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The continuous synthesis of nickel nanoparticles (NiNPs) in a static microchannel T-mixer by the reduction of NiCl2·6H2O in the presence of ethylene glycol without a stabilizing/capping agent was investigated. The nanoparticles were formed in accordance with the modified polyol process with hydrazine used as a reducing agent and NaOH as a catalyst for nanoparticle formation. The reaction mechanism for NiNP formation was investigated in batch with the help of Fourier transform infrared spectroscopy and X-ray diffraction (XRD) techniques. Parameters were found for reducing reaction times from 60 to 1?min. The effects of temperature (60?C120?°C) and NaOH concentration (0.1 and 0.5?M) on batch-processed particle characteristics were also studied using XRD, transmission electron microscope and electron microprobe analysis. Average particle size was reduced from 9.2?±?2.9 to 5.4?±?0.9?nm at higher temperature and NaOH concentration. Adaptation of this chemistry to a static microchannel T-mixer for continuous synthesis resulted in smooth, spherical particles. Increases in the reaction temperature from 120 to 130?°C resulted in a narrow size distribution of 5.3?±?1?nm and also resulted in magnetic properties of 5.1?emu/g (saturation magnetization), 1.1?emu/g (remanent magnetization), and 62?Oe (coercivity).  相似文献   

3.
Summary The relaxation process in an ideal magnetohydrodynamic (MHD) plasma with fluid velocity and enclosed in a toroidal vessel has been discussed. The expressions for the field parameters and the energy state of the system have been derived. The expression for the minimum energy state of the system has been deduced. An analysis of the conservation of energy of the system in the presence of weak and strong magnetic fields has also been presented. The author of this paper has agreed to not receive the proofs for correction. This work was commenced and partly completed during author's short stay at I.C.T.P.-Trieste, Italy, in 1988.  相似文献   

4.
This Letter is an extension to a multilayer model of porous bone first proposed by Hughes et al. [Ultrasound Med. Biol. 25, 811-821 (1999)]. Both slow and fast compressional waves propagate when the acoustic wave propagation is parallel to the trabecular alignment. However, a slow wave disappears at high refraction angles. To explain this phenomenon, the multilayer model is extended to compute group velocity surface and arrival times with an angle. Two major effects are highlighted as the refraction angle increases. First, the energy of the slow wave is refracted from the phase propagation direction. Second, the signals of fast and slow waves overlap. As a consequence, the slow wave may not be observed for a refraction angle greater than 40 degrees, which is in agreement with previous experimental data published by Hughes et al. and others.  相似文献   

5.
Ten chinchilla cochleas which ranged in length from 16.00 to 19.71 m were used for this study. The cross-sectional area and perimeter of the inner and outer hair cells and their nuclei were determined at two locations per cochlear turn and at the junction between each of the turns (11 locations from apex to base). Some interanimal variation in hair cell dimensions was noted. However, none of these size variations could be attributed to any known differences among the animals. It was concluded that the data reported here represent the natural variation in hair cell size in chinchillas. The data establish a baseline to which the dimensions of cells from abnormal cochleas can be compared, regardless of the length of the cochlea or the base-to-apex location of the cells.  相似文献   

6.
A non-Markovian partial differential equation, rooted in the theory of Brownian motion, is proposed for describing heat conduction by phonons. Although a finite speed of propagation is a built-in feature of the equation, it does not give rise to an inauthentic wave front that results from the application of Cattaneo's equation. Even a simplified, analytically tractable version of the equation yields results close to those found by solving, through more elaborate means, the equation of phonon radiative transfer.  相似文献   

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Evolution of small disturbances in a fully developed incompressible turbulent flow is considered on the base of the transport equation for the single-point probability density function (PDF) of velocity fluctuations. It is shown that at high frequencies this equation is similar to the Vlasov equation for charged plasma in a self-consistent electromagnetic field having longitudinal wave solutions for turbulent stresses similar to Langmuir waves. It is found that the longitudinal waves of turbulent stresses have a constant phase velocity and can be damped, neutral, or growing waves, depending on the type of undisturbed probability density function of velocity fluctuations. The obtained result differs from the previously published solutions to this problem using the statistical moments closures according to which the wave disturbances should be neutral or damped. The possibilities of experimental observation of longitudinal waves of turbulent stresses are analyzed.  相似文献   

9.
Free-moving simulations of airplanes, submarines and other automobiles under extreme and emergency conditions are becoming increasingly important from operational and tactical perspectives. Such simulations are fairly challenging due to the extreme unsteady motions and high Re(Reynolds) numbers. The aim of this study is to perform a six-DOF motion simulation of a 6:1prolate spheroid that is falling in a fluid field. Prior to conducting the six-DOF simulation, some verification simulations were performed. First, a laminar flow past an inclined prolate spheroid at a Re number of 1000 and incidence angle of 45. with a tetrahedral mesh was simulated to verify the relevant targeted discrete method for an unstructured mesh. Second, to verify the LES(large eddy simulation) models and dependent parameters for the DDES(delayed detached eddy simulation), a turbulent flow past a sphere was performed at a subcritical Re number of 10000. Third, a steady maneuvering problem about a prolate spheroid pitching up from 0. to 30. incidence at a uniform angular velocity was established based on a dynamic tetrahedral mesh with changing topology and the ALE(arbitrary Lagrangian-Eulerian) method of fluid-structure coupling at a Re number of 4.2 × 10~6.Finally, two six-DOF motions of an inclined 6:1 prolate spheroid at an initial incidence of 45. were simulated at different Re numbers of 10000 and 4.2 × 10~6.  相似文献   

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We have constructed a kinetic theory of Brownian motion in a rheologically complex medium—a Jeffreys fluid that is characterized by a combination of two viscosity mechanisms: ordinary and delayed. This model is shown to be much better suited for the interpretation of experiments on the microrheology of viscoelastic media than the standard Maxwell model. In particular, no oscillations of the mean-square particle displacement arise in a Jeffreys fluid, which is a nonremovable artifact of the theory of Brownian motion in a Maxwell fluid. The developed approach can to be used also consider the diffusion of particles in other complex fluids whose rheology is described by phenomenological schemes.  相似文献   

12.
Conditional velocity cross correlation functions of the form <vi (0)vj (t); rij (0)> in the Lennard-Jones fluid are investigated by molecular dynamics simulation. As shown in previous work, these cross correlation functions may be related to memory functions in a similar manner as the usual velocity auto-correlation function. To compute the memory functions, a modified version of Detyna and Singer's algorithm has been used.  相似文献   

13.
Brownian motion of a spherical particle in stationary elongational flow is studied. We derive the Langevin equation together with the fluctuation-dissipation theorem for the particle from nonequilibrium fluctuating hydrodynamics to linear order in the elongation-rate-dependent inverse penetration depths. We then analyze how the velocity autocorrelation function as well as the mean square displacement are modified by the elongational flow. We find that for times small compared to the inverse elongation rate the behavior is similar to that found in the absence of the elongational flow. Upon approaching times comparable to the inverse elongation rate the behavior changes and one passes into a time domain where it becomes fundamentally different. In particular, we discuss the modification of thet –3/2 long-time tail of the velocity autocorrelation function and comment on the resulting contribution to the mean square displacement. The possibility of defining a diffusion coefficient in both time domains is discussed.  相似文献   

14.
S K Saha 《Pramana》1983,20(3):245-249
In some recent papers, it has been shown that electrovac spacetimes may sometimes be interpreted as space-time filled with a viscous fluid—one such spacetime being the Kerr-Newman metric. Here the possible fluid motion in that case is studied in some detail and some interesting features of the motion in the black hole region are pointed out.  相似文献   

15.
The distribution of the two-dimensional gas velocity inside ion-irradiated laser cells is considered for low ion energy deposits into the gas. It is shown that, if the energy deposit is smoothly nonuniform, the twodimensional motion has two quasi-one-dimensional components: the longitudinal gas velocity is practically uniform across the cell and depends on the transversely averaged energy deposit, while the transverse velocity component depends on the difference between the local energy deposit and energy deposit averaged over the transverse direction.  相似文献   

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Measurement of the motion of the malleus umbo and stapes footplate during bone conduction (BC) stimulation was conducted in vitro in 26 temporal bones using a laser Doppler vibrometer over the frequency range 0.1 to 10 kHz. For lower frequencies, both ossicular sites followed the motion of the temporal bone. The differential motion between the malleus and the surrounding bone was greater than the differential motion of the stapes footplate; both resonated near 1.5 kHz. Different lesions were shown to affect the response: (1) a mass attached to the umbo lowered the resonance frequency of the ossicular vibration; (2) fixation of either the malleus or stapes increased the stiffness and shifted the resonance frequency upward; and (3) dislocation of the incudo-stapedial joint did not significantly affect the ossicular vibration. The sound radiated from the tympanic membrane was approximately 85 dB SPL at an umbo differential velocity of 1 mm/s for low frequencies in an open ear canal and about 10 dB higher for an occluded one; at higher frequencies (above 2 kHz) resonances of the canal determine the response. It was also found that the motion between the footplate and promontory was within 5 dB when the specimen was stimulated orthogonal to the vibration direction of the ossicles than in line with the same. Measurement of the differential motion of the umbo in one live human skull gave similar response as the average result from the temporal bone specimens.  相似文献   

18.
The ear canal sound pressure and the malleus umbo velocity with bone conduction (BC) stimulation were measured in nine ears from five cadaver heads in the frequency range 0.1 to 10 kHz. The measurements were conducted with both open and occluded ear canals, before and after resection of the lower jaw, in a canal with the cartilage and soft tissues removed, and with the tympanic membrane (TM) removed. The sound pressure was about 10 dB greater in an intact ear canal than when the cartilage part of the canal had been removed. The occlusion effect was close to 20 dB for the low frequencies in an intact ear canal; this effect diminished with sectioning of the canal. At higher frequencies, the resonance properties of the ear canal determined the effect of occluding the ear canal. Sectioning of the lower jaw did not significantly alter the sound pressure in the ear canal. The sound radiated from the TM into the ear canal was investigated in four temporal bone specimens; this sound is significantly lower than the sound pressure in an intact ear canal with BC stimulation. The malleus umbo velocity with air conduction stimulation was investigated in nine temporal bone specimens and compared with the umbo velocity obtained with BC stimulation in the cadaver heads. The results show that for a normal open ear canal, the sound pressure in the ear canal with BC stimulation is not significant for BC hearing. At threshold levels and for frequencies below 2 kHz, the sound in the ear canal caused by BC stimulation is about 10 dB lower than air conduction hearing thresholds; this difference increases at higher frequencies. However, with the ear canal occluded, BC hearing is dominated by the sound pressure in the outer ear canal for frequencies between 0.4 and 1.2 kHz.  相似文献   

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The classical two-dimensional motion of a parabolically confined charged particle in presence of a perpendicular magnetic is studied. The resulting equations of motion are solved exactly by using a mathematical method which is based on the introduction of complex variables. The two-dimensional motion of a parabolically charged particle in a perpendicular magnetic field is strikingly different from either the two-dimensional cyclotron motion, or the oscillator motion. It is found that the trajectory of a parabolically confined charged particle in a perpendicular magnetic field is closed only for particular values of cyclotron and parabolic confining frequencies that satisfy a given commensurability condition. In these cases, the closed paths of the particle resemble Lissajous figures, though significant differences with them do exist. When such commensurability condition is not satisfied, path of particle is open and motion is no longer periodic. In this case, after a sufficiently long time has elapsed, the open paths of the particle fill a whole annulus, a region lying between two concentric circles of different radii.  相似文献   

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