共查询到20条相似文献,搜索用时 15 毫秒
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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(41):12686-12691
We report the experimental demonstration of coherent enantiomer‐selective enrichment of chiral molecules by employing a novel microwave five‐pulse scheme. Our results show that enantiomers can be selectively transferred to a rotational level of choice by applying sequences of resonant microwave pulses in a phase‐ and polarization‐controlled manner. This is achieved by simultaneously exciting all three kinds of electric dipole‐allowed rotational transitions and monitoring the effect on a fourth rotational transition of choice. Using molecular beams, we apply our method to two chiral terpenes and obtain a 6 % enantiomeric enrichment, which is one order of magnitude larger than that recently reported in a buffer‐gas cell experiment. This approach establishes a robust scheme for controlled manipulation of enantiomers using tailored microwave fields and opens up new avenues for chiral purification and enrichment that can be used in a broad scope of analytical or spectroscopic applications. 相似文献
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Manfred Parschau Daniele Passerone Karl‐Heinz Rieder HansJ. Hug Karl‐Heinz Ernst 《Angewandte Chemie (International ed. in English)》2009,48(22):3884-3884
Wrong handedness? No problem! K.‐H. Ernst et al. describe in their Communication on page 4065 ff. how the chirality of single adsorbates can be switched into the opposite enantiomeric state. By using inelastically tunneling electrons from the tip of a scanning tunneling microscope in an ultra‐high vacuum, certain molecular vibrations are excited that, in turn, cause different actions such as hopping, rotation, and chirality conversion at the surface.
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Inside Cover: Quantitative Trace Analysis of Complex Mixtures Using SABRE Hyperpolarization (Angew. Chem. Int. Ed. 5/2015) 下载免费PDF全文
Nan Eshuis Bram J. A. van Weerdenburg Dr. Martin C. Feiters Prof. Dr. Floris P. J. T. Rutjes Prof. Dr. Sybren S. Wijmenga Dr. Marco Tessari 《Angewandte Chemie (International ed. in English)》2015,54(5):1372-1372
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Inside Cover: Inversion of the Supramolecular Chirality of Nanofibrous Structures through Co‐Assembly with Achiral Molecules (Angew. Chem. Int. Ed. 7/2016) 下载免费PDF全文
Guo‐Feng Liu Dr. Ling‐Yun Zhu Wei Ji Prof. Chuan‐Liang Feng Prof. Zhi‐Xiang Wei 《Angewandte Chemie (International ed. in English)》2016,55(7):2276-2276
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