Calculation of the dispersion of the third-order optical nonlinearity in C60 films

Using wave functions determined from ground-state local-density calculations, we have calculated the wave-dispersed free response of the optical nonlinear polarizability ⁽³⁾(–3;,,), for the C₆₀ molecule and ⁽³⁾(–3;,,) i.e. Third-Harmonic Generation (THG) for films using a sum-over-states approach. The influence of screening was determined by applying an external static electric field in separate selfconsistent calculations to evaluate induced dipole moments which was used to determine the static linear and nonlinear polarizabilities. The polarizabilities calculated in the static limit were used to determine an effective screening parameter which was, in turn, used together with an RPA approach to calculate screened wave-dispersed, third-order nonlinear optical properties such as ⁽³⁾(–3;,,) and ⁽³⁾(–3;,,). Comparing evaluated polarizabilities with experimental values we found that the non-resonant free polarizability compares well in absolute magnitude with experimental results. Inclusion of screening results in a polarizability about two orders of magnitude below the experimental values.Paper presented at the 129th WE-Heraeus-Seminar on Surface Studies by Nonlinear Laser Spectroscopies, Kassel, Germany, May 30 to June 1, 1994     

Zur Temperaturabhängigkeit einiger Kenngrössen der Verfestigungskurven von Zinkeinkristallen

Zusammenfassung Es werden Ergebnisse beschrieben über die Temperaturabhängigkeit: der kritischen Schubspannung ₀, des Verfestigungskoeffizienten _A , im BereichA der Verfestigungskurve; des Verfestigungskoeffizienten _B im BereichB, der Längea _A des BereichsA und der Schubspannung _A am Ende des BereichsA. Die kritische Schubspannung wächst im Temperaturbereich 225–344°K linear mit abnehmender Temperatur. Der Temperaturverlauf des Verfestigungskoeffizienten _A , stimmt überein mit älteren Messungen an h.k.p. Metallen. Ähnlich verhält sich der Verfestigungskoeffizient _B . Die Schubspannung am Ende des BereichsA wird durch thermisch aktivierte Vorgänge beeinflußt. Der BereichA verkürzt sich im Temperaturbereich 0–85°C linear mit zunehmender Temperatur. Temperaturwechselversuche zeigen, daß im BereichB thermisch irreversible Änderungen in der Versetzungsstruktur auftreten.

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: ₀, _A , _B , _{A A} . 226 344°K . _A . _B . . 0–85°C . , .

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Herrn Dr. F. Kroupa und Ing. B. esták bin ich für das Durchlesen des Manuskripts sowie wertvolle Hinweise zu Dank verpflichtet. Mein besonderer Dank für zahlreiche fruchtbare Diskusionen und Anregungen gilt Herrn P. Kratochvíl. Herrn Prof. Dr. A. Seeger danke ich ganz besonders für Kritik des Manuskripts und wertvolle Ratschläge.     

The modular group and super-KMS functionals

Every normal, faithful, self-adjoint functional on a von Neumann algebraA canonically determines a one-parameter-weakly continuous *-automorphism group (the analog of the modular group) and a canonical ₂ grading onA, commuting with . We show that the functional satisfies the weak super-KMS property with respect to and Furthermore, we prove that and are the unique pair of a-weakly continuous one-parameter *-automorphism group and a grading of the algebra, commuting with each other, with respect to which is weakly super-KMS. The above results thus provide a complete extension of the theory of Tomita and Takesaki to the nonpositive case.Supported in part by the National Science Foundation under Grant DMS-8922002.     

Thermostimulierte Exoemission und Lumineszenz von MgO und CaO

Ohne Zusammenfassung

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MgO CaO

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Ich danke bestens Frau K. Listoová für die sorgfältige Durchführung der Versuchsreihen und Ing. S. urovi und Dr. A. Bergstein für das liebenswürdige Überlassen der Präparate.     

ЭЛЕКТРИЧЕСКАЯ ЭКВИВ АЛЕНТНАЯ СХЕМА ЗАТУХАЮЩИХ КОЛЕБАНИ Й СДВИГА ПЬЕЗОЭЛЕКТРИЧЕСКИХ СТЕРЖНЕЙ

n - , - .     

Das Anhaften von Exzitonen an Störstellen des Kristallgitters

Zusammenfassung Es wird der Proze des Anhaftens von Exzitonen an Vakanzen und F-Zentren in den Ionenkristallen studiert. Die Bewegung der Exzitonen im Felde der Vakanz und des F-Zentrums wird in adiabatischer Annäherung untersucht. Mit Hilfe der klassischen Methoden werden die Wirkungsquerschnitte des Anhaftens des Exzitons an den Vakanzen und F-Zentren bestimmt und diskutiert.

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F- . F- . F- .

     

Bunching phenomena during electron injection into the betatron II. Theory of starting conditions

A theory of the azimuthal bunching of electrons injected into the betatron is presented and compared with the experiments described in [1]. The bunching is treated as a small perturbation of the stationary beam.The stationary injected beam is replaced by the corresponding equilibrium beam of the same perveance so that the angular velocity spread of the injected electrons is proportional to the square root of the injection perveance.Self-consistent wave solutions for the perturbation of the stationary solution are then found. Equations giving the amplification of small density or energy disturbances along the beam are derived. These disturbances are assumed to be introduced by density or velocity modulation of the injected beam. The condition for the spontaneous occurrence of bunching is deduced by assuming that the disturbances do not vanish even when there is no modulation of the injected beam. The resulting expressions for the threshold perveance and the rise-time of the disturbance are in reasonably good agreement with the experiments. Such agreement may be considered as further verification of the statement made in [1] that the amplification of the disturbances is caused by the negative mass instability mechanism.

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, .

, . , [1]. . . , , . . , ., . , , . . , , [1].

     

The use of the repulsive potential in the quantum theory of solids

A new method is proposed for calculating the energy in certain special points of the Brillouin zone. The wave functions of valence and conduction electrons are given in the form of the linear combination of plane waves and the orthogonality condition of these functions to the wave functions of lower states is replaced by the repulsive potential. The practical application of this very simple method is illustrated on the energy spectrum of silicon in the centre of the Brillouin zone. It is proved that the results are comparable with some other methods, e. g. the orthogonalized plane-wave method.

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. . . , , .

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The basic thesis of this paper, together with concrete calculation of the energy spectrum of diamond, was delivered at the Czechoslovak-Polish conference in Sopoty in November 1956.

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In conclusion the autor would like to thank K. Trnková for carrying out the numerical calculations.     

Замечание К теории по степенного возникновения подви жных слоев в плазме инертных газов

[1] t _B , t _B . , t _B , . .

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A note on the theory of the successive production of moving striations in the plasma of inert gases

Approximate expressions are derived on the basis of Pekárek's theoretical paper [1] for the period of the maximum t_B of a wave packet produced by the passage of a wave of stratification before the aperture of a photomultiplier, and for its time width in the half-height t_B. The relaxation time of a wave of stratification, following from the theory [1], can thus be calculated by means of the experimentally measured velocity of motion of the maximum of a wave packet u and its width t_B. The calculation is supplemented by numerical data on the magnitude of errors committed by using approximate expressions.

     

An attempt at a phenomenological interpretation of the influence of a polarizing field on piezoelectric resonators

The change in frequency of quartz piezoelectric resonators in a d-c electric polarizing field cannot be explained merely by a change in the dimensions of the resonator due to the polarizing field caused by the inverse piezoelectric effect and electrostriction. We are forced to admit that the elastic constants also change in a polarizing field. A phenomenological interpretation of the influence of a d-c electric polarizing field on the frequency of quartz resonators is proposed here, based on newly introduced quantities characterizing such a change. In conclusion it is shown in what way the quantities, on which the phenomenological theory is based, can be determined experimentally.

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, . , . , , . , , .

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The author would like to thank Dr. J. Tichý for carefully reading the paper, for valuable discussion and numerous remarks on style and subject matter, which greatly helped to improve the text. He is also indebted to V. Janovec, C. Sc., for some new aspects and the exceptional interest with which he reviewed the paper.     

On Average Properties of Inhomogeneous Fluids in General Relativity: Dust Cosmologies

For general relativistic spacetimes filled with irrotational dust a generalized form of Friedmann's equations for an effective expansion factor a _D of inhomogeneous cosmologies is derived. Contrary to the standard Friedmann equations, which hold for homogeneous-isotropic cosmologies, the new equations include the backreaction effect of inhomogeneities on the average expansion of the model. A universal relation between backreaction and average scalar curvature is also given. For cosmologies whose averaged spatial scalar curvature is proportional to a _D ^-2, the expansion law governing a generic domain can be found. However, as the general equations show, backreaction acts as to produce average curvature in the course of structure formation, even when starting with space sections that are spatially flat on average.     

The energy of periodic surface structures in ferromagnetism

The periodic domain structures on unfavourably oriented surface layers of ferromagnetic materials were studied both experimentally and theoretically. The connection between the surface structure and the crystallographic orientation of the crystals was confirmed. All the terms contributing to the total energy of the surface layer were calculated. A general solution of the potential problem is given for arbitrary periodic distribution of the charges.

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Mikrophy'sikalische Vorgänge,die die Entstehung der Schnellen Schichtungswellen in der Neonglimmentladung bedingen

Zusammenfassung Im nachstehenden Artikel werden mikrophysikalische Vorgänge behandelt, die das Auftreten schneller Schichtungswellen in Neonglimmentladungen veranlassen können. Es werden sowohl die qualitativen Abhängigkeiten, als auch die ziffernmäigen Werte der Parameter der Schichtungswellen mit den charakteristischen Gröenwerten der in diesem Entladungstypus vor sich gehenden Vorgänge verglichen. Auf Grund der vorgenommenen Vergleiche kann gesagt werden, da die Relaxationszeiten der schnellen Wellen durch die Diffusionslebensdauer der atomaren, bzw. molekularen Ionen gegeben sind.

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,

, . , . , , .

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Zum Schlu danken wir F. Kroupa und V. Krejí für die aufmerksame Lesung der Arbeit und wertvolle Hinweise.     

An interpretation of the conditions for the existence of Shockley surface states

A study is made of the Shockley surface states in a linear chain of equal atoms, joined by alternately strong bonds. If the simple MO LCAO method is used, which considers the exchange integrals between nearest neighbours and next nearest neighbours, we get the surface states for a semi-infinite chain if the stronger bond is interrupted. The connection between Shockley and Tamm surface states is shown and the hypothesis is put forward that the condition for the existence of Shockley surface states has a generally simple physical interpretation, the validity of which is proved on the models of a semi-infinite crystal studied up to now.

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, . MO LCAO, , , . , , , .

     

ИспОльжОВАНИЕ ФлУОР ЕсцЕНтНОгО РЕНтгЕНО ВскОгО ИжлУЧЕНИь Дль кОНтАк тНОИ МИкРОРАДИОгРАФ ИИ

( )K- Fe, Ti Ca . , , , . , , , K- , .

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The use of fluorescent X-rays for contact microradiography

The possibilities of using fluorescentK-radiation of the elements Fe, Ti and Ca for contact microradiography of thin, little absorbing samples were studied and a simple set-up for carrying out this method, which uses a common type of microstructural X-ray tube as a source of the exciting radiation, was proposed. The experiments performed showed that if large magnifications are not required secondary-excitedK-radiation of the above-mentioned elements can be advantageously used for contact microradiography without the exposure times becoming impracticably long.

     

О взаимодействии экс итонов с колебаниями кристаллической реш етки

, - . : - . - .     

К теории коэрцитивно й силы и кривой намагничивания

. , , . .     

К ТЕОРИИ РЕЗОНАНСНОЙ МИГРАЦИИ ЭНЕРГИИ ВОЗ БУЖДЕНИЯ В ТВЕРДЫХ ТЕЛАХ

- - . - .     

A Rigorous Derivation of a Linear Kinetic Equation of Fokker–Planck Type in the Limit of Grazing Collisions

We rigorously derive a linear kinetic equation of Fokker–Planck type for a 2-D Lorentz gas in which the obstacles are randomly distributed. Each obstacle of the Lorentz gas generates a potential V( ), where V is a smooth radially symmetric function with compact support, and >0. The density of obstacles diverges as ^– , where >0. We prove that when 0< <1/8 and =2+1, the probability density of a test particle converges as 0 to a solution of our kinetic equation.     

The interaction of pions with deuterons

Summary There has been remarkable experimental and theoretical progress in the field ofd interactions in the last few years. Within the uncertainties of the theory the experimental data in thed breakup and thed elastic scattering reaction can be fairly well reproduced. Theoretical problems remain in the absorption channel, but there is a hope that with a few additional measurements of tensor polarization and spin transfer observables in this reaction a partial wave amplitude analysis may localize the theoretical difficulties. In addition it is very important to provide data on the deuteron tensor polarizations and the spin transfer parameters for thed elastic scattering reaction in order to obtain a reliable set of phase shifts, which may reveal resonance structures in this reaction channel.Invited talk to the symposium Mesons and Light Nuclei, Bechyn, Czechoslovakia, May 27–June 1, 1985.