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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(13):3611-3615
The role of low concentrations of carbon complexes in hydrocarbon decomposition over transition metal surfaces has been a topic of much debate over the past decades. It is also a mystery as to whether or not electric fields can enhance hydrocarbon conversion in an electrochemical device at lower than normal reforming temperatures. To provide a “bottom‐up” fundamental insight, C−H bond cleavage in methane over Ni‐based catalysts was investigated. Our theoretical results show that the presence of carbon or carbide‐like species at the interface between the Ni cluster and its metal‐oxide support, as well as the application of an external positive electric field, can significantly increase the Ni oxidation state. Furthermore, the first C−H bond cleavage in methane is favored as the local oxidation state of Ni increases. Thus, the presence of a low concentration of carbon species, or the addition of a positive electric field will improve the hydrocarbon activation process. 相似文献
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Inside Back Cover: Selective Production of Carbon Monoxide via Methane Oxychlorination over Vanadyl Pyrophosphate (Angew. Chem. Int. Ed. 50/2016) 下载免费PDF全文
Vladimir Paunović Guido Zichittella Dr. Réne Verel Dr. Amol P. Amrute Prof. Javier Pérez‐Ramírez 《Angewandte Chemie (International ed. in English)》2016,55(50):15681-15681
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Inside Back Cover: Bandgap Engineering through Controlled Oxidation of Polythiophenes (Angew. Chem. Int. Ed. 7/2014) 下载免费PDF全文
Dr. Sujun Wei Dr. Jianlong Xia Emma J. Dell Yivan Jiang Rui Song Dr. Hyunbok Lee Philip Rodenbough Prof. Alejandro L. Briseno Prof. Luis M. Campos 《Angewandte Chemie (International ed. in English)》2014,53(7):2003-2003
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Inside Cover: Electronic Metal–Support Interactions in Single‐Atom Catalysts (Angew. Chem. Int. Ed. 13/2014) 下载免费PDF全文
Pingping Hu Zhiwei Huang Dr. Zakariae Amghouz Prof. Michiel Makkee Fei Xu Prof. Freek Kapteijn Dr. Alla Dikhtiarenko Yaxin Chen Dr. Xiao Gu Prof. Xingfu Tang 《Angewandte Chemie (International ed. in English)》2014,53(13):3284-3284