Some Aspects of Stability for Semigroup Actions and Control Systems

The present paper introduces both the notions of Lagrange and Poisson stabilities for semigroup actions. Let \(S\) be a semigroup acting on a topological space \(X\) with mapping \(\sigma :S\times X\rightarrow X\) , and let \(\mathcal {F}\) be a family of subsets of \(S\) . For \(x\in X\) the motion \(\sigma _{x}:S\rightarrow X\) is said to be forward Lagrange stable if the orbit \(Sx\) has compact closure in \(X\) . The point \(x\) is forward \(\mathcal {F}\) -Poisson stable if and only if it belongs to the limit set \(\omega \left( x,\mathcal {F}\right) \) . The concept of prolongational limit set is also introduced and used to describe nonwandering points. It is shown that a point \(x\) is \( \mathcal {F}\) -nonwandering if and only if \(x\) lies in its forward \(\mathcal {F} \) -prolongational limit set \(J\left( x,\mathcal {F}\right) \) . The paper contains applications to control systems.     

Towards the Development of an Evolution Equation for Flame Turbulence Interaction in Premixed Turbulent Combustion

Flame turbulence interaction is one of the leading order terms in the scalar dissipation \(\left (\widetilde {\varepsilon }_{c}\right )\) transport equation [35] and is thus an important phenomenon in premixed turbulent combustion. Swaminathan and Grout [36] and Chakraborty and Swaminathan [15, 16] have shown that the effect of strain rate on the transport of \(\widetilde {\varepsilon }_{c}\) is dominated by the interaction between the fluctuating scalar gradients and the fluctuating strain rate, denoted here by \(\overline {\rho }\widetilde {\Delta }_{c}= \overline {\rho {\alpha }\nabla c^{\prime \prime }S_{ij}^{\prime \prime }\nabla c^{\prime \prime }}\) ; this represents the flame turbulence interaction. In order to obtain an accurate representation of this phenomenon, a new evolution equation for \(\widetilde {\Delta }_{c}\) has been proposed. This equation gives a detailed insight into flame turbulence interaction and provides an alternative approach to model the important physics represented by \(\widetilde {\Delta }_{c}\) . The \(\widetilde {\Delta }_{c}\) evolution equation is derived in detail and an order of magnitude analysis is carried out to determine the leading order terms in the \(\widetilde {\Delta }_{c}\) evolution equation. The leading order terms are then studied using a Direct Numerical Simulation (DNS) of premixed turbulent flames in the corrugated flamelet regime. It is found that the behaviour of \(\widetilde {\Delta }_{c}\) is determined by the competition between the source terms (pressure gradient and the reaction rate), diffusion/dissipation processes, turbulent strain rate and the dilatation rate. Closures for the leading order terms in \(\widetilde {\Delta }_{c}\) evolution equation have been proposed and compared with the DNS data.     

On the neutralization of bacterial spores in post-detonation flows

In multiple operational scenarios, explosive charges are used to neutralize confined or unconfined stores of bacterial spores. The spore destruction is achieved by post-detonation combustion and mixing of hot detonation product gases with the ambient flow and spore clouds. In this work, blast wave interaction with bacterial spore clouds and the effect of post-detonation combustion on spore neutralization are investigated using numerical simulations. Spherical explosive charges (radius, \(R_\mathrm{C}\) = 5.9 cm) comprising of nitromethane are modeled in the vicinity of a spore cloud, and the spore kill in the post-detonation flow is quantified. The effect of the mass of the spores and the initial distance, \(d^0\) , of the spore cloud from the explosive charge on the percentage of spores neutralized is investigated. When the spores are initially placed within a distance of 3.0 \(R_\mathrm{C}\) , within 0.1 ms after detonation of the charge, all the spores are neutralized by the blast wave and the hot detonation product gases. In contrast, almost all the spores survived the explosion when \(d^0\) is greater than 8.0 \(R_\mathrm{C}\) . The percentage of intact spores varied from 0 to 100 for 3.0 \(R_\mathrm{C}\) \( 8.0 \(R_\mathrm{C}\) with spore neutralization dependent on time spent by the spores in the post-detonation mixing/combustion zone.     

Stable disarrangement phases of elastic aggregates: a setting for the emergence of no-tension materials with non-linear response in compression

A recent field theory of elastic bodies undergoing non-smooth submacroscopic geometrical changes (disarrangements) provides a setting in which, for a given homogeneous macroscopic deformation \(F\) of the body, there are typically a number of different states \(G\) of smooth, submacroscopic deformation (disarrangement phases) available to the body. A tensorial consistency relation and the inequality \(\det G\le \det F\) that guarantees that \(F\) accommodates \(G\) determine the totality of disarrangement phases \(G\) corresponding to \(F\) , and it is natural to seek for a given \(F\) those disarrangement phases that minimize the Helmholtz free energy (stable disarrangement phases). We introduce these concepts in the particular context of continuous bodies comprised of many small elastic bodies (elastic aggregates) and in the context where disarrangements do not contribute to the Helmholtz free energy (purely dissipative disarrangements). In this setting, the Helmholtz free energy response \(G\longmapsto \varPsi (G)\) of the pieces of the aggregate determines the totality of disarrangement phases corresponding to \(F\) , which necessarily includes the phase \(G=F\) (compact phase) in which every piece of the aggregate undergoes the given macroscopic deformation \(F\) . When the response function \(\varPsi \) is isotropic and smooth, and when \(\varPsi \) possesses standard semiconvexity and growth properties, the body also admits phases of the form \(G=\zeta _{\min }R\) (loose phases) with \(R\) an arbitrary rotation, provided that \(\zeta _{\min }R \) satisfies the accommodation inequality \(\zeta _{\min }^{3}\le \det F\) . Loose phases, when available, achieve the global minimum \(\varPsi (\zeta _{\min }R)\) of the free energy and consequently are stable and stress-free. When \( \varPsi (G)\) has the specific form \(\varPsi _{\alpha \beta }(G)=(\alpha /2)(\det G)^{-2}+(\beta /2)tr(GG^{T})\) , with \(\alpha \) , \(\beta \) given elastic constants, we determine all of the disarrangement phases corresponding to \(F\) . These include not only the compact and loose phases, but also disarrangement phases \(G\) in which the stress \(D\varPsi (G)\) is uniaxial or planar. Our main result (“stability implies no-tension”) is the assertion that every stable disarrangement phase for \(\varPsi _{\alpha \beta }\) cannot support tensile tractions, and our treatment of elastic aggregates thus provides a natural setting for the emergence of no-tension materials whose response in compression is non-linear. Existing treatments of no-tension materials assume at the outset that the body cannot support tension and that the response in compression is linear.     

Miscible and Immiscible Foam Injection for Mobility Control and EOR in Fractured Oil-Wet Carbonate Rocks

Foam injection is a proven enhanced oil recovery (EOR) technique for heterogeneous reservoirs, but is less studied for EOR in fractured systems. We experimentally investigated tertiary \(\text {CO}_{2}\) injections, and \(\text {N}_{2}\) - and \(\text {CO}_{2}\) -foam injections for enhanced oil recovery in fractured, oil-wet limestone core plugs. Miscible \(\text {CO}_{2}\) and \(\text {CO}_{2}\) -foam was compared with immiscible \(\text {CO}_{2}\) - and \(\text {N}_{2}\) -foam as tertiary recovery techniques, subsequent to waterfloods, in fractured rocks with different wettability preferences. At water-wet conditions waterfloods produced approximately 40 % OOIP, by spontaneous imbibition. Waterflood oil recovery at oil-wet conditions was below 20 % OOIP, due to suppressed imbibition where water predominantly flowed through the fractures, unable to mobilize the oil trapped in the matrix. Tertiary, supercritical \(\text {CO}_{2}\) -mobilized oil trapped in the matrix, particularly at weakly oil-wet conditions, by diffusion. Recovery by diffusion was high due to small core samples, high initial oil saturation and a continuous oil phase at oil-wet conditions. Both immiscible \(\text {CO}_{2}\) - and \(\text {N}_{2}\) -foams and miscible, supercritical \(\text {CO}_{2}\) -foam demonstrated high ultimate oil recoveries, but immiscible foam was less efficient (30 pore volumes injected) compared to miscible foam (2 pore volumes injected) to reach ultimate recovery. This is explained by the capillary threshold pressure preventing the injected \(\text {N}_{2}\) gas from entering the matrix, verified by computed X-ray tomography, and the mobilized oil was displaced by the aqueous surfactant in the foam. At miscible conditions, there exists no capillary entry pressure between the oil-saturated matrix and the injected \(\text {CO}_{2}\) , allowing foam to invade the matrix for efficient oil recovery.     

Drainage of Capillary-Trapped Oil by an Immiscible Gas: Impact of Transient and Steady-State Water Displacement on Three-Phase Oil Permeability

In a previous paper (Dehghanpour et al., Phys Rev E 83:065302, 2011a), we showed that relative permeability of mobilized oil, $k_\mathrm{ro}$ , measured during tertiary gravity drainage, is significantly higher than that of the same oil saturation in other tests where oil is initially a continuous phase. We also showed that tertiary $k_\mathrm{ro}$ strongly correlates to both water saturation, $S_\mathrm{w}$ , water flux (water relative permeability), $k_\mathrm{rw}$ , and the change in water saturation with time, $\mathrm{d}S_\mathrm{w}/\mathrm{d}t$ . To develop a model and understanding of the enhanced oil transport, identifying which of these parameters ( $S_\mathrm{w},\,k_{\mathrm{rw}}$ , or $\mathrm{d}S_\mathrm{w}/\mathrm{d}t$ ) plays the controlling role is necessary, but in the previous experiments these could not be deconvolved. To answer the remaining question, we conduct specific three-phase displacement experiments in which $k_{\mathrm{rw}}$ is controlled by applying a fixed water influx, and $S_\mathrm{w}$ develops naturally. We obtain $k_{\mathrm{ro}}$ by using the saturation data measured in time and space. The results suggest that steady-state water influx, in contrast to transient water displacement, does not enhance $k_{\mathrm{ro}}$ . Instead, reducing water influx rate results in excess oil flow. Furthermore, according to our pore scale hydraulic conductivity calculations, viscous coupling and fluid positioning do not sufficiently explain the observed correlation between $k_{\mathrm{ro}}$ and $S_{\mathrm{w}}$ . We conclude that tertiary $k_{\mathrm{ro}}$ is controlled by the oil mobilization rate, which in turn is linked to the rate of water saturation decrease with time, $\mathrm{d}S_\mathrm{w}/\mathrm{d}t$ . Finally, we develop a simple model which relates tertiary $k_{\mathrm{ro}}$ to transient two-phase gas/water relative permeability.     

Incompressible 3D Navier–Stokes Equations as a Limit of a Nonlinear Parabolic System

In this paper, we consider the Cauchy problem for a nonlinear parabolic system ${u^\epsilon_t - \Delta u^\epsilon + u^\epsilon \cdot \nabla u^\epsilon + \frac{1}{2}u^\epsilon\, {\rm div}\, u^\epsilon - \frac{1}{\epsilon}\nabla\, {\rm div}\, u^\epsilon = 0}$ in ${\mathbb {R}^3 \times (0,\infty)}$ with initial data in Lebesgue spaces ${L^2(\mathbb {R}^3)}$ or ${L^3(\mathbb {R}^3)}$ . We analyze the convergence of its solutions to a solution of the incompressible Navier?CStokes system as ${\epsilon \to 0}$ .     

Microsize and initial pressure effects on shock wave propagation in a tube

In this paper, the shock wave propagation in a channel with a micrometric hydraulic diameter is numerically simulated for an initial Mach number \(M_{s}=2.61\) . The obtained values of the Mach number along the tube are compared to experimental and numerical data given in the literature. The microscale effects on the flow behavior, such as shock wave attenuation and pressure increase behind the shock wave, are amplified by further reducing the scaling ratio (or Reynolds number) of the flow. This reduction is obtained by either decreasing the hydraulic diameter \(D_\mathrm{H}\) or the initial driven gas pressure \(P_1\) . Under these conditions, the flow behavior changes drastically.     

Experimental Characterization of Porosity Structure and Transport Property Changes in Limestone Undergoing Different Dissolution Regimes

Limestone dissolution by $\hbox {CO}_2$ -rich brine induces critical changes of the pore network geometrical parameters such as the pore size distribution, the connectivity, and the tortuosity which govern the macroscopic transport properties (permeability and dispersivity) that are required to parameterize the models, simulating the injection and the fate of $\hbox {CO}_2$ . A set of four reactive core-flood experiments reproducing underground conditions ( $T = 100\,^{\circ }\hbox {C}$ and $P = 12$ MPa) has been conducted for different $\hbox {CO}_2$ partial pressures $(0.034 < P_{\mathrm{CO}_2}< 3.4\; \hbox {MPa})$ in order to study the different dissolution regimes. X-ray microtomographic images have been used to characterize the changes in the structural properties from pore scale to Darcy scale, while time-resolved pressure loss and chemical fluxes enabled the determination of the sample-scale change in porosity and permeability. The results show the growth of localized dissolution features associated with high permeability increase for the highest $P_{\mathrm{CO}_2}$ , whereas dissolution tends to be more homogeneously distributed for lower values of $P_{\mathrm{CO}_2}$ . For the latter, the higher the $P_{\mathrm{CO}_2}$ , the more the dissolution patterns display ramified structures and permeability increase. For the lowest value of $P_{\mathrm{CO}_2}$ , the preferential dissolution of the calcite cement associated with the low dissolution kinetics triggers the transport that may locally accumulate and form a microporous material that alters permeability and produces an anti-correlated porosity–permeability relationship. The combined analysis of the pore network geometry and the macroscopic measurements shows that $P_{\mathrm{CO}_2}$ regulates the tortuosity change during dissolution. Conversely, the increase of the exponent value of the observed power law permeability–porosity trend while $P_{\mathrm{CO}_2}$ increases, which appears to be strongly linked to the increase of the effective hydraulic diameter, depends on the initial rock structure.     

Advection–Dispersive Mechanisms of Electrolyte Species in Porous Matrix

Advection–dispersive phenomena inside two geometries of porous media, corresponding to a structured and unstructured network of minichannels, are studied from a combination of analytical, numerical, and electrodiffusion techniques. The instantaneous limiting diffusion current, connected to the concentration of electroactive species flowing in the porous matrix, is recorded and measured during flow experimentation. Transport phenomena investigation consists of the step injection of a tracer of higher concentration than the bulk flow in order to characterize the mixing of electrolyte species inside two arrangements of network, so called \(\times \) _network and T_network. The experimental results are supported by 2D-numerical simulations performed in the \(\times \) _network. A pore model is proposed in order to predict the pore velocity, which is used within the resolution of the diffusion–convection balance. The numerical simulations, based on a second-order finite difference scheme, give rise to a good agreement in terms of mixing index and the methodology employed for the numerical injection concentration appears suitable. The numerical experiments are quite-well representative in laminar regime below the critical Reynolds number ( \(Re_{\mathrm{crit}}\approx \,200\) ). Above \(Re_{\mathrm{crit}}\) , the inertial effects are not negligible and the momentum transfer needs to be taken into account. This latter phenomenon is analyzed at the pore-scale in term of local skin friction measured at the channels crossing, then compared and discussed from analytical solutions.     

Flow Dynamics of \hbox {CO}_{2}/brine at the Interface Between the Storage Formation and Sealing Units in a Multi-layered Model

Pressure distribution and \(\hbox {CO}_{2}\) plume migration are two major interests in \(\hbox {CO}_{2}\) geologic storage as they determine the injectivity and storage capacity. In this study, we adopted a three-layer model comprising a storage formation and the over- and underlying seals and determined three distinct flow regions based on the vertical flux exchange of \(\hbox {CO}_{2}\) and native brine. Regions 1 and 2 showed \(\hbox {CO}_{2}\) flowing from the storage formation to adjacent seals with counter-flowing brine. The characteristics of these fluxes in Region 1 were governed by permeability change due to salt precipitation whereas buoyancy force controlled the flux pattern in Region 2. Region 3 showed brine flowing from storage formation toward the over- and underlying seals, which enabled the displaced brine to escape from the storage formation and make room for \(\hbox {CO}_{2}\) to store as well as reduce the pressure build-up. In the multi-layered model, the counter-flowing brine in flow Region 1 resulted in localized salt precipitation at the upper and lower boundary of storage formation. We assessed the bottom-hole pressure and \(\hbox {CO}_{2}\) mass in caprock with respect to reservoir size. While the formation thickness influenced the bottom-hole pressure in the early stage of injection, the horizontal extension of the reservoir was more influential to pressure build-up during the injection period, and to the stabilized pressure during the post-injection period. The \(\hbox {CO}_{2}\) mass in caprock gently increased during the injection period as well as during the post-injection period and reached about 4–5 % of injected \(\hbox {CO}_{2}\) . The percentage of escaped brine from the storage formation ranged from 80–100 % of the \(\hbox {CO}_{2}\) mass stored in the storage formation depending on the reservoir scale.     

Estimability Analysis for Optimization of Hysteretic Soil Hydraulic Parameters Using Data of a Field Irrigation Experiment

To improve the quality of parameter optimization, estimability analysis has been proposed as the first step before inverse modeling. When using field data of irrigation experiments for the determination of soil hydraulic parameters, wetting and drying processes may complicate optimization. The objectives of this study were to compare estimability analysis and inverse optimization of the soil hydraulic parameters in the models with and without considering hysteresis of the soil water retention function. Soil water pressure head data of a field irrigation experiment were used. The one-dimensional vertical water movement in variably saturated soil was described with the Richards equation using the HYDRUS-1D code. Estimability of the unimodal van Genuchten–Mualem hydraulic model parameters as well as of the hysteretic parameter model of Parker and Lenhard was classified according to a sensitivity coefficient matrix. The matrix was obtained by sequentially calculating effects of initial parameter variations on changes in the simulated pressure head values. Optimization was carried out by means of the Levenberg-Marquardt method implemented in the HYDRUS-1D code. The parameters \(\alpha , K_{s}, \theta _{s}\) , and \(n\) in the nonhysteretic model were found sensitive and parameter \(\theta _{s}\) strongly correlated with parameter \(n\) . When assuming hysteresis, the estimability was decreased with soil depth for \(K_{s}\) and \(\alpha ^{d}\) , and increased for \(\theta _{s}\) and n. Among the shape parameters, \(\alpha ^{w}\) was the most estimable. The hysteretic model could approximate the pressure heads in the soil by considering parameters from wetting and drying periods separately as initial estimates. The inverse optimization could be carried out more efficiently with most estimable parameters. Despite the remaining weaknesses of the local optimization algorithm and the inflexibility of the unimodal van Genuchten model, the results suggested that estimability analysis could be considered as a guidance to better define the optimization scenarios and then improved the determination of soil hydraulic parameters.     

Heterogeneous Alkane Reactions over Nanoporous Catalysts

Pt-USY-712 (Si/Al = 6) and three SBA-15 catalysts (metal-loaded with 1 wt% Pt, 1 wt% Ni or 0.5 wt% Pt and 0.5 wt% Ni) were prepared and characterised using scanning electron microscopy (SEM), X-ray diffraction (XRD), N \(_{2}\) adsorption porosimetry / BET and transmission electron microscopy (TEM). The catalysts were then tested in the hydroisomerisation and hydrocracking of \(n\) -heptane using a micro-reactor at atmospheric pressure, and the products were analysed by GC-FID. Reaction temperatures ranged from 250– \(400\,\,^{\circ }\hbox {C}\) while the W/F values of \(n\hbox {-C}_{7}\) varied from 224.70–550.57 kg \(\hbox {mol}^{-1}\) . The coke content of each catalyst was measured using thermo gravimetric analysis (TGA). The catalytic activity was highest on Pt-USY-712 at the lowest reaction temperatures due to (a) the presence of strong Brønsted acids sites on the zeolite and (b) the smaller and more highly dispersed metal clusters on Pt-USY-712, relative to Pt-SBA-15. The activity was higher on the bimetallic Pt/Ni-SBA-15 than on mono-metallic Pt-SBA-15 as the co-impregnation of Ni with Pt enhanced the distribution of the metal clusters on the catalyst and resulted in improved surface area for reaction. The Pt-SBA-15 and Pt/Ni-SBA-15 catalysts both had the lowest and approximately equal coke percentages with 0.116 and 0.119 wt%, respectively.     

Elucidating the Role of Interfacial Tension for Hydrological Properties of Two-Phase Flow in Natural Sandstone by an Improved Lattice Boltzmann Method

We investigated the interfacial tension (IFT) effect on fluid flow characteristics inside micro-scale, porous media by a highly efficient multi-phase lattice Boltzmann method using a graphics processing unit. IFT is one of the most important parameters for carbon capture and storage and enhanced oil recovery. Rock pores of Berea sandstone were reconstructed from micro-CT scanned images, and multi-phase flows were simulated for the digital rock model at extremely high resolution (3.2  \(\upmu \) m). Under different IFT conditions, numerical analyses were carried out first to investigate the variation in relative permeability, and then to clarify evolution of the saturation distribution of injected fluid. We confirmed that the relative permeability decreases with increasing IFT due to growing capillary trapping intensity. It was also observed that with certain pressure gradient \(\Delta P\) two crucial IFT values, \(\sigma _{1}\) and \(\sigma _{2}\) , exist, creating three zones in which the displacement process has totally different characteristics. When \(\sigma _{1}< \sigma < \sigma _{2}\) , the capillary fingering patterns are observed, while for \(\sigma < \sigma _{1}\) viscous fingering is dominant and most of the passable pore spaces were invaded. When \(\sigma > \sigma _{2}\) the invading fluid failed to break through. The pore-throat-size distribution estimated from these crucial IFT values ( \(\sigma _{1 }\) and \(\sigma _{2})\) agrees with that derived from mercury porosimetry measurements of Berea sandstone. This study demonstrates that the proposed numerical method is an efficient tool for investigating hydrological properties from pore structures.     

The Effects of Brine Species on the Formation of Residual Water in a \hbox {CO}_{2}–Brine System

Geological storage of \(\hbox {CO}_{2}\) in deep saline aquifers is achieved by injecting \(\hbox {CO}_{2}\) into the aquifers and displacing the brine. Although most of the brine is displaced, some residual groundwater remains in the rock pores. We conducted experiments to investigate factors that influence how much of this residual water remains after \(\hbox {CO}_{2}\) is injected. A rock sample was saturated with brines of two different salts. Supercritical \(\hbox {CO}_{2}\) was injected into the samples at aquifer temperature and pressure, and the displaced water and water–gas mixtures were collected and measured. The results show that deionized water drains more completely than either of the two brines, and NaCl brine drains more completely than \(\hbox {CaCl}_{2}\) brine. The ranking of the irreducible water saturation at the end of the experiment is deionized \(\hbox {water}<\hbox {NaCl brine } <\hbox {CaCl}_{2}\) brine. The process of drainage can be divided into three stages according to the drainage flow rates; the Pushing Drainage, Portable Drainage, and Dissolved Drainage stages. This paper proposed a capillary model which is used to interpret the mechanisms that characterize these three stages.     

A fast algorithm to calculate the critical coupling strength for synchronization in a chain of Kuramoto oscillators

Synchronization in a one-dimensional chain of Kuramoto oscillators with periodic boundary conditions is studied. An algorithm to rapidly calculate the critical coupling strength \(K_c\) for complete frequency synchronization is presented according to the mathematical constraint conditions and the periodic boundary conditions. By this new algorithm, we have checked the relation between \(\langle K_c\rangle \) and \(N\) , which is \(\langle K_c\rangle \sim \sqrt{N}\) , not only for small \(N\) , but also for large \(N\) . We also investigate the heavy-tailed distribution of \(K_c\) for random intrinsic frequencies, which is obtained by showing that the synchronization problem is equivalent to a discretization of Brownian motion. This theoretical result was checked by generating a large sample of \(K_c\) for large \(N\) from our algorithm to get the empirical density of \(K_c\) . Finally, we derive the permutation for the maximum coupling strength and its exact expression, which grows linearly with \(N\) and would provide the theoretical support for engineering applications.     

Elongational rheology of NIPAM-based hydrogels

Hydrogels of different composition based on the copolymerization of N-isopropyl acrylamide and surfmers of different chemical structure were tested in elongation using Hencky/real definitions for stress, strain, and strain rate, offering a more scientific insight into the effect of deformation on the properties. In a range between $\dot {\varepsilon }=10$ and 0.01 s $^{-1}$ , the material properties are independent of strain rate and show a very clear strain hardening with a “brittle” sudden fracture. The addition of surfmer increases the strain at break $\varepsilon _{\mathrm {H}}^{\max }$ and at the same time leads to a failure of hyperelastic models. The samples can be stretched up to Hencky strains $\varepsilon _{\mathrm {H}}^{\max }$ between 0.6 and 2.5, depending on the molecular structure, yielding linear Young’s moduli E $_{0}$ between 2,700 and 39,000 Pa. The strain-rate independence indicates an ideal rubberlike behavior and fracture in a brittle-like fashion. The resulting stress at break $\sigma _{\textrm max}$ can be correlated with $\varepsilon _{\mathrm {H}}^{\max } $ and $E_{0}$ as well as with the solid molar mass between the cross-linking points $M_{\mathrm {c}}^{\textrm {solids}} $ , derived from $E_{0}$ .     

Study of TATP: blast characteristics and TNT equivalency of small charges

Blast wave parameters including incident overpressure, impulse and duration of the positive phase of the incident blast wave and its time of arrival were experimentally determined for 50 g charges of low bulk density ( \(0.4\, \hbox {g/cm}^{3}\) ) dry TATP (3,3,6,6,9,9-hexamethyl-1,2,4,5,7,8-hexoxonane). The results were compared with published TNT data, and TNT equivalencies were determined, resulting in the values of 70 % based on overpressure and 55 % based on impulse of the positive phase of the blast wave. Brisance by the Hess method (lead cylinder compression) was found to be about one-third of that for TNT (at density \(1.2\, \hbox {g/cm}^{3})\) . Detonation velocities averaged around \(2,660 \,\hbox {m/s}^{1}\)      

Expansivity and Cone-fields in Metric Spaces

Due to the results of Lewowicz and Tolosa expansivity can be characterized with the aid of Lyapunov function. In this paper we study a similar problem for uniform expansivity and show that it can be described using generalized cone-fields on metric spaces. We say that a function \(f:X\rightarrow X\) is uniformly expansive on a set \(\varLambda \subset X\) if there exist \(\varepsilon >0\) and \(\alpha \in (0,1)\) such that for any two orbits \(\hbox {x}:\{-N,\ldots ,N\} \rightarrow \varLambda \) , \(\hbox {v}:\{-N,\ldots ,N\} \rightarrow X\) of \(f\) we have $$\begin{aligned} \sup _{-N\le n\le N}d(\hbox {x}_n,\hbox {v}_n) \le \varepsilon \implies d(\hbox {x}_0,\hbox {v}_0) \le \alpha \sup _{-N\le n\le N}d(\hbox {x}_n,\hbox {v}_n). \end{aligned}$$ It occurs that a function is uniformly expansive iff there exists a generalized cone-field on \(X\) such that \(f\) is cone-hyperbolic.     

\mathcal {H}_{\infty } filtering for sample data systems with stochastic sampling and Markovian jumping parameters

This paper deals with the problem of \(\mathcal {H}_{\infty }\) filtering for sample data systems that possess random jumping parameters described by a finite-state Markov process with stochastic sampling. Multiple stochastic sampling periods are considered in which each sampling period is assumed to be time varying that switches between two different values in a random way with given probability. The aim of this paper is to design a filter such that the filtering error system is stochastically stable with a prescribed \(\mathcal {H}_{\infty }\) disturbance attenuation level. Sufficient conditions for the existence of \(\mathcal {H}_{\infty }\) filters are expressed in terms of linear matrix inequalities (LMIs), which can be solved by using Matlab LMI toolbox. Numerical examples are given to illustrate the effectiveness of the proposed result including a realistic Transmission Control Protocol network model.