共查询到20条相似文献,搜索用时 46 毫秒
1.
2.
ICP-AES法测定矿石中的BeO 总被引:1,自引:0,他引:1
报道了采用ICP-AES法测定矿石中的BeO。对试样的溶解进行了选择;考察了其体和无机酸对测定的影响。采用基体匹配法进行测定。在优化条件下,对三个试样进行测定,其相对标准偏差(n=9)为0.28%;回收率为97%-103%。 相似文献
3.
4.
5.
本文报告了在0.01mol/LCTAB体系中,以F-为掩蔽剂、苯芴酮显色、用分光光度法测定饮料食品中Ge-132含量,最低检测限0.054μg/mL;线性范围0.54~27.14μg/mL;回收率96.3%~101.5%,并确定了Ge-132摩尔吸收系数(ε)3.39×104。用本法测定了康寿茶、矿泉水和博士奶中Ge-132含量,灵敏度高、重现性和准确度好。用盐酸化本体系,研究了二氧化锗(Ge~(4+))的含量测定,其最低检测限0.021μg/mL;线性范围1.0~21.0μg/ml;回收率95.8%~102.8%,Ge-132不干扰。饮料食品中同时存在Ge-132和Ge(4+)时,本体系可分别测定两者含量。 相似文献
6.
7.
8.
9.
ICP-AES法同时测定石英砂中的痕量元素 总被引:3,自引:0,他引:3
采用微波溶样,并通过条件试验,建立了微波溶样ICP-AES法同时测定石英砂中13种痕量元素的分析方法并已应用于实际样品的分析,方法的相对标准偏差≤10%,加标回收率为90%-107%。 相似文献
10.
氢化物发生-冷阱捕获-色谱分离-原子吸收法测定天然水中砷的形态 总被引:4,自引:0,他引:4
研究建立了氢化物发生-冷阱捕获-色谱分离-原子吸收方法测定天然水中四种主要砷形态。测试系统自行组装,色谱住填料采用ChromosorbGAW-DMCS(粒径0.3~0.45mm),其上涂布3%OV-101。方法的检出限以砷计分别为:As(V)0.51ng,As(Ⅲ)0.43ng,MMA0.38ng,DMA067ng;12ng砷标准偏差As(Ⅴ)4.21%,As(Ⅲ)3.56%,MMA3.23%,DMA5.46%。在0~50ng砷量范围标准曲线线性关系良好。该法适用性广,已用于湖水、河水、海水和地下水等不同水样神形态测定,加标回收率93.5%~104.9%。给出了上述水样四种砷形态的分析结果。 相似文献
11.
用溶胶-凝胶法以磷钼酸(MPA)的镍盐溶液水解钛酸四丁酯制备了NiPMo/TiO2催化剂.使用ICP、 XRD、 TG-DTA、 IR、 TPD-MS和微反应技术研究了催化剂的化学组成、热稳定性、化学吸附性质和催化反应性能.杂多钼酸盐与TiO2通过O2-在TiO2表面发生了键合.在623 K下,杂多阴离子仍保持原有的Keggin结构.CO2在Lewis酸位Ni(Ⅱ)和Lewis碱位Ni-O-Mo的桥氧协同作用下生成CO2卧式吸附态Ni(Ⅱ)←O-(CO)←(O--Ni).丙烯有多种吸附态在催化剂上吸附.在563 K、 1 MPa和空速1500 h-1的反应条件下,丙烯的摩尔转化率为3.2%,产物MAA选择性为95%. 相似文献
12.
Toward new camptothecins. Part 6: Synthesis of crucial ketones and their use in Friedländer reaction
Laurent Gavara Thomas Boisse Jean-Pierre Hénichart Adam Daïch Philippe Gautret 《Tetrahedron》2010,66(38):7544-5571
In the context of the preparation of camptothecin and luotonin A analogs, the synthesis of some key keto-precursors and their use in Friedländer condensation are described. This paper also focuses on the stability of these keto intermediates and emphasizes the major differences between indolizinones and pyrroloquinazolinones series. Noteworthy is also the report of some original structures isolated as by-products of some experiments. 相似文献
13.
The Langevin paramagnetic theory can’t describe the relation between magnetization of ferrofluids and applied magnetic field. The structuralization of ferrofluids, which is considered the main influence factor of the magnetization, is regarded. The part of magnetization works is deposited when the structure is forming. This action influences the magnetization of ferrofluids directly or indirectly. On the base of the “compressing” model, the Langevin function that usually describes the magnetization of ferrofluid is modified, and a well-fitted curve is obtained. An equation of the relation between the equivalent volume fraction after being “compressed” and the intensity of magnetic field is discovered, which approximately describes the process of magnetization. The relation between the approximate initial susceptibility and the volume fraction can be obtained from modified formula. 相似文献
14.
Rebecca J. Burton Mandy L. CrowtherNeal J. Fazakerley Shaun M. FilleryBarry M. Hayter Jason G. KettleCaroline A. McMillan Paula PerkinsPeter Robins Peter M. SmithEmma J. Williams Gail L. Wrigley 《Tetrahedron letters》2013
The highly regioselective Buchwald–Hartwig amination at C-2 of the cheap and readily accessible reagent, 2,4-dichloropyridine with a range of anilines and heterocyclic amines is described. This new methodology is robust and provides a facile access to 4-chloro-N-phenylpyridin-2-amines on 0.25 mol scale. These intermediates undergo a further Buchwald–Hartwig amination at higher temperature to enable rapid exploration of the chemical space at C-4 and to provide a library of 2,4-bisaminopyridines. 相似文献
15.
KMnO4-mediated oxidative CN bond cleavage of tertiary amines producing secondary amine was introduced, which was trapped by electrophiles (acyl chloride and sulfonyl chloride) to form amides and sulfonamides. The reaction could take place at mild condition, tolerating a wide range of function groups and affording products in moderate to excellent yields. 相似文献
16.
N. A. Nedolya 《Chemistry of Heterocyclic Compounds》2008,44(10):1165-1219
The review contains a concise historical account and information on the most significant researches undertaken by the staff
at the A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences on the Chemistry
of Heterocyclic Compounds.
Dedicated to Academician of the Russian Academy of Sciences B. A. Trofimov on his 70th jubilee.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1443–1502, October, 2008. 相似文献
17.
Regiospecific and direct imidation of the methyl C(sp3)–H bond of thioanisoles is realized under mild and metal-free conditions with N-fluorobis(benzenesulfonyl)imide as an oxidant and nitrogen source. Proposed mechanism suggests that thionium ion intermediates and a Pummerer-type reaction are involved. The imidation has advantages such as high step-economy, excellent functionality tolerance, and regiospecificity, giving structurally diverse imidation products. 相似文献
18.
19.
《Tetrahedron》2014,70(21):3377-3384
The Rh(II)-catalyzed reaction of 2-carbonyl-substituted 2H-azirines with ethyl 2-cyano-2-diazoacetate or 2-diazo-3,3,3-trifluoropropionate provides an easy access to 2H-1,3-oxazines and 1H-pyrrol-3(2H)-ones. These compounds can be selectively prepared from the same starting material using temperature as the only varied parameter. The 2-azabuta-1,3-diene intermediate, a common precursor for both heterocyclic products, isomerizes into 2H-1,3-oxazine under kinetic control, while 1H-pyrrol-3(2H)-one is the sole product of the reaction at elevated temperatures. According to DFT-calculations a one-atom oxazine ring contraction involving ring-opening to a 2-azabuta-1,3-diene intermediate, followed by a 1,5- and 1,2-prototropic shift leads to the consecutive formation of imidoylketene and azomethine ylide, which then further undergo cyclization to the pyrrole derivative. 相似文献
20.
Different approaches for the synthesis of 1-benzyloxypyrazin-2(1H)-one derivatives from simple amino acids have been investigated. A library of 33 precursors for the preparation of N-hydroxy pyrazinones was obtained in moderate to good yields. 相似文献