Analysis of average primary gamma-transition intensities and cross sections of the113Cd(n, γ) reaction

A combined analysis of the available data on the primaryγ-ray intensities from the¹¹³Cd(n, γ) reaction atE _n=1.9 and 24.3 keV neutron energies together with the data on¹¹³Cd neutron capture cross sections in theE _n=3–200 keV energy region was carried out. The neutron strength functions were determined asS _n0=(0.260±0.073) 10^?4 and S_n1=(5.06±0.67) 10^?4. No spin-orbit splitting of thep-wave neutron strength function was found. The energy dependence of theE 1 radiative strength function {ie147-01} was fitted by the Kadmenski-Furman model somewhat better than by a standard Lorentzian. TheM 1 giant resonance parameters were obtained as E _G ^{M 1} =8.8±1.6 MeV and Γ _G ^{M 1} = 4.7±2.6 MeV. The neutron capture cross section of¹¹³Cd from its isomeric state ({ie147-02}=11/2^?, E ₁ ^m =263.7 keV) was calculated.     

IsoscalarE2 transition strengths in 10≦A≦48 nuclei

Electric quadrupole transition strengths for the 2 ₁ ⁺ ,T=1→0 ₁ ⁺ ,T=1γ-decay branches are summarized for 10≦A≦42 nuclei. In¹⁰B the corresponding branch has been remeasured by use of the⁹Be(p, γ)¹⁰B resonance reaction atE _p =320 keV; an upper limit of 0.6% is found. The variation of theE2 strengths within each individualT=1 isobaric multiplet reveals the particleor hole-character of the levels involved. The isoscalar 2 ₁ ⁺ →0 ₁ ⁺ transition strengths in 10≦A≦48 nuclei vary between 2 and 20 Weißkopf units showing drastic shell effects. Results for the ratio of neutron and proton matrix elements deduced from analogγ-decay studies and from inelastic pion scattering are compared.     

Atomic-vacancy ordering in the lowest tungsten carbide W2C

Atomic-vacancy ordering in the lowest tungsten carbide W₂C with an L′3-type basic hexagonal structure has been studied by neutron diffraction and X-ray diffraction. In the temperature range 2700–1370 K, the only ordered phase of the lowest tungsten carbide is shown to be the trigonal ?-W₂C phase (space group P $\overline 3 $ 1m). This trigonal ?-W₂C phase is found to form via a disorder-order phase transition channel, which includes three superstructure vectors (k ₁₅ ⁽¹⁾ , k ₁₅ ⁽²⁾ , k ₁₇ ⁽¹⁾ ) of two Lifshitz stars ({k ₁₅}, {k ₁₇}, and to be described by two long-range order parameters (η₁₅, η₁₇). The distribution function of carbon atoms in the trigonal ?-W₂C superstructure is calculated, and the corresponding region of the allowable values of the long-range order parameters η₁₅ and η₁₇ is found. Symmetry analysis of other possible superstructures of the lowest tungsten carbide W₂C is performed, and the physically acceptable sequence of phase transformations in W₂C is determined.     

The crystal structure and magnetic properties of the 1-dimensional dihalide-bridged polymers dichlorobis(thiazole)cobalt(II) and dibromobis(thiazole)-cobalt(II)

The isostructural polymeric compounds Co(thiazole)₂X₂ (X=Cl (1), Br(2)) have been synthesised by the addition of thiazole to an ethanolic solution of the corresponding anhydrous cobalt halide. Powder X-ray and neutron diffraction measurements were used for structural determination. The structures were determined using powder neutron diffraction data and Rietveld techniques: (1) C2/c, a=17.806(2) Å, b=3.6806(6) Å, c=14.807(3) Å, β=94.78(1)°, V=967.1(3) ų, Z=4; (2) C2/c, a=18.079(3) Å, b=3.8138(8) Å, c=15.022(4) Å, β=92.71(1)°, V=1034.6(4) ų, Z=4. Each linear polymer chain is composed of pseudo-octahedral, high-spin Co²⁺ centres, doubly linked by halide bridges. Magnetisation measurements of 1 and 2 at 5 K between 0 and 10 kG reveals a metamagnetic transition between antiferromagnetic and ferromagnetic states. Low temperature susceptibility data have been fitted to a one-dimensional Ising model with a mean field correction and were found to be anisotropic with ferromagnetic intrachain interactions along the b-axis and weaker antiferromagnetic interchain interactions.     

A new molecular C60 complex with bis(methylenedithio)tetrathiafulvalene (BMDT-TTF): Synthesis, crystal structure, and properties

A new molecular C₆₀ complex of the composition (BMDT-TTF) · C₆₀ · 2CS₂ (I) with the bis(methylenedithio)tetrathiafulvalene (BMDT-TTF) organic donor is synthesized. The molecular and crystal structures of this complex are determined by x-ray diffraction. The (BMDT-TTF) · C₆₀ · 2CS₂ (I) compound crystallizes in a monoclinic crystal system. The main crystal data are as follows: a=13.550(5) Å, b=9.964(7) Å, c=17.125(8) Å, β=99.52(4)°, V=2280(2) ų, M=1229.45, and space group P2₁/m. Crystals of I have a layered structure: layers consisting of C₆₀ molecules alternate with layers composed of BMDT-TTF and CS₂ molecules. It is found that, in complex I, the donor and C₆₀ molecules are linked through the shortest contacts, which leads to a change in the molecular geometry of BMDT-TTF. The donor molecules in a crystal layer are characterized by the shortest S...S contacts. The IR data indicate the electroneutrality of the fullerene molecule. The electrical conductivity of (BMDT-TTF) · C₆₀ · 2CS₂ single crystals is measured using the four-point probe method at room temperature: σ_RT=2×10^?5 Ω^?1 cm^?1.     

Heavy-light meson spectroscopy and Regge trajectories in the relativistic quark model

The masses of the ground, orbitally and radially excited states of heavy-light mesons are calculated within the framework of the QCD-motivated relativistic quark model based on the quasipotential approach. Both light (q=u,d,s) and heavy (Q=c,b) quarks are treated fully relativistically without application of the heavy-quark 1/m _Q expansion. The Regge trajectories in the (M ²,J) and (M ²,n _r ) planes are investigated and their parameters are obtained. The results are in good agreement with available experimental data except for the masses of the anomalous $D^{*}_{s0}(2317)$ , D _s1(2460) and $D_{sJ}^{*}(2860)$ states.     

Parametrization of two-body perturbation on atomic fine and hyperfine structure. The configuration (6p)3 in the bismuth atom

A method of simultaneous parametrization of one- and two-body interactions on atomic hyperfine structure of configurationl ^N is proposed and applied for the analysis of the configuration (6p)³ in the bismuth atom. For this purpose, the hyperfine structure splittings of the levels²D ₃ ^2/0 ,²D ₅ ^2/0 and²P ₁ ^2/0 were measured. The finally obtained values of HFS parameters are: for one-body parameters (in MHz):a _p ⁰¹ =2,537(9),a _p ¹² =5,182 (12),a′¹⁰=?2,019(10),b _p ⁰² =?3,198(53),b _p ¹¹ =2,816(54); for two-body parameters (in MHz):x _pp ^′/01 ,₂=284(3),x _pp ^′/12 ,₂=581(5),x _pf ^′/12 ,₂=170(70),x _pp ^′/02 ,₂=?359(36),x _pf ^′/02 ,₂=?33(100). The value of the quadrupole moment of the nucleus ₈₃ ²⁰⁹ Bi is also discussed.     

The crystal structures of the ion conductors (NH+4)Zr2(PO4)3and (H3O+)Zr2(PO4)3

The crystal structures of (NH⁺₄)Zr₂(PO₄)₃ and (H₃O⁺)Zr₂(PO₄)₃ have been determined from neutron time-of-flight powder diffraction data obtained at 15 K. Both compounds are rhombohedral, $\text{R}\text{3}\text{c}$, with cell parameters a=8.7088(1) and c=24.2197(4) Å for the ammonium compound and a=8.7528(2), c=23.6833(11) Å for the hydronium compound. In both cases the ions are completely localized in the type I cavities and hydrogen bonded to lattice oxygens. The measured unit cell parameters are relatively large for this class of compounds but the entrance ways into the cavities are still too small to allow for unrestricted movement of the ions. Thus the low conductivity of the hydronium ion is related to this and other structural features.     

New spectral representation and evaluation of f π and the quark condensate \left\langle {\bar qq} \right\rangle in the terms of string tension

New spectral representations for f _π and chiral condensate are derived in QCD and used for calculations in the large-N _c limit. Both quantities are expressed in this limit through string tension σ and gluon correlation length T _g without fitting parameters. As a result, one obtains $\left\langle {\bar qq} \right\rangle = - N_c \sigma ^2 T_g a_1 $ , $f_\pi = \sqrt {N_c } \sigma T_g a_2 $ , with a ₁=0.0823, a ₂=0.30. Taking σ=0.18 GeV² and T _g=1 GeV^?1, as known from analytic and lattice calculations, this yields $\left\langle {\bar qq} \right\rangle $ (μ=2 GeV)=?(0.225 GeV)³, f _π=0.094 GeV, which is close to the standard values.     

Neutron hole states in theN=81 nuclei

The energy spectra of theN=81 nuclei have been calculated by coupling the neutron single-hole motion to the quadrupole vibrations of the nuclear surface. The wave functions are used to calculateM1 andE2 moments. Gamma-ray branching ratios are extensively discussed and compared with the many experimental data on ₅₄ ¹³⁵ Xe₈₁, ₅₈ ¹³⁹ Ce₈₁ and ₆₀ ¹⁴¹ Nd₈₁. Also spectroscopic factors for (p,d) reactions have been calculated and compared to experimental single-neutron pick-up reactions. The excitation energy and the lifetime of the isomeric stateπ ^π, decaying by anM4 transition, are studied, in particular in their dependence on the number of extra protons. The behaviour of the centroid of the neutron single-hole energies as a function of the number of extra protons is calculated with a delta force for the neutron-proton interaction.     

Synthesis, crystal structure, and spectroscopic study of K0.92(2) Zn0.08(2) H1.92(2) (PO4) (Zn-KDP)

The structure of K0.92₍₂₎ Zn_0.08(2) H_1.92(2) (PO₄) was determined using single-crystal X-ray diffraction. The crystal structure of the Zn-KDP belonged to the tetragonal space group $ \mathrm{I}\overline{4}2\mathrm{d} $ , with cell parameters of a?=?b?=?7.4487(5)?Å and c?=?6.9703(5)?Å, 386.73(5) Å3, Z?=?4, and R?=?0.023. Zn²⁺ ions were used as substitutes for K⁺ ions with hydrogen vacancy. The Zn-KDP single crystals were submitted to further Raman, infrared, and ¹H NMR studies to investigate chemical group functionalisation, possible bonding between the organic and inorganic materials, and partial substitution of K⁺ by Zn²⁺. The latter partial substitution was confirmed by the deviation of IR frequencies for O–H stretching, the variation of IR and Raman frequencies for stretching and bending vibrations ν(PO₄) of H₂PO₄, and the appearance of additional Raman (147, 386 and 481 cm^?1) vibrational bands. Electrical conductivity measurements were performed on polycrystalline pellets of Zn-KDP and pure KDP at room temperatures (RT) of up to 473K. In both cases, a conductivity jump close to 453K was observed, and a stronger increase of conductivity was measured.     

Nanoscale distortions of the lattice of a ZnSe crystal doped with 3d elements

The structure of semiconductor crystals Zn_1?x V _x ²⁺ Se (x = 0.0018) and Zn_1?x Cr _x ²⁺ Se (x = 0.0006) was studied for the first time using thermal neutron diffraction at 300 and 120 K. The diffraction patterns of the crystals were revealed to contain diffuse scattering regions near the Bragg reflections of the initial cubic lattice. The experimental results are discussed in combination with earlier obtained data on neutron diffraction and propagation of ultrasonic waves in Zn_1?x Ni _x ²⁺ Se (x = 0.0025) and Zn_1?x Cr _x ²⁺ Se (x = 0.0029). The diffuse scattering is shown to be due to nanoscale shear strains of the ZnSe lattice. The character of these strains is determined by Jahn-Teller 3d ions.     

Microscopic foundation of the interacting boson model in thes d-shell nuclei

Starting from an isospin invariant shell-model hamiltonian, we describe a method for deriving microscopically the IBM-hamiltonian appropriate to lights d-shell nuclei. The key ingredients of our approach are:a) the Belyaev-Zelevinsky-Marshalek (BZM) bosonization procedure;b) two successive unitary transformations that extract the “maximally decoupled” collective bosons with angular momentaJ=0(s _ππ ⁺ ,s _νν ⁺ ,s _πν ⁺ ) andJ =2(d _ππ ⁺ ,d _νν ⁺ ,d _πν ⁺ (T=0),d _πν ⁺ (T=1)). The method is applied to obtain the low-energy spectra and the electron scattering form factors for the 0 ₁ ⁺ →2 ₁ ⁺ transitions in²⁰Ne and²⁴Mg. Good agreement with the exact shell-model results is achieved. The inclusion of proton-neutron bosons (s _πν ⁺ ,d _πν ⁺ (T=1),d _πν ⁺ (T=0)), as well as the renormalization of boson parameters due to the non-collective degrees of freedom, are shown to play a crucial role.     

The magnetic moment of the 10+ isomer in140Ce andE1 transitions inN=82 isotones caused by outer subshell configurations

Using the reaction¹³⁸Ba(α,2n)¹⁴⁰Ce the magnetic moment of the 10 ₁ ⁺ isomer atE _x =3714.7 keV in theN=82 nucleus¹⁴⁰Ce has been determined by means of the TDPAD method toμ=+10.3(4)μ _N . Measuredg-factors in¹⁴⁰Ce are compared to calculations within the shell model with configuration mixing. For the 10 ₁ ⁺ isomer in¹⁴⁰Ce the four proton configuration π(1g ₇ ^2/2 ,2d ₅ ^2/2 ) has been found to be dominant. From theg-factor measurement strong contributions of multiparticle excitations to thegp2d _3/2,π3s ₁ ² or π1h ₁₁ ² shells and admixtures of neutron excitations to the wave function of the 10 ₁ ⁺ state could be excluded. The strongE1γ-branch of the deexcitation of the 10 ₁ ⁺ isomer in¹⁴⁰Ce can be explained by means of small admixtures of configurations which contain the outer subshell excitationsπ2f _7/2 andπ1h _9/2. On this basisE1 transitions experimentally observed in theN=82 nuclei¹⁴⁰Ce,¹⁴¹Pr and¹⁴⁵Eu may be understood.     

Measurement of the axial-vector to vector coupling constant, ¦g 1/f 1¦, in Σ−→ne − \bar v decay

The ratio of the axial-vector to vector coupling constant, ¦g ₁/f ₁¦, in theΣ ^?→ne ^? \(\bar v\) decay was determined from the electron-neutrino angular distribution. In a sample of 454Σ ^?→ne ^? \(\bar v\) decays a search was made for subsequent neutron proton scattering in order to detect the decay neutrons. TheΣ hyperons were produced by stoppingK ^?-mesons in the 81 cm Saclay hydrogen bubble chamber. For the kinematical analysis 33Σ ^?→ne ^? ν events with associatednp→np interactions were accepted. The value ¦g ₁/f ₁¦=0.37 _?0.19 ^+0.26 was obtained.     

Electron (positron) impact excitation (2p state) of lithium at intermediate energies

In this work, studies have been carried out to investigate theoretically the electron (positron)-impact-induced 2s → 2p lithium (Li) transition at 20 and 60 eV using the coupled-channel optical method (CCOM). The inelastic differential cross sections (DCS) together with the reduced Stokes parameters ( $\bar P_1$ , $\bar P_2$ , $\bar P_3$ ) and other parameters such as the alignment (γ, $\bar P_l$ ), orientation (L _⊥) and coherence parameters (P ⁺) are reported in the present calculations. Comparison is made with other available theoretical and experimental measurements.     

ΛΛ 6 He and Λ 9 Be systems in the three-body cluster model treated on the basis of differential Faddeev equations

The _ΛΛ ⁶ He and _Λ ⁹ Be hypernuclei are treated as the S=0, T=0 (for the former) and S=1/2, T=0 (for the latter) bound states of the three-cluster systems ΛΛα and Λαα, respectively. The cluster-reduction method is used to solve the s-wave differential Faddeev equations for these systems. On the basis of the MT I–III model, the ΛΛ interaction potential is specified in the form $V_{\Lambda \Lambda } = \frac{2}{3}V_{NN} $ . Phenomenological potentials are used to describe Λα and αα interactions. The binding energies of the _ΛΛ ⁶ He and _Λ ⁹ Be hypernuclei and the parameters of low-energy Λ-hyperon and α-particle scattering on a _Λ ⁵ He hypernucleus are calculated. It is shown that the proposed ΛΛ interaction potential makes it possible to reproduce faithfully the binding energy of the _ΛΛ ⁶ He hypernucleus and that scattering in the Λ _Λ ⁵ He system is similar to neutron scattering on a deuteron.     

Study of spin-wave dynamics in Fe65Ni35 ferromagnetic via small-angle polarized-neutron scattering

The results of studying the spin dynamics of a classical Fe₆₅Ni₃₅ invar alloy are presented and analyzed. The investigations are performed via small-angle polarized-neutron scattering in the oblique geometry of a magnetic field at various temperatures (T < T _C). This approach is based on the analysis of left-right asymmetry in the magnetic scattering of polarized neutrons. The asymmetry effect arises when the magnetization direction of a sample is inclined with respect to the wave vector of the incident beam. The spin-wave scattering is concentrated within a range bounded by the cutoff angle θ_c determined by the magnetic field: θ _c ² (H) = θ ₀ ² ?(gμ_B H)θ₀/E, where \(\theta _0 = \hbar ^2 \frac{1} {{2Dm_n }}\) , H is the external magnetic field, E is the initial neutron energy, D is the spin-wave stiffness constant, and m _n is the neutron mass. The scattering is blurred by spinwave damping in the vicinity of the cutoff angle. The spin-wave stiffness constant can be obtained from a comparison of the asymmetric contribution to scattering and a model function. The temperature dependence D = D(T) is well defined by the expression D = D ₀ |τ| ^x , where \(\tau = 1 - \frac{T} {{T_C }}\) , x = 0.47 ± 0.01, D ₀ = 137 ± 3 meVŲ, and τ > 0.1 in the entire temperature range. The given method enables us to construct the temperature dependence of the spin-wave stiffness constant with a high accuracy and a small step.     

The crystal structure of bis-(L-threonine) copper(II).H2O

The crystal structure of bis-(L-threonine) copper (II).H₂O, Cu (C₄H₈NO₃)₂.H₂O has been determined by heavy atom and Fourier methods and refined by least-squares using visually estimated three-dimensional x-ray data of 893 reflections. The blue crystals are monoclinic, space groupP2₁ withα=11·02,b=4·90,c=11·16Å andβ=93·5°,Z=2. The finalR is 0·10. Coordination of copper is distorted square pyramidal with ligands intrans configuration. The conformation of one of the aminoacid ligand is identical with L_s-Threonine while the other has a conformation with torsional angleχ ^{1, 2}=?74(1)°.