Screening of strongly charged macroparticles in liquid electrolyte solutions

A modified Poisson-Boltzmann model has been proposed which makes it possible to describe the screening of strongly charged macroparticles in liquid electrolyte Z: Z solutions in the case when parameter B= ZeQ₀/εRT?1(Q₀ is the surface electric charge, T is the temperature, ε is the solution permittivity, and Z is the valence of ions) provided that the solution is dilute: κR ≡ (8πZ²e²n_i0/εT)^1/2R?1 (n_i0 is the equilibrium number density of ions). It is assumed that the charge Q₀ of a macroparticle appears as a result of adsorption of ions of a certain polarity on its surface. Quantitative criteria of division of dissolved ions into capable and incapable of adsorption are formulated. For aqueous solutions, the adsorption mechanism always leads to values of B ? 1. It is shown that the charge inversion effect predicted by other authors on the basis of different models must be observed for such solutions for all Z ≥ 1. The effect of Brownian movement of macroparticles on their screening is considered. It is shown that viscous forces emerging during such movement lead to peripheral destruction (“washing out”) of the screening ionic shell of macroparticles and, as a result, to violation of their electroneutrality. This results in the emergence of two types of oppositely charged compound particles with small radii close to R and with radii much larger than R, the charge polarity of the latter being opposite to the polarity of Q₀. It is found that both types of ions of compound particles obey the “law of distribution” of the mean energy of their electric field, expressed by formula (29). The problem of ionic screening of gas bubbles accompanied by the formation of bubstons (bubbles stabilized by ions) is considered separately. It is shown that the bubston radius R in pure water and in aqueous solutions of electrolytes is equal to 14 nm irrespective of the ion number density n_i0. The value of n_i0 determines the number density n _b of bubstons themselves, which are formed spontaneously under equilibrium conditions.     

Effective refractive index of a quasi-two-dimensional polydomain film of a conjugated polymer

The relation between the effective ordinary refractive index n* = (n _o n _e )^1/2 of a quasi-two-dimensional polydomain uniaxial film of a conjugated polymer F8BT in the visible transparency region and the refractive indices (n _o,e ) of uniaxial domains with the optical axes randomly oriented in the plane of the film has been confirmed experimentally. The permissible interval of variations in n* has been established and a strong spectral dispersion of this interval near the long-wavelength electronic absorption band of the film has been demonstrated.     

Grundzustand eines Fermi-Gases mit hard-sphere-Wechselwirkung

The decomposition of the ground state wave function of a Fermi gas interacting via hard core potentials into cluster functionsS _n leads to a systematic expansion of wave function and energy in powers of the parameterc=P _F r _c (r _c =hard core radius,P _F =Fermi momentum). For instance,S _n has the order of magnitudec ^n-λ-1, if λ=number of Fermion coordinates with distances smaller thanr _c . The first three energy terms agree with the ones given by other authors. Any occurrence of singular terms in the intermediate steps of the derivation can be avoided     

On correlators for high multiplicity events

We present the results of the study of the energy correlators K₂(n) and K₃(n) and their ratio R₃(n) as a function of the hadron multiplicity at the LHC. The PYTHIA generator has been used. PYTHIA predicts that R₃(n) is not dependent on multiplicity. K₂(n), K₃(n), and the R₃(n) ratio can be studied at ATLAS.     

Charged <Emphasis Type="Italic">ρ</Emphasis>-meson production in neutrino-induced reactions at &lt;<Emphasis Type="Italic">E</Emphasis><Subscript><Emphasis Type="Italic">ν</Emphasis></Subscript>&gt;≈ 10 GeV

The production of charged ρ mesons on nuclei and nucleons is investigated in charged current neutrino interactions at moderate energies (〈E _〉 ≈ 10 GeV), using the data obtained with SKAT bubble chamber. No strong nuclear effects are observed in ρ ⁺ and ρ ^? production. The fractions of charged and neutral pions originating from ρ decays are obtained and compared with higher-energy data. From analysis of the obtained and available data on ρ ⁺ and K*⁺(892) neutrino production, the strangeness suppression factor is extracted: λ _s = 0.18 ± 0.03. Estimation is obtained for cross section of coherent ρ ⁺ neutrino production on nuclei.     

Proton-proton interaction with high multiplicity at energy of 70 GeV (proposal)

The goal of the proposed experiment is to investigate the collective behavior of particles in the process of multiple hadron production in pp interaction pp → n _π π + 2N at the beam energy E_lab = 70 GeV. The domain of high multiplicity n _π = 30–40, or z = n/\(\bar n\) = 4–6, will be studied. Near the threshold of reaction n _π → 69, z → z_th = 8.2, all particles acquire small relative momentum Δq < 1/R, where R is the dimension of the particle production region. As a consequence of multiboson interference, a number of collective effects may show up: (a) a drastic increase in the partial cross section σ(n) of production of n identical particles is expected, compared with commonly accepted extrapolation; (b) the formation of jets consisting of identical particles may occur as a result of the multiboson Bose-Einstein correlation (BEC) effect; (c) a large fluctuation of charged n(π⁺,π^?) and neutral n(π⁰) components and onset of centauros or chiral condensate effects are anticipated; (d) an increase in the rate of direct γ as a result of the bremsstrahlung in the partonic cascade and annihilation of π⁺π^? → nγ in dense and cold pionic gas or condensate is expected. In the domain of high multiplicity z ≥ 5, a major part of the c.m. energy \(\sqrt s = 11.6\) GeV is materialized, leading to a high-density thermalized hadronic system. Under this condition, a phase transition to cold quark-gluon plasma (QGP) may occur. The search for QGP signatures like large intermittency in the phase-space particle distribution and an enhanced rate of direct photons will be performed. The experimental setup is designed for detection of rare high-multiplicity events. The experiment is to be carried out at the extracted proton beam of the IHEP U-70 accelerator. The required beam intensity is ～10⁷ s^?1. Under the assumption that the partial cross section σ(n _π = 35) = 10-1 nb, the anticipated counting rate is 10-1 events/h. The multiboson BEC enhancement may drastically increase the counting rate.     

The Structure of Radiative Tunnel Recombination Sites in Emulsion Microcrystals of AgBr(I)

To identify the structure of emissive tunnel recombination sites in the emulsion microcrystals of silver bromide AgBr(I) with iodine contaminations and to determine the role of an emulsion medium in their formation, the temperature dependence of the luminescence spectra in the range from 77 to 120 K, the kinetics of the growth of the maximum luminescence intensity value at λ ≈ 560 nm, and the luminescence flash spectrum stimulated by the infrared light are investigated. Two types of the AgBr_{1 – x}(I _x ) (x = 0.03) microcrystals—namely, obtained in an aqueous solution and on a gelatin substrate—are used in the studies. It is established that the emissive tunnel recombination sites with a luminescence maximum at λ ≈ 560 nm in AgBr_{1 – x}(I _x ) (x = 0.03) are the {(I _a ^- I _a ^- )Ag _i ⁺ } donor–acceptor complexes with the I _a ^- iodine ions located in neighbor anionic sites of the AgBr(I) crystal lattice, next to which the Ag _i ⁺ interstitial silver ion is positioned. With an increase in the temperature, the {(I _a ^- I _a ^- )Ag _i ⁺ } sites undergo structural transformation into the {(I _a ^- I _a ^- )Ag_in⁺} sites, where n = 2, 3, …. Moreover, the {(I _a ^- I _a ^- )Ag _in ⁺ } sites (n = 2) after the capture of an electron and hole also provide the tunnel recombination with a luminescence maximum at λ ≈ 720 nm. The influence of an emulsion medium consists in that gelatin interacts with the surface electron-localization sites, i.e., the interstitial silver ions Ag _in ⁺ , n = 1, 2, and forms the complexes {Ag _in ⁰ G⁺} (n = 1, 2) with them. The latter are deeper electron traps with a small capture cross section as compared to the Ag _in ⁺ sites (n = 1, 2) and that manifest themselves in that the kinetics of the luminescence growth in AgBr(I) to a stationary level at λ ≈ 560 nm is characterized by the presence of “flash firing.” At the same time, the luminescence flash stimulated by IR light, for which the Ag _in ⁺ (n = 1, 2) electron-localization sites are responsible, is absent. It is supposed that the electrons localized on the {Ag _in ⁺ G⁺} complexes (n = 2) retain the capability for emissive tunnel recombination with holes localized on paired iodine sites with a luminescence maximum at λ ≈ 750 nm.     

Refractometry of mechanically compressed (NH<Subscript>4</Subscript>)<Subscript>2</Subscript>SO<Subscript>4</Subscript> crystals

The effect of uniaxial mechanical pressure σ _m ≤ 150 bar on the spectral (300–800 nm) dependence of the birefringerence Δn _i and refractive indices n _i of (NH₄)₂SO₄ crystals has been investigated. It is shown that the dispersion of n _i (λ) and Δn _i (λ) is normal and sharply increases with approach to the absorption edge. It is established that uniaxial pressure does not change the character of the dispersions dn _i /dλ and dΔn _i /dλ and only affects their magnitudes. It is shown that the increase in the refractive indices under uniaxial stress is mainly due to the increase in the refraction caused by the increase in the band gap and long-wavelength shift of the UV absorption band maximum.     

Pion decay constants in a strong magnetic field

Decay constants of the charged and neutral pions in magnetic field are considered in the framework of the effective quark-antiquark lagrangian respecting Gell-Mann–Oakes–Renner (GOR) relations at zero field. The \(\sqrt {\frac{{{e_q}B}}{\sigma }} \) dependence is found in strong fields e_qB ? σ for the neutral pion, while the charged pion constant decreases as \(\sqrt {\frac{\sigma }{{{e_q}B}}} \).     

Diffraction spectra of order–order transition structural states in titanium monoxide

A new class of M_(n?i)X_(n?i) superstructures (n is an integer constant and i is a rational variable) that are formed after incomplete equilibrium second-order order–order phase transitions in solid solutions and in compounds with atom–vacancy ordering is proposed. New superstructures are superpositions of partially disordered M _n ?X _n superstructures of various symmetries in the matrix of the basic crystal structure. The model parameters affecting the positions and intensities of superstructure reflections on diffraction patterns have been studied by example of the high-temperature ordered phase β-TiO of titanium monoxide. It has been shown that the diffraction spectra of the low-symmetric M_(5-i)X_(5-i) superstructure (space group P1m1) and the high-symmetric M₅X₅ superstructure (space group Pm3?m) at certain parameters are identical in the positions of superstructure reflections.     

On a Semiclassical Formula for Non-Diagonal Matrix Elements

Let H(?)=?? ²d²/dx ²+V(x) be a Schrödinger operator on the real line, W(x) be a bounded observable depending only on the coordinate and k be a fixed integer. Suppose that an energy level E intersects the potential V(x) in exactly two turning points and lies below V _∞=lim?inf?_|x|→∞ V(x). We consider the semiclassical limit n→∞, ?=? _n →0 and E _n =E where E _n is the nth eigenenergy of H(?). An asymptotic formula for 〈n|W(x)|n+k〉, the non-diagonal matrix elements of W(x) in the eigenbasis of H(?), has been known in the theoretical physics for a long time. Here it is proved in a mathematically rigorous manner.     

Ion dynamics in methylcellulose–LiBOB solid polymer electrolytes

A polymer electrolyte system comprising methylcellulose (MC) as the host polymer and lithium bis(oxalato) borate (LiBOB) as the lithium ion source has been prepared via the solution cast technique. The electrolyte with the highest conductivity of 2.79 μS cm^?1 has a composition of 75 wt% MC–25 wt% LiBOB. The mobile ion concentration (n) in this sample was estimated to be 5.70?×?10²⁰ cm^?3. A good correlation between ionic conductivity, dielectric constant, and free ion concentration has been observed. The ratio of mobile ion number density (n) at a particular temperature to the concentration n ₀ of free ions at T?=?∞ (n/n ₀) and the power law exponents (s) exhibit opposite trends when varied with salt concentration.     

Coulomb deexcitation of muonic hydrogen within the quantum close-coupling method

The Coulomb deexcitation of muonic hydrogen in collisions with the hydrogen atom has been studied in the framework of the fully quantum-mechanical close-coupling method for the first time. The calculations of the l-averaged cross sections of the Coulomb deexcitation are performed for (μp)_n and (μd)_n atoms in the initial states with the principal quantum number n = 3–9 and at relative energies E = 0.1–100 eV. The obtained results for the n and E dependences of the Coulomb deexcitation cross sections drastically differ from the semiclassical results. An important contribution of the transitions with Δn > 1 to the total Coulomb deexcitation cross sections (up to ～37%) is predicted.     

Calculation of refractive indices for the (NH<Subscript>2</Subscript>CH<Subscript>2</Subscript>COOH)<Subscript>2</Subscript> · HNO<Subscript>3</Subscript> crystal

The refraction R of the diglycine nitrate (DGN) crystal, (NH₂CH₂COOH)₂ · HNO₃, in the para-and ferroelectric phases has been calculated in the model of noninteracting diatomic chemical bonds of the elementary unit cell of the crystal on the basis of the longitudinal and transversal polarizabilities of these bonds. The calculated magnitudes of the principal refractive indices n _p , n _m , and n _g and the orientations of the optical indicatrix of the crystal agree satisfactorily with experimentally observed values. Introducing the coefficient of Lorenz-Lorentz interaction x into the corresponding formula permits better agreement of the calculated and experimental refractive indices of DGN crystal to be obtained. The temperature changes of these x coefficients upon the ferroelectric phase transition in the DGN crystal have been analyzed.     

Quasi-normal Modes of Rerssner-Nordström Black Hole

The minimum interval of event horizon area of Rerssner-Nordström black hole was calculated via using the loop quantum gravity theory. Based on the first law of black hole thermodynamics, the real part of quasi-normal modes frequency of the black hole was calculated. The expression of asymptotically quasi-normal mode frequency of Rerssner-Nordström black hole was deduced strictly. By analyzing the value of the minimum spin j _{m i n} , the two families of quasi-normal mode spectra of the charged black hole were obtained for j _{m i n} = 1/2 and j _{m i n} = 1 respectively. Our conclusion is in complete agreement with the analytical results of Hod. Our results provide the theoretical basis for the source of the real part of the quasi-normal mode frequency of the black hole.     

Electron gas induced in SrTiO<Subscript>3</Subscript>

This mini-review is dedicated to the 85th birthday of Prof. L.V. Keldysh, from whom we have learned so much. In this paper, we study the potential and electron density depth profiles in surface accumulation layers in crystals with a large and nonlinear dielectric response such as SrTiO₃ (STO) in the cases of planar, spherical, and cylindrical geometries. The electron gas can be created by applying an induction D₀ to the STO surface. We describe the lattice dielectric response of STO using the Landau–Ginzburg free energy expansion and employ the Thomas–Fermi (TF) approximation for the electron gas. For the planar geometry, we arrive at the electron density profile n(x) ∝ (x + d)^–12/7, where d ∝ D₀^–12/7. We extend our results to overlapping electron gases in GTO/STO/GTO heterojunctions and electron gases created by spill-out from NSTO (heavily n-type doped STO) layers into STO. Generalization of our approach to a spherical donor cluster creating a big TF atom with electrons in STO brings us to the problem of supercharged nuclei. It is known that for an atom with a nuclear charge Ze where Z > 170, electrons collapse onto the nucleus, resulting in a net charge Zn < Z. Here, instead of relativistic physics, the collapse is caused by the nonlinear dielectric response. Electrons collapse into the charged spherical donor cluster with radius R when its total charge number Z exceeds the critical value Z_c ≈ R/a, where a is the lattice constant. The net charge eZ_n grows with Z until Z exceeds Z* ≈ (R/a)^9/7. After this point, the charge number of the compact core Z_n remains ≈ Z*, with the rest Z* electrons forming a sparse TF atom with it. We extend our studies of collapse to the case of long cylindrical clusters as well.     

The electromagnetic effects in <Emphasis Type="Italic">K</Emphasis><Subscript><Emphasis Type="Italic">e</Emphasis>4</Subscript> decay

The final-state interaction of pions in K _e4 decay allows to obtain the value of the isospin and angular-momentum-zero ππ scattering length a ₀ ⁰ .We take into account the electromagnetic interaction of pions and isospin-symmetry-breaking effects caused by different masses of neutral and charged pions and estimate the impact of these effects on the procedure of scattering-length extraction from K _e4 decays.     

Coulomb Rydberg electron <Emphasis Type="Italic">L</Emphasis>-mixing in collisions with atomic ions

The cross sections of the Rydberg electron L-mixing in a hydrogen atom and a hydrogen-like ion are calculated for slow collisions with atomic ions H*(n, L) + A⁺ = H*(n, L′) + A⁺ without variation of the principal quantum number n. The probability of the L-mixing L → L′ is associated with the quantum interference of the wave functions of adiabatic states, i.e., with the mixing of the time phases of these functions exp(?i∫E _k (t)dt). The effective cross section of such L-mixing for the states with n = 28 are 4–5 orders of magnitude greater than the cross sections determined in previous investigations. The expansion coefficients of spherical Coulomb wave functions in terms of parabolic ones and vice versa, which are necessary for determining cross sections, are calculated on the basis of a comprehensive analysis of the spatial properties of these functions.     

Growth of (GaAs)<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>(ZnSe)<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript> solid solution films and investigation of their structural and some photoelectric properties

Single-crystal films of the substitutional solid solution (GaAs)_{1 ? x} (ZnSe) _x (0 ≤ x ≤ 0.80) on GaAs substrates have been grown using liquid phase epitaxy. The X-ray diffraction patterns, photoluminescence spectra, and current-voltage characteristics of the n-(GaAs)-p-(GaAs)_{1 ? x} (ZnSe) _x (0 ≤ x ≤ 0.80) heterostructures prepared have been investigated. The lattice parameters of the film a _f = 5.6544 Å and the substrate a _s = 5.6465 Å have been determined, and the profile of the molecular distribution of the solid solution components has been obtained. The photoluminescence spectrum of the (GaAs)_{1 ? x} (ZnSe) _x (0 ≤ x ≤ 0.80) films exhibits a narrow peak (against the background of the broad luminescence band) with a maximum in the luminescence intensity at a photon energy of 2.67 eV due to the presence of Zn-Se bonds in the structure (ZnSe is covalently bonded to the tetrahedral lattice of the GaAs matrix). It has been shown that the direct branch of the current-voltage characteristics of the structures under investigation is described by an exponential dependence I = I ₀exp(qV/ckT) at low voltages (V > 0.3 V) and by a power-law dependence I ～ V ^α with exponents α = 4 at V = 0.4–0.8 V, α = 2 at V = 0.8–1.4 V, and α = 1.5 at V > 2 V. The experimental results have been explained in the framework of the double-injection model for the n-p-p ⁺ structure under the condition that the concentration distribution of nonequilibrium charge carriers has a minimum.