TE CO2 infrared emission apparatus with a half cavity

A TE CO₂ infrared emission apparatus with a half cavity is described . Via grating-tune the emissions p(12)–p(28), 00°1–10°0 of CO₂ are obtained for gas mixtures of 15%CO₂:20% N₂:65%He and 20%CO₂:15%N₂:65%He at a total pressure of 60 kPa; the output energy and pulse width are 20–850 mJ and 60–70 ns, respectively.     

Determination of absorption length of CO2 and high power diode laser radiation for ordinary Portland cement and its influence on the depth of melting

The laser beam absorption lengths of CO₂ and a high power diode laser (HPDL) radiation for concrete have been determined. By employing Beer–Lambert’s law the absorption lengths for concrete of CO₂ and a HPDL radiation were 470±22 μm and 177±15 μm, respectively. Indeed, this was borne out somewhat from a cross-sectional analysis of the melt region produced by both lasers which showed melting occurred to a greater depth when the CO₂ laser was used.     

Numerical modeling of a fast-axial-flow CW–CO2 laser

A four-temperature model has been applied on a fast axial flow, longitudinal discharge CO₂ laser. Using Runge–Kutta method, a set of differential equations of the model is numericaly solved. These equations describe the operation of the laser with certain ratio 1:3:6 of the mixture CO₂:N₂: He and average output power of 550 W.The temporal behaviour of the output power and photon density was obtained. The effects of kinetic temperature, coupled mirror reflectivity, gas flow speed, and cavity loss on the output power were studied.Calculated output power was compared with its measured value taken from experiment and a good agreement was observed.     

Waveguide CO2 lasers on sequence-band transitions

Two waveguide CO₂ lasers, a quartz waveguide and an alumina waveguide, have been studied on the 00°2–[10°l,02°1]_I,II sequence bands. The use of an intra-cavity hot CO₂ cell, which is a part of the waveguide, suppresses the regular-band transitions. The quartz waveguide laser has a total of 58 lines lasing on both the 9.4 µm and 10.4 µ,m sequence bands. The alumina waveguide laser has 36 lines lasing on the 10.4 µm sequence band and twice the output power of the quartz waveguide laser, whereas lasing on the 9.4 µm sequence band is difficult. The lasers can be operated on the selected single line without line jumping problem. The frequency tuning range of the strong lines is limited by the free spectral range of the cavity.     

Construction of a photon drag detector for evaluating the performance of a CO2 laser amplifier

In this article, the construction of P-type germanium (Ge) photon drag detector which is used to characterize the gain and output powers of a 10 W CO₂ laser and a CO₂ laser amplifier is described. Gain and laser amplifier output power versus laser input power measurements collected at 4.7 mbar and 12.0 mbar amplifier tube pressures are discussed. Moreover, measurements relating the CO₂ laser output power to the laser tube discharge current are provided at 6.9 mbar and 7.3 mbar tube pressures.     

Mathematical modeling of tunable TEA CO2 lasers

A mathematical model, based on the Landau–Teller equations of six-temperature model for the CO₂–N₂–He–CO system, to describe the process of dynamic emission in tunable TEA CO₂ lasers is introduced. In this model, the Landau–Teller equations are rewritten with regard to fine longitudinal mode frequencies in the laser resonator. These revised equations can be utilized to estimate the laser output spectra as well as other laser output pulse parameters. Examples are given to show the modeling results of non-tunable, grating tuned or injection-locking TEA CO₂ lasers.     

Assignments of optically pumped CD3OH laser lines

Six FIR laser lines from CD₃OH pumped by the 10R(36) and the 10R(18) CO₂ laser lines are assigned to specific rotational energy levels in the excited C–0 stretch state. It is found that their upper laser levels are shifted by a Fermi resonance between the C–0 stretch vibration and the third and forth harmonics of the torsional mode. The Fermi resonance shifts are +0.332 cm^–1 and +2.251 cm^–1 for the upper laser levels pumped by the 10R(36) and the 10R(18) CO₂ laser lines, respectively. Calculated frequencies of the pump and the laser transitions agree with those of the pump CO₂ laser lines and the observed FIR laser lines within estimated accuracy.     

Development of a cw Co : MgF2 laser

The results obtained in the development of a cryogenic cw Co : MgF₂ laser, realized at the Dipartimento di Fisica of the Università di Pisa are presented. The laser can be tuned continuously in the range between 1.6 and 2.1 μm, with a typical output power of 1–2 W. A preliminary application to the spectroscopy of a Tm : YLF doped crystal is reported by using a photoacoustic apparatus.     

Lithium ion conductive glass–ceramics with Li3Fe2(PO4)3 and YAG laser-induced local crystallization in lithium iron phosphate glasses

The glasses with the composition of 37.5Li₂O–(25 − x)Fe₂O₃–xNb₂O₅–37.5P₂O₅ (mol%) (x = 5,10,15) are prepared, and it is found that the addition of Nb₂O₅ is effective for the glass formation in the lithium iron phosphate system. The glass–ceramics consisting of Nasicon-type Li₃Fe₂(PO₄)₃ crystals with an orthorhombic structure are developed through conventional crystallization in an electric furnace, showing electrical conductivities of 3 × 10^− 6 Scm^− 1 at room temperature and the activation energies of 0.48 eV (x = 5) and 0.51 eV (x = 10) for Li⁺ ion conduction in the temperature range of 30–200 °C. A continuous wave Nd:YAG laser (wavelength: 1064 nm) with powers of 0.14–0.30 W and a scanning speed of 10 μm/s is irradiated onto the surface of the glasses, and the formation of Li₃Fe₂(PO₄)₃ crystals is confirmed from XRD analyses and micro-Raman scattering spectra. The crystallization of the precursor glasses is considered as new route for the fabrication of Li₃Fe₂(PO₄)₃ crystals being candidates for use as electrolyte materials in lithium ion secondary batteries.     

Luminescence of Strontianite (SrCO3) from Strontian (Scotland, UK)

An historic Strontianite-type specimen from Strontian, Scotland, UK, was characterized to broaden our knowledge on luminescence properties of common carbonates. These fibrous aggregates are Strontianite (Sr_xCa_1−xCO₃) with circa 6% of CaO, interfacial water, hydrosilicate anions and substitutional divalent cations, e.g., Ca²⁺, Mn²⁺, Fe²⁺ in structural Sr²⁺ positions. The specimen was analyzed by X-ray Fluorescence Spectrometry (XRF), Environmental Scanning Electron Microscopy coupled with an Energy Dispersive X-ray Spectroscopy (ESEM-EDS) probe, Spatially-resolved Cathodoluminescence under the Scanning Electron Microscope (SEM-CL), Differential-Thermal Analyses (DTA), Thermogravimetry (TG), Thermoluminescence (TL), Radioluminescence (RL) and High Resolution Spectra Thermoluminescence (3DTL), to gain an overview of the spectral emissions, the defect linkages were modified by heating from room temperature (RT) up to 500 °C. Substitutional transition elements are probably responsible for the spectral emission bands from 500 nm to 800 nm and hydrous molecules from 300 nm to 400 nm. DTA–TG analyses performed on little chips, to preserve the fiber interfaces coherence, exhibit minor endothermic peaks attributed to outflow of water groups in fiber interfaces. Both, CL and RL curves show common spectral positions but UV–blue and red emission intensities are counterbalanced since electron irradiation reduces the UV–blue emissions while X-irradiation increases them. The TL curves show a top thermal limit at 300 °C for the 300–400 nm TL emissions which become irreversibly destroyed, whereas the longer wavelength region emits at higher temperature. The non-reversible changes observed in the 320 nm and 360 nm bands during the spectra 3DTL emission could be linked with non-bridging oxygen defects, protons and hydroxyl groups and the red emissions to the ⁴G (⁴T_1g)–⁶S Mn²⁺ ion transition. Following assignations and similar spectral CL patterns of Russian Strontianite samples, the emission-defect assignments: Dy³⁺ 480 nm; Tb³⁺ 540 nm; Dy³⁺ 580 nm and Sm³⁺ 640 nm cannot be disregarded.     

High-power end-pumped CW Nd:GdVO4 laser formed with a flat–flat cavity

Formed with a flat–flat resonator, a diode-laser-array end-pumped CW Nd:GdVO₄ laser at 1.06 μm, capable of generating 8.6 W of TEM₀₀ output power with optical conversion efficiency of 43% and slope efficiency of 48%, has been developed. The laser beam was nearly diffraction limited, with the beam quality factor measured to be M²=1.22. Under the conditions of multi-mode operation, the laser was able to produce 11.2 W of low-order transverse mode radiation (M²<2) at the incident pump power of 22 W, giving an optical conversion efficiency of 51%, and a slope efficiency of 55%.     

Anodization of aluminium thin films on pSi and annihilation of strong luminescence from Al2O3

Photoluminescence (PL) of Al₂O₃ films obtained by anodization of thermally evaporated and annealed thin Al films on p⁺⁺Si in 0.3 M oxalic acid has been investigated. Thermal annealing at 200–950 °C under the dry nitrogen atmosphere was used for deactivation of luminescence centres. Luminescence from as grown films was broad and located at 425 nm. This luminescence reached to highest level after annealing at 600 °C. Maximum 10 min was required for full optical activation and prolonged annealing up to 4 h did not change the luminescence intensity. Because of deep levels, absorption band edge of as grown films was shifted to the lower energy which is 3.25 eV. Annealing above 800 °C reduced the PL intensity and this observation was correlated with the blue shift of band edge as the defects annealed out. Disappearing PL intensity and blue shift of band edge absorption after annealing at 950 °C was mainly attributed to the oxygen-related defects and partly to impurities that may be originated from oxalic acid. AFM results did not show any hexagonally ordered holes but uniformly distributed nanosized Al₂O₃ clusters that were clearly seen. XRD measurements on as grown Al₂O₃ showed only [1 1 0] direction of α phase. Debye–Scherer calculation for this line indicates that cluster size is 35.7 nm. XRD and AFM pictures suggest that nanocrystalline Al₂O₃ are embedded in amorphous Al₂O₃.     

Neon matrix isolation spectroscopy of CO2 isotopologues

The solid neon matrix isolated spectrum of CO₂ are recorded in the 2–5 μm region. Natural and ¹³C or ¹⁸O enriched CO₂ samples were used and the nν₁ + ν₃ (n = 0, 1, 2) series bands of different CO₂ isotopologues have been observed. The solid neon matrix shift due to Fermi-resonance of bands within the same vibrational polyad is analyzed.     

AC-chopper application for CW CO2 laser

A microprocessor-based algorithm was developed to control the power supply to a CO₂ laser using an AC-chopper method. This system was connected directly to a CO₂ laser tube without the need for a dc-dc converter or the storage capacitance of a multilevel circuit. The typical CO₂ laser power supply system had a full-bridge series resonant inverter or voltage multiplier. AC-to-AC converter schemes using zero voltage switching (ZVS) can be used efficiently and economically for low and medium power applications.This paper reports the performance characteristics of a symmetrical AC-chopper technology that can maintain the quality of the ac output of a CO₂ laser tube, regardless of the amount of switching loss. The laser was operated to an output power, maximum system efficiency total gas mixture of 37.2 W, 92%, and CO₂:N₂:He=1:9:15, respectively. The laser system, AC-chopper power supply and its operation were examined.     

Methanol laser lines from torsionally excited co stretch states, and from OH-bend, CH3-rock, and CH3-deformation states

Using a quasi-CW CO₂ oscillator-amplifier combination with peak power 300 Watt, we have generated FIR laser emission in weak absorption bands of CH₃OH. 40 new lines are reported, and their wavelengths are measured with a relative accuracy of 5×10^–5. A total of 72 lines are assigned. 34 of these involve torsional n=1, 2, and 3 states of the CO stretch and the vibrational ground state. The remaining lines are associated with the CH₃-rock, OH-bend, and CH₃-deformation modes. The latter are located 1460 cm^–1 above the ground state, and are pumped by simultaneous vibrational excitation and torsional deexcitation.     

High repetition rate mid-infrared laser source

An efficient, high-power mid-infrared laser source based on ZnGeP₂ (ZGP) optical parametric oscillator (OPO) is presented. Using a Q-switched Ho:YAG laser as the pump source a total output power of 10.6 W was obtained in the 3–5 μm band at 10 kHz and 8.5 W at 20 kHz. The Ho:YAG laser was pumped by two diode-pumped polarization coupled Tm:YLF lasers. Optical-to-optical efficiency achieved is >8.8% (laser-diode 792 nm to mid-IR 3–5 μm). With a commercial PtSi infrared camera (256×256 pixel focal plane array, 24 μm pitch) the pointing stability of Ho pump, signal and idler beam was measured to be better than 30 μrad. Whilst propagating the OPO beams over 100 m, little absorption for the idler beam was observed, resulting in a significant higher peak-to-peak value of ±22%, whereas the peak-to-peak stability of the signal pulses remained unchanged (±13%). To cite this article: M. Schellhorn et al., C. R. Physique 8 (2007).     

Detailed vibrational population distributions in a CO2 laser discharge as measured with a tunable diode laser

A tunable diode laser (TDL) operating in the 2150–2350 cm^–1 wavenumber region is used to probe a conventional cw CO₂ laser discharge. Absorption lines in more than 25 different vibrational bands are observed, enabling us to determine absolute vibrational populations inall levels of concern to the dynamics of the 10 m CO₂ laser. Levels in thev ₃ mode of CO₂ as high as 00°9 are monitored, and it is found that anharmonic effects play a significant role in the populations of such levels. Thev ₁ andv ₂ mode populations are also investigated in detail, and it is found that these modes are strongly coupled and maintain a common vibrational temperature under all discharge conditions. The use of a TDL is shown to be a powerful technique for investigating the dynamics of infrared molecular lasers.This work was supported in part by the National Science and Engineering Research Council, Canada     

Transport properties and defect analysis of La1.9Sr0.1NiO4 + δ

The oxygen flux through La_1.9Sr_0.1NiO_4 + δ has been measured as a function of oxygen activity gradient and temperature (750–1000 °C). The oxygen nonstoichiometry was determined by thermogravimetry in the temperature range of 400–1000 °C and oxygen partial pressures of 0.0002–1 atm. The total conductivity was measured over a similar range of conditions. The oxide ion partial conductivity derived from the oxygen flux data is approximately 4 orders of magnitude lower than the total, mainly p-type electronic conductivity. The defect structure was derived based on the data. Combining the oxygen flux and oxygen nonstoichiometry, the self diffusion coefficient of oxygen interstitials was evaluated.     

A new technique for the measurement of the product CO/CO2 ratio at the surface of char particles burning in a fluidized bed

A new experimental technique is proposed to measure the product CO/CO₂ ratio at the surface of spherical char particles during fluidized bed combustion. It is based on the measurement of the burning rate of a single char particle under low oxygen concentration conditions and on the use of an accurate prediction of the particle Sherwood number. This technique was applied to spherical char particles obtained from a bituminous coal which is characterized by a low attrition and fragmentation propensity. The product CO/CO₂ ratio was measured at a bed temperature of 850 °C and at a fluidization velocity of 0.3 m/s in a lab-scale apparatus operated with a bed of 0.5–0.6 mm sand. The char particle size was varied between 2 and 7 mm and the inlet oxygen concentration between 0.1% and 2.0%. Results showed that under the experimental conditions investigated carbon was mostly oxidized to CO₂ within the particle boundary layer, with a maximum fraction of carbon escaping as CO of 10–20% at the lowest oxygen concentrations and largest particle sizes.     

Submillimeter laser action of CW optically pumped CF2Cl2 (Fluorocarbon 12)

Eleven new CW far infrared (FIR) laser lines have been observed in the 600 m–1200 m range from the CF₂Cl₂ (Fluorocarbon 12) molecule optically pumped by a CO₂ laser. A 510^–4–10^–3 accuracy is achieved in the measurement of the FIR wavelengths.The frequency offset between the CO₂ pump center and the absorption line centers are measured using the transferred Lamb dip technique. Owing to a recent spectroscopic study of the CF₂ ³⁵Cl₂ molecule three lines may be assigned with great confidence as rotational transitions in thev ₆ vibrational band 923 cm^–1 of this main isotope.