Computational advances in organic chemistry: Molecular structure and reactivity. Edited by C. Ögretir and I. G. Csizmadia,NATO ASI Series C,Vol, 330.

We here report an AM 1 study for the reaction of different types of radicals with the acetone enolate ion 1 and other ambident nucleophiles. The theoretical reactivity order determined is phenyl > methyl > tert-butyl ? bicyclo-[2.2.1]hept-1-yl. The activation energy for the coupling of aliphatic radicals is ascribed mainly to nonbonded interactions. Considering possible solvent effects, we propose the same order of reactivity in solution. The coupling reaction of phenyl radical with 1 is an exothermic process with nonactivation energy in the gas phase. Any energy barrier in solution is here ascribed to desolvation of the anion. The regiochemistry of the coupling of radicals with ambident nucleophiles such as 1 , phenoxide, or phenylamide anions is also explained on a theoretical basis. © 1992 John Wiley & Sons, Inc.     

Catalysis in C1 Chemistry : Edited by Wilhelm Keim (Series: Catalysis by Metal Complexes,Vol. 4), D. Reidel Publishing Company,Dordrecht, The Netherlands, 1983, xii + 312 pages,Dfl. 135.00, US$58.50, ISBN 90-277-1527-0.

Nickelocene reacts with anhydrous LiI in the presence of ligands L to give the complexes C₅H₅Ni(L)I and [C₅H₅Ni(L)₂]I.