弹性壳结构静力与动力分析的光滑粒子法

本文通过采用移动最小二乘函数作为近似函数 和完全拉格朗日方程作为近似方程来改善光滑粒子法的稳定性和数值精度; 在此基础上, 提出了壳结构静力分析的光滑粒子法, 并完善了壳结构动力分析方法; 最后, 采用国际公认的壳结构的标准测试模型对静力和动力问题分别进行了验证, 所得结果与已有数据吻合良好, 证明了本文数值模型的有效性和可靠性, 为光滑粒子法进一步在裂纹、破碎等非线性壳结构中的应用提供参考. 关键词： 弹性壳 静力与动力分析 光滑粒子法 完备性和稳定性     

Static and dynamic wetting measurements of single carbon nanotubes

Individual carbon nanotubes were immersed and removed from various organic liquids using atomic force microscopy. The carbon nanotube-liquid interactions could be monitored in situ, and accurate measurements of the contact angle between liquids and the nanotube surface were made. These wetting data were used to produce Owens and Wendt plots giving the dispersive and polar components of the nanotube surface.     

动态双光栅测量金属热膨胀系数

在双光栅测量音叉微小振幅的理论基础上,利用静光栅纵向位移对金属热膨胀系数进行测量.本文给出了动态双光栅测量金属热膨胀系数的理论拓展与实验结果.     

Influence of chemical treatments on the interfacial adhesion between sisal fibre and different biodegradable polymers

The influence of chemical treatments on the interfacial adhesion of sisal fibres and biodegradable matrices were studied in the present work. For that purpose, four different polymers were used: polycaprolactone (PCL), cellulose acetate, MaterBi Z (a commercial starch/polycaprolactone blend) and MaterBi Y (a commercial starch/cellulose derivatives blend). Alkaline and acetylation treatments were performed on sisal fibres. Properties were determined by means of tensile tests, adhesion measurements and contact angle determination. The interfacial shear strength was correlated with the hydrophilic character of the material.     

Effect of surface-grafted molecular brushes on the adhesion performance of bonded polymers and composite interfaces

This paper reviews the theoretical principles of the macromolecular design of polymer interface/interphase systems for obtaining maximum adhesion and fracture performance of composite materials and adhesively bonded assemblies. Subsequently, a relatively simple and industry-feasible technology for surface grafting molecular brushes is discussed in detail and supported by a range of experimental examples. It is shown, in agreement with contemporary theory, that the use of chemically attached graft chemicals of controlled spatial geometry and chemical functionality enables a significant increase in the strength and fracture energy of the interphase, to the point of cohesive fracture of the substrate, or that of an adjacent medium such as adhesive, elastomer or matrix material. This occurs even after prolonged exposure of investigated systems to adverse environments such as hot water.     

Linear and non-linear optical properties of hetero-cyclic aromatic polymers

We investigated linear and non-linear optical properties of non-fused and fully fused hetero-cyclic thiophene, selenophene and pyrrole oligomers. We found that these oligomers show relatively better environmental stability in their fused form than non-fused geometry. Linear extrapolation of calculated energy gap between highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) in the polymer limit exhibits extremely good agreement with experimentally reported band gap for thiophene, selenophene and pyrrole oligomers in their non-fused form. The lowest singlet dipole allowed excited state was calculated using time-dependent density functional theory and extrapolated optical gap estimated were in good agreement with experimental observation. Static linear and first hyperpolarisabilities were also studied as a function of chain length for donor–acceptor substituted polymers. The (hyper)polarisabilities are increasing as a function of chain length in both forms although the non-fused pyrrole oligomers show slow variation. Our study on hyperpolarisability also shows that donor–acceptor substituted non-fused selenophene oligomers are most promising candidates to contribute significantly in non-linear photonics and all fully fused hetero-cyclic oligomers show strong NLO responses.     

Ablation behaviors of carbon/carbon composites with C-SiC-TaC multi-interlayers

Carbon/carbon composites with C-SiC-TaC multi-interlayers were prepared by isothermal chemical vapor infiltration. The ablation behaviors of the composites were tested with an oxyacetylene flame. The mass loss rate increases markedly in the initial 10 s, then reaches a steady state or decreases slightly in 10–40 s; while after 40 s, the mass loss rate increases remarkably. A similar trend is observed in the linear loss rate, except that it begins to increase only after 60 s. After ablation for 5 s, the composite surface consists in black carbon fibers and white ceramic oxides. After 20 s, three different regions with different ablation behaviors are observed: central, transition and border. After 100 s, the composites are severely ablated and the shape is completely destroyed. A cross-section of the composites after ablation for 20 s shows three distinct regions: a rugged oxide layer, a smooth oxide layer and the matrix. The tantalum compounds have not been able to protect efficiently the material from constant oxide evolution, possibly because of a too large pore volume fraction.     

导热高分子聚合物研究进展

传统高分子聚合物是良好的电绝缘体和热绝缘体.高分子聚合物具备质量轻、耐腐蚀、可加工、可穿戴、电绝缘、低成本等优异特性.高分子聚合物被广泛应用于各种器件.由于高分子材料的热导率比较低(0.1—0.5 W·m^-1·K^-1),热管理(散热)面临严峻的挑战.理论及实验工作表明,先进高分子材料可以具有比传统传热材料(金属和陶瓷)更高热导率. Fermi-Pasta-Ulam (FPU)理论结果发现低维度原子链具有非常高的热导率.广泛使用的聚乙烯热绝缘体可以被转变为热导体:拉伸聚乙烯纳米纤维的热导率大约为104 W·m^-1·K^-1,拉伸的聚乙烯薄膜热导率大约为62 W·m^-1·K^-1.首先,本文通过理论和实验结果总结导热高分子材料的传热机理研究进展,并讨论了导热高分子聚合物的制备策略;然后,讨论了在传热机制及宏量制备方面,高分子聚合物研究领域所面临的新挑战;最后,对导热高分子的热管理应用前景进行了展望.例如,导热高分子聚合物在耐腐蚀散热片、低成本太阳能热水收集器、可穿...     

Mechanical and AFM investigations of elastomers filled with multiwall carbon nanotubes

Strong reinforcing effects are observed when multiwall carbon nanotubes are incorporated in a styrene–butadiene copolymer. The good level of dispersion of carbon nanotubes in the host matrix that allows to take advantage of their high aspect ratio as well as their orienting capability under uniaxial extension, appear to be the main parameters for mechanical reinforcement. Atomic force microscopy carried out in the unstretched and stretched states has been shown to bring important insights for the understanding of the mechanical properties of the composites.     

Thermal transport of oil and polymer composites filled with carbon nanotubes

We studied the thermal transport properties of multi-walled carbon nanotubes (MWNTs) in polymer and oil matrices. The thermal conductivity of the oils and polymers increased linearly when adding tubes. We observe a particularly high increase in the thermal diffusivity of carbon-nanotube-loaded liquid crystal polymers (6×10⁻⁵ cm²/s wt%), which is due to a spontaneous alignment of the MWNTs. Carbon nanotubes increased the thermal conductivity of oil by a factor of three for 20 wt% loading. We found little or no dependence of the thermal enhancement on the specific flavor of multiwall nanotubes used in the composites. Carbon nanotubes are excellent nanoscale fillers for composites in thermal management application.     

Static and dynamic properties of pseudoscalar mesons

We report the results of form factors, charge radii and decay constants of both light and heavy flavoured pseudoscalar mesons in a QCD inspired quark model. We use the quantum mechanical perturbation theory and discuss its limitations in the present problem. Several predictions are also made for bottom and top flavours.     

Static and dynamic properties of polymer brush with topological ring structures: Molecular dynamic simulation

By defining a topological constraint value(rn),the static and dynamic properties of a polymer brush composed of moderate or short chains with different topological ring structures are studied using molecular dynamics simulation,and a comparison with those of linear polymer brush is also made.For the center-of-mass height of the ring polymer brush scaled by chain length h~N~v,there is no significant difference of exponent from that of a linear brush in the small topological constraint regime.However,as the topological constraint becomes stronger,one obtains a smaller exponent.It is found that there exists a master scaling power law of the total stretching energy scaled by chain length N for moderate chain length regime,F_(ene)~Np~v,for ring polymer brushes,but with a larger exponent v than 5/6,indicating an influence of topological constraint to the dynamic properties of the system.A topological invariant of free energy scaled by(c)~(5/4) is found.     

Static and dynamic properties of unidirectional CFRP laminates with flexible interphase

In this study, a flexible interphase than matrix resin is studied. The fabrication method of unidirectional CFRP laminates with flexible fiber/matrix interphase has been established. The influence of the flexible interphase thickness on the flexural modulus and strength are experimentally investigated. The influence on the vibration properties are also investigated. It has been concluded that the flexible interphase with the optimized thickness could improve both the static and dynamic properties.     

Effects of particle size of silica aerogel on its nano-porous structure and thermal behaviors under both ambient and high temperatures

Silica aerogel as the most commonly used aerogel has attracted increasing attention from both academia and industries due to its extraordinary performances and potentials. Through this study, influences of the particle size (38–880 μm) on its nano-porous structure and thermal behaviors were addressed based on a series of experimental tests under both ambient and high temperatures (i.e., 1000 °C). It was known from the experimental results that the fractional densities of samples with particle sizes of 270–880 μm were similar, which were about 40% of the sample with a particle size of 38 μm. The ratio of densification was found decrease to about 10–40% when heating time increased from 10 to 90 min. For those samples with 150 μm or finer particles, SiC crystal with 70.8 nm particles was generated, and the pore shape was slit in the silica aerogel. The Brunauer–Emmett–Teller (BET) surface area, cumulative pore volume, and average pore diameter of those heated samples with over 75 μm diameter were about 40%, 20%, and 50% of those unheated (virgin) samples, respectively. Virgin samples showed 18% lower thermal conductivity for 75 μm particles compared to that of 38 μm, while for the heated samples, 38 μm particles showed a 28% lower thermal conductivity than that with 880 μm. Mixture of silica aerogel and other inorganic material particles are recommended for high-temperature applications, while the silica aerogel with different-sized particles are observed better for applications under ambient temperature.     

Study of the non-linear dynamic response of a rotor system with faults and uncertainties

In this paper, the quantification of uncertainty effects on the variability of the nonlinear response in rotor systems with multi-faults (such as unbalance, asymmetric shaft, bow, parallel and angular misalignments) is investigated. To take account of uncertainties in this kind of nonlinear problem, it is proposed to use the Harmonic Balance Method (HBM) with a polynomial chaos expansion (PCE). The efficiency and robustness of the proposed methodology is demonstrated by comparison with Monte Carlo simulations (MCS) for different kinds and levels of uncertainties.     

Static and dynamic properties of cavity solitons in VCSELs with optical injection

The static and dynamical properties of cavity solitons in a vertical cavity surface emitting laser with optical injection are investigated. Analytical results about the instabilities affecting the homogeneous steady state are presented. These instabilities play a key role in the determination of the necessary and favorable conditions for cavity soliton existence. Optimization of an all-optical delay line by tuning the injected field frequency leads to a five fold increase of the soliton velocity in the transverse plane. Finally, the phenomenon of cavity soliton merging is applied to combine input signals in optical information processing and to manipulate two dimensional optical memories.     

Detection of positive and negative ions in a wire ionization counter filled with atmospheric air

The physical processes occurring during the detection of individual ions in a wire counter filled with atmospheric air are studied, and the amplitude distribution of electric pulses is measured. It is shown that a positive ion is detected due to electron emission from the surface of a negatively charged wire, whereas a negative ion is detected due to electron detachment near a positively charged wire. The secondary processes accompanying the neutralization of positive ions at a negatively charged external electrode and negatively charged wire are considered. It is established that, in contrast to standard proportional counters, these secondary processes result in an increase in the number of electric pulses rather than in an increase in the electric pulse amplitude. The wire counter allows the detection of both ions produced inside the detector and ions injected into the detector from the ambient air. Possible applications of air-filled wire detectors are described.