X- ray photoemission study of the interaction of oxygen and air with clean cobalt surfaces

The interaction of oxygen with polycrystalline cobalt surfaces has been studied at 300 K (1 × 10^?6 to 1 × 10^?5 Torr) using high-resolution (monochromatized) X-ray photoemission. At high exposures (> 100 L nominal) CoO is identified as the product from the nature of the $\text{Co}\text{2}\text{p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{, 2}\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{, 3}\text{s}$, and valence band spectra. There is no evidence for measurable amounts of Co₃O₄ or Co₂O₃. Two O 1s features are observed at both high and low (10L) exposures. The dominant O 1s feature at 529.5 ± 0.2 eV corresponds to the oxide and a minor feature at 531.3 ± 0.2 eV is attributed to non-stoichiometric surface oxygen. Exposure to air produces quite different results, with a dominant O 1s feature at 531.5 ± 0.2 eV and dominant $\text{Co}\text{2}\text{p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ and $\text{2}\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ features centered at 781.3 ± 0.2 eV and 797.1 ± 0.2 eV. These three values are very close to those reported here for bulk Co(OH)₂. Ion etching of the air-exposed surface removes this dominant surface product rapidly revealing some oxide and finally metal.     

Trapping probabilities and desorption energies of alkali atoms on a clean and an oxygen covered tungsten (110) surface

Alkali atoms were scattered with hyperthermal energies from a clean and an oxygen covered (θ ≈ 0.5 ML) W(110) surface. The trapping probability of K and Na atoms on oxygen covered W(110) has been measured as a function of incoming energy (0–30 eV) and incident angle. A considerable enhancement of trapping on the oxygen covered surface compared to a clean surface was observed. At energies above 25 eV there are still K and Na atoms being trapped by the oxygen covered surface. From the temperature dependence of the mean residence time τ of the initially trapped atoms the pre-exponential factor τ₀ and the desorption energy Q were derived using the relation: $\text{τ = τ}{}_0\text{exp}\text{(}\text{Q}\text{kT}{}_{\mathrm{<mtext>s</mtext>}}\text{)}$. On clean W(110) we obtained for Li: $\text{τ}{}_0\text{= (8 ±}\text{8}\text{4}\text{) × 10}{}^{\mathrm{?14}}\text{sec}$, Q = (2.78 ± 0.09) eV; for Na: τ₀ = (9 ± 3) × 10^?14 sec, Q = (2.55 ± 0.04) eV; and for K: τ₀ = (4 ± 1) × 10^?13 sec, Q = (2.05 ± 0.02) eV. Oxygen covered W(110) gave for Na: τ₀ = (7 ±3) × 10^?15 sec, Q = (2.88 ± 0.05) eV; and for K: $\text{τ}{}_0\text{= (1.3 ±}\text{0.9}\text{0.6}\text{) × 10}{}^{\mathrm{?14}}\text{sec}$, Q = (2.48 ±0.05) eV. The adsorption on clean W(110) has the features of a supermobile two-dimentional gas; on the oxygen covered W(110) adsorbed atoms have the partition function of a one-dimen-sional gas. The binding of the adatoms to the surface has a highly ionic character in the systems of the present experiment. An estimate is given for the screening length of the non-perfect conductor W(110):k_s^?1≈ 0.5 Å.     

Deposition of nickel from Ni(CO)4 on palladium and iron surfaces studied by X-ray photoelectron spectroscopy

The interaction of nickel carbonyl, Ni(CO)₄, with evaporated palladium and iron surfaces has been studied at 90 and 290 K by X-ray photoelectron spectroscopy. The carbonyl is weakly adsorbed in molecular form at 90 K on the metals giving a $\text{Ni 2p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ peak at 854.6 eV, a C 1s at 287.2 eV and an O 1s at 533.8 eV. Some fraction of the carbonyl decomposes even at 90 K on iron to give deposited nickel atoms. In the interaction with palladium at 290 K, deposited nickel atoms $\text{(Ni 2p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{= 852.9 eV)}$ and chemisorbed CO are observed. A satellite feature of the $\text{Ni 2p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ peak varies depending on the quantity of the deposited nickel atoms; the main peak-satellite separation increases with increase in the quantity. The same variation is observed for evaporated nickel-palladium alloys. This can be ascribed to the difference in the electronic states of the nickel atoms. The difference is reflected in the reactivity of the atoms with O₂. With iron the deposited nickel atoms show an increase in binding energy of 0.4 eV in the $\text{Ni 2p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ Peak and no satellite when the number of nickel atoms is small. The oxidation of the surface is also studied.     

A LEED determination of the structures of Ru(001) and of CORu(001)−√3 × √3 R30°

The structures of Ru(001) and of the √3 × √3 R30° overlayer of CO on Ru(001) have been determined by LEED I–V measurements and comparison to calculations. Special attention was paid to accurate angular alignment, selection of a well-ordered portion of the surface, and avoidance of beam-induced changes of the CO layer. Five orders of reflexes over a range of 300 eV each were used for the clean surface and 7 orders over 200 eV each for the CO superstructure. For the clean surface, a slight contraction of the first layer spacing (by 2%) was found which gave r-factors of 0.04 (Zanazzi-Jona) and 0.16 (Pendry) for 5 non-degenerate beams. For the CO structure the most probable geometry is the on-top site with spacings $\text{d(}\text{RuC}\text{) = 2.0 ± 0.1}\text{A}\text{?}\text{and}\text{d(}\text{CO}\text{) = 1.10 ± 0.1}\text{A}\text{?}\text{(r}{}_{\mathrm{<mtext>ZJ</mtext>}}\text{= 0.21; r}{}_{\mathrm{<mtext>P</mtext>}}\text{= 0.51)}$. The two threefold hollow and the bridge sites can be clearly excluded.     

The surface structure of V(100)

The structure of the clean V(100)?(1×1) surface is determined, based on an r-factor comparison of experimental LEED intensity-energy spectra with the results of multiple-scattering model calculations. Minimization of the r-factor with respect to the calculational variables leads to optimum values of the first and second interlayer spacings of $\text{d}{}_1\text{=1.41 ± 0.01}\text{A}\text{?}$ and $\text{d}{}_2\text{=1.53 ±0.01}\text{A}\text{?}$, corresponding respectively to a contraction of 7% and an expansion of 1% with respect to the bulk value of $\text{d}{}_{\mathrm{<mtext>B</mtext>}}\text{=1.5141}\text{A}\text{?}$. Preliminary studies of the adsorption of O₂ and CO confirm that the V(100)?(5×1) structure observed during the process of cleaning the crystal is not characteristic of the clean surface, as suggested recently by Davies and Lambert (Surface Science 107 (1981) 391), but rather is associated with the presence of a significant concentration of oxygen in the surface region.     

Oscillator strengths in the Cameron system of carbon monoxide

Relative oscillator strengths in the Cameron system of CO(a³Π ← X¹Σ) have been observed in absorption for six bands (υ′ = 0–5, υ″ = 0) with the result, normalized to the absolute (0, 0) band measurement of Hasson and Nicholls, $\text{?}{}_{00}\text{= (1.62±0.07) × 10}{}^{\mathrm{?7}}$, $\text{?}{}_{10}\text{= (1.96±0.09) × 10}{}^{\mathrm{?7}}$, $\text{?}{}_{20}\text{= (1.41±0.04) × 10}{}^{\mathrm{?7}}$, $\text{?}{}_{\mathrm{3\; 0}}\text{= (0.72±0.03) × 10}{}^{\mathrm{?7}}$, $\text{?}{}_{40}\text{= (0.31±0.02) × 10}{}^{\mathrm{?7}}$, $\text{?}{}_{50}\text{= (0.14±0.01) × 10}{}^{\mathrm{?7}}$. The density of CO was modulated with a motor-driven vacuum valve and synchronous fluctuations (?1 per cent) in the transmitted intensity detected with a lock-in amplifier. Peak pressure in the 21 cm absorption cell was approximately 10 torr. A curve of growth analysis was used to correct saturation effects by less than 3 per cent.     

Pionic and muonic X-ray transitions in liquid helium

Energies and intensities of pionic and muonic X-rays in liquid ⁴He have been measured with a Si (Li) detector. The energy shift due to strong interaction effects of the pionic 1s level in ⁴He was determined to be ?75.7±2.0 eV. The natural line width of this level is 45±3 eV. These values are compared with different theoretical predictions. Cascade calculations, including external Auger effect and sliding transitions, have been performed to reproduce the yields of the muonic and pionic transitions. The pionic 2p level width is deduced: $\text{Γ}{}_{\mathrm{<mtext>2</mtext><mtext>p</mtext>}}\text{= (1.1 ± 0.5) × 10}{}^{12}\text{sec}{}^{\mathrm{?1}}\text{=}\text{(7.2±3.3) × 10}{}^{\mathrm{?4}}\text{eV}$.     

Xe monolayer adsorption on Ag(111) I. Structural properties

The monolayer of adsorbed xenon on the (

1) surface of silver was studied using low- energy electron diffraction. The structure is an hexagonal lattice aligned with but out of registry with the substrate. The Xe-Xe spacing at 25 K is 4.44 ± 0.01 Å in the full monolayer and 4.47 ± at less than full coverage. The Xe-Ag spacing is 3.5 ± 0.1 Å. Here $\text{〈u}{}_{\mathrm{\perp }}\text{〉}{}^2\text{T}$, the meansquare vibrational amplitude normal to the surface divided by the temperature is (1.83 ± 0.4 × 10^?4 A²/K. The heat of adsorption is 0.28 ± 0.03 eV/atom.     

Direct transfer and two-step processes in the 42Ca(α, 3He)43Ca reaction

The ⁴²Ca(α, ³He)⁴³Ca reaction has been studied at 36 MeV incident energy. Angular distributions have been measured from 4° to 42° using a split-pole spectrometer and position sensitive Si detectors, for about 40 levels located up to 6 MeV excitation energy. A local zero-range DWBA analysis has been carried out; l = 3 and 4 assignments are tentatively proposed for levels located above 4 MeV excitation energy, indicating a strong fragmentation of the $\text{1}\text{f}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ strength between 4 and 6 MeV and the location of the main component of the $\text{1}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ strength above 6 MeV. A number of weakly excited levels cannot be reproduced by DWBA analysis. Their angular distributions have been compared with the results of coupled-reaction-channel calculations assuming two-step excitation of weak coupling states with a [⁴²Ca¹ ? $\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}$ structure. A reasonable agreement has been obtained, confirming that the two-step process cannot be neglected in the analysis of the (α, ³he) reaction.     

Uniaxial stress effects on the 3.4 eV optical structure of silicon by schottky-barrier electroreflectance

The electroreflectance of Si under uniaxial stress has been measured in the 3.0–4.0 eV region at 77 K. The results indicate that the dominant structure in this energy region is attributed to Λ^v₃ → Λ^c₁ (or L^v_3′ → L^c₁ transition. The deformation potentials of these bands are determined to be $\text{D}{}^1{}_1\text{= -7 ± 3 eV,}\text{D}{}^3{}_3\text{= 4 ± 1 eV}\text{and}\text{D}{}^5{}_1\text{= 5 ± 2 eV}$.     

Three-body effective interactions in the f72 region

The three-body effective forces in a pure $\text{(0}\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}\text{)}{}^{\mathrm{<mtext>n</mtext>}}$ model space are calculated to second order in perturbation theory. The full effect of the $\text{(0f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}\text{1}\text{p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{)}{}^3$ configuration on the effective interaction in the $\text{(0}\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}\text{)}{}^3$ model space leading to three-body forces is calculated to all orders in G. The resulting three-body force matrix elements come out much weaker than demanded by phenomenological fits. Their main effect is to push the spectra as a whole up in energy, improving the fit of the calculated ground state binding energies with experiment. The biggest three-body-force contribution appears toward the end of the $\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}$ shell where its main object is to compensate for Pauli violations arising from the two-body diagrams.     

Neutron resonance parameters and radiative capture cross sections of 147Sm and 149Sm

Neutron capture and transmission measurements have been carried out on the separated isotopes of ¹⁴⁷Sm (98.34 %) and ¹⁴⁹Sm (97.72 %) at the 55 m time-of-flight station of the Japan Atomic Energy Research Institute electron linear accelerator. Resonance energies and neutron widths for a large number of resolved resonances were determined up to 2 keV for ¹⁴⁷Sm and 520 eV for ¹⁴⁹Sm. Radiation widths for 5 resonances in ¹⁴⁷Sm + n and 7 resonances in ¹⁴⁹Sm + n were derived. The s-wave strength functions, average level spacings and average radiation widths were obtained to be: $\text{10}{}^4\text{S}{}_0\text{= 4.8 ± 0.5,}\text{D}\text{= 5.7 ± 0.5}\text{eV}$ and $\text{Γ}{}_{\mathrm{\gamma }}\text{= 69 ± 2}\text{meV for}{}^{147}\text{Sm}$; a $\text{10}{}^4\text{S}{}_0\text{= 4.6 ± 0.6,}\text{D}\text{= 2.2 ± 0.2}\text{eV}$ and $\text{Γ}{}_{\mathrm{\gamma }}\text{= 62 ± 2}\text{meV for}{}^{149}\text{Sm}$. The average capture cr sections were deduced from 3.3 to 300 keV with an estimated accuracy of 5 to 15 %. The measured capture cross sections for ¹⁴⁹Sm are largely different from the evaluated data, which are obtained based on the statistical model calculation. Possible reasons for this disagreement are discussed.     

Lifetime measurements of 7P levels of Cs(I) by means of laser excitation

Measurements of the lifetimes of the $\text{7}{}^2\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and $\text{7}{}^2\text{P}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ levels of Cs are described. The populations of these excited levels were produced by using a tunable dye laser. The fluorescence signals from a gated photomultiplier were recorded by analog sampling. The results of the measurements are 133±2 and 155±4 ns for the 7${}^2\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ levels, respectively.     

Measurement of the background energy content of Nd-glass picosecond pulses with saturable absorbers

The background energy content of a mode-locked Nd-glass laser is determined with photodetectors and saturable absorbers. By comparing the signal height of a fast detector with the readout of an integrating energy meter the noise energy E_u2 outside the rise-time of the fast detector is measured. The background energy E_u1 within the rise-time is analysed by transmission measurements through two subsequent absorber cells. The obtained mean background to pulse energy (and intensity) ratios of ( and indicate a high degree of mode-locking.     

Coverage and adsorption-site dependence of core-level binding energies for tin and lead on Al(111) and Ni(111)

Thin layers (0.2–10 monolayers) of Pb and Sn were prepared on Al(111) and Ni(111) surfaces and characterized by means of LEED, AES, UPS and work-function measurements. The binding energy of the shallow Sn 4d and Pb 5d core-levels was investigated with respect to coverage and adsorption-site-dependent changes. On Al(111) the Sn and Pb monolayers exhibit ordered, two-domain, aligned but not in registry structures. For these layers core-level binding energies were found identical to those of the bulk metals. On Ni(111), Pb gives rise to a 3 × 3 structure, followed then by a 4 × 4 structure at higher coverages. The Pb 5d core-level binding energies shift continuously to higher values. A final shift of 0.42 eV is reached after about 2 monolayers. Sn on Ni(111) exhibits two welll separated peaks lying at 23.70 and 23.97 eV for the $\text{4d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ line. These two lines can be correlated with two different adsorption sites which have to be assumed for the $\text{(}\text{3}\text{×}\text{3}\text{)R30°}$ and the (2 × 2) structure found at different coverages. The binding energy shifts are discussed in a model based on a Born-Haber cycle.     

Magnetic moment of the 2543 keV 7+ state in 40K

The nuclear g-factor of the 2543 keV, 7⁺ state ⁴⁰K has been measured as g = 0.59 ± 0.10. Time-integral perturbed angular distributions were measured in an external magnetic field and, after implantation, in the hyperfine field at potassium in nickel. The experimental value is discussed within the $\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}{}^2\text{and}\text{d}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}{}^{\mathrm{?2}}\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}{}^2$, configurations.     

Photoemission of Xe and Kr adsorbed on the W(110) plane

The UPS and XPS spectra of Xe adsorbed on clean, O, CO, and Xe covered W(110) surfaces and the UPS spectrum for Kr on clean and O covered W(110) surfaces have been investigated. On clean W, Xe and Kr show a splitting of the $\text{5p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ and $\text{4p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ hole states respectively. For Xe the coverage dependence of this splitting was investigated in detail; neither the positions nor the intensity ratio of the substates are coverage dependent for θ ? 0.04, suggesting that splitting is due to differences in the image interaction of the $\text{m}{}_{\mathrm{j}}\text{= ±}\text{3}\text{2}$ and $\text{m}{}_{\mathrm{j}}\text{= ±}\text{1}\text{2}$ components. For Xe equal shifts, relative to vacuum, of ~1.0 eV were observed for 5p, 4d, and 3d levels, suggesting that initial state effects are small. Image interaction for Xe and Kr on clean W could best be fitted by assuming an increase, rather than a decrease in the effective hole-image separation from the nominal value, suggesting that the image plane is moved back into the metal by a screening length. For Xe adsorbed on $\text{Xe}\text{W}$(110), or on virgin-$\text{CO}\text{W}\text{(110)}$ polarization of the intermediate layers was found to contribute significantly to relaxation. Coadsorbed oxygen broadened Xe 5p and Kr 4p peaks. There was an almost linear relation between O 2p UPS intensity at the energies of the various peaks and the amounts of broadening, suggesting that the latter results from resonance neutralization by electrons from the O 2p states.     

Spectroscopy of 42Ca from 41Ca(d,p)

Energy levels in ⁴²Ca up to 7.8 MeV have been studied in the neutron capture reaction ⁴¹Ca(d, p)⁴²Ca with 12 MeV bombarding energy. Ninety-four excited states have been identified and angular distributions have been measured in the interval from 5° to 110° by means of a broad-range magnetic spectrograph. The angular distributions together with DW calculations have been used to determine I_n values and spectroscopic factors. The $\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}$ strength sum agrees with shell-model expectations if the f_{$\text{7}\text{2}$} spectroscopic factors are renormalized by $\text{1}\text{0.75}$, in line with other $\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}$. transfer experiments on ⁴⁰Ca and ⁴¹Ca. A similar renormalization of the l_n = 1 spectroscopic factors brings this strength sum in accordance with the shell-model calculations. The effective ($\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}{}^2$) matrix elements for ⁴²Ca are compared with the corresponding matrix elements of ⁴²Sc and ⁴⁸Sc. The differences between the three sets of matrix elements are of the order of a few hundred keV or less. The monopole centroid energy of the ($\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}\text{)}{}^2$ multiplet is shifted downwards in the mass-42 nuclei compared to ⁴⁸Sc, possibly indicating the importance of the monopole pairing force near ⁴⁰Ca.     

Two-magnon Raman scattering in the two-dimensional antiferromagnet K2FeF4

Two-magnon Raman scattering in the planar quadratic antiferromagnet K₂FeF₄ is investigated. The temperature dependence of the energy shift is in good agreement with second-order Green-function theory, as is the linewidth at low temperature. Numerical results, including renormalization, are the Heisenberg exchange $\text{J}\text{k}{}_{\mathrm{B}}\text{= ?14.5 ± 0.7}\text{K}$ and the anisotropy $\text{Δ(T = 0) = gμ}{}_{\mathrm{B}}\text{H}{}_{\mathrm{A}}\text{4|J|S = 0.18 ± 0.05}$, but with $\text{J[1 + Δ(T = 0)]}\text{k}{}_{\mathrm{B}}\text{= ?17.06 ± 0.10}\text{K}$.     

Isomers and high-spin states in 205At

The properties of high-spin states in ²⁰⁵At have been investigated to $\text{J ?}\text{37}\text{2}$ and an excitation energy of > 4.0 MeV. The properties of the $\text{29}\text{2}$⁺ isomer at 2340 keV have been established and those of the $\text{25}\text{2}$⁺ isomer at 2063 keV have been further investigated. In the present study the mean lives of these isomers have been determined as 11.2±0.2μs and 98±2 ns respectively. The M2 branch of the $\text{13}\text{2}$⁺ state at 970 keV to the $\text{9}\text{2}$⁺ ground state has been measured. This decay is attributed to a proton single-particle $\text{i}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}\text{→}\text{h}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ transition. The trend of excitation energies of a number of proton excitations in the odd-mass nuclei from ²¹¹At to ²⁰¹At has been compared to the corepolarization model and the average $\text{ν}\text{f}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}\text{π}\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}$ interaction energy has been deduced. Comments are made upon probable configurations for many of the levels.