北极水下声信号跨冰层变化分析

北极海冰阻碍了海水和空气两个空间的信息传输.为获得冰层对水下声信号跨冰层传输的影响,采用三维检波器在北冰洋中心区开展了水下声信号的跨冰层实验.利用水冰界面反射模型和自由冰层Lamb波模型,对水下声信号小角度(小于10°)入射冰层时测量数据进行分析,结果表明:(1)20 Hz～1 kHz声信号入射到光滑冰层时,某些频率声...     

A two-fraction model for the calculation of the resonance spectra of the complex permittivity of ice in the far infrared

A two-fraction model that makes it possible to calculate analytically the complex dielectric permittivity of ice in the far infrared and submillimeter wavelength ranges is proposed. The librational and vibrational fractions are considered. The first fraction, consisting of rigid dipoles executing anharmonic reorientations in defects of the structure, gives rise to the librational band of ice at 800 cm^?1. The second fraction consists of elastically vibrating oppositely charged H-bonded molecules. This fraction describes two bands of ice in the range 100–300 cm^?1, and the nonresonant background of dielectric losses in the submillimeter wavelength range. The dielectric permittivity spectra of ice calculated for the temperature of ?7°C are consistent with the experimental spectra. The spectra of ice at the temperature ?30°C are predicted.     

Proton segregation on a growing ice interface

Hydronium segregates to the surface of H₂O (D₂O) ice films grown on Pt(1 1 1) above 151 K (158 K). This is observed via the voltage that develops across the films, utilizing work function measurements. The dependence of this voltage on the film’s thickness is explained by a simple equilibrium model: as the film grows, most of the surface ions migrate so as to remain at the ice–vacuum interface, while a fixed percentage (0.05%) take the thermodynamically–unfavored route, to become incorporated into the growing bulk ice. This model implies a ΔG of about +0.1 eV for the movement of ions from the ice surface into the bulk ice.     

The temperature evolution of the magnetic correlations in pure and diluted spin ice Ho2−xYxTi2O7

Diffuse polarized neutron scattering studies have been carried out on single crystals of pyrochlore spin ice Ho_2−xY_xTi₂O₇ (x=0, 0.3, and 1) to investigate the effects of doping and anisotropy on spin correlations in the system. The crystals were aligned with the (1 −1 0) orientation coincident with the direction of neutron polarization. For all the samples studied the spin flip (SF) diffuse scattering (i.e. the in-plane component) reveals that the spin correlations can be described using a nearest-neighbour spin ice model (NNSM) at higher temperatures (T=3.6 K) and a dipolar spin ice model (DSM) as the temperature is reduced (T=30 mK). In the non-spin flip (NSF) channel (i.e. the out-of-plane component), the signature of strong antiferromagnetic correlations is observed for all the samples at the same temperature as the dipolar spin ice behaviour appears in the SF channel. Our studies show that the non-magnetic dopant Y does not significantly alter SF or NSF scattering for the spin ice state, even when Y doping is as high as 50%. In this paper, we focus on the experimental results of the highly doped spin ice HoYTi₂O₇ and compare our results with pure spin ice Ho₂Ti₂O₇. The crossover from a dipolar to a nearest-neighbour spin ice behaviour and the doping insensitivity in spin ices are briefly discussed.     

Evaluation of the ice ratio formed during quasi-adiabatic pressure shift freezing

Abstract

Pressure shift freezing consists in cooling a biological substance (mainly containing water) under pressure without phase change followed by a sudden release of the pressure. The high supercooling obtained during the quasi adiabatic depressurisation permits to achieve a rapid and uniform ice nucleation. The ice fraction formed during the pressure release of a sample of pure water has been calculated using a mathematical model. In addition, this fraction was experimentally evaluated by isothermal calorimetry. The calculations and measurements were carried out at 3 different initial points of the ice I melting curve. A relatively good agreement is observed between the experimental and calculated ice ratio which were between 0.117 and 0.402 (kg ice/kg ice-water mixture) for an initial temperature-pressure values of -10°C/1 15 MPa and -21°C/210 MPa respectively.     

A fast infrared radiative transfer model for overlapping clouds

A fast infrared radiative transfer model (FIRTM2) appropriate for application to both single-layered and overlapping cloud situations is developed for simulating the outgoing infrared spectral radiance at the top of the atmosphere (TOA). In FIRTM2 a pre-computed library of cloud reflectance and transmittance values is employed to account for one or two cloud layers, whereas the background atmospheric optical thickness due to gaseous absorption can be computed from a clear-sky radiative transfer model. FIRTM2 is applicable to three atmospheric conditions: (1) clear-sky, (2) single-layered ice or water cloud, and (3) two simultaneous cloud layers in a column (e.g., ice cloud overlying water cloud). Moreover, FIRTM2 outputs the derivatives (i.e., Jacobians) of the TOA brightness temperature with respect to cloud optical thickness and effective particle size. Sensitivity analyses have been carried out to assess the performance of FIRTM2 for two spectral regions, namely the longwave (LW) band (587.3-1179.5 cm⁻¹) and the short-to-medium wave (SMW) band (1180.1-2228.9 cm⁻¹). The assessment is carried out in terms of brightness temperature differences (BTD) between FIRTM2 and the well-known discrete ordinates radiative transfer model (DISORT), henceforth referred to as BTD (F−D). The BTD (F−D) values for single-layered clouds are generally less than 0.8 K. For the case of two cloud layers (specifically ice cloud over water cloud), the BTD (F−D) values are also generally less than 0.8 K except for the SMW band for the case of a very high altitude (>15 km) cloud comprised of small ice particles. Note that for clear-sky atmospheres, FIRTM2 reduces to the clear-sky radiative transfer model that is incorporated into FIRTM2, and the errors in this case are essentially those of the clear-sky radiative transfer model.     

Testing an ensemble model of cirrus ice crystals using midlatitude in situ estimates of ice water content,volume extinction coefficient and the total solar optical depth

In this paper an ensemble model of cirrus ice crystals is tested against midlatitude in situ estimates of ice water content, volume extinction coefficient and the total solar optical depth. During the Winter of 2005 and Spring 2006 the FAAM (Facility for Airborne Atmospheric Measurements) BAE-146 G-LUXE aircraft flew three flights as part of the CAESAR (Cirrus and Anvils: European Satellite and Airborne Radiation measurements project) campaign of flying in cirrus around the UK. The suite of microphysical instrumentation onboard the aircraft included the PMS 2D-C probe and the Stratton Park Engineering Company (SPEC) cloud particle imager (CPI). The campaign characterized cirrus properties such as ice water content, volume extinction coefficient, ice crystal geometric shape and ice crystal effective dimension. Cirrus cloud temperatures ranged approximately between 215 and 240 K. From the CPI instrument 60–80% of the ice crystal habits were estimated to be either indeterminate or ‘irregular’ (though such irregular crystals could be composed of pristine components) of some form with hexagonal columns and hexagonal plates accounting for generally much less than 3% of the ice crystal population. The CPI estimated integrated ice water content ranged between 5±2 and 45±22 gm^?2, whilst the CPI estimate of the total solar optical depth was found to lie between 0.2±0.1 and 1.0±0.5. The CPI estimate of the mean ice crystal effective dimension was found to range between about 59±9 and 90±75 μm.The particle size distribution (PSD) function was estimated using a PSD scheme that requires as input the in situ estimated IWC and measured in-cloud temperature. The CPI estimates of the bulk and microphysical properties of the midlatitude cirrus are used to test whether an ensemble model of cirrus ice crystals together with a PSD scheme can predict CPI in situ estimates to within the experimental uncertainty. This paper demonstrates that the ensemble model coupled with a PSD scheme can predict the ice water content and the integrated ice water content to generally well within the experimental uncertainty if a varying density with respect to size is assumed. The ensemble model together with a PSD scheme is also shown to predict the CPI estimated volume extinction coefficient and the derived total solar optical depth to generally well within the experimental uncertainty. The paper demonstrates that an ensemble model of cirrus combined with a PSD scheme can predict the radiative properties of cirrus without the need to invoke the concept of an ice crystal effective dimension.     

A dislocation-based model for creep recovery in ice

Creep recovery strain is significant in polycrystalline ice, and its stress dependence is strongly dependent on ice type and deformation history. Although it is generally recognized that creep recovery strain is largely attributable to dislocations, a dislocation-based model that rectifies the observed differences in two important ice types (freshwater and sea ice) has not previously emerged; and the development of such a model forms the goal of the present effort. The model considers basal dislocation distributions, employs a dislocation density–stress relationship from previous work, and uses an empirical expression for the decrease in slip-line spacing with increasing stress. The dislocation processes are taken to operate over a subgrain-sized domain, and the strain associated with the relative motion of neighbouring domains is considered. The model accounts for dislocation multiplication and the decrease in slip-line spacing if the applied stress is sufficiently high. The model explains the observed differences in creep recovery strain for freshwater and sea ice and adequately reproduces both the stress dependence and the limiting value of the experimentally observed behaviour. It also reproduces the shift from nonlinear to linear behaviour that has been observed in prestrain experiments on freshwater and sea ice cores.     

Penetration of ammonia molecule into ice film; activation energy analysis using Xe molecular beam irradiation

We have investigated the barrier energy for an ammonia molecule to penetrate into ice film by the use of infrared spectroscopy and Xe supersonic beam. After the ice film on a Pt(1 1 1) surface is exposed to ammonia molecules, an umbrella mode of ammonia molecules adsorbed on the ice film has been observed in infrared spectra. After the irradiation of accelerated Xe beam, we observed an energy shift of the mode of ammonia. The shifted mode is assigned to that of ammonia molecules at the interface between the ice film and the Pt(1 1 1) surface. This indicates that the collision with Xe beam induced the penetration of an ammonia molecule to the interface through the ice film. Using this feature, we estimate a barrier for penetration as 0.28 ± 0.03 eV which is much smaller than the one previously reported for bulk ice.     

双基地冰-水界面混响强度的理论预报

针对北极冰层冰水界面具有小尺度粗糙界面的情况,给出由冰层造成的混响平均强度的理论预报公式。首先将北极冰层等效为具有粗糙界面的弹性介质,并且采用小粗糙度微扰理论在精细拟合粗糙度谱的基础上,建立粗糙冰层的三维散射强度模型,然后建立三维双基地声呐几何模型确定有效散射区域,最后给出双基地冰下混响平均强度的估算公式,并在所拟合的粗糙度谱的情况下,利用该预报公式计算双基地声呐配置参数和海冰物理及声学特性对冰下混响强度的影响算例。数值仿真表明该公式能够估算出北极冰下双基地声呐产生的混响平均强度,并且分析出了时延、基线长度等声呐配置参数和冰层声速比、密度比等海冰物理参数会对混响强度造成的影响。声呐的配置参数主要影响散射的有效面积,海冰的物理参数则影响着冰层的散射强度。其中,冰层声速比不仅影响混响强度的大小,还会影响混响强度随时间的衰减速度。      

The 3-dimensional eight vertex model and the proton-proton correlation functions in ice

The transition temperature of the isotropic eight vertex model¹ (i.e. all vertices with 2 arrows have the same energy) is found to be the same for 2-or 3-dimensional (or more) lattices. The partition function of ice has the same diagrammatic expansion as the eight vertex model at the transition point (as already known³ in 2 dimensions). Therefore, the Fourier transform of the proton-proton correlation function in ordinary ice is expected to have a singularity at the origin, in agreement with approximate calculations.     

On quantum solitons and their classical relatives: Bethe Ansatz states in soliton sectors of the sine-Gordon system

Previously we have found that the semiclassical sine-Gordon/Thirring spectrum can be received in the absence of quantum solitons via the spin $\text{1}\text{2}$ approximation of the quantized sine-Gordon system on a lattice. Later on, we have recovered the Hilbert space of quantum soliton states for the sine-Gordon system. In the present paper we present a derivation of the Bethe Ansatz eigenstates for the generalized ice model in this soliton Hilbert space. We demonstrate that via “Wick rotation” of a fundamental parameter of the ice model one arrives at the Bethe Ansatz eigenstates of the quantum sine-Gordon system. The latter is a “local transition matrix” ancestor of the conventional sine-Gordon /Thirring model, as derived by Faddeev et al. within the quantum inverse-scattering method. Our result is essentially based on the N < ∞, Δ = 1, m ? 1 regime. Consequently, the spectrum received, though resembling the semiclassical one, does not coincide with it at all.     

Ultrasonic study of solid-phase amorphization and polyamorphism in an H2O-D2O (1: 1) solid solution

The elastic moduli and volume of H₂O-D₂O (1: 1) isotopically mixed ice (solid solution) have been studied at the solid-phase amorphization of normal 1h ice under compression at a temperature of 77 K and at the transition from high-density amorphous ice to low-density amorphous ice with subsequent successive crystallization to cubic (1c) and hexagonal (1h) ice at isobaric (0.05 GPa) heating. Comparison of the results with the respective data for H₂O and D₂O ices indicates that the observed concentration (in the isotopic composition) dependences of the elastic moduli and their derivatives for different phases of ice at isotopic hydrogen substitution in the H₂O, H₂O-D₂O (1: 1), and D₂O chain can be both monotonic and significantly nonmonotonic.     

Ultralow elastic stability of salt ice at low temperatures

A model is developed to describe the elastic stability of saline ice with a homogeneous distribution of the components in the volume at high pressures (P > 0.1 GPa) and low temperatures (T < 220 K). This model is based on the basic principles of the theory of elastic percolation and the theory of ion hydration (formation of spherical clusters with water molecule dipoles oriented toward ions) in a liquid solution. This model can be used to find the dependence of the elastic stability of an ice solution on the concentration and temperature for any salts decomposing into ions with various valences and effective radii. Good agreement between the calculated and experimental dependences indicates the existence of hydration spheres in an ice solution, which is characterized by a narrower size distribution of spheres as compared to the liquid state and by a steeper decrease in the sphere size when the salt concentration increases in the range x ?? 0.001?C0.01. The stability of a solid ice solution depends on the temperature and the salt concentration in a complicated manner, having specific features in the form of maxima near phase transitions in a water matrix as a result of competing effects that enhance or weaken the elastic contributions of the frozen spheres. As follows from the model calculations, solid ice solutions can have an ultralow elastic stability (which is lower than that of pure water ice by a factor of 5?C30), which was experimentally detected even at low weight fractions of salts at a level of x ?? 0.0001?C0.01 for T < 220 K.     

Estimates of Europa’s ice shell thickness and strain rate from flanking cracks and bulge along Ridge R

Europa, the second Galilean satellite outward from Jupiter, has an outer layer of water of about 100 km thick and an outmost ice shell. The thickness of the ice shell is very important in understanding Europa’s habitability and thermal history, but estimates from different studies are very inconsistent, ranging from 0.2 to 30 km. Here we obtain an estimate of the ice shell thickness from locations of flanking crack and forebulge along Ridge R. Considering the water’s heating process to nearby ice shell in the crack, a flexure model is applied and it suggests the thickness of an ice shell to be 500–1500 m without a convective layer. Compared with previous studies using the same method but ignoring the water’s heating process, the rationality and accuracy have been improved dramatically in our results. We also get some constraints on the strain rate and the characteristic temperature T _c, which defines the base of the elastic layer.     

Effects of sea surface temperature, cloud radiative and microphysical processes, and diurnal variations on rainfall in equilibrium cloud-resolving model simulations

The effects of sea surface temperature(SST),cloud radiative and microphysical processes,and diurnal variations on rainfall statistics are documented with grid data from the two-dimensional equilibrium cloud-resolving model simulations.For a rain rate of higher than 3 mm.h 1,water vapor convergence prevails.The rainfall amount decreases with the decrease of SST from 29℃ to 27℃,the inclusion of diurnal variation of SST,or the exclusion of microphysical effects of ice clouds and radiative effects of water clouds,which are primarily associated with the decreases in water vapor convergence.However,the amount of rainfall increases with the increase of SST from 29℃ to 31℃,the exclusion of diurnal variation of solar zenith angle,and the exclusion of the radiative effects of ice clouds,which are primarily related to increases in water vapor convergence.For a rain rate of less than 3 mm.h 1,water vapor divergence prevails.Unlike rainfall statistics for rain rates of higher than 3 mm.h 1,the decrease of SST from 29℃ to 27℃ and the exclusion of radiative effects of water clouds in the presence of radiative effects of ice clouds increase the rainfall amount,which corresponds to the suppression in water vapor divergence.The exclusion of microphysical effects of ice clouds decreases the amount of rainfall,which corresponds to the enhancement in water vapor divergence.The amount of rainfall is less sensitive to the increase of SST from 29℃ to 31℃ and to the radiative effects of water clouds in the absence of the radiative effects of ice clouds.     

Entropy of amorphous ice as determined by a new thermodynamic method

Abstract

The difference of the entropies of ice Ih and high-density amorphous ice and of low-density and high-density amorphous ice have been measured by a new direct method as about 2.1 and 1.1 J K^?1 mol^?1 respectively.     

Optical properties of ice particles in young contrails

The single-scattering properties of four types of ice crystals (pure ice crystals, ice crystals with an internal mixture of ice and black carbon, ice crystals coated with black carbon, and soot coated with ice) in young contrails are investigated at wavelengths 0.65 and 2.13 μm using Mie codes for coated spheres. The four types of ice crystals show differences in their single-scattering properties because of the embedded black carbon whose volume ratio is assumed to be 5%. The bulk-scattering properties of young contrails consisting of the four types of ice crystals are further investigated by averaging their single-scattering properties over a typical ice particle size distribution found in young contrails. The effect of the radiative properties of the four types of ice particles on the Stokes parameters I, Q, U, and V is also investigated for different viewing zenith angles and relative azimuth angles with a solar zenith angle of 30° using a vector radiative transfer model based on the adding-doubling technique. The Stokes parameters at a wavelength of 0.65 μm show pronounced differences for the four types of ice crystals, whereas the counterparts at a wavelength of 2.13 μm show similar variations with the viewing zenith angle and relative azimuth angle. However, the values of the results for the two wavelengths are noticeably different.     

Water monolayer and multilayer adsorption on Ni(1 1 1)

Water adsorbed on Ni(1 1 1) forms an ordered, hydrogen bonded ice structure with a (2√7 × 2√7)R19° unit cell. The 2√7 wetting structure forms as islands and persists up to saturation of the first layer. Adsorption of a fraction of a monolayer more water into a second layer destroys the 2√7 registry and creates a disordered ice film. Gas adsorption measurements indicate that the wetting layer is completely covered by a second layer of water before thicker multilayer ice forms. As the second layer is completed the film orders to form an incommensurate crystalline ice film with a hexagonal LEED pattern, oriented to the Ni close packed rows. This ordered, incommensurate structure persists as the ice multilayer grows thicker.     

静电场对红细胞悬液冻结特性的影响

本文以红细胞悬液为研究模型,通过在对其进行慢速冻结的过程中引入静电场,具体研究了静电场对降温过程中红细胞悬液冻结特性的影响。实验结果表明:静电场在一定程度上改变了冰晶的形成与生长特性,抑制了晶核的形成, 使晶枝出现不对称生长,并减缓了冰晶的生长速度,这些影响随着场强的增加而逐渐加强。在较强的静电场的影响下,冰晶明显变粗,最终成为块状,细胞也不再与冰晶分离而是完全融入粗大的冰晶之中,在冻结的末期,细胞不再受到冰晶挤压,从而减少了其所受的机械性损伤。