共查询到20条相似文献,搜索用时 31 毫秒
1.
Three new Cu(II) supramolecular complexes [Cu(L1)Cl2]·2DMF (1), [Cu(L2)Cl2] (2) and [Cu(L3)Cl2]·DMF (3) (L1 = 3,3′-bis(2-benzimidazolyl)-2,2′-dipyridine, L2 = 3,3′- bis(N-ethyl-2-benzimidazolyl)-2,2′-dipyridine and L3 = 3,3′-bis(N-benzyl-2-benzimidazolyl)-2,2′-dipyridine) have been prepared and characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. X-ray structural analysis of L1, L2·3.5H2O and L3·H2O indicates that all three ligands adopt the trans conformation with the two benzimidazole fragments located on opposite sides of the dipyridyl backbone. While in complexes 1–3, all the ligands display the cis conformation and behave as bidentate chelating reagents to coordinate with Cu(II). The inorganic chloride ions always act as a reliable hydrogen bonded acceptor in these structures, and the resulting C–HCl2Cu supramolecular synthons play a significant role in the formation and stabilization of the structures. Moreover, additional non-covalent interactions, such as C–Hπ, are also identified to extend the discrete (0-D) or low-dimensional (1-D) motifs into high-dimensional architectures. 相似文献
2.
Ying Ma Yangguang Li Enbo Wang Ying Lu Cao Qin Xinxin Xu 《Journal of Cluster Science》2006,17(2):167-181
Two new materials built from reduced molybdenum (V) phosphates as building blocks and zinc coordination complexes as linkers, (H3O)2[Zn(2,2′-bpy)]4[Zn(H2O)]2[Zn(HPO4)2 (PO4)6(MoO2)12(OH)6] · 6H2O (2,2′-bpy=2,2′-bpyridine) 1 and [Zn(phen)(H2O)2]2[Zn(phen) (H2O)]2[Zn(H2O)]2[Zn(HPO4)4 (PO4)4(MoO2)12 (OH)6] · 7H2O (phen=1,10-phenanthroline) 2, have been synthesized and characterized by elemental analyses, IR, TG, and single crystal X-ray diffraction. Compound 1 is a new 3-D structure which constructed from Zn[P4Mo6]2 dimers bonded together with [Zn(2,2′-bpy)] coordination complexes and [Zn(H2O)] fragments. In compound 2, the Zn[P4Mo6]2 dimeric units are linked by [Zn(phen)(H2O)] coordination complexes and [Zn(H2O)] fragments to form a new 2-D framework. The fluorescent activities of compounds 1 and 2 were reported. The crystal data for the two compounds are the following: 1, triclinic, P−1, a=13.036(3) ?, b=13.765(3) ?, c=14.459(3) ?,
, Z=1; 2, triclinic, P−1, a=12.708(3) ?, b=14.016(3) ?, c=14.646(3) ?,
, Z=1.Dedicated to Professor Michael T. Pope on the occasion of his retirement. 相似文献
3.
Andrei V. Bogdanov Vladimir F. Mironov Lenar I. Musin Rashid Z. Musin Dmitry B. Krivolapov Igor A. Litvinov 《Monatshefte für Chemie / Chemical Monthly》2011,41(3):81-85
Abstract
The reaction of aminomethylisatins (isatin N-Mannich bases) with hexaethylphosphorous triamide leads to the formation of 1,1′-bis(dialkylaminomethyl)-3,3′-bis(indolin-3-ylidene)-2,2′-diones and 1,1′-bis(1,3-dioxo-1,3-dihydroisoindol-2-ylmethyl)-1H,1′H-[3,3′]bisindolylidene-2,2′-dione. 相似文献4.
M. Aksu S. Durmu M. Sari K. C. Emregül I. Svoboda H. Fuess O. Atakol 《Journal of Thermal Analysis and Calorimetry》2007,90(2):541-547
N,N′-bis(salicylidene)-1,3-propanediamine (LH2), N,N′-bis(salicylidene)-2,2′-dimethyl-1,3-propanediamine (LDMH2), N,N′-bis(salicylidene)-2-hydroxy-1,3-propanediamine (LOH3), N,N′-bis(2-hydroxyacetophenylidene)-1,3-propanediamine (LACH2) and N,N′-bis(2-hydroxyacetophenone)-2,2′-dimethyl-1,3-propanediamine (LACDMH2) were synthesized and reduced to their phenol-amine form in alcoholic media using NaBH4 (LHH2, LDMHH2, LOHHH2, LACHH2 and LACDMHH2). Heterodinuclear complexes were synthesized using Ni(II), Zn(II) and Cd(II) salts, according to the template method in DMF
media.
The complex structures were analyzed using elemental analysis, IR spectroscopy, and thermogravimetry. Suitable crystals of
only one complex were obtained and its structure determined using X-ray diffraction, NiLACH·CdBr2·DMF2, space group orthorhombic, Pbca, a=20.249, b=14.881, c=20.565 ? and Z=8. The heterodinuclear complexes were seen to be of [Ni·ligand·MX2·DMF2] structure (ligand=LH2−, LDMH2−, LOHH2−, LACH2−, LACDMH2−, M=ZnII, CdII, X=Br−, I−). Thermogravimetric analysis showed irreversible bond breakage of the coordinatively bonded DMF molecules followed by decomposition
at this temperature. 相似文献
5.
A novel 4d-4f complex, {Cs[Yb(MeOH)3(DMF)(H2O)Mo(CN)8] · H2O}
n
(1) (DMF = N,N′-dimethylformamide) has been synthesized and structurally characterized. The complex 1 is a one-dimensional (1D) infinite chain, which adopts a 1D ladder-like structure motif assembled from an edge-sharing rhombus
and square of Mo2Yb2 based on the [Mo(CN)8]4− and Yb3+ as building blocks. The complex 1 crystallizes in triclinic, space group P1 with a = 9.841(2) b = 10.226(2) ?, c = 13.404(3) ?, α = 82.02(3)°, β = 86.86(3)°, γ = 65.10(3)°, V = 1211.7(4) ?3 and Z = 2. 相似文献
6.
Abstract
Based on the polydentate ligand 3,5-bis(3-pyridyl)-1H-1,2,4-triazole (3,3′-Hbpt), three coordination compounds [Zn(3,3′-Hbpt)(ip)]·2H2O (1), [Zn(3,3′-Hbpt)(5-NO2-ip)]·H2O (2), and [Zn(3,3′-Hbpt)2(H2pm)(H2O)2]·2H2O (3) have been hydrothermally constructed with H2ip, 5-NO2-H2ip and H4pm as auxiliary ligands (H2ip = isophthalic acid, 5-NO2-H2ip = 5-NO2-isophthalic acid, H4pm = pyromellitic acid). Structural analysis reveals that Zn(II) ions serve as four-coordinated, five-coordinated, and six-coordinated connectors in 1–3, respectively, while 3,3′-Hbpt adopts μ-Npy and Npy coordination modes in two typical conformations in these target coordination compounds. Dependently the applied ligand, compounds 1–3 exhibit either 1D channel, cage or chain structures, respectively. In addition, the luminescence properties of 1–3 have been investigated in the solid state at room temperature. 相似文献7.
M. M. Monchak A. V. Pavlyuk V. V. Kinzhibalo M. G. Mys’kiv 《Russian Journal of Coordination Chemistry》2009,35(6):405-410
The alkylation of ethylenediamine with allyl bromide in the presence of a fourfold (with respect to ethylenediamine) molar
amount of NaHCO3 in acetone with an ethanol admixture (15: 1) affords LBr2 · 2H2O (I), where L2+ is the N,N,N,N′,N′,N′-hexaallylethylenediaminium cation. Single crystals of complexes L[CuII(Br0.45Cl3.55)] (II), L[Cu4I(Br4.55Cl1.45)] (III), and L[Cu4IBr6] (IV) are prepared by ac electrochemical synthesis from an ethanolic solution of LBr2 · 2H2O, CuCl2 · 2H2O (or CuBr2) at copper wire electrodes. The crystal structures of compounds I–IV are determined by X-ray diffraction analysis. The crystals of complex I are monoclinic: space group P21/n, a = 8.544(3), b = 10.404(3), c = 13.350(4) ?, β = 97.29(3)°, V = 1177.2(6) ?3, Z = 2. The bromine anions in compound I are bonded to the L2+ cations and water molecules through hydrogen contacts (E)H…Br (E = O, C) of 2.57(3)–2.86(3) ?. The crystals of compounds
II–IV are triclinic: space group P
. For II: a = 8.762(4), b = 9.163(4), c = 16.500(6) ?, α = 95.62(4)°, β = 96.39(4)°, γ = 111.46(4)°, V = 1211.4(9) ?3, Z = 2; for III: a = 9.074(4), b = 9.435(4), c = 9.829(5) ?, α = 116.12(4)°, β = 104.14(4)°, γ = 100.22(4)°, V = 692.3(6) ?3, Z = 1; for IV isostructural III: a = 9.084(4), b = 9.404(4), c = 9.869(4) ?, α = 116.31(3)°, β = 104.00(3)°, γ = 100.37(3)°, V = 692.1(5) ?3, Z = 1. Unlike the isolated tetrahedral CuX42− anion in structure II, an original chain anion (Cu4X62−)
n
is observed in the structures of π complexes III and IV.
Original Russian Text ? M.M. Monchak, A.V. Pavlyuk, V.V. Kinzhibalo, M.G. Mys’kiv, 2009, published in Koordinatsionnaya Khimiya,
2009, Vol. 35, No. 6, pp. 414–419. 相似文献
8.
Chang-Qing Wang Jie Han Mei-Li Pang Ji-Ben Meng 《Research on Chemical Intermediates》2010,36(3):301-307
A new biindenylidenedione compound, named [trans-anti-3,3′-Di-p-hydroxyl phenyl-3,3′-dihydroxy-[2,2′-bi-1H-indene]-1,1′-dione] (2) was synthesized and characterized by means of 1H-NMR, IR, MS and X-ray crystallographic diffraction techniques. The photochromic behavior was investigated by means of UV–Vis
spectroscopy, and the results showed that the inclusion complex of 2 with guest solvent N,N-dimethylformamide (DMF) did not exhibit photochromism in crystal state. The structure–property relation
was discussed briefly in context to the intermolecular interactions and the solvent-dependent effect on photochromism. 相似文献
9.
D. B. Vasilchenko I. A. Baidina E. Yu. Filatov S. V. Korenev 《Journal of Structural Chemistry》2009,50(2):335-342
[RhPy4Cl2]Cl·4H2O (I), [RhPy4Cl2]ReO4 (II), [RhPy4Cl2]ClO4 (III), and [RhPy4Cl2]ReO4·2H2O complex salts were synthesized. The crystal structure of compounds II (P4/ncc, a = 25.5655(3) ?, c = 14.3521(4) ?), III (P21/n, a = 13.5308(3) ?, b = 15.1044(5) ?, c = 23.3457(8) ?, β = 93.327°), and dyhydrate of II (Pbcm, a = 10.6199(9) ?, b = 10.4964(9) ?, c = 22.9834(16)?) was determined by X-ray diffraction analysis. The thermal transformations of the complexes were studied by
differential thermal analysis. The substances were characterized by IR spectroscopy, XRPA, and element analysis
Original Russian Text Copyright ? 2009 by D. B. Vasilchenko, I. A. Baidina, E. Yu. Filatov, and S. V. Korenev
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 2, pp. 349–356, March–April, 2009. 相似文献
10.
Wan-Yun Huang Zi-Lu Chen Kai Wang Xiang Zhou Fu-Pei Liang 《Transition Metal Chemistry》2012,37(3):291-296
Three isomorphous coordination polymers of general formula {[M(H2bna)·(DMF)2·(H2O)2]·DMF}n (M = Co for 1, Mn for 2, Ni for 3, respectively, where H4bna = 2,2′-dihydroxy-[1,1′]-binaphthalene-3,3′-dicarboxylate) were synthesized under solvothermal conditions and characterized
by FTIR, single crystal X-ray diffraction, thermogravimetric analysis, and X-ray power diffraction analysis. All three polymers
crystallize in the same monoclinic space group P21/n. The complexes are assembled into 1D helical chains, and each adjacent helical chain of the same chirality is further connected
to form a chiral layer by hydrogen bond interactions. The layers are packed in alternating left-(M) and right-handed (P) chirality arrays. Magnetic studies reveal the presence of antiferromagnetic coupling interactions in complexes 1 and 2. 相似文献
11.
Six new coordination polymers constructed from two structurally related ligands, 2,2′-bis(2-methylbenzimidazole) ether (L1)
and 2,2′-bis(2-ethylbenzimidazole)ether (L2), have been synthesized. They are [Cu(L1)(bz)2] (1), [Cu(L2)(bz)2] (2), [Zn2(L1)(m-bdc)2] (3), [Cd2(L2)(m-bdc)2(H2O)]2·H2O (4), [Zn(L1)(OH-bdc)-(H2O)] (5) and [Zn2(L2)(btca)] (6), where Hbz = benzoic acid, m-H2bdc = 1,3-benzenedicarboxylic acid, OH-H2bdc = 5-hydroxyisophthalic acid, and H4btca = 1,2,4,5-benzenetetracarboxylic acid. In 1 and 2, the bidentate N-donor ligands (L1 and L2) bridge neighboring metal
centers to form 1D single chains. The bz anions are attached on both sides of the chains. In 3 and 4, the N-donor ligands
(L1 and L2) in cis conformations bridge two metal centers to generate a [M2(L1)]4+ unit (M = Zn(II) and Cd(II)). The adjacent [M2(L1)]4+ units are further linked via the dicarboxylate anions to form 1D double chain structures. In 5, the Zn(II) cations are bridged
by OH-m-bdc anions to form an infinite polymeric chain. The L1 ligands are attached on one side of the chain in a monodentate mode.
In 6, two Zn(II) cations are bridged by two L2 ligands to form a [ZnL2]2
4+ ring, which is further linked by btca anions to generate a 2D layer. The luminescent properties of the ligands and 3–6 in
the solid state at room temperature were also studied. 相似文献
12.
L. A. Glinskaya R. F. Klevtsova T. G. Leonova S. V. Larionov 《Journal of Structural Chemistry》2000,41(1):161-165
While seeking molecular precursors for ZnS films obtained by gas phase chemical deposition [1, 2] we synthesized mixed-ligand
compounds ZnL(ROCS2)2 [R = i-Pr. /-Bu; L = 2,2′-bipyridyl (2,2′-Bipy), 1,10-phenanthroline (Phen)] [3]. The volatile complex Zn(2,2′-Bipy)(i-PrOCS2)2 was used as a precursor to obtain electroluminescent ZnS:Mn films [4]. According to XRD data, the compound Zn(Phen)(i-BuOCS2)2 is monomeric. The c.n. of zinc is six. The Phen and 1-B11OCS2 ions behave as cyclic bidentate ligands [3, 5]. It was assumed that other mixed-ligand complexes with Phen and 2,2′-Bipy
have an analogous structure [3]. Here we report on the structure of the known mixed-ligand complex of zinc(II) ethylxanthate
with 2,2′-bipyridyl [6, 7]. It was found that the behavior of alkylxanthate ligands in mixed-ligand complexes of zinc(II)
is more complex.
Translated from Zhumal Stmktumoi Khimii, Vol. 41, No. 1, pp. 196-201, January–February, 2000. 相似文献
13.
X. Chen P. Yang S. -L. Ma S. Ren M. -Y. Tang Y. Yang Z. -J. Guo L. -Z. Liu 《Journal of Structural Chemistry》2009,50(3):495-499
Two novel cyano-bridged complexes, {[Cu(men)2][Ni(CN)4]
n
(1) (men = N,N′-dimethyl-ethylenediamine) and [Mn(bpy)2]4[Mo(CN)8]2·0.5MeOH·0.75H2O (2) (bpy = 2,2′-bipyridine) have been synthesized and structurally characterized by IR spectroscopy and X-ray crystallography.
The complex 1 has onedimensional zigzag chain structure in which the Ni atom is coordinated by four cyanide groups, and the Cu atom is
surrounded by four nitrogen atoms of the two men ligands in equatorial plane and two nitrogen atoms of the bridging cyanide
in axial positions; the Cu centre is in a distorted octahedral environment. Owing to weak interactions, complex 1 is self-assembled into two-dimensional network via N-H...N hydrogen bonds. In 2, the basic structural unit is centrosymmetric and contains four Mn centers connected by two octacyanomolybdates via eight
cyanide bridges. Each Mo atom is linked via four cyanide groups to four Mn, and the other four cyanide groups are terminal.
From X-ray single crystal analysis (room temperature), 1 crystallizes in monoclinic space group P21/n with a = 6.7332(7) ?, b = 13.9248(15) ?, c = 9.0869(10) ?, β = 98.4030(10)°, V = 843.05(16) ?3, Z = 2; 2 crystallizes in monoclinic space group P21/n with a = 13.886(6) ?, b = 24.116(11) ?, c = 15.263(7) ?, β = 90.175(6)°, V = 5111(4) ?3, Z = 2.
Original Russian Text Copyright ? 2009 by X. Chen, P. Yang, S.-L. Ma, S. Ren, M.-Y. Tang, Y. Yang, Z.-J. Guo, and L.-Z. Liu
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 50, No. 3, pp. 518–521, May–June, 2009. 相似文献
14.
S. B. Artemkina M. S. Tarasenko A. V. Virovets N. G. Naumov 《Russian Journal of Coordination Chemistry》2012,38(4):257-263
Heterometallic chloride complexes [Mo5NbI8Cl6]
n− (n = 2, 3) are synthesized. The crystal structures of their salts are determined: for (Ph4P)2[Mo5NbI8Cl6] (I), triclinic crystal system, spacegroup P
[`1]\bar 1, a = 10.9886(6), b = 11.4604(5), c = 13.4343(7) ?, α = 66.124(2), β = 86.892(2), γ = 86.490(2)°, Z = 1, V = 1543.35(13) ?3; and for (4-MePyH)5[Mo5NbI8Cl6]Cl2 (II), monoclinic crystal system, space group C2/m, a = 16.4937(4), b = 14.7335(3), c = 11.6534(3) ?, β = 99.8750(10)°, Z = 2, V = 2789.94(11) ? The geometric parameters of compounds I and II and the conditions for the formation of the complexes with the charges −2 and −3 are discussed. 相似文献
15.
The kinetics of propene hydroformylation in the presence of the catalytic system Rh(acac)(CO)2/nL (L = 2,2′-bis[(1,1′-diphenyl-2,2′-diyl)phosphito]-3,3′,5,5′-tetra-tert-butyl-1,1′-diphenyl, 0.5 < n < 20) in para-xylene at 90°C is reported. At n ≥ 2, the rate and regioselectivity of the process are independent of the L concentration. The reaction is of positive fractional
order with respect to propene and hydrogen and of negative order with respect to CO. The molar ratio between the linear product
and the branched product decreases with an increasing CO pressure and increases with an increasing H2 pressure. The kinetic data are consistent with a process mechanism involving irreversible propene addition to the unsaturated
hydride complex HRh(CO)L with the formation of the π-complex HRh(CO)L(C3H6). The insertion of coordinated propene into the H-Rh bond of this complex is reversible in the linear aldehyde formation
route and is quasi-equilibrium in the branched isomer formation route. The conclusions as to the character of these reaction
steps are corroborated by the compositions of the but-1-ene and but-2-ene hydro-formylation products. 相似文献
16.
Mohamad Jaber Al-Jeboori Hasan Ahmad Hasan Worood A. Jaafer Al-Sa’idy 《Transition Metal Chemistry》2009,34(6):593-598
The new multidentate Schiff-base (E)-6,6′-((1E,1′E)-(ethane-1,2-diylbis(azan-1-yl-1-ylidene))bis(methan-1-yl-ylidene))bis(4-methyl-2-((E)(pyridine-2-ylmethylimino)methyl)phenol) H2L and its polymeric binuclear metal complexes with Cr(III), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II)
are reported. The reaction of 2,6-diformyl-4-methyl-phenol with ethylenediamine in mole ratios of 2:1 gave the precursor 3,3′-(1E,1′E)-(ethane-1,2-diylbis(azan-1-yl-1ylidene))bis(methan-1-yl-1-ylidene)bis(2-hydroxy-5-methylbenzaldehyde) W. Condensation of the precursor with 2-(amino-methyl)pyridine in mole ratios of 1:2 gave
the new N6O2 multidentate Schiff-base ligand H2L. Upon complex formation, the ligand behaves as a dibasic octadentate species with the involvement of the nitrogen atoms
of the pyridine groups in coordination for all complexes. The mode of bonding and overall geometry of the complexes were determined
through physico-chemical and spectroscopic methods. These studies revealed octahedral geometries for Cr(III), Mn(II), Fe(II),
Co(II), Ni(II), Cu(II), Cd(II) and Hg(II) complexes of general formulae [Cr2III(L)Cl2]Cl2, [Ni2II(L)(H2O)2]Cl2 and [M2(L)Cl2] and five co-ordinate Zn(II) complex of general formula [Zn2II(L)]Cl2. 相似文献
17.
Nucleophilic substitution of Pd(RaaiR′)Cl2 [(RaaiR′ = 1-alkyl-2-(arylazo)imidazole, p-R-C6H4-N=N-C3H2NN-1-R′; where R = H(a)/ Me(b)/ Cl(c) and R′ = Et(1)/Bz(2)] with 2-Mercaptopyridine (2-SH-Py) in acetonitrile (MeCN) at 298 K, to form [Pd2(2-S-Py)4], has been studied spectrophotometrically under pseudo-first-order conditions and the analyses support the nucleophilic association
path. The reaction follows the rate law, Rate = {k
0 + k [2-SH-Py]
0
2
}[Pd(RaaiR′)Cl2]: first order in Pd(RaaiR′)Cl2 and second order in 2-SH-Py. The rate of the reaction follows the order: Pd(RaaiEt)Cl2
(1) < Pd(RaaiBz)Cl2
(2) and Pd(MeaaiR′)Cl2 (b) < Pd(HaaiR′)Cl2 (a) < Pd(ClaaiR′)Cl2 (c). External addition of Cl− (LiCl) and HCl suppresses the rate (Rate ∝ 1/[Cl−]0 & ∝1/[HCl]0). The reactions have been studied at different temperatures (293–308 K) and activation parameters (Δ‡ H° and Δ ‡ S°) of the reactions were calculated from the Eyring plot and support the proposed mechanism. 相似文献
18.
A DTA study of thermal decomposition of (NH4)2[Ru(NO)Cl5] in helium atmosphere has been carried out, a synthetic procedure for preparation of the trans-diammine complex mer-[Ru(NO)(NH3)2Cl3] (I) with yield ∼70% has been developed. On re-crystallization of I from aqueous solution a trans-aquanitroso complex [Ru(NO)(NH3)2Cl2(H2O)]Cl·H2O (II) has been isolated. The structures of the compounds have been determined by single crystal X-ray diffraction: space group
Pbcn, a = 6.607(1) ? b = 11.255(2) ? c = 9.878(2) ? (I) and space group Ima2, a = 8.3032(3) ?, b = 8.0890(2) ?, c = 15.9192(5) ? II).
Original Russian Text Copyright ? 2008 by M. A. Il’in, V. A. Emel’yanov, and I. A. Baidina
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 49, No. 6, pp. 1128–1136, November–December, 2008. 相似文献
19.
I. B. Baranovskii M. D. Surazhskaya G. G. Aleksandrov M. A. Golubnichaya 《Russian Journal of Inorganic Chemistry》2008,53(7):1055-1060
The reaction of chlorine with triamine [PtEnPyCl3]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile
isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy(NH2CH2CN)Cl4] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro
complex [PtPy(NClCH2CH2NH2)Cl3] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) ?, b = 11.413(2) ?, c = 9.979(2) ?, V = 1244.3(4) ?3, Z = 8, R
hk1
= 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C≡N 1.07(2) ?, angle C-C≡N 178(1)°. Compound III: space group P21/n, a = 7.3016(8) ?, b = 7.8879(9) ?, c = 22.336(2) ?, β = 96.107(2)°, V = 1279.1(2) ?3, Z = 4, R
hk1
= 0.0808, N-Cl = 1.77(2) ?.
Original Russian Text ? I.B. Baranovskii, M.D. Surazhskaya, G.G. Aleksandrov, M.A. Golubnichaya, 2008, published in Zhurnal
Neorganicheskoi Khimii, 2008, Vol. 53, No. 7, pp. 1136–1141. 相似文献
20.
The H-shaped block copolymers (PTMSPMA)2-PEG(PMPSTMSPMA)2 with two compositions, (EG)91-b-(TMSPMA)92 and (EG)455-b-(TMSPMA)176 have been successfully synthesized by atom transfer radical polymerization (ATRP) of tri(methoxylsilyl)propyl methacrylate
(TMSPMA) at room temperature in methanol. The initiation system applied was composed of 2,2-bis(methylene α-bromoisobutyrate)propionyl
terminated poly(ethylene glycol) (Br2PEGBr2) with M
n = 4000 or 2000, CuBr and 2,2′-bipyridine. The macroinitiator, Br2PEGBr2, was prepared by the reaction of two hydroxyl groups terminated PEG with 2,2-bis(methylene α-bromoisobutyrate)propionyl chloride.
The NMR spectroscopy and GPC measurements were used to characterize the structure and molecular weight and molecular weight
distribution of the resultant copolymers. The H-shaped block copolymers Sam 1 and Sam 2 were self-assembled in DMF/water mixtures
and then the trimethoxysilyl groups in PTMSPMA were cross-linked by condensation reaction in the presence of triethylamine.
Stable large-compound vesicles with 10 nm diameter of cavities were formed for Sam 1 which contains a short PEG chain. However,
the self-assembling of the Sam 2 in the selective solvents resulted in big vesicles aggregates. These two different morphologies
of aggregates are attributed to their relative chain length of water soluble PEG. The vesicles formed from Sam1 with short
PEG chains have big surface energy which will lead them to self-assemble further, forming large-compound vesicles.
__________
Translated from Acta Polymerica Sinica, 2007, 10: 974–978 [译自: 高分子学报] 相似文献