Rigid medium stabilization of metal-to-ligand charge transfer excited states

The salts [Ru(bpy)3](PF6)2, cis-[Ru(bpy)2(py)2](PF6)2, trans-[Ru(bpy)2(4-Etpy)2](PF6)2, [Ru(tpy)2](PF6)2, and [Re(bpy)(CO)3(4-Etpy)](PF6) (bpy=2,2'-bipyridine, py=pyridine, 4-Etpy=4-ethylpyridine, and tpy=2,2':6',2-terpyridine) have been incorporated into poly(methyl methacrylate) (PMMA) films and their photophysical properties examined by both steady-state and time-resolved absorption and emission measurements. Excited-state lifetimes for the metal salts incorporated in PMMA are longer and emission energies enhanced due to a rigid medium effect when compared to fluid CH3CN solution. In PMMA part of the fluid medium reorganization energy, lambdaoo, contributes to the energy gap with lambdaoo approximately 700 cm-1 for [Ru(bpy)3](PF6)2 from emission measurements. Enhanced lifetimes can be explained by the energy gap law and the influence of the excited-to-ground state energy gap, Eo, on nonradiative decay. From the results of emission spectral fitting on [Ru(bpy)3](PF6)2* in PMMA, Eo is temperature dependent above 200 K with partial differentialEo/ partial differentialT=2.8 cm-1/deg. cis-[Ru(bpy)2(py)2](PF6)2 and trans-[Ru(bpy)2(4-Etpy)2](PF6)2 are nonemissive in CH3CN and undergo photochemical ligand loss. Both emit in PMMA and are stable toward ligand loss even for extended photolysis periods. The lifetime of cis-[Ru(bpy)2(py)2](PF6)2* in PMMA is temperature dependent, consistent with a contribution to excited-state decay from thermal population and decay through a low-lying dd state or states. At temperatures above 190 K, coinciding with the onset of the temperature dependence of Eo for [Ru(bpy)3](PF6)2*, lifetimes become significantly nonexponential. The nonexponential behavior is attributed to dynamic coupling between MLCT and dd states, with the lifetime of the latter greatly enhanced in PMMA with tau approximately 3 ns. On the basis of these data and data in 4:1 (v/v) EtOH/MeOH, the energy gap between the MLCT and dd states is decreased by approximately 700 cm-1 in PMMA with the dd state at higher energy by DeltaH0 approximately 1000 cm-1. The "rigid medium stabilization effect" for cis-[Ru(bpy)2(py)2](PF6)2* in PMMA is attributed to inhibition of metal-ligand bond breaking and a photochemical cage effect.     

Electron transfer initiated Diels-Alder reaction with allenes as dienophiles

The first examples of using aryl allenes as dienophiles in the electron transfer induced Diels-Alder reaction are described. According to mechanistic tests the reaction proceeds via a cycloaddition of the diene^+· to the allene.     

Dipolar stabilization of emissive singlet charge transfer excited states in polyfluorene copolymers

The singlet excited-state dynamics in poly[(9,9-dioctylfluorene)-(dibenzothiophene-S,S-dioxide)] (PFSx ) random copolymers with different contents of dibenzothiophene-S,S-dioxide (S) units have been studied by steady-state and time resolved fluorescence spectroscopies. Emission from PFSx copolymers shows a pronounced solvatochromism in polar chloroform, relative to the less polar toluene. An excited intramolecular charge transfer state (ICT) is stabilized by dipole-dipole interactions with the polar solvent cage, and possibly accompanied by conformational rearrangement of the molecular structure, in complete analogy with their small oligomer counterparts. The spectral dynamics clearly show that the ICT stabilization is strongly affected by the surrounding medium. In the solid state, emission from PFSx copolymers depends on the content of S units, showing an increase of inhomogeneous broadening and a red shift of the optical transitions. This observation is consistent with stabilization of the emissive ICT state, by the local reorientation of the surrounding molecules at the location of the excited chromophore, which results in favorable dipole-dipole interactions driven by the increase in the dielectric constant of the bulk polymer matrix with increasing S content, in analogy to what happens in polar solvent studies. Furthermore, in clear agreement with the interpretation described above, a strong increase in the emission quantum efficiency is observed in the solid state by decreasing the temperature and freezing out the molecular torsions and dipole-dipole interactions necessary to stabilize the ICT state.     

Application of the energy gap law to the decay of charge transfer excited states,solvent effects

Values of non-radiative decay rate constants (k_nr) and emission energies (E_cm) have been obtained for Os(Phen₃)²⁺ in a series of solvents and the results are consistent with the energy gap law. For hydroxylic solvents like water or methanol related studies suggest the existence of strong, specific contributions to the vibrational trapping energy of the solvent.     

Ligand-to-metal charge transfer excited states with unprecedented luminescence yield in fluid solution

A bridged d0 zirconocene dichloride is reported as a first group 4 metal complex possessing rare long-lived ligand-to-metal charge transfer (LMCT) excited states with high emission yields and excited-state lifetimes in fluid solutions (e.g., PhiLUM = 0.41 and tau = 17.6 micros in 1,2-dichlorobenzene at 20 degrees C). The basic emission parameters PhiLUM and tau are shown to be extremely solvent-dependent in fluids at room temperature. The first principle dependences of LMCT emission parameters on solvent properties are revealed with use of the target complex. For fluid solutions, the linear correlation between PhiLUM and tau is reported, thus suggesting that a solvent determines the rate constant for nonradiative decay, knr.     

Influence of localized excited states on the transition moment directions of charge transfer complex absorptions

The influence of localized excited (LE) states on the spectroscopy of charge transfer (CT) complexes has been examined for a series of complexes formed between methyl-substituted benzene donors and 1,2,4,5-tetracyanobenzene as acceptor in 1,2-dichloroethane and octanenitrile solvents. A molecular orbital model was used to describe the appearance of multiple CT absorption bands that occur in the spectra of these complexes. The influence of LE states in these CT absorptions was explored using time-resolved linear dichroism spectroscopy where the direction of the CT transition moment vector (TMV) was used to probe the magnitude of intensity borrowing. The TMV directions for each of the observed CT transitions within the absorption spectra were determined for several complexes. In some cases, the observed CT transitions were interpreted as being pure CT transitions; in others the observed transitions are influenced significantly by a LE transition. The correlation between the TMV directions and the transition energy suggests that the magnitude of intensity borrowing is influenced not only by the energy difference between the CT and LE transitions but also by the specific character of the transitions under consideration.     

Anthracene array-type porous coordination polymer with host-guest charge transfer interactions in excited states

Confinement of electron donor guests affords an efficient, photo-induced charge transfer (CT) with the anthracene moieties of a porous coordination polymer.     

The excited states of some organic charge transfer complexes studied by modulation excitation spectrophotometry

The excited states of some complexes between polycyclic aromatic hydrocarbons and chloranil dissolved in polymethylmethacrylate have been studied with a modulation excitation spectrophotometer. New bands similar to but slightly shifted in position as compared to the T₁–T₃ transition of the aromatic hydrocarbon are observed. Regressional analysis points to the new bands arising from transitions from a level in the chloranil to the T₃ level of the hydrocarbon. An enhancement of the T₁–T₃ bands of the hydrocarbon occurs in the complex. Other bands are also seen which are believed to be due to new levels of the complex which cannot be identified with local levels of the hydrocarbon or chloranil.     

Chemical bonding in excited states: Energy transfer and charge redistribution from a real space perspective

This work provides a novel interpretation of elementary processes of photophysical relevance from the standpoint of the electron density using simple model reactions. These include excited states of H₂ taken as a prototype for a covalent bond, excimer formation of He₂ to analyze non‐covalent interactions, charge transfer by an avoided crossing of electronic states in LiF and conical interesections involved in the intramolecular scrambling in C₂H₄. The changes of the atomic and interaction energy components along the potential energy profiles are described by the interacting quantum atoms approach and the quantum theory of atoms in molecules. Additionally, the topological analysis of one‐ and two‐electron density functions is used to explore basic reaction mechanisms involving excited and degenerate states in connection with the virial theorem. This real space approach allows to describe these processes in a unified way, showing its versatility and utility in the study of chemical systems in excited states. © 2017 Wiley Periodicals, Inc.     

Photochemistry in the charge transfer and neutral excited states of HCl in Xe and Kr matrices

HCl-doped Xe and Kr films are irradiated with wavelength dispersed synchrotron radiation in the wavelength range from 200 to 130 nm. The growth of H, Cl, Xe2H+, XeH2, HXeCl, Kr2H+, and HKrCl as well as the decomposition of HCl are recorded by a combination of UV, VIS, and IR spectroscopy. A turnover in the formation of Xe2H+ and Kr2H+ by a predominant two-step reaction on neutral surfaces at low energies to a one-step formation on ionic surfaces is determined at 172 and 155 nm in Xe and Kr, respectively. A potential energy diagram for neutral and ionic states is derived that is consistent with a DIIS calculation, with new UV fluorescence bands from Xe+HCl- centers, with the turnover energies and with a deconvolution of the absorption spectra in neutral and ionic contributions. The cage exit of charged as well as of neutral H, the latter via a harpoon reaction, is discussed for the ionic surfaces. The self-limitation of HCl decomposition on the neutral surfaces due to absorption by H and Cl fragments is treated quantatively. Dissociation efficiencies phi(e), together with absolute absorption cross sections sigma(H) and sigma(Cl) of the fragments, are derived. sigma(H) and sigma(Cl) are of the order of 10(-16) cm(2) compared to 10(-18) cm(2) for sigma(HCl). Dissociation is accompanied by many excitation cycles of the fragments, which leads to light-induced migration of H and recombination. phi(e) therefore represents a product of the cage exit probability phi that was treated theoretically and the survival probability concerning geminate and nongeminate recombination.     

The equilibria and conversions between three excited states: the LE state and two charge transfer states, in twisted pyrene-substituted tridurylboranes

Excited-state conversions were observed from a series of twisted pyrene-substituted tridurylboranes, corresponding to a locally excited (LE) state, a more planar charge transfer (CT) state with a higher fluorescence quantum efficiency, and a more twisted CT state.     

Multiple emissions from charge transfer excited states of ruthenium(II)—polypyridine complexes

The complex cis-[(bpy)₂Ru

₂]⁴⁺ (bpy is 2,2′-bipyridine) has been prepared by methylation of (bpy)₂Ru

₂]²⁺. Electrochemical studies show that introduction of the bound pyridinium group creates a chemically attached electron acceptor site (E_1/2 = ?0.76 V in 0.1 M [N(n-C₄H₉)₄]PF₆-acetonitrile versus the SSCE). Evidence for a low-lying dπ — π^*

charge transfer (CT) state has been obtained by the appearance of a low energy emission at λ_max 680 nm in ecetonitrile (τ₀ = 104 ns) and for an upper dπ — π^* (bpy) state by a higher energy emission at 580 nm in a methanol glass at 77 K (τ₀ = 7.59 μs). Both emissions appear in a water—ethylene glycol solution containing 5% by weight polyvinyl alcohol at room temperature.     

Double hybrids and time-dependent density functional theory: An implementation and benchmark on charge transfer excited states

In this paper we present the implementation and benchmarking of a Time Dependent Density Functional Theory approach in conjunction with Double Hybrid (DH) functionals. We focused on the analysis of their performance for through space charge-transfer (CT) excitations which are well known to be very problematic for commonly used functionals, such as global hybrids.Two different families of functionals were compared, each of them containing pure, hybrid and double-hybrid functionals.The results obtained show that, beside the robustness of the implementation, these functionals provide results with an accuracy comparable to that of adjusted range-separated functionals, with the relevant difference that for DHs no parameter is tuned on specific compounds thus making them more appealing for a general use. Furthermore, the algorithm described and implemented is characterized by the same computational cost scaling as that of the ground state algorithm employed for MP2 and double hybrids.     

Molecular complexity via C-H activation: a dehydrogenative Diels-Alder reaction

Traditionally, C-H oxidation reactions install oxidized functionality onto a preformed molecular skeleton, resulting in a local molecular change. The use of C-H activation chemistry to construct complex molecular scaffolds is a new area with tremendous potential in synthesis. We report a Pd(II)/bis-sulfoxide-catalyzed dehydrogenative Diels-Alder reaction that converts simple terminal olefins into complex cycloadducts in a single operation.     

Hydrogen atom transfer reaction from excited carbazole to pyridine

The hydrogen bonding interaction between excited carbazole and pyridine was investigated in cyclohexane by an emission—absorption flash technique. Triplet carbazole is deactivated by pyridine with a rate constant of 4.9 × 10⁷ M⁻¹ s⁻¹, yielding the carbazyl radical with a reaction yield of unity. The triplettriplet absorption of carbazole hydrogen bonded with pyridine was not observed. By means of the triplet energy transfer from N-ethylcarbazole to the hydrogen-bonded carbazole it was found that the triplet state of the hydrogen-bonded carbazole yields the carbazyl radical wtih a reaction yield of 0.7. Excited singlet carbazole is deactivated by pyridine with a diffusion-controlled rate, yielding the carbazyl radical with a reaction yield of 0.1. Flashing of the hydrogen-bonded carbazole does not yield carbazyl radical. The difference in the reaction yields between the free and the hydrogen-bonded species indicates that the dynamic hydrogen atom transfer reaction occurs from the encounter state in competition with hydrogen bond formation.     

Quantum chemical study on excited states and charge transfer of oxazolo[4,5-b]-pyridine derivatives

The excitedstate intramolecular charge transfer of four oxazolo[4,5-b]pyridine derivatives with different electron donating and electron withdrawing groups was investigated using the time-dependent density functional theory. The vertical excitation energies and the electronic structures were explored. Their distinct properties of absorption and fluorescence spectra in solvent phase were explained according to the electronic coupling matrix elements calculated by the Mulliken-Hush theory. The sub-stituent on the oxazolo[4,5-b]pyridines will remarkably change their spectra properties and increase the first excited-state dipole moments. The effect of protonation on the absorption and fluorescence spectra was also investigated systematically. Our study suggests that the present method is feasible to explain charge transfer excitation and predict the properties of absorption and emission spectra in the studied systems.     

Substituent effects on twisted internal charge transfer excited states of N-borylated carbazoles and (diphenylamino)boranes

N-Boryl-substituted carbazoles (carBR(2)) and (diphenylamino)boranes (Ph(2)NBR(2)) with R = Mes (mesityl) and FMes [tris(trifluoromethyl)phenyl] substituents on boron exhibit large UV/vis Stokes shifts. To investigate the substituent effect on the magnitude of the Stokes shifts, we studied the electronic structure and spectroscopic properties of carBR(2) and Ph(2)NBR(2) with R = H, Mes, and FMes using hybrid density functional theory (B3LYP) and time-dependent density functional theory (TD-B3LYP) for ground and low-lying excited states. The lowest lying excited state with a nonvanishing oscillator strength is a twisted internal charge transfer (TICT) (1)A state in the C(2) point group, owing to a single-electron excitation from the nitrogen lone pair to the unoccupied boron p(z) AO, Nlp → Bp(z). Emission from these (1)A excited states are predicted to be much brighter than from the energetically close (1)B excited states that are not directly related to CT excitation from N to B, due to symmetry. An analysis of geometrical relaxations in the excited state and the state energies relative to the ground state energy of the equilibrium geometry reveals that (a) the carbazole skeleton induces a general red shift in UV/vis spectra, (b) bulky boryl substituents reduce the predicted Stokes shifts of TICT states, and (c) the presence of electron-withdrawing functional groups induces a further general red shift in UV/vis spectra but does not significantly alter Stokes shifts.     

Metal-to-metal electron-transfer emission in cyanide-bridged chromium-ruthenium complexes: effects of configurational mixing between ligand field and charge transfer excited states

Irradiations of the transition metal-to-transition metal charge transfer (MMCT) absorption bands of a series of cyanide-bridged chromium(III)-ruthenium(II) complexes at 77 K leads to near-infrared emission spectra of the corresponding chromium(II)-ruthenium(III) electron transfer excited states. The lifetimes of most of the MMCT excited states increase more than 10-fold when their am(m)ine ligands are perdueterated. These unique emissions have weak, low frequency vibronic sidebands that correspond to the small excited-state distortions in metal-ligand bonds that are characteristic of transition metal electron transfer involving only the non-bonding metal centered d-orbitals suggesting that the excited-state Cr(II) center has a triplet spin configuration. However, most of the electronically excited complexes probably have overall doublet spin multiplicity and exhibit an excitation energy dependent dual emission with the near in energy Cr(III)-centered and MMCT doublet excited states forming an unusual mixed valence pair.