共查询到20条相似文献,搜索用时 31 毫秒
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超高效合相色谱法定性与定量分析补肾健脑颗粒 总被引:2,自引:0,他引:2
用超高效合相色谱法(Ultra performance convergence chromatography,UPC2)建立补肾健脑颗粒及各药材提取物的指纹图谱,对补肾健脑颗粒主要色谱峰进行归属分析,并测定有效成分β-蜕皮甾酮和松果菊苷的含量。样品经乙醇提取后,进样1μL,用Waters ACQUITY UPC2TMBEH柱(100 mm×3.0 mm,1.7μm)分离,柱温为40℃,以超临界CO2-0.05%H3PO4-甲醇溶液为流动相,梯度洗脱,流速为0.8 m L/min。分析补肾健脑颗粒和各药材提取物的UPC2指纹图谱,利用各峰相对保留时间、紫外光谱图及部分对照品归属主峰。结果表明,补肾健脑颗粒UPC2指纹图谱中15个主峰来源明确,其中12号峰为β-蜕皮甾酮,含量为380μg/g,15号峰为松果菊苷,含量为9.562 mg/g。与HPLC和UPLC法相比,本方法简便、快速,精密度高,重现性好。 相似文献
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对施用新型“农药”——植物营养素后几种不同农作物的前处理方法进行了研究,提出了操怍简便、精密、准确的测定方法,为在我国建立评价施药后农作物中微量元素变化水平提供了可靠的测试手段。并通过对施药前后,农作物中锌、铜、铁三种微量元素含量的测定和比较,为植物营养素类“农药”的卫生鉴定提供了新的指标。 相似文献
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1 学生学情分析和教学资源的处理 北京市第五十中学高二(一)班为实验班,在2007年5月学完人教版高二化学第七章糖类油脂蛋白质以后,在糖类的主要化学性质方面有一定的基础,可以在此基础上加以拔高,学习淀粉的消化过程、生理作用、在人体中生理转化过程中所表现出的部分化学性质以及代谢过程中的某些生化反应.同时补充学习维生素的相关知识. 相似文献
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营养素能有效防治亚临床铅中毒,阐述了钙、铁、锌、硒及维生素等营养素与铅毒性作用的相互关系。 相似文献
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干燥剂是实验室常需应用的。但是在不同的场合与不同的要求下,需要有选择地使用。现在将实验室常用的几种干燥剂的性质与性能介绍于后,另外对硅胶与过氯酸镁的装备也作一简要介绍。1.氯化钙:CaCl_2·6H_2O 为无色结晶,加热失去4H_2O 而变为白色多孔的二水化合物 CaCl_2·2H_2O,再赤热时,完全失去结晶水而变为白色结晶 CaCl_2。由于CaCl_2常含有 CaO,因此具硷性反应。CaCl_2易溶于水并放出大量热。它具有强的吸湿性,常温时它上面的 相似文献
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对于均相与非均相反应动力学研究一般根据不同反应类型与条件选择不同的反应器,而对不同的反应器,求取反应速度的数学方法也不同。例如,选用连续搅拌的恒容反应器、循环反应器(包括内循环和外循环反应器)或微分反应器时,这种类型的反应器可视为反应器内各 相似文献
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好斗、逃学等不良行为的产生不但是一种心理的作用,而且还与人体内的一些化学物质有关.一些内源性化学物质在人体中含量的多少对人的心理健康有直接的影响,例如:钙可使人镇静;镁能减轻心理压力;锌与记忆和智力有关;多巴胺能使人产生快感等. 相似文献
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Airapetyan S. S. Balayan G. G. Khachatryan A. G. 《Russian Journal of Applied Chemistry》2001,74(3):519-521
A possibility of production of nonporous magnetic matrices with two-layer coating based on cobalt ferrite with the aim to use these matrices for fixation of biologically active substances was considered. The function of the first layer (silica coating) is to shield the cobalt ferrite surface and provide conditions for applying the second (polymer) layer containing various functional groups. 相似文献
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《液相色谱法及相关技术杂志》2012,35(1):81-92
Abstract Ion-pair HPLC of some basic drugs using alkane sulfonic acid as counter ion is described. Various ways to manipulate the retention of the compounds are discussed. 相似文献
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The adsorption of polar organic substances (methanol, pyridine, and acetonitrile) and water was studied from the vapor phase on microporous adsorbent prepared by the substitution of polyhydroxyaluminum ions for the sodium ions of natural montmorillonite clay. The differential isosteric heats of adsorption of these substances were calculated and analyzed in a wide range of fillings. 相似文献
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高效液相色谱法检测食品中多种香料共存时的罂粟壳 总被引:4,自引:0,他引:4
采用高效液相色谱法检测食品中多种香料共存时的罂粟壳。样品经碱化后采用氯仿 乙醇 (体积比为 9∶1)提取 ,在苯基柱上以乙腈 甲醇 水为流动相进行分离 ,外标法定量。罂粟碱 ,吗啡 ,可待因在 1 2mg/L~ 10 0mg/L范围内线性关系良好 ,平均回收率为 79.3%~ 86 .1%。该方法的专属性和准确度较高。 相似文献
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Effect of molecular interaction between species undergoing coadsorption on the potential dependences of coverages 1and 2, surface tension, and equilibrium and nonequilibrium differential capacitances is analyzed on the basis of a set of isotherms for coadsorption of components 1 and 2 within a common monolayer when the EDL inner part obeys a model of three parallel capacitors. It is shown that, in a certain potential interval, at a certain ratio between adsorption parameters, the set of isotherms may have solutions that correspond to a minimum in a free energy surface, which is a function of 1and 2. 相似文献
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The simplest topological molecular parameters were applied to predict critical temperatures and critical pressures in terms of the QSAR/QSPR theory. Through the development of four different calculation schemes, the convenience of using the atomic coordination numbers for different atoms and the corresponding identity of chemical bonds was shown. A satisfactory agreement between the theoretical and experimental data was attained. Some limitations of the proposed approach are pointed out. 相似文献
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Dr. Longteng Tang Dr. Yunkai Xu Weiyi Zhang Yiming Sui Alexis Scida Sean R. Tachibana Mounesha Garaga Sean K. Sandstrom Nan-Chieh Chiu Prof. Kyriakos C. Stylianou Prof. Steve G. Greenbaum Prof. Peter Alex Greaney Prof. Chong Fang Prof. Xiulei Ji 《Angewandte Chemie (International ed. in English)》2023,62(35):e202307212
Aqueous electrolytes typically suffer from poor electrochemical stability; however, eutectic aqueous solutions—25 wt.% LiCl and 62 wt.% H3PO4—cooled to −78 °C exhibit a significantly widened stability window. Integrated experimental and simulation results reveal that, upon cooling, Li+ ions become less hydrated and pair up with Cl−, ice-like water clusters form, and H⋅⋅⋅Cl− bonding strengthens. Surprisingly, this low-temperature solvation structure does not strengthen water molecules’ O−H bond, bucking the conventional wisdom that increasing water's stability requires stiffening the O−H covalent bond. We propose a more general mechanism for water's low temperature inertness in the electrolyte: less favorable solvation of OH− and H+, the byproducts of hydrogen and oxygen evolution reactions. To showcase this stability, we demonstrate an aqueous Li-ion battery using LiMn2O4 cathode and CuSe anode with a high energy density of 109 Wh/kg. These results highlight the potential of aqueous batteries for polar and extraterrestrial missions. 相似文献
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H. G. Zachmann 《Angewandte Chemie (International ed. in English)》1974,13(4):244-252
Unlike low molecular weight substances, high polymers do not crystallize completely. However long the crystallization process is continued, they still consist of a mixture of crystalline and non crystalline regions. In the undrawn material, these regions form larger units which are known as spherulites. Questions that are of special interest concern the arrangement of the chains in the noncrystalline regions, the causes of chain folding, and the imperfections in the crystals. The incomplete crystallization is a consequence of kinetic inhibitions. This can be deduced from the fact that the crystalline fraction increases with rising crystallization temperature. If polymerization is carried out in the solid crystalline state, one obtains a completely crystalline polymeric material. 相似文献