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低温水热合成是水热化学一个活跃的研究方向,在氧化物粉末的合成方面具有潜在的应用价值.La2M2O7(M=Ti,Zr)陶瓷材料的优良特性使其多晶粉末的合成倍受关注[1,2]. 相似文献
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采用CoCl2·6H2O、4,4′-联吡啶和NH4VO3,以H2O作溶剂(摩尔比1:2:2:1950)在170℃下水热反应合成无机-有机杂化化合物Co(μ2-bpy)V2O6(bpy=4,4′-联吡啶),经单晶X射线衍射测定其晶体结构.此晶体属三斜晶系,空间群为Pi,晶胞常数a=0.81599(7)nm,b=0.85826(7)nm,c=1.02031(8)nm,α=87.111(2)°,β=75.305(2)°,y=74.784(2)°,Z=2.Co(μ2-bpy)V2O6是无机的双金属氧化物层,[Co2V4O12]n通过有机的桥式配体μ2-bpy以N-Co配位键桥联而成.晶体的三维共价结构含有多种开放式孔道,其中最大孔道的尺寸为0.5nm×0.7nm.漫反射光谱研究表明,此晶体具有约2.0 eV的光学能隙,属于半导体,在420℃以下是热稳定的. 相似文献
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Co(μ2-bpy)V2O6 (bpy =4,4′-联吡啶)的水热合成和晶体结构 总被引:3,自引:0,他引:3
采用CoCl2•6H2O、4,4′-联吡啶和NH4VO3,以H2O作溶剂(摩尔比1∶2∶2∶1950)在170 ℃下水热反应合成无机-有机杂化化合物Co(μ2-bpy)V2O6 (bpy=4,4′-联吡啶), 经单晶X射线衍射测定其晶体结构.此晶体属三斜晶系,空间群为Pī,晶胞常数a=0.81599(7) nm,b=0.85826(7) nm, c=1.02031(8) nm,α=87.111(2)°, β=75.305(2)°,γ=74.784(2)°, Z=2. Co(μ2-bpy)V2O6是无机的双金属氧化物层,[Co2V4O12]n通过有机的桥式配体μ2-bpy以N-Co配位键桥联而成.晶体的三维共价结构含有多种开放式孔道,其中最大孔道的尺寸为0.5 nm×0.7 nm.漫反射光谱研究表明,此晶体具有约2.0 eV的光学能隙,属于半导体,在420 ℃以下是热稳定的. 相似文献
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γ—Mo2N合成过程中的热变化及中间产物的研究 总被引:2,自引:0,他引:2
采用DTA技术,通过改变升温速率研究了γ-Mo2N合成过程中的热变化,并经XRD,BET及IR测试,对DTA曲线中的谱峰进行归属,考察了中间产物,DTA结果表明,在MoO3和NH3程序升温反应过程中有放热峰及吸热峰出现,且随升温速率的长高,放热峰面积与吸热峰面积之比逐渐减小,结合XRD及IR结果可知,DTA曲线听放热峰可归属为由MoO3变化为MoO2的还原峰,吸热峰则归属为由MoO2变化为Mo2N 相似文献
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将原位XRD反应装置与在线气相色谱技术结合,研究了不同H_2O含量(4.36%、1.68%、0.56%)条件下单一相Fe_5C_2的氧化速率,并考察了不同Fe_5C_2氧化程度(0、25%、55%、68%)和氧化次数对其费托合成(F-T)反应性能的影响。研究结果表明,Fe_5C_2物相的氧化速率随H_2O含量的提高而逐渐增加,同时H_2O氧化使Fe_5C_2颗粒粒径减小,暴露出更多活性位点,造成F-T反应活性提高,且氧化程度越大,活性提高越明显;随着氧化次数的增加,F-T反应活性逐渐提高,但CH_4选择性增加,C_(5+)选择性逐渐降低。 相似文献
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Differential thermal analysis (DTA) and X-ray powder diffraction (XRD) were used to study phase equilibria, established in
air in the V2O5-Sb2O4 system up to 1000°C. It has been found that there is a new phase =SbVO5. The =SbVO5 has been prepared by two methods: by heating equimolar mixtures of V2O5 and α-Sb2O4 in air and by oxidation of the known phase of rutile type obtained in pure argon at temperatures between 550 and 650°C. Thermal
decomposition of =SbVO5 in the solid state starts at 710°C giving off oxygen. The results provide a basis for constructing only a part of the phase
diagram of the investigated system (up to 50.00 mol% Sb2O4).
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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Kurzawa Maria Błońska-Tabero Anna Rychłowska-Himmel Izabella 《Journal of Thermal Analysis and Calorimetry》2003,74(2):543-547
Using DTA and XRD methods, a diagram of phase equilibria in ZnV2O6-ZnFe2O4 system has been constructed. System ZnV2O6-ZnFe2O4 is in subsolidus area a real binary system and its components form a compound Zn2FeV3O11. Zn2FeV3O11 melts incongruently at 835±5°C with deposition of two solid phases: b-Zn2V2O7 and ZnFe2O4.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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Differential thermal analysis (DTA) and X-ray diffraction (XRD) were utilized to study the phase equilibrium established in
the subsolidus area of the system Cr2 O3 –Sb2 O4 . It was found that the components of the title system interact in ambient air to produce CrSbO4 . The compound is stable up to ~1380°C, at which temperature it starts to decompose.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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Madarász J. Beregi E. Sztatisz J. Földvári I. Pokol G. 《Journal of Thermal Analysis and Calorimetry》2001,64(3):1059-1065
Sintering processes in the Y2O3–Al2O3–B2 O3 system and its subsystems (Y2O3–B2O3 and Al2 O3–B2O3) have been investigated by using combined DTA and XRD measurements to get a better understanding of solid state chemical
changes resulting in the formation of yttrium aluminum borate (YAl3(BO3)4, YAB) phase and to study the possible role and contribution of various simple borates formed also in the former processes.
Two new exothermic heat effects of YBO3 formation have been detected by DTA in the Y2O3–B2O3 system between 720 and 980°C. In the Al2O3–B2O3 system a new experimental XRD profile of Al4B2O9 was observed. Formation of these borates seems to promote the nucleation of double borate YAB below 1000°C. Conversion of
Al4B2O9 to Al18B4 O33 was observed after a long term (10 h) sintering at 1050°C. Similarly, an increased formation of YAB has been observed as
a product of the sintering reaction between YBO3 and Al18B4O33 at 1150°C. The two latter single borates are found to be identical with the high temperature decomposition products of YAB.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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Reactivity of FeVO4 towards Ni2V2O7 and Ni3V2O8 in the solid state was investigated. On the base of XRD and DTA results, phase diagrams in subsolidus area of the FeVO4-Ni2V2O7 and FeVO4-Ni3V2O8 intersections of the ternary system NiO-V2O5-Fe2O3 have been worked out and the phase diagram of this ternary system in subsolidus area in the whole component concentration
range has been verified.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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Rychlowska-Himmel I. Blonska-Tabero A. 《Journal of Thermal Analysis and Calorimetry》1999,56(1):205-210
Studies on the reactivity of ZnFe2O4 towards ZnV2O6 revealed that in the solid state the phases interact in a molar ratio of 1:3 to form a new compound, to which the molecular
formula Zn2FeV3O11 was assigned. The compound melts congruently at 825±5°C.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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Phase relations in subsolidus area of ZnO-V2O5-Fe2O3 system 总被引:1,自引:0,他引:1
Kurzawa Maria Blłońska-Tabero Anna Rychłowska-Himmel Izabella 《Journal of Thermal Analysis and Calorimetry》2003,74(2):537-542
Phase equilibria in subsolidus area in the ZnO-V2O5-Fe2O3 system have been investigated over the whole concentration range of the oxides. The components of this system form two compounds:
Zn2FeV3O11 and Zn3Fe4(VO4)6. A solidus area projection onto the component concentration triangle plane of the ZnO-V2O5-Fe2O3 system has been constructed using DTA and XRD methods. 11 subsidiary subsystems can be distinguished in this system. Melting
temperatures of mixtures of solid phases coexisting at equilibrium in each of subsidiary subsystems were determined.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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Carbonizate as a model soot has been submitted to oxidation using Al2O3, Cr2O3, Ni2O3 and Fe2O3 as catalysts in the temperature range from RT up to 1000°C. The results obtained indicate that Fe2O3 is the most active catalyst in soot oxidation. However, all the catalysts examined are active in transformation of carbonizate
components. It has been shown that DTA and TG methods can be used as fast methods testing the carbonizate oxidation.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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The thermal behaviour of the MH2(IO3)3 (M=K, Rb and NH4) isomorphous compounds, as well as the IR and Raman spectra have been investigated as part of a study of the properties of solid protonic conductors. Detailed stoichiometries, sustained by TG, DTA, XRD and IR analysis, have been developed into the three phases. There were also evidences of the formation of the [I3O8]– polymeric phases. Their stabilities were associated to the different polarizing power of the H, K and Rb cations.This work was supported by CONICET (Programa QUINOR) and CICPBA. 相似文献
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The reaction of the phosphine oxides, OPEt31 and OPn-Bu32 with pinacolborane (HBpin) results in phosphine oxide reduction and the formation of O(Bpin)23. In contrast, the phosphine oxide OPn-Bu3 reacts with HB(C6F5)2 or B(C6F5)3 to give only the donor-acceptor adducts. Compound 3 reacts with HNPt-Bu3 to give the phosphinimonium borate salt, [t-Bu3PNH2][(Bpin(OBpin)2]6, while reaction with Cp2ZrMe2 affords the species Cp2Zr(OBpin)27. 相似文献