共查询到19条相似文献,搜索用时 171 毫秒
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研究了铌掺杂锆锡钛酸铅铁电陶瓷Pb0.99Nb0.02[(Zr0.90Sn0.10)0.96Ti0.04]0.98O3(PZST 90/10-4-2Nb)在静水压(0-300 MPa)下的电荷释放量和介电性能. 对压力诱导的低温铁电三方(FR(LT))→反铁电正交(AO)相变进行了研究. PZST 90/10-4-2Nb铁电陶瓷分为未极化、极化和压力去极化三种. 极化PZST 90/10-4-2Nb陶瓷FR(LT)→AO相变过程中,电荷释放量为29.3 μC/cm2,相变压力为140 MPa. 介电性能表明:极化PZST 90/10-4-2Nb陶瓷相变压力为136 MPa,而未极化陶瓷相变压力为104 MPa,压力去极化陶瓷未表现出明显的相变特征.
关键词:
静水压
铁电陶瓷
相变
介电 相似文献
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采用改进的溶胶-凝胶方法在单晶Si(100)衬底上制备了介电性能优异的(Ba0.7Sr0.3)TiO3/LaNiO3异质薄膜.实验发现,在750 ℃下 、O2气氛中晶化的LaNiO3薄膜的电阻率最小.C-V与I-V特性测量表明(Ba0.7Sr0.3)TiO3薄膜具有优异的介电性能,在频率为50kHz、零偏压下的相对介电常数εr>300,偏压为6V时漏电流密度JL<1.2×10-6A/cm2.
关键词:
xSr1-x)TiO3铁电薄膜')" href="#">(BaxSr1-x)TiO3铁电薄膜
3底电极')" href="#">LaNiO3底电极
溶胶-凝胶法 相似文献
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概括介绍了铁电致冷基本原理,给出了三种电生热效应,即线性电生热效应、二次电生热效应和电场诱导一级相变型电生热效应的表达式,测量了(1-x)Pb(Mg1/3 Nb2/3 )O3-xPbTiO3[简记为(1-x)PMN-xPT],当x=0.08, 0.10和0.25时在室温附近的电生热性能,分析了其电生热效应的起源.研究结果表明,(1-x)PMN-xPT铁电固溶体陶瓷在室温附近具有较大的电生热效应;该效应起源于电场诱导一级相变型电生热效应和线性电生热效应;该系列陶瓷可望用于室温附近多级铁电致冷.
关键词: 相似文献
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采用溶胶-凝胶法在氧化镁单晶衬底上制备了符合化学计量比的完全填充型铁电钾钠铌酸锶钡(KNSBN)薄膜,通过X射线衍射,摇摆曲线,X射线Φ扫描,扫描电子显微镜等方法研究了薄膜的微结构,采用Adachi法研究了薄膜的电光特性. 实验发现,KNSBN薄膜在氧化镁(001)单晶衬底上沿c轴外延生长,K+,Na+的引入有效地提高了薄膜的横向电光系数r51. 成分为K0.2Na0.2Sr0.24Ba0.56Nb2O6, K0.2Na0.2Sr0.6Ba0.2Nb2O6, K0.2Na0.2Sr0.72Ba0.08Nb2O6的三种KNSBN薄膜的r51值分别为108.52pm/V, 119.98pm/V, 126.96pm/V,r51的数值随Sr2+含量增加而增大.
关键词:
横向电光系数
钾钠铌酸锶钡
外延生长 相似文献
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用传统固相烧结法制备了Sr2Bi4-xDyxTi5 O18(SBDT-x, x=0—0.20)陶瓷样品. x射线衍射分析表明, 微量的Dy掺杂没有影 响Sr2Bi4Ti5O18(SBTi) 原有的层状钙钛 矿结构. 通过研究样品的介电特性, 发现Dy掺杂减小了材料的损耗因子, 降低了样品铁电- 顺电相转变的居里温度. 铁电性能测量结果表明, 随Dy含量的增加, SBDT-x系列样品的剩余 极化先增大, 后减小. 当Dy掺杂量为0.01时, 剩余极化达到最大值, 约为20.1 μC·cm-2. 掺杂引起剩余极化的变化, 与材料中缺陷浓度、内应力以及晶格畸变程度等因 素有关, 是多种作用机理相互竞争的结果. (Bi2O2)2+ 层通常被看作是绝缘层和空间电荷库, 对材料的铁电性能起关键作用. 掺杂离子进入(Bi2O2)2+层会导致铁电性能变差.
关键词:
2Bi4Ti5O18陶瓷')" href="#">Sr2Bi4Ti5O18陶瓷
Dy掺 杂
铁电性能
居里温度 相似文献
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采用脉冲激光沉积技术制备了SrTiO3和SrNb0.2Ti0.8O3薄膜.X射线衍射分析表明在LaAlO3(100)单晶平衬底上生长的SrTiO3及SrNb0.2Ti0.8O3薄膜是沿[001]取向的近外延生长.随着氧压在一定范围内逐渐增大,SrTiO3薄膜的晶格参数减小,而SrNb0.2Ti0.8O3薄膜的晶格参数先减小后增大.同时摸索出制备具有二维电子气超晶格(SrTiO3/SrNb0.2Ti0.8O3)L的最佳氧压为1.0×10-2Pa.另外在LaAlO3(100)倾斜衬底上制备的SrNb0.2Ti0.8O3薄膜中观察到激光感生热电电压效应.
关键词:
0.2Ti0.8O3薄膜')" href="#">SrNb0.2Ti0.8O3薄膜
晶格参数
激光感生热电电压
脉冲激光沉积 相似文献
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采用高温熔融法制备出了尺寸达5 mm×3 mm×1 mm的(K0.45Na0.55)NbO3(KNN)无铅铁电晶体. XRD测试结果表明KNN晶体结构为纯的钙钛矿正交相结构,晶体的显露面为〈001〉结晶面. SEM显微结构分析表明晶体沿[001]方向呈现层状生长台阶,采用负离子配位多面体生长基元模型解释了晶体层状台阶的生长机理. 研究了晶体样品在室温至500 ℃温度范围内的介电性能,两个介电异常峰出现在240和405 ℃,分别对应正交铁电-四方铁电以及四方铁电-立方顺电相相变温度. 采用修正后的居里外斯定律研究了KNN晶体的介电弛豫特性,结果表明KNN晶体的介电弛豫特性接近于普通铁电体特征.
关键词:
0.45Na0.55)NbO3晶体')" href="#">(K0.45Na0.55)NbO3晶体
无铅
晶体结构
介电性能 相似文献
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太赫兹辐射已经成为研究稀土铁氧化物(RFeO3)的远红外响应和电子自旋特性的有效手段.本文研究了高通量制备的稀土共掺杂SmxPr1-xFeO3单晶在零磁场下的反铁磁自旋模式(qAFM)和稀土离子的晶体场跃迁.利用透射型太赫兹时域光谱,实验测得Sm0.2Pr0.8FeO3和Sm0.4Pr0.6FeO3单晶的qAFM共振频率位于PrFeO3单晶和SmFeO3单晶的qAFM共振频率(分别为0.57和0.42 THz)的连线上.SmxPr1-xFeO3的qAFM模式频率随Sm3+离子掺杂浓度的增大而增大.实验结果表明,Sm0.4Pr0.6FeO3在160 K左右发生温度诱导的自旋重取... 相似文献
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G. Rujijanagul 《Phase Transitions》2013,86(3):209-215
(Pb1? x Ba x )ZrO3 ceramics for the composition range 0?≤?x?≤?0.30 were prepared by the mixed oxide solid state reaction method. Phase transition was studied by dielectric and dilatometric measurements. The ferroelectric to paraelectric phase transition temperature was progressively shifted to a lower temperature by replacing lead with barium. The x?=?0.20 sample showed the maximum dielectric constant of 16,300 at the transition temperature. For compositions 0?≤?x?≤?0.075, the antiferroelectric to ferroelectric phase transition exhibited a large linear thermal expansion. However, the antiferroelectric to ferroelectric phase transition did not exist for 0.10?≤?x?≤?0.30 samples. A phase diagram for PBZ ceramics prepared by the conventional mixed oxide method was also present. 相似文献
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《Current Applied Physics》2020,20(12):1373-1378
The microstructure, dielectric and piezoelectric properties of Zr doped BaTiO3 ceramics sintered at optimum temperature, are investigated. High energy ball milling technique is adopted to realize nano-sized powders of Ba(Zr0.15Ti0.85)O3 ceramics. Increased boundary mobility of fine powders aided to obtain a relative density of >98.8% of theoretical density corresponding to ceramics under study. Internal stresses in these ceramics are found to be relieved by grain-boundary sliding. The Ba(Zr0.15Ti0.85)O3 ceramics synthesized at relatively low sintering temperatures exhibit remarkable, enhanced dielectric properties viz. improved polarization, high unipolar strain values comparable to Zr doped BaTiO3 single crystals of same composition, at relatively lower electric fields and also exhibit better fatigue tolerant properties. The underlying mechanisms responsible for superior dielectric, ferroelectric and piezoelectric properties are discussed. 相似文献
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Perovskite type Ba1? x Sr x Ti0.6Zr0.4O3 (with x = 0.0, 0.1, 0.2, 0.4 and 0.5) ceramics have been synthesized through solid oxide reaction route. The room temperature XRD study suggests the compositions have single phase cubic symmetry. Microstructural studies have shown a step decrease in grain size. The dielectric study reveals that the materials are of relaxor type and undergo a diffuse type ferroelectric phase transition. The diffusivity increases with increase in Sr contents in the studied composition range. The transition temperature decreases with increase in Sr contents due to the decrease in grain size. 相似文献
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The effect of antimony dopant on phase transition, dielectric response and relaxor behaviour of (Pb0.75Ba0.25)(Zr0.70Ti0.30)O3 ceramics was studied. Ceramic samples, with various Sb concentration from the range 1 to 4 at.%, were prepared by a conventional mixed oxide method. The crystal structure of the investigated ceramics was determined by an X-ray diffraction at room temperature that allowed to determine the unit cell parameters. Dielectric relaxation typical for ferroelectric relaxors was observed in the vicinity of diffuse ferroelectric–paraelectric phase transition. All parameters describing the relaxor behaviour determined from the Vogel–Fulcher relationship depend on the concentration of Sb dopant. The strong influence of antimony on grain structure and on remanent polarisation was confirmed as well. 相似文献
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The dielectric and ferroelectric properties of Ba1−xSrxTiO3 (BST) (x=0.10,0.20,0.30,0.40 and 0.60) ceramics and Ba1−2xSrxCaxTiO3 (BSCT) (x=0.10,0.20,0.30) ceramics have been investigated. The low temperature phase transitions of BST ceramics vanish after Ca2+ substitution while the high temperature transition is diffused and relaxed, which becomes more obvious with increasing x. Ca2+ substitution obviously decreases the dielectric constant maximum, Km, of BST ceramics and changes the temperature of dielectric constant maximum, Tm, of BST ceramics. The shift of Tm in BST is attributed mainly to the Sr2+ and Ba2+ concentration. BST ceramics exhibit almost normal ferroelectric characteristics, while a typical relaxor behavior was observed in BSCT ceramics. The relaxor behavior observations may be understood by a random electric field induced domain state. 相似文献
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This paper reports the observation of hexagonal phase of barium titanate by Mn doping and its effect on dielectric and magnetic properties. Ceramic samples of Ba0.98Zn0.02Ti1−xMnxO3 (where, x= 0.04, 0.06 and 0.08) were prepared by traditional solid-state reaction route. The hexagonal phase is stabilized in the composition Ba0.98Zn0.02Ti0.92Mn0.08O3 and a very feeble M–H loop is also observed in that composition. This induced magnetism is expected due to the exchange interactions between magnetic polarons formed by oxygen vacancies with Mn ions. The dielectric constant as well as the ferroelectric to paraelectric transition temperature is systematically decreased with increasing of Mn doping concentration. Further to that, the temperature dependent dielectric constant curve is also broadened at transition temperature with increasing of Mn concentration. However, the ferroelectric to paraelectric transition temperature is well above room temperature. 相似文献
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J. ShankarV.K. Deshpande 《Physica B: Condensed Matter》2011,406(3):588-592
Glass samples with composition of (50−X)PbO-(25+X)TiO2-25B2O3 (where X=0, 5, 10 and 12.5 mol%) were prepared using conventional quenching technique. The glass transition temperature, Tg and crystallization temperature Tc were determined from the DTA. These glass samples were converted to glass ceramics by following two stage heat treatment schedule. The glass ceramic samples were characterized by XRD, SEM and dielectric constant measurements. The XRD results revealed the formation of ferroelectric lead titanate (PT) as a major crystalline phase in the glass ceramics. The density increases and the CTE decreases for all glass ceramics with increase in X (mol%). This may be attributed to increase in PT phase. The SEM results which show rounded crystallites of lead titanate, also supports other results. Hysteresis loops observed at room temperature confirms the ferroelectric nature of glass ceramics. The optimized glass ceramic sample exhibits high dielectric constant which is of technical importance. 相似文献
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Ba[(Fe0.5Nb0.5)1−xTix]O3 (x=0.2,0.4,0.6,0.8,0.85,0.9 and 0.95) solid solutions were synthesized by a standard solid-state reaction technique. X-ray diffraction at room temperature and dielectric characteristics over a broad temperature and frequency range were evaluated systematically. The structure of Ba[(Fe0.5Nb0.5)1−xTix]O3 solid solutions changed from cubic to tetragonal with increasing x. A Debye-like dielectric relaxation following the Arrhenius law similar to that in Ba(Fe0.5Nb0.5)O3 was observed at lower temperature in the composition range 0.2≤x≤0.8, while the relaxor ferroelectric, diffused ferroelectric and normal ferroelectric behavior were observed for x=0.85,0.9 and 0.95, respectively. The process of the evolution of relaxor-like dielectric to ferroelectric suggested the changing from dilute polar micro-domains to polar micro-domains, polar micro/macro-domains and then polar macro-domains in the present ceramics. 相似文献