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1.
SnS/CNTs composite as anode for SIBs exhibits high reversible capacity, good cyclability as well as rate performance, which is superior to that of pure SnS. The enhanced electrochemical performance can be attributed to the adding of CNTs as a flexible and conductive structure supporter and the formation of SnS nanoparticles with small diameter.  相似文献   

2.
The SnO2 sheet/graphite composite was synthesized by a hydrothermal method for high-capacity lithium storage. The microstructures of products were characterized by XRD and FE-SEM. The electrochemical performance of SnO2 sheet/graphite composite was measured by galvanostatic charge/discharge cycling and EIS. The first discharge and charge capacities are 1,072 and 735 mAh g?1 with coulombic efficiency of 68.6 %. After 40 cycles, the reversible discharge capacity is still maintained at 477 mAh g?1. The results show that the SnO2 sheet/graphite composite displays superior Li-battery performance with large reversible capacity and good cyclic performance.  相似文献   

3.
We report the electrochemical performance of carbon-coated TiO2 nanobarbed fibers (TiO2@C NBFs) as anode material for lithium-ion batteries. The TiO2@C NBFs are composed of TiO2 nanorods grown on TiO2 nanofibers as a core, coated with a carbon shell. These nanostructures form a conductive network showing high capacity and C-rate performance due to fast lithium-ion diffusion and effective electron transfer. The TiO2@C NBFs show a specific reversible capacity of approximately 170 mAh g 1 after 200 cycles at a 0.5 A g 1 current density, and exhibit a discharge rate capability of 4 A g 1 while retaining a capacity of about 70 mAh g 1. The uniformly coated amorphous carbon layer plays an important role to improve the electrical conductivity during the lithiation–delithiation process.  相似文献   

4.
Journal of Solid State Electrochemistry - In this paper, nanocarbon-isolated nano-sheet silicon(Si) electrode Si@CNT/C has been developed by pyrolysis of the compound of Si and polyaniline...  相似文献   

5.
A new strategy was applied to synthesise a porous nanostructure of α-Fe(2)O(3) xerogel assembled from nanocrystalline particles (~5 nm) with abundant mesopores (~3 nm) using a hydrothermal method. The α-Fe(2)O(3) xerogel exhibits excellent cycling performance (up to 1000 cycles) and rate capability (reversible discharging capacity 280 mAh g(-1) at 10 C) as a potential anode for high power lithium-ion batteries.  相似文献   

6.
In this paper, the petal-like MoS2/MXene composite has been successfully synthesized by one-step hydrothermal method. With the combination of few-layer MoS2 nanosheets and the high conductive MXene substrate, the composite exhibits enhanced capacities and rate performance as cathode material of Mg batteries.  相似文献   

7.
Zhou  Jiahui  Jiang  Feng  Li  Sijie  Xu  Zhijie  Sun  Wei  Ji  Xiaobo  Yang  Yue 《Journal of Solid State Electrochemistry》2019,23(7):1991-2000
Journal of Solid State Electrochemistry - Considering serious pollution from the traditional chemical synthesis process, the resource-rich, clean electrode materials are greatly desired....  相似文献   

8.
Journal of Solid State Electrochemistry - In this study, an MoS2/graphene composite is fabricated from bulk MoS2 and graphite rod via a facile electrochemical exfoliation method. The as-prepared...  相似文献   

9.
We have developed a Si/graphene oxide electrode synthesized via ultrasonication-stirring method under alkaline condition. Scanning electron microscopy(SEM), transmission electron microscope(TEM), EDS dot-mapping and high-resolution transmission electron microscopy(HRTEM) results show that Si particles are evenly dispersed on the graphene oxide sheets. The electrochemical performance was investigated by galvanostatic charge/discharge tests at room temperature. The results revealed that Si/graphene oxide electrode exhibited a high reversible capacity of 2825 mAh/g with a coulombic efficiency of 94.6%at 100 mA/g after 15 cycles and a capacity retention of 70.8% after 105 cycles at 4000 mA/g. These performance parameters show a great potential in the high-performance batteries application for portable electronics, electric vehicles and renewable energy storage.  相似文献   

10.
Iron oxide (Fe2O3) was utilized to enhance the electrochemical properties of SiO as a promising anode for Li-ion batteries. An SiO/Fe2O3 composite, composed of SiO coated with Fe2O3 nanoparticles, was synthesized by mechanical milling and characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and energy-dispersive X-ray spectroscopy. The electrochemical properties of the SiO/Fe2O3 composite, SiO, and mechanically milled SiO as anodes for Li-ion batteries were then investigated. The SiO/Fe2O3 composite showed superior performance compared with the two Fe2O3-free SiO samples, including an increased initial coulombic efficiency, enhanced rate capability, and better capacity retention.  相似文献   

11.
Ni(OH)2 was compounded to MnO2 in an easy liquid phase process to improve the diffusion process of the electrode. The as-prepared materials were a mixture of amorphous and nanocrystalline with aggregated nanoparticles forming slit-shaped pore structures. The composite has higher specific surface area and smaller pore volume compared with pristine MnO2. Electrochemical properties of the electrodes were carried out with cyclic voltammetry (CV), galvanostatic charge–discharge tests, and electrochemical impedance spectroscopy (EIS). The MnO2/Ni(OH)2 composites exhibited enhanced electrochemical properties than that of pristine MnO2. Remarkably, the composite which contains 3 % Ni(OH)2 exerted the best discharged specific of 408 F g?1 under 0.2 A g?1, much higher than 247 F g?1 of pristine MnO2 at the same current density. Better rate capability and cycling stability were also realized by the same composite in comparison.  相似文献   

12.
Zn3V3O8 two-dimensional micro sheets are successfully synthesized by combination of solvothermal method and heat treatment. The Zn3V3O8 has better electrochemical performances after calcinations.  相似文献   

13.
Nano-sized nickel ferrite (NiFe2O4) was prepared by hydrothermal method at low temperature. The crystalline phase, morphology and specific surface area (BET) of the resultant samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) and nitrogen physical adsorption, respectively. The particle sizes of the resulting NiFe2O4 samples were in the range of 5–15 nm. The electrochemical performance of NiFe2O4 nanoparticles as the anodic material in lithium ion batteries was tested. It was found that the first discharge capacity of the anode made from NiFe2O4 nanoparticles could reach a very high value of 1314 mAh g−1, while the discharge capacity decreased to 790.8 mAh g−1 and 709.0 mAh g−1 at a current density of 0.2 mA cm−2 after 2 and 3 cycles, respectively. The BET surface area is up to 111.4 m2 g−1. The reaction mechanism between lithium and nickel ferrite was also discussed based on the results of cycle voltammetry (CV) experiments.  相似文献   

14.
Journal of Solid State Electrochemistry - In this work, a spherical Sn-MOF precursor was synthesized through hydrothermal method using 1,3,5-benzenetricarboxylic acid (H3BTC) as the organic ligand....  相似文献   

15.
16.
Journal of Solid State Electrochemistry - A simple modified combustion method was demonstrated in the development of cobalt ferrite (CoFe2O4) and samarium (Sm)-doped CoFe2O4 nanostructures. The...  相似文献   

17.
Zhang  Xia  Dong  Chaoyang  Sun  Yangang  Liu  Binyang  Sun  Lili  Lu  Yongjuan  Yu  Jing  Wei  Yajun  Xu  Yuandong 《Journal of Solid State Electrochemistry》2022,26(2):491-501
Journal of Solid State Electrochemistry - Grapefruit peel carbon (GPC) is prepared from waste grapefruit peel and further used as substrate for in situ construction of MoS2 arrays, forming MoS2/GPC...  相似文献   

18.
The vertical crosslinking MoS2/three-dimensional graphene composite has been prepared by hydrothermal method, which delivered a superior and stable electrochemical capacitive performance.  相似文献   

19.
In the present work,an interconnected sandwich carbon/Si-SiO2/carbon nanospheres composite was prepared by template method and carbon thermal vapor deposition(TVD).The carbon conductive layer can not only efficiently improve the electronic conductivity of Si-based anode,but also play a key role in alleviating the negative effect from huge volume expansion over discharge/charge of Si-based anode.The resulting material delivered a reversible capacity of 1094 mAh/g,and exhibited excellent cycling stability.It kept a reversible capacity of 1050 mAh/g over 200 cycles with a capacity retention of 96%.  相似文献   

20.
In the present work,an interconnected sandwich carbon/Si-SiO_2/carbon nanospheres composite was prepared by template method and carbon thermal vapor deposition(TVD).The carbon conductive layer can not only efficiently improve the electronic conductivity of Si-based anode,but also play a key role in alleviating the negative effect from huge volume expansion over discharge/charge of Si-based anode.The resulting material delivered a reversible capacity of 1094 mAh/g,and exhibited excellent cycling stability.It kept a reversible capacity of 1050 mAh/g over 200 cycles with a capacity retention of 96%.  相似文献   

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