期越大,层状界面越多,超导转变温度就越低.磁传输测量表明,准多层的样品不仅具有较高的超导转变温度,而且具有较强的磁通钉扎性能,77 K零场下的临界电流密度高达4×106 A/cm2,显示出良好的应用前景. 相似文献
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采用脉冲激光沉积技术,在单晶SrTiO3基底上外延生长了一系列名义结构为p×(NdBa2Cu3O7-δ(m)/YBa2Cu3O7-δ(n))的多层膜和准多层膜(单元层NdBa2Cu3O7-δ较厚而YBa2Cu3O7-δ呈非连贯的岛状分布,m,n为激光脉冲数,p为重复周期).样品的超导转变温度在87—91 K范围,具体大小取决于不同的调制结构,多层膜的重复周期越大,层状界面越多,超导转变温度就越低.磁传输测量表明,准多层的样品不仅具有较高的超导转变温度,而且具有较强的磁通钉扎性能,77K零场下的临界电流密度高达4×106 A/cm2,显示出良好的应用前景.
关键词:
2Cu3O7-δ')" href="#">NdBa2Cu3O7-δ
多层膜
磁通钉扎
临界电流密度 相似文献
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以铝酸镧(001)单晶为基片,采用两步法制备Tl2Ba2CaCu2Oy(Tl 2212)高 温超导薄膜.首先,利用脉冲激光沉积(PLD)工艺沉积Ba2CaCu2Ox非晶前驱体薄膜;然后,前驱体薄膜在高温(720—850℃)下密封钢容器里铊化结晶形成Tl 2212薄膜.XRD结果表明Tl2212 薄膜是沿c轴方向生长的,其相组成为Tl 2212,摇摆曲线(0012)的半高宽为0.72° ,SEM图像显示其表面光滑平整,其零电阻温度为106.2K.
关键词:
Tl 2212超导薄膜
脉冲激光沉积 相似文献
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Agáta Dujavová Michaela Valeriánová Vladimír Štrbík Zuzana Matkovičová Gustav Plesch Ivan Kostič 《Central European Journal of Physics》2007,5(2):229-235
Rhenium avoids air degradation of the target as well as of precursor thin films during the preparation of high temperature
Tl-based superconductors. Addition of Re has been used during synthesis of oriented Tl(Re)-Ba-Ca-Cu-O films. High temperature
superconducting Tl-based thin films were prepared by a two step method combining RF magnetron sputtering and ex-situ thallination. Precursors with a composition of Re0.1Ba2Ca2Cu3Ox were deposited on a CeO2 buffered R-plane sapphire substrate. The sputtered films were prepared at room temperature in an Ar atmosphere. The thallination
of the precursor films was performed in a one zone configuration, where both the pellet and precursor film were kept at the
same temperature. The thallination temperature varied in the range of 850–880°C and samples were held for 30, 45 and 60 min
at this temperature in a flowing oxygen atmosphere. Besides Tl-2212, X-ray diffraction reveals the possibility of also preparing
the Tl-2223 phase, which was until now not reported in a Re doped form.
Presented at 5-th International Conference Solid State Surfaces and Interfaces, November 19–24, 2006, Smolenice Castle, Slovakia 相似文献
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在蓝宝石基片上,以CeO2为缓冲层制备了高质量的双面Tl2Ba2CaCu2O8(Tl-2212)超导薄膜。以金属铈靶作为溅射源生长了c轴取向的CeO2缓冲薄膜,并对CeO2薄膜进行了高温处理,有效改善了其结晶质量和表面形貌。采用两步法制备了双面的Tl-2212超导薄膜。XRD测试显示,薄膜为纯的Tl-2212相,且其晶格c轴垂直于衬底表面。超导薄膜的Tc为106K,Jc(77K,0T)为3.5MA/cm2,微波表面电阻Rs(77K,10GHz)为390μΩ。 相似文献
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研究了蓝宝石(1102)基片在不同温度和时间下退火时表面形貌和表面相结构的变化,以及它对CeO2缓冲层和Tl-2212超导薄膜生长的影响.原子力显微镜(AFM)研究表明,在流动氧环境中1000℃温度下退火,蓝宝石(1102)的表面首先局部区域形成台阶结构,然后表面形成叠层台阶结构,随着退火时间的延长,表面发生了台阶合并现象,表面形貌最终演化为稳定的具有光滑平台的宽台阶结构.XRD测试表明,通过高温热处理可以大幅度提高蓝宝石基片表面结构的完整性.在1000℃温度下热处理20 h的蓝宝石
关键词:
Tl-2212超导薄膜
蓝宝石
缓冲层 相似文献
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Zuzana Matkovičová Vladimír Štrbík Gustav Plesch Michaela Valeriánová Agáta Dujavová 《Central European Journal of Physics》2007,5(3):398-404
Superconducting Tl-based films were prepared on a LaAlO3 single crystal substrate. Spray pyrolysis of Ba, Ca and Cu nitrate solutions was used for deposition of the precursor films.
They were subsequently ex-situ thallinated in flowing oxygen (open system). While the superconducting Tl-2212 phase formed at an annealing temperature
of 880°C, thallination at 900°C led to the formation of a Tl-2223 /Tl-2212 mixture. The amount of Tl-2223 increased with prolonged
thallination, whereas the Tl-2212 phase progressively disappeared. Films prepared in such a manner were c-oriented and contained only low amounts of non-superconducting impurities. The resulting samples were characterized by XRD
and SEM and their T
C
values were determined by resistive four-point measurements. They showed critical temperatures in the range of T
ON
= 125–135 K, T
C0 = 91–93 K. Differences between the composition and properties of the obtained films and those thallinated in closed systems
under 50 kPa of oxygen are discussed in this paper. Results show that the Tl-2212 → Tl-2223 transformation proceeds at a slower
rate under flowing oxygen than in a closed system.
Presented at 5-th International Conference Solid State Surfaces and Interfaces, November 19–24, 2006, Smolenice Castle, Slovakia. 相似文献
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报道了在铝酸镧(00l)衬底上生长Tl-1223超导薄膜的快速升温烧结方法以及铊(Tl)源陪烧靶的配比对Tl-1223薄膜晶体结构的影响.扫描电子显微镜观测表明,采用快速升温烧结方法生长的Tl-1223超导薄膜具有致密的晶体结构.X-射线衍射等测试表明,采用合适配比的陪烧靶在氩气环境下可以制备出纯c轴取向的Tl-1223超导薄膜,充氧退火后的薄膜具有较好的电学性能,其临界转变温度T_(c onset)达到116K,临界电流密度达到1.5MA/cm~2(77 K,0 T).实验结果表明,采用这一新的烧结方法制备Tl系超导薄膜具有升降温时间和恒温时间短、生产成本低等特点. 相似文献
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Formation of epitaxial Tl_2Ba_2Ca_2Cu_3O_(10) superconducting films by dc-magnetron sputtering and triple post-annealing method 下载免费PDF全文
For obtaining pure phase T12Ba2Ca2Cu3O10 (T1-2223) films with good superconducting properties, the growth technique is improved by dc magnetron sputtering and a triple post-annealing process. The triple post-annealing process comprises annealing twice in argon and once in oxygen at different temperatures. In the first low-temperature annealing phase in argon, T12Ba2CaCu2O8 (T1-2212) is obtained to effectively minimize evaporation in the next step. With the increase of temperature in the second annealing stage in argon, the previously prepared T1-2212 inter-phase is converted into T1-2223 phase. An additional annealing in oxygen is also adopted to improve the properties of T1-2223 films, each containing an optimal oxygen content value. The results of X-ray diffraction (XRD) θ-2θ scans, 09 scans and rotational φ scans show that each of the T1-2223 films has a high phase purity and an epitaxial structure. Smooth films are observed by scanning electron microscopy (SEM). The critical temperatures Tc of the films are measured to be about 120 K and the critical current densities Jc can reach 4.0 MA/cm2 at 77 K at self field. 相似文献
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A square hole array is fabricated over a micro-bridge of NbN thin
film by electron beam lithography and reactive ion milling.
Magneto-resistance is measured across the micro-bridge filled with a
hole array near the superconducting transition temperature. It is
found that magneto-resistance minima occur when the number of
vortices is an integer multiple or a fractional multiple of the
number of holes. The temperature and the current dependences of the
matching effect are studied. 相似文献