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Ye‐Xiang Tong Cheng‐Yong Su Ze‐Fu Zhang Bei‐Sheng Kang Xiao‐Lan Yu Xiao‐Ming Chen 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(1):44-45
In the title compound, [Zn(CH5N3S)2](NO3)2, the zinc(II) ion is located on the twofold axis and chelated by two thiosemicarbazide ligands with Zn—S and Zn—N distances of 2.0904 (17) and 2.2672 (6) Å, respectively. Thus the central zinc(II) is four‐coordinated and in a distorted tetrahedral geometry. The inter‐ and intramolecular hydrogen bonds formed between thiosemicarbazide ligands and nitrate anions assemble the molecules into a one‐dimensional chain. 相似文献
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