A simple parametrization of thermal desorption spectra: Y-factor

The parameter Y, the ratio between the full width at half maximum (FWHM) and the temperature at peak maximum (T_p), may be easily obtained from thermal desorption (TD) spectra. In this paper we exploit the functional dependences of Y on the coverage θ, the adsorption energy E(θ), and the pre-exponential factor v(θ) using computer simulations, and demonstrate their usefullness for a quick evaluation of TD spectra. (1) Since Y is independent of E as well as of the applied heating rate it may serve for comparison of spectra from different sources. (2) For a fixed value of v, Y(θ) is a smooth function if E(θ) = E₀(1 + bθ) (Bragg-Williams approximation), which makes it possible to extract b values from the Y/b relationship. (3) If both E and v are constant the simple Y/v correlation yields v values. This relationship may be used even in the case when both kinetic parameters are coverage dependent, but only in the very low coverage regime. (4) Any deviation from the trends of the Y(θ) dependences simulated for various values of b indicates that either the Bragg-Williams approximation is not justified or that both E and v are coverage dependent.     

On the cΠ (v = 0) state of carbon monoxide

A full analysis of the near infrared c³Π-b³Σ⁺ (0-0) band is given and term values for both states determined. The c³Π (v = 0) state was jointly analysed with the perturbing k³Π (v = 2) state and data from the c³Π-X¹Σ⁺ (0-0) transition and 3A band system were included. It is shown that the available data are consistent with the c³Π (v = 0) state having near Hund’s case b coupling with a spin-orbit constant of A = 0.45 ± 0.02 cm⁻¹, a homogeneous perturbation with the k³Π (v = 2) state, and Λ-type doubling arising predominantly from its interaction with the j³Σ⁺ state. A discrepancy with a more recent report of the 3A band system is identified and discussed. The perturbed b³Σ⁺ state term values are consistent with a previously reported five state interaction model.     

Inclusive semileptonic decays of polarized Λb Baryons into polarized τ-leptons

We employ OPE techniques within HQET to calculate the inclusive semileptonic decays of polarized Λ_b baryons. Lepton mass effects are included which enables us to also discuss rates into polarized τ-leptons. We present explicit results for the longitudinal polarization of the τ in the Λ_b rest frame as well as in the (τ^?, v_τ) c.m. frame. In both the Λ_b rest frame and in the (τ^?, v_τ) c.m. frame we make use of novel calculational techniques which considerably simplify the calculations. The transverse polarization components of the τ are calculated in the (τ^?, v_τ) c.m. frame. We delineate how to measure the full set of 14 polarized and unpolarized structure functions of the decay process by angular correlation measurements. A set of observables are identified that allow one to isolate the contributions of the twoO(1/m _t ²) nonperturbative matrix elementsK _b and ε_b.     

An intermodulated fluorescence study of the A2Σ−-X2Πi band system of copper monoxide

Several lines in the A²Σ⁻(v = 0)-X²Π_i(v = 0) visible band system of gas phase copper monoxide have been measured at sub-Doppler resolution using the technique of intermodulated fluorescence. The copper nuclear magnetic hyperfine splitting is clearly resolved. The observations were fitted to an effective Hamiltonian model and values of the magnetic hyperfine parameters of b_F = −0.0302 cm⁻¹ for the A state and d = 0.0024 cm⁻¹ for the X state were determined. An interpretation of these values in terms of the proposed electronic configurations of these states is presented.     

Parton densities beyond perturbation theory

I compute non-perturbative corrections to the kernel governing the evolution of non-singlet parton densities. The model used is QED in the limit of many charged particles. I find an infrared renormalon at b₀t = −1, where t is the Borel variable and b₀ is the first coefficient of the β-function. This term has a non-trivial dependence on the variable x = -q²/(2p · q) and its coefficient scales as x³/(1 − x)² (p is the momentum of the hadron and q is the momentum transfer). An extrapolation of my results to QCD implies a breakdown of the parton model near the elastic region.     

Effects of the velocity dependence of the collision frequency on the Dicke line narrowing

The effect of the velocity (v) dependence of the transport collision frequency ν_trv on the Dicke line narrowing is analyzed in terms of the strong-collision model generalized to velocity-dependent collision frequencies (the so-called kangaroo model). This effect has been found to depend on the mass ratio of the resonance (M) and buffer (M _b) particles, β = M _b/M: it is at a minimum for β ? 1 and reaches a maximum for β ? 3. A power-law particle interaction potential, U(r) ∝ r ^?n , is used as an example to show that, compared to ν_trv (v) = const (n = 4), the line narrows if ν_trv (v) decreases with increasing v (n < 4) and broadens if ν _trv (v) increases with v(n > 4). At β ? 3, the line width can increase [compared to ν_trv (v) = const] by 5 and 12% for the potentials with n = 6 and n ? 10, respectively; for the potentials with n = 1 (Coulomb potential) and n = 3, it can decrease by more than half and 6%, respectively. The line profile I(Ω) has been found to be weakly sensitive to ν_trv (v) at some detuning Ω_c of the radiation frequency Ω. Dicke line narrowing is used as an example to analyze the collisional transport of nonequilibrium in the resonance-particle velocity distribution in a laser field. The transport effect is numerically shown to be weak. This allows simpler approximate one-dimensional quantum kinetic equations to be used instead of the three-dimensional ones to solve spectroscopic problems in which it is important to take into account the velocity dependence of the collision frequency when the phase memory is preserved during collisions.     

Laser absorption spectroscopy of the A1Σu+-X1Σg+(v′, v″) bands of Na2

Laser absorption spectra of the band system A¹Σ_u⁺-X¹Σ_g⁺(v′,v″) of Na₂ in the range between 16835 and 16960 cm^?1 are analyzed. The spectra are free of first-order-Doppler broadening at low internal temperature. Rotational and vibrational assignments of 10 bands are reported. Rotational and vibrational levels, especially the (22, 1) band, are found to be perturbed by the b³Π_u state. The band origins and line frequencies calculated from previously reported constants do not reproduce the observed values. The disagreement between the calculated and observed values is discussed. More accurate constants are needed to predict the line locations.     

Charged hyperpions,charged higgs bosons and the leptonic decays of the heavy open-top mesonsT b * andT b

We study the leptonic decay modes of the vectorT _b ^* and pseudoscalarT _b t-flavored mesons in the framework of some extended technicolor models and for the standardSU(2)×U(1) model with two complex Higgs doublets. We find that the ratioГ(T _b ^* →? v Г(T →? v) bcan help in discriminating among these models but, unfortunately, the experimental prospects for detecting these decay modes are not very bright.     

Analysis of price diffusion in financial markets using PUCK model

Based on the new type of random walk process called the potentials of unbalanced complex kinetics (PUCK) model, we theoretically show that the price diffusion in large scales is amplified 2(2+b)^-1 times, where b is the coefficient of quadratic term of the potential. In short time scales the price diffusion depends on the size M of the super moving average. Both numerical simulations and real data analysis of Yen-Dollar rates are consistent with theoretical analysis.     

Neutrinorückstoßexperiment am Li8

The beta-decay of Li⁸→Be^8*→2α is especially suitable in neutrino recoil experiments on account of the large beta-decay energy available and on account of the subsequent break up of Be^8* into two α-particles. For the angular correlation between the antineutrino and the α-particle one obtains for our counter geometry and a Gamow-Teller interaction the angular distributionw(v)dv=(1+b v/c 0.707 cosv)dv, whereb=?1 for axial vector interaction (A) orb=+1 for tensor interaction (T) and wherev is the angle between the direction of emission of the antineutrino and the α-particle. The measurement of the energy difference of the two α-particles in the Be^8* decay, when the direction of the emission of the beta-particle is fixed, defines the angular correlation coefficientb. In this experiment the value ofb is found to be equal to ?1.12±0.20, which shows axial vector interaction in the Gamow-Teller decay.     

The analytical treatment of magnetic properties of three-layer ferrimagnetic superlattice

The Hamiltonian of the magnetic superlattice with three-layer unit cell was treated within the Boson formalism. The Boson Green’s functions (BGFs) were derived and it was shown that the system for BGFs splits into two sets which lead to the energies with opposite signs, although the energies of elementary excitations are strictly only the positive ones. However, when corresponding energies are used, the correlation functions calculated from both sets are the same. All the physically relevant quantities: total energy of the system, ground state energy, layer magnetization and zero-point (quantum) fluctuations are derived analytically by using both sets, showing that they lead to the same expressions. The Hamiltonian was also diagonalized by the so-called “u-v” transformation of the operators. It is shown that in spite of formal independence of the approaches, there exists a close relationship between BGF and “u-v” transformations.     

Variation of average charged particle multiplicity inp-nucleus interactions with energy and the two component description of particle production at high energies

Experimental data on average shower particle multiplicity (〈N _s〉) accumulated onp-nucleus interactions in the wide momentum region of 7.1–8000 GeV/c is investigated. It is observed that 〈N _s〉 is represented exceedingly well as a function of (v _vS). There are two physical processes which represent the experimental data reasonably well in the two momentum regionsviz 7.1–67.9 GeV/c and 67.9–8000 GeV/c. 〈N _s〉=a( _v ^S)/a+b fits the data in the low momentum region, whereas 〈N _s〉=a +b ln (v _vS) fits the experimental data in the high momentum region. The two physical processes are unified and represented by a single equation which is shown to be the consequence of two component theory and collective models.     

Upper limit on the branching ratio for the decay τ-→Π-ηvτ

We have searched for the decay τ^-→Π^-ηv_τ using the MARK II detector at the PEP e⁺e^- storage ring. No evidence for the decay is found; the upper limit for the branching ratio is B(τ^-→Π^-ηv_τ)<1.0% at the 95% confidence level.     

K-shell polarization of O ions in ferromagnets by spin dependent electron promotion via molecular orbitals

Transient field precessions of the 6.13 MeV¹⁶O(3^-) state have been measured in polarized Fe and Ni in order to corroborate our earlier results on C ions. It is found that precessions in Fe and Ni scale with the polarized electron density of the host at v_ion = 3.0 v₀ and are comparable at v_ion = 1.5 v₀. The latter is attributed to direct K-shell polarization of the ion by spin dependent electron promotion via molecular orbitals.     

High mobility organic thin-film transistors on plastic substrate

We have fabricated organic thin-film transistors (OTFTs) based on di-n-decyldinaphtho[2,3-b:2′,3′-f]thieno[3,2-b]thiophene (C₁₀-DNTT) on a polyimide gate dielectric coated on a polycarbonate substrate with a bottom-gate, top-contact configuration. Mobilities of the C₁₀-DNTT-based TFTs were as high as 2.4 cm² V^?1 s^?1, which are much better than those of the parent dinaphtho[2,3-b:2′,3′-f]thieno[3,2-b]thiophene (DNTT)-based TFTs (mobility ～ 0.5 cm²/V) fabricated on the same substrate. Compared to the C₁₀-DNTT-TFTs on the conventional Si/SiO₂ substrate, the present mobility of C₁₀-DNTT-TFTs are somewhat reduced, which can be attributed to reduced crystallinity on the polyimide gate dielectric, although the crystalline phase on the polyimide is the same as on the Si/SiO₂ substrate.     

Deperturbation study of the 0–1 band of the d3Πi-b3Πr transition of the SiO molecule

The structure of the (0–1) band of the d³Π_i-b³Π_r system of SiO has been photographed under high resolution with a chemiluminescent flame source, and a rotational analysis has been carried out. All theoretically predicted 27 branches of the d³Π_i-b³Π_r transition have been identified. The upper-state level is shown to be perturbed by the v = 23 level of the A¹Π state. Due to mixing of the A¹Π with the d³Π, the (23-1) band of the A¹Π-b³Π_r transition has also been observed. The deperturbed molecular constants of the d³Π_i and A¹Π levels have been evaluated.     

Predictions for the A2∑-X2Π system of LiO

Theoretical potential well constants for the ⁷Li¹⁶O molecule were used to predict the spectral and intensity distribution (equal level population assumption) of the A²∑-X²Π emission band system, so far not experimentally detected. Morse Franck-Condon factors were computed and are given. The system should be sought in the infrared, via the Δv = 0 sequence (0, 0 at 4.3 μ) and stronger but overlapped sequences Δv = -1 (3.2 μ), Δv = -2(2.5 μ), and Δv = -3 (2.1 μ).     

Smectic A order parameter measurements and critical scattering near the smectic A↔nematic phase transition in CBOOA

The temperature dependence of the order parameter for the smectic A phase of CBOOA is determined by measuring, with elastic coherent neutron scattering, the intensity of the Bragg reflection from the smectic layers. Within the experimental accuracy, the transition smectic A? nematic appears continuous in this system. However, a fit with (T_c-T)^2β yields β = 0.18 ± 0.01. Critical scattering is also observed in both phases. It can be described with an anisotropic Ornstein-Zernike law. The correlation length perpendicular to the smectic layers behaves like (T-T_c)^?v, with an exponent v = 0.47 ± 0.06. In contrast, the lateral extension of the layers seems to increase uncritically.     

Soil radon concentration and effective stress variation at Mt. Etna (Sicily) in the period January 2003–April 2005

In this study we discuss the relationship between the in-soil radon concentration and the effective stress variation at Mt. Etna volcano in the period January 2003–April 2005. The acquired radon concentration trend was compared with the one obtained by the b-value variation analysis in the frequency–magnitude relationship for earthquakes that occurred at Mt. Etna volcano (Sicily) during the investigation period. The b-value calculated using both the maximum likelihood and the least square methods shows a similar trend and, in particular, an increase starting a few months before the 7th September 2004 eruption and a decrease during the following 9 months. A similar trend was recorded during 2003 when a recharging magma phase of the volcano occurred. Results obtained by studying the b-value trend and the comparison with in-soil radon concentration are also discussed.     

Evaluation of assumed-PDF methods in two-phase flows using direct numerical simulation

The hypothesis of uncorrelated temperature (T) and vapor-fuel mass fraction (Y_v), frequently made when modeling reaction rates using assumed-PDF models, is examined utilizing transitional databases from direct numerical simulation (DNS) of three-dimensional mixing-layers two-phase (TP) flows with evaporation. Because the databases do not contain chemical reaction, which would further correlate variables, finding here a correlation between T and Y_v is sufficient for invalidating reaction rate modeling of the joint (T, Y_v) probability distribution function (PDF) as a product of the marginal PDFs. The databases comprise four multicomponent fuels, two mass loadings and two free-stream gas temperatures. For comparison, databases for single-phase (SP) flows are also analyzed at two initial Reynolds numbers. The examination is conducted in the mixing layer excluding the free streams and in a more restricted part of the mixing layer constituting its core. The analysis is performed at the DNS and large eddy simulation (LES) scales, and subgrid scale (SGS). To obtain the LES database, the DNS database is filtered, and an evaluation of the examined correlation at the LES and SGS scales is made at two filter sizes. At the DNS scale, T and Y_v are practically uncorrelated for SP flows, showing the weak influence of the perfect-gas equation of state, whereas for TP flows the correlation is strong and increases with mass loading indicating the powerful effect of the phase change. At the LES scale, the findings emulate those at the DNS scale. The fluctuations of the SGS scale are uncorrelated for SP flows, but the product of the marginal PDFs is different from the joint PDF. For TP flows, the fluctuations are correlated and the correlation increases with temperature, casting doubt on current assumed PDFs used to model chemistry in reacting sprays. These results are independent of filter size. The joint PDFs for TP and SP fluctuations are successfully modeled.