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1.
1.5at% Eu-doped GaN powders were prepared by a co-precipitation method.Powder X-ray diffraction(XRD)results shows that there is only the wurtzite phase.Cathodoluminescence spectra were measured at room temperature and liquid nitrogen temperature,respectively.The band-to-band luminescence of GaN was shifted from 373 nm to 368 nm with the temperature decreasing from room temperature to liquid nitrogen temperature.The luminescence peaks at 537,557,579,590,597,614,653 and 701 nm are attributed to the Eu ions related transitions in the host of GaN powders and the peak positions were not influenced by the variation of temperature.With the increase of accelerating voltage,the intensity of all luminescence peaks was increased.The strongest luminescence peak at 614 nm shows non-symmetrical shape and is composed of 612,615 and 621 nm through Lorentzian fitting,which indicates there are oxygen and nitrogen environments of the Eu3+ions in the Eu-doped GaN powders. 相似文献
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Whispering-gallery-mode (WGM) microresonators are used as optical transducers for sensing applications. The typical detection scheme is based on tracking the WGM resonance shift, by scanning with a tunable laser, when a change of the refractive index in the region probed by the WGM takes place. We propose a sensing approach based instead on monitoring the position of the laser line of a fiber ring laser having a WGM microsphere in its loop. We have demonstrated that the induced shift is the same for the ring laser line and for the microsphere resonance. The proposed method requires simpler, cheaper equipment and may also improve the sensor resolution because the ring laser line is much narrower than the microsphere WGM resonance. 相似文献
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BaFBr:Eu^2 是利用色心存储电子-空穴对并用可见光激励读出存储信息(产生Eu^2 的4f^65d→4f^7的跃迁)的优良的光激励发光材料。通过热释发光技术研究了BaFBr:Eu^2 的热激活行为,对其低温段和高温段的热释发光峰分别进行了归属,通过对BaFBr:Eu^2 以及掺杂Na^ 或Al^3 的BaFBr:Eu^2 的热释发光(TL)谱和光激励发光(PSL)谱的表征,指出在BaFBr:Eu^2 中掺杂Na^ 或Al^3 影响了F(Br^-)色心,使其陷阱深度变涛,并从理论上加以计算,得出的热致激发能量的变化与光致激光能量的变化能很好地吻合。 相似文献
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D. Ristić A. Chiappini M. Mazzola D. Farnesi G. Nunzi-Conti G.C. Righini P. Féron G. Cibiel M. Ferrari M. Ivanda 《The European physical journal. Special topics》2014,223(10):1959-1969
The properties of whispering gallery modes (WGM) of a microsphere can be tailored by coating the resonator with a thin film. If the coating has a higher refractive index than the microsphere core, the resulting structure will have a configuration which has similarities both with a classical WGM resonator and with a planar waveguide. By choosing the film thickness and refractive index we can tailor the degree of confinement of the WGMs inside the sphere core, coating and surrounding medium, which will in turn influence the WGMs contact with its surroundings. We present a study of the effect of the coating on the WGM mode profiles in particular of a silicon coating on a silica sphere. 相似文献
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As an optically pumped device, the lasing characteristics of a spherical microcavity laser depend on the optical pumping processes. These characteristics can be described in term of the Q factor and the optical field distribution in a microsphere. We derived analytical expressions and carried out numerical calculation for Q factor and optical field. The Q factor is found to be oscillatory functions of the radius of a microsphere and the pumping wavelength, and the pumping efficiency for a resonating microsphere is much higher than that for an anti-resonating microsphere. Using tunable lasers as pumping sources is suggested in order to achieve a higher pumping efficiency. Numerical calculation on optical field distribution in spherical microcavities shows that a well focused Gaussian beam is a suitable incident wave for cavity quantum electrodynamics experiments in which strong confinement of optical field in the center of a microsphere is requested, but higher order spherical wave should be used instead for exciting whispering-gallery-mode (WGM) microsphere lasers, for the purpose of favoring optical energy transferring to WGM in optical microspheres. 相似文献
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稀土有机配合物进行无机化能提高热稳定性,但无机化基质对稀土有机配合物的荧光性影响较大,采用PEG3400对复合体进行改性,有利于改善荧光性.文章采用溶胶-凝胶法合成Eu(BA)3/SiO2和Eu(BA)3/PEG400-SiO2复合发光材料.研究了PEG400掺入量对SiO2中Eu(BA)3发光性能的影响,PEG400作为路易斯硬酸和稀土离子配体增强了Eu(BA)3的发光性能.用红外光谱说明PEG400的掺人有利于减少发光材料中的结晶水和羟基数目.通过原子力显微镜分析了PEG400的掺入量对SiO2基质结构的影响. 相似文献
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S. V. Zaitsev A. N. Gruzintsev Yu. V. Yermolayeva N. A. Matveevskaya I. I. Zverkova G. A. Emelchenko A. V. Tolmachev 《JETP Letters》2017,106(3):145-151
The kinetics of luminescence of Eu3+ ions in Lu2O3:Eu nanospheres with diameters of 100–270 nm and a small standard deviation of the size distribution <15% has been studied. A sharp decrease in the decay time of luminescence of Eu3+ ions in the red range with an increase in the diameter of nanospheres has been attributed to the appearance of a photon mode accelerating spontaneous luminescence, which is confirmed by the calculation of ranges of existence of whispering-gallery modes in studied nanospheres. 相似文献
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用溶胶-凝胶法制备以Eu-苯甲酸-1,10-菲咯啉为掺杂剂的SiO2,SiO2-B2O3和SiO2-B2O3-Na2O为基质的发光材料.材料经1000℃退火处理后,结构十分稳定.通过激发光谱和发射光谱、红外光谱、TEM、XRD研究了基质结构对Eu3 发光性能的影响.结果显示:在589和614 nm处显示Eu3 的特征发射带,对应于Eu3 的5D0→7Fj(j=1,2)跃迁;与直接掺入EuCl3的玻璃材料相比,以Eu-苯甲酸-1,10-菲咯啉为掺杂剂的玻璃材料,虽然Eu的掺杂量较小,但Eu的发光强度较大.与以SiO2为基质的玻璃材料相比,以SiO2-B2O3为基质的玻璃材料Eu3 的发光减弱,其红外光谱显示形成Si-O-B键,说明该结构对Eu3 的发光有猝灭作用,以SiO2-B2O3-Na2O为基质的玻璃材料Eu3 的发光明显增强,其红外光谱显示不存在SiOB键的振动吸收,可能是Na取代B的位置,形成Si-O-Na键,此结构对Eu3 的发光有一定的增强作用. 相似文献
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采用高温固相法制备了ACaPO4∶Eu2+,Nd3+(A=Li,K,Na)系列近红外发光材料,研究了材料中Eu2+对Nd3+的近红外发光的敏化作用。发现共掺Eu2+后,材料的Nd3+的近红外发光显著提高。同时考察了ACaPO4∶Eu2+可见荧光性能、ACaPO4∶Eu2+,Nd3+近红外荧光发光性能及其荧光寿命,研究了不同Eu2+的发射波长对Nd3+近红外发光的敏化效果,分析探讨了ACaPO4体系中Eu2+-Nd3+之间的能量传递机理。在ACaPO4(A=Li,K,Na)中,随基质的不同,Eu2+的发射峰有逐步红移的现象,与Nd3+的不同激发峰重叠程度也会发生明显的变化,表明Eu2+的荧光发射波长是影响能量传递的一个重要因素,可以推测发射波长处于500~550 nm之间的Eu2+对Nd3+近红外发光具有最佳的敏化效果。 相似文献
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用高温固相法制备了Sr2SiO4∶Eu2+,Nd3+发光材料,研究了样品中Eu2+对Nd3+的近红外发光敏化.发现Sr2SiO4基质中Eu2+的存在可以大大增强Nd3+的特征近红外发光.通过对样品中不同位置Eu2+荧光激发和发射光谱、荧光寿命以及Nd3+荧光光谱的研究,对Eu2+向Nd3+能量传递的机理进行了分析.在S... 相似文献
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In this work we demonstrate the formation of a new type of polariton on the interface between a cuprous oxide slab and a polystyrene microsphere placed on the slab. The evanescent field of the resonant whispering gallery mode (WGM) of the microsphere has a substantial gradient, and therefore effectively couples with the quadrupole 1S excitons in cuprous oxide. This evanescent polariton has a long lifetime, which is determined only by its excitonic and WGM component. The polariton lower branch has a well-pronounced minimum. This suggests that this excitation is localized and can be utilized for possible BEC. The spatial coherence of the polariton can be improved by assembling the microspheres into a linear chain. 相似文献
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新型稀土铕配合物Eu(o-BBA)3(phen)电致发光研究 总被引:1,自引:1,他引:0
研究了一种新的稀土配合物邻苯甲酰苯甲酸-1,10-菲咯啉-铕(Eu(o-BBA)3(phen))的电致发光特性.采用不同的电子传输层材料,制备了多种结构的有机电致发光器件及有机无机复合器件.比较了单层电致发光器件A:ITO/PVK:Eu/Al与有机无机复合器件B:ITO/PVK:Eu/ZnS/Al发光性能的不同.分析了采用无机半导体材料ZnS作为电子传输层的优点.研究结果表明采用无机的电子传输层,能有效地避免激基复合物的形成,提高器件的亮度同时保持稀土离子发光的色纯性. 相似文献
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采用低温燃烧合成(LCS)法制备了存储型上转换发光材料CaS∶Eu,Sm,并对其上转换发光机理进行了研究。研究表明:样品的激发光谱位于200~600nm之间,紫外或可见光均可有效地激发该材料来完成充能过程,且可见光激发占优势;样品的红外响应光谱范围为800~1600nm,由辅助激活离子Sm所形成的劈裂的深陷阱能级是该材料具有宽频谱红外转换特性的根本原因;样品的热释光谱高温峰值位于351.02℃,计算得到的陷阱能级深度为0.82eV,深度适中,利于激发能的储存和上转换发光的产生。 相似文献
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采用低温燃烧合成(LCS)法制备了存储型上转换发光材料CaS∶Eu,Sm,并对其上转换发光机理进行了研究.研究表明:样品的激发光谱位于200~600nm之间,紫外或可见光均可有效地激发该材料来完成充能过程,且可见光激发占优势;样品的红外响应光谱范围为800~1600nm,由辅助激活离子Sm所形成的劈裂的深陷阱能级是该材料具有宽频谱红外转换特性的根本原因;样品的热释光谱高温峰值位于351.02℃,计算得到的陷阱能级深度为0.82eV,深度适中,利于激发能的储存和上转换发光的产生. 相似文献
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Microlasers based on high quality(Q) whispering-gallery mode(WGM) resonance are promising low threshold laser sources for bio-sensing and imaging applications. In this Letter, dye-doped polymer microspheres were fabricated by a controlling emulsion solvent evaporation method. WGM lasing with low threshold and high Q factors was realized in an individual microsphere under femtosecond laser pumping. The slight change of environmental relative humidity(RH) can be monitored by measuring the shift of the lasing modes at the exposure of water molecules, which demonstrates the sensitivity is as high as 6 pm/RH%. The results would offer an insight into employing microlasers as sensors. 相似文献