The conventional magnetic materials used in present-day technology, such as Fe, Fe2O3, Cr2O3, SmCo5, Nd2Fe14B, etc. are all atom-based, whose synthesis requires high-temperature routes. Employing ambient-temperature synthetic organic chemistry, it has become possible to engineer a bulk molecular material with long-range magnetic order, primarily due to the weak nature of intermolecular interactions in it. Typical synthetic approach to design molecule-based magnets consists of choosing molecular precursors, each bearing an unpaired spin, and assembling them in such a way that there is no compensation of spins at the scale of the crystal lattice. Magnetism being a co-operative effect, the spin-spin interaction must extend to all the three dimensions, either through space or through bonds. Specific occurrence of ‘spin delocalisation’ and ‘spin polarisation’ in molecular lattices is helpful in bringing about ferromagnetic interaction by facilitating necessary intermolecular exchange interactions. Since the first successful synthesis of molecular magnets in 1986, a large variety of them have been synthesized, which can be classified on the basis of the chemical nature of the magnetic units involved: organic systems, metal-based systems, hetero-bimetallic assemblies, or mixed organic-inorganic systems. The design of molecular magnets has also opened the doors for the unique possibility of designing polyfunctional molecular materials, such as magnets exhibiting second-order optical nonlinearity, liquid crystalline magnets, or chiral magnets. Solubility of molecular magnets, their low density and biocompatibility are attractive features. Being weakly colored, unlike the opaque classic magnets, possibilities of photomagnetic switching can be envisaged. Persistent efforts continue to design the ever-elusive polymer magnets for applications in industry. While providing a brief overview of the field of molecular magnetism, we highlight some recent developments, with emphasis on a few studies from the author's own lab. 相似文献
A series of amphiphilic copolymers is prepared by copolymerization of choline methacrylate with 1,1,2,2-tetrahydroperfluorooctyl methacrylate in varying amounts. The copolymers bearing fluorocarbon chains are studied concerning their effects on viscosity, solubilization and surface activity in aqueous solution, exhibiting a general behavior characteristic for polysoaps. The results are compared with the ones obtained for an analogous series of amphiphilic copolymers bearing hydrocarbon chains. 相似文献
A new series of azobenzene‐containing polyfluorenes have been successfully prepared through polymer reactions by the utilization of “click” chemistry. All the polymers were well characterized and soluble in common solvents. By the application of the concept of “suitable isolation group”, the macroscopic nonlinear optical (NLO) properties of the polymers could be boosted to as large as three times that of the polymer without isolation moieties. Also, all the polymers were thermally stable, and demonstrated good procesability, coupled with improved optical transparency. Thus, they are good candidates for the practical applications as new photonic materials.
Water-soluble polymers containing amine, carboxylic acid, and sulfonic acid groups were investigated as polychelatogens through the liquid phase polymer-based retention, LPR technique, under different experimental conditions. The metal ions investigated are: Ag(I), Cu(II), Co(II), Ni(II), Ca(II), Hg(II), and Cr(III). An important effect of the pH and the ligand type was observed on the metal ion retention. As the pH increases the metal ion retention increases. Two types of metal ion interactions are involved: coordination and electrostatic. 相似文献
Amphiphilic hybrid π‐conjugated polymers that have polyhedral oligomeric silsesquioxanes on their side chains have been successfully synthesized by the Sonogashira–Hagihara polycondensation reaction. The obtained polymers were studied with ultraviolet‐visible absorption and photoluminescence spectra. In these polymers, the π‐conjugation length was extended along the poly(p‐phenylene‐ethynylene) backbone. Furthermore, the content of the POSS substituents can influence the aggregation behavior of the polymers and subsequent luminescent properties.
Summary: The oxidative polymerization of N‐glucosylaniline was carried out using ammonium persulfate as the oxidant in phosphate buffer. The structure of the isolated polymer was determined by 1H NMR, 13C NMR, and UV‐vis spectroscopy to be the polyaniline having glucose residues attached to the general polyaniline unit. Participation of the ortho‐position of the aromatic ring in the polymerization was also confirmed by the analyses.
The oxidative polymerization of N‐glucosylaniline. 相似文献
The degradation and repair of uniform sequence-defined poly(N-substituted urethane)s was studied. Polymers containing an ω-OH end-group and only ethyl carbamate main-chain repeat units rapidly degrade in NaOH solution through an ω→α depolymerization mechanism with no apparent sign of random chain cleavage. The degradation mechanism is not notably affected by the nature of the side-chain N-substituents and took place for all studied sequences. On the other hand, depolymerization is significantly influenced by the molecular structure of the main-chain repeat units. For instance, hexyl carbamate main-chain motifs block unzipping and can therefore be used to control the degradation of specific sequence sections. Interestingly, the partially degraded polymers can also be repaired; for example by using a combination of N,N′-disuccinimidyl carbonate with a secondary amine building-block. Overall, these findings open up interesting new avenues for chain-healing and sequence editing. 相似文献
This article provides a comprehensive review of the synthesis, properties and applications of organometallic polymers of the transition metals. The different classes of organometallic polymers are described according to their structural make‐up, as well as by their methods of synthesis. A number of examples of each class are given to emphasize the richness and diversity in these areas of research. In addition to linear polymers, hyperbranched, crosslinked, star and dendritic polymers are also described. The properties that transition metal‐containing organometallic polymers possess, as well as the applications that these materials have found in various domains are highlighted.