Overtone bands of 14N16O and determination of molecular constants

The wavenumbers of the rotation-vibration lines of ¹⁴N¹⁶O are reported for the (2-0) and (3-0) bands. The full set of spectroscopic constants for the three bands (1-0), (2-0), and (3-0) has been determined with the method developed by Albritton, Schmeltekopf, and Zare for merging the results of separate least-squares fits. The vibrational constants ω_e, ω_ex_e, ω_ey_e, and the vibrational dependence of the rotational constants have been deduced. The apparent spin-orbit constant $\text{A}\text{?}{}_{\mathrm{<mtext>v</mtext>}}$ and its centrifugal correction $\text{A}\text{?}{}_{\mathrm{<mtext>D</mtext>}}$ (including the spin-rotation constant) have a vibrational dependence of the following form: $\text{A}\text{?}{}_{\mathrm{v}}\text{=}\text{A}\text{?}{}_{\mathrm{e}}\text{? α}{}_{\mathrm{A}}\text{(v +}\text{1}\text{2}\text{) + γ}{}_{\mathrm{A}}\text{(v +}\text{1}\text{2}\text{)}{}^2$ and $\text{A}\text{?}{}_{\mathrm{<mtext>D</mtext><mtext>v</mtext>}}\text{=}\text{A}\text{?}{}_{\mathrm{<mtext>D</mtext><mtext>e</mtext>}}\text{? β}{}_{\mathrm{A}}\text{(v +}\text{1}\text{2}\text{) + δ}{}_{\mathrm{A}}\text{(v +}\text{built+1}\text{2}\text{)}{}^2$; the values of the constants in these two equations have been determined.     

Vibration-rotation bands of 14N15N16O15N14N16O: 1.6–5.7 μm region

The infrared Fourier spectrum of 63 bands of ¹⁴N¹⁵N¹⁶O and of 69 bands of ¹⁵N¹⁴N¹⁶O have been measured and analyzed from 1750 to 6000 cm^?1. The rotational constants are given for 20 Σ, 11 Π, 7 Δ, and 3 Φ levels of ¹⁴N¹⁵N¹⁶O and 21 Σ, 14 Π, 8 Δ, and 5 Φ levels of ¹⁵N¹⁴N¹⁶O. Two bands of the previously unreported isotopic species ¹⁴N¹⁵N¹⁷O and ¹⁵N¹⁴N¹⁷O have been observed. Several local resonances are present in the levels 31^1c0 and 04⁰1 in ¹⁴N¹⁵N¹⁶O; 10⁰1, 06⁰0, 11^1d1, 12⁰1 in ¹⁵N¹⁴N¹⁶O. In both isotopes two “forbidden” Δ-Σ transitions are observed: 04^2c0-00⁰0 and 12^2c0-00⁰0.     

15N16O的激光磁共振谱与同位素分子15N17O和15N18O的光谱分析

采用内腔式饱和吸收技术获得Lamb凹陷,使CO激光磁共振谱仪的灵敏度及分辨率大大提高.利用该技术对自然丰度下¹⁵N¹⁶O的X²Π(υ=1)←X²Π(υ=0)塞曼跃迁进行测量,实现了包括Λ双分裂在内的各种精细结构的谱分辨.结合已发表的¹⁵NO同位素分子光谱实验数据进行分析计算,拟合得到迄今最完备、最精确的各相关同位素分子¹⁵N^mO(m=16—18)的结构参 关键词：     

Vibration-rotation bands of 15N216O14N218O

The infrared spectrum of 64 bands of the isotopic species ¹⁵N₂¹⁶O of nitrous oxide and of 37 bands of ¹⁴N₂¹⁸O have been analyzed. The studied spectral range extends from 1750 to 6000 cm^?1 for ¹⁵N₂¹⁶O and from 1750 to 3100 cm^?1 for ¹⁴N₂¹⁸O. The effective rotational constants are given for 44 levels of ¹⁵N₂¹⁶O comprising 21Σ, 12Π, 7Δ, 4Φ levels and also for 29 levels of ¹⁴N₂¹⁸O comprising 13Σ, 7Π, 6Δ, 3Φ levels. Thirty-one levels (20Σ, 11Π) of the following isotopic species have also been studied: ¹⁵N₂¹⁷O, ¹⁵N₂¹⁸O, ¹⁴N¹⁵N¹⁸O, ¹⁵N¹⁴N¹⁸O, ¹⁴N₂¹⁷O. In ¹⁵N₂¹⁶O a local Coriolis resonance affects the 10⁰1 level. The “forbidden” Δ-Σ transition 12^2c0-00⁰0 is observed in the spectrum of ¹⁵N₂¹⁶O. The equilibrium values for the internuclear distances have been calculated.     

Rotational spectra of 16O3 and of the five 18O isotopic species

The pure rotational spectrum of all of the isotopic species (with ¹⁸O in place of ¹⁶O) of the molecule of ozone has been studied in the range of 18 to 382 GHz. The Watson Hamiltonian developed up to terms in P⁶ is used. For each substituted form, the Watson molecular parameters, measured frequencies, calculated frequencies, and associated uncertainties are given. By using the distortion parameters, the Coriolis coupling constant and the force constants are calculated. The equilibrium structure is obtained from the particular isotopic substitution ¹⁶O₃ ? ¹⁸O₃.     

Measurement and interpretation of the 1-0 band of 14N16O at 1900 cm−1

The wavenumbers of the vibration rotation band lines of ¹⁴N¹⁶O are reported for the ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{-}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{-}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{-}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ subbands of the 1-0 transition in the infrared. The full set of spectroscopic constants for this band has been determined by direct approach using the analysis of Zare, Schmeltekopf, Harrop, and Albritton. In addition to the band origin ν₀ and the B, D, H constants for the lower and upper vibrational levels, the following spin-orbit coupling constants have been derived: $\text{A}\text{?}{}_0\text{= 123.02772 ± 0.00011}$ and $\text{A}\text{?}{}_1\text{= 122.78248 ± 0.00011}$ (in cm^?1). Apparent centrifugal corrections to these constants have been determined and the values obtained for them are $\text{A}\text{?}{}_{\mathrm{<mtext>D</mtext><mtext>0</mtext>}}\text{= (0.347573 ± 0.00051) × 10}{}^{\mathrm{?3}}$ and $\text{A}\text{?}{}_{\mathrm{<mtext>D</mtext><mtext>1</mtext>}}\text{= (0.337135 ± 0.00050) × 10}{}^{\mathrm{?3}}\text{cm}{}^{\mathrm{?1}}$. Λ-Type doubling constants evaluated by using both grating and tunable laser data are also reported.     

The (3He,n) reaction on 16O and 18O

The (³He, n) reaction on ¹⁶O and ¹⁸O has been used to study low-spin states in ¹⁸Ne and ²⁰Ne up to E_x ≈ 8 and 20 MeV, respectively. The measured neutron angular distributions have been analysed using DWBA. By a comparison with shell-model calculations in the (s, d) shell it is found that most of the two-proton transfer strength can be explained within that shell. Important contributions, however, from the (f, p) shell in low-lying negative parity states are also present.     

Comparison of inner shell ionization by 16O and 18O projectiles

K-shell ionization induced by oxygen isotopes has been studied for several elements ranging from sulphur to bromine. Ionization cross sections and K_α/K_β intensity ratios are compared at equal projectile velocities.     

Proton polarization in 16O(p,p0)16O and states in 17F1 (II)

The proton polarization in ¹⁶O(p, p₀)¹⁶O has been measured for laboratory proton energies between 10.0 and 16.0 MeV. Measurements were made for 18 or more angles at 60 energies. In addition, excitation functions of polarization were measured at 6 angles in 50 keV steps from 12.8 to 16.0 MeV. Both optical-model and phase-shift analyses were performed using published cross-section data in conjunction with the polarization data. The energy dependence of the complex phase shifts yielded spin, parity, and width assignments for 10 levels in ¹⁷F and possible assignments for 10 additional levels. A review of the energy levels of ¹⁷F below 16 MeV is given.     

The reaction 14C(3He,n)16O and the coexistence model of 16O

The reaction ¹⁴C(³He, n)¹⁶O has been measured at a ³He bombarding energy of 25.4 MeV. The zero-degree differential cross section for the excitation of the three low lying 0⁺T = 0 states, at energies 0.0, 6.05 and 12.05 MeV are, respectively, 1.33 ± 0.10, 0.49 ± 0.10, and 0.50 ± 0.10 mb/sr These measured cross sections are in rough agreement with single-step zero-range DWBA calculations using an empirically determined ¹⁴C ground state wave function and in which the Brown and Green coexistence-model wave functions are used to describe the ¹⁶O 0⁺ states. The angular distribution of the transition to the ground state is measured between 0° and 32°.     

Structure of 0+ states in 18O

Analysis of spectroscopic factors obtained in single-nucleon transfer reactions leading to and from ¹⁸O yields two different sets of wave functions for the first three O⁺ states. One set of wave functions is in agreement with ¹⁶O(t, p)¹⁸O data for the three states-the other set is not. The wave functions that agree with the experimental data have the majority of the $\text{(s}\text{1}\text{2}\text{)}{}^2$ strength in the third O⁺ state.     

Microwave spectrum of 15N16O2 in the ground state

¹⁵NO₂ (88 lines) in the ground state has been observed in the microwave spectral region up to 170 GHz. The least squares analysis gave the higher order distortion terms of rotational and spin-rotational Hamiltonian.     

15N excitation contribution to 48Ca(16O, 15N)49Sc reaction

The effect of ¹⁵N excitation process is studied in the reaction ⁴⁸Ca(¹⁶O, ¹⁵N)⁴⁹Sc. The excitation process is included into a generalized non-local optical potential for a scattersing ¹⁵N-⁴⁹Sc and is found to be responsible for a shift of a grazing peak in the exact finite-range DWBA calculation.     

15N216O在1650-3450 cm-1的高分辨红外光谱

采用傅里叶变换红外光谱仪记录了富含¹⁵N₂¹⁶O同位素的一氧化二氮样品在1650-3450 cm^-1波段的高分辨振转光谱,得到了该同位素分子超过7300吸收谱线位置的实验值,经分析实验精确度好于5.0×10^-4 cm^-1. 基于有效哈密顿量模型预测和带带转动分析,确定了所有吸收线的归属;获得了29个新吸收带的振转光谱参数,并优化了其他44个吸收带的光谱参数值. 并且发现有效哈     

Absolute frequency measurements of the 0002-0000, 2001-0000, and 1201-0000 bands of N2O by heterodyne spectroscopy

The absolute frequencies of 39 lines in the 00⁰2-00⁰0, 20⁰1-00⁰0, and 12⁰1-00⁰0 bands of N₂O in the range 4300–4800 cm^?1 have been measured by heterodyne frequency techniques. The lines were each measured in Doppler-limited absorption, with a color-center laser as a tunable probe of the N₂O and two stabilized CO₂ lasers as reference frequencies. New rovibrational constants have been fitted to these measurements. Tables of calculated transition frequencies are given, with estimated absolute uncertainties as small as 10^?4 cm^?1. The pressure shifts of four lines have been measured, and the values fall within the range of 0 to ?2 MHz/kPa (0 to ?0.2 MHz/Torr).     

Rotational structure of 16O2, 16O17O,and 16O18O (X3Σg−) from laser magnetic resonance spectra

Improved values of the rotational constants B and D of ¹⁶O¹⁷O(v = 0) and D of ¹⁶O₂(v = 1) were obtained from an analysis of the laser magnetic resonance spectra at 765 and 4252 GHz.     

Spectroscopy of intermediate 16F states with the reaction 14N(3He,np)15O

Excited states of ¹⁶F have been investigated with the reaction ¹⁴N(³He, np)¹⁵O at E = 10.5 and 12 MeV in kinematically complete experiments. Proton groups corresponding to the decays of intermediate ¹⁶F states were observed at various angles with counter telescopes in time coincidence with the associated neutrons detected at θ_n^lab = 0° with a time-of-flight spectrometer. Excitation energies and decay widths Γ_p0 of these states have been extracted from the proton spectra. Lower limits for the orbital angular momentum in the decay channel and for the spin of the states have been deduced from the obtained angular correlations. By comparison with the reaction ¹⁴N(³He, pp)¹⁵N measured at E = 13 MeV, pairs of $\text{T = 1}{}^{16}\text{F}$ parent/¹⁶O analog states have been identified. J^π assignments and shell-model configurations are discussed on the basis of the selectivity of the reactions measured.     

Levels of 16O near 13 MeV excitation from 15N + P reactions

Angular distributions, a 0° excitation function and Doppler-broadened γ-ray profiles for the reaction ¹⁵N(p, α₁γ), and angular distributions for the ¹⁵N(p, α₀) reaction, have been measured for proton energies from about 900 to 1250 keV. These data, together with analysing powers from the ${}^{15}\text{N}\text{(}\text{p}$, α₀) reaction, have been satisfactorily fitted by means of R-matrix theory in terms of the known levels of ¹⁶O in the 13 MeV region together with background contributions.