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胺类萃淋树脂吸萃金(Ⅲ)性能及萃合物组成研究 总被引:1,自引:0,他引:1
朱妙琴 《理化检验(化学分册)》2006,42(4):249-251
研究了三种胺类萃淋树脂(季胺7402-Cl、叔胺7301-Cl、伯胺1923-Cl)吸萃金的性能,确定了三种树脂吸萃金的最佳条件,比较了各种树脂吸萃金的最大吸萃容量。分别用饱和吸萃法、离子分析法、电导法、IR、UV法,推测出负栽树脂上吸萃物的组成为R(H):AuCl4^-=1:1的离子缔合物,吸萃机理为配阴离子交换机理。 相似文献
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在叔胺的催化作用下,合成了一类含芳醚结构的新型二苯甲烷双马来酰亚胺-二烯丙基双酚A共聚树脂,与未用催化剂时合成的共聚树脂相比,该树脂具有更优良的贮存稳定性和热稳定性,耐热温度指数达214~238℃而固化性能相似。 相似文献
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运用高分子反应法,制备脱氢枞胺键合交联聚苯乙烯树脂,反应分三步进行:醚化反应,双键环氧化和脱氢枞胺与环氧基开环反应,探讨了每一步合成的最佳工艺条件,通过红外光谱对该功能高分子进行了结构表征,并对该合成产物进行对映体分离的初步应用。 相似文献
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聚苯乙烯型双季铵树脂的制备及性能研究 总被引:3,自引:0,他引:3
三乙烯二胺和四甲基乙二胺与氯甲基聚苯乙烯反应,得到同时含有季铵和叔胺的强-弱碱型树脂,再用碘甲烷季铵化叔胺,制备聚苯乙烯双季铵树脂;另一种方法是将二甲基苄胺型叔胺树脂用4-溴丁基三甲基溴化铵季铵化引入4碳链双季铵基团。反应结果表明,两类强弱碱基树脂的季铵化反应结果并不理想,二甲基苄胺型叔胺树脂季铵化反应的转化率最高为36%。考察了这些新型双季铵树脂的热稳定性及对水溶液中有机酸(如苯磺酸和对-硝基苯乙酸)的吸附、脱附性能。 相似文献
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本文探讨了用二甲胺胺化的大孔弱碱性阴离子交换树脂,在胺化过程中,不同的反应温度对树脂强碱基因含量及全交换容量的影响. 相似文献
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Aminolysis of nitrilacrylate–divinylbenzene–methyl methacrylate copolymers by diethylenetriamine is studied under various conditions. The effect of temperature and catalyst concentration on the properties of synthesized anion exchangers depending on the duration of aminolysis is investigated. The conditions for synthesizing anion exchangers with high capacity characteristics are proposed according to the study results. 相似文献
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Polyanionic cellulose carbamates were synthesized by rapid and efficient homogeneous aminolysis of cellulose carbonate half-esters in an ionic liquid/DMF medium. Cellulose bis-2,3-O-(3,5-dimethylphenyl carbamate), as a model compound, reacted with different chloroformates to cellulose carbonates. These intermediates were subjected to aminolysis, for which both the reactivity of different chloroformates towards C6-OH and the reactivity/suitability of the respective carbonate half-ester in the aminolysis were comprehensively studied. Phenyl chloroformate and 4-chlorophenyl chloroformate readily reacted with C6-OH of the model cellulose derivative, while 4-nitrophenyl chloroformate did not. The intermediate 4-chlorophenyl carbonate derivative with the highest DS (1.05) was then used to evaluate different aminolysis pathways, applying three different amines (propargyl amine, β-alanine, and taurine) as reactants. The latter two zwitterionic compounds are only sparingly soluble in pure DMF as the typical reaction medium for aminolysis; therefore, several alternative procedures were suggested, carefully evaluated, and critically compared. Solubility problems with β-alanine and taurine were overcome by the binary solvent system DMF/[EMIM]OAc (1:1, v/v), which was shown to be a promising medium for rapid and efficient homogeneous aminolysis and for the preparation of the corresponding cellulose carbamate derivatives or other compounds that are not accessible by conventional isocyanate chemistry. The zwitterionic cellulose carbamate derivatives presented in this work could be promising chiral cation exchangers for HPLC enantiomer separations. 相似文献
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通过苯乙烯-甲基丙烯酸甲酯(St-MMA)共聚物与羟基胺氨解反应,进行线型可溶和交联不溶的两种N-取代甲基丙烯酰胺共聚物的合成。线型可溶性共聚物是将St-MMA聚合所得的产物进行氨解得到;交联小球是通过使St-MMA-DVB悬浮聚合产物氨解制备。为得到具有适度亲水性的共聚物,考察了氨解条件;用元素分析、红外光谱和核磁共振谱证实发生了氨解反应。实验结果表明,通过控制共聚物的组成比,交联度和氨解度,以期获得具有预想亲水程度的甲基丙烯酰胺共聚物。 相似文献
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对苯乙烯-丙烯腈-二乙烯基苯(S/AN/DVB)交联共聚机理研究曾发现,丙烯腈作为第三单体,可使DVB竞聚率比在S/DVB共聚体系中降低,相互分离显著,从而有利于合成性能较好的离子交换树脂;本文在此基础上,将S/AN/DVB共聚体中的氰基水解成羧基来合成含磺酸、羧酸双功能基树脂,解决了前人研究中仅有50%的氰基水解成羧基的问题,并首次将这种树脂应用于混合氨基酸的分离。 相似文献
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A novel type of ion exchanger was prepared by multipoint covalent binding of polystyrene chains onto the surface of porous silica followed by polymer-analogous modification of the bonded layer. Both anion and cation exchangers were synthesized and examined in the separation of nucleotides and proteins. Rapid and efficient separation of basic polypeptides on strong anion exchangers and that of acidic polypeptides on strong cation exchangers could be achieved. For the separation of complete mixtures of polypeptides the application of zwitter-ionic ion exchangers can be recommended. 相似文献
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Jei-Kwon Moon Ki-Wook Kim Chong-Hun Jung Yong-Gun Shul Eil-Hee Lee 《Journal of Radioanalytical and Nuclear Chemistry》2000,246(2):299-307
Composite ion exchanger beads were prepared to remove the strontium and silver ions in acidic solution. Potassium titanate and nickelferrocyanate powder, which are acid resistant inorganic ion exchangers were synthesized and then mixed with polyacrylonitrile (PAN) binder to form a PAN-potassium titanate and a PAN-nickelferrocyanate composite ion exchanger beads. Spherical composite beads could be obtained by adjusting the viscosities of the composite dope in the range of 700–1000 cP. The composite beads porosities such as macropore volume and pore size were increased in proportion to the contents of PVP (polyvinylpyrrolidone) which was used as the porosity modifying chemical. The synthesized composite ion exchangers were evaluated on their adsorption characteristics for the Ag1 and Sr21 ion solutions of pH 2. 相似文献
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Ergozhin E. E. Menayakova G. A. Atshabarova R. B. 《Russian Journal of Applied Chemistry》2001,74(1):36-38
New polyfunctional anion exchangers are synthesized from dextramine (waste from levomycetin production) by condensation of its glycidyl ethers with certain polyamines. The polycondensation conditions are optimized, and physicochemical properties of the resulting ion exchangers are studied. 相似文献
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Nagawa Y Suga J Hiratani K Koyama E Kanesato M 《Chemical communications (Cambridge, England)》2005,(6):749-751
A novel [3]rotaxane composed of two 25-membered crownophanes and one axle molecule having two anthryl end groups was successfully synthesized via covalent bond formation followed by aminolysis, and can incorporate caesium ion into the space between the two macrocycles as a 1 : 1 sandwich-type complex, whereas it makes a 1 : 2 complex with lithium ion. 相似文献
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E. E. Ergozhin T. K. Chalov A. G. Rozhkova R. A. Iskakova 《Russian Journal of Applied Chemistry》2005,78(10):1600-1604
Polyfunctional polyelectrolytes were synthesized by polycondensation of epichlorohydrin oligomer in the presence of allyl bromide. The polycondensation conditions were optimized, and composition and the properties of the resulting ion exchangers were studied. 相似文献