共查询到20条相似文献,搜索用时 31 毫秒
1.
红藻中的R-藻红蛋白(R-PE)依照其吸收光谱可分为两种不同的光谱类型,即“双峰型”和“三峰型”。本文通过对不同pH条件下的R-PE的荧光光谱及荧光寿命的研究,发现“三峰型”R-PE的pH稳定范围较“双峰型”R-PE大。在R-PE浓度对荧光光谱的影响实验中,随着蛋白浓度的增加,荧光峰位置逐渐红移。荧光寿命逐渐增大,荧光强度先行增加而后减弱。用碘离子对其荧光进行猝灭,随着碘离子浓度的增大,荧光强度逐渐降低,荧光寿命逐渐缩短,并服从Stem-Volmer规则。 相似文献
2.
本文讨论了配位多面体的群重叠积分计算问题, 给出了这种群重叠积分的一般形式以及它们满足的一些关系, 用第一类点群将群重叠积分的计算化简, 由此定义了有关的几何参数并研究了它们的性质, 以正六面体为例说明了这些参数的具体计算。 相似文献
3.
利用分布函数理论导出了液体的内能和内压公式.液体的内压和过剩内能可以表示成体积的幂级数形式,其中的系数可以用多体相互作用势和多体径向分布函数表出,它们仅仅与温度有关.讨论了液体仅存在第n次多体相互作用势情形的内压和过剩内能的表达式,结果与Egelstaff的微扰理论结果具有相同的形式,不仅给出了相应参数的表达式而且适用于多体相互作用较强的情形.定义了物性参数α(T)和m,得到的液体过剩内能和内压的表达式与Frank实验结果具有相同的形式,其结果不仅给出了参数α(T)和m的表达式,而且指出了Frank的过剩内能和内压公式只适用于参数α(T)和m与体积无关的液体. 相似文献
4.
《Journal of Saudi Chemical Society》2023,27(4):101670
Designing of molecules for drugs is important topic from many decades. The search of new drugs is very hard, and it is expensive process. Computer assisted framework can provide the fastest way to design and screen drug-like compounds. In present work, a multidimensional approach is introduced for the designing and screening of antioxidant compounds. Antioxidants play a crucial role in ensuring that the body's oxidizing and reducing species are kept in the proper balance, minimizing oxidative stress. Machine learning models are used to predict antioxidant activity. Three hydroxycinnamates are selected as standard antioxidants. Similar compounds are searched from ChEMBL database using chemical structural similarity method. The libraries of new compounds are generated using evolutionary method. New compounds are also designed using automatic decomposition and construction building blocks. The antioxidant activity of all designed and searched compounds is predicted using machine learning models. The chemical space of searched and generated compounds is envisioned using t-distributed stochastic neighbor embedding (t-SNE) method. Best compounds are shortlisted, and their synthetic accessibility is predicted to further facilitate the experimental chemists. The chemical similarity between standard and selected compounds is also studied using fingerprints and heatmap. 相似文献
5.
《Journal of Dispersion Science and Technology》2013,34(6):499-527
The precipitation and condensation of submicron organic particles are reviewed. The importance of physical state effects is discussed, and the role of compartmentalization in controlling particle size is introduced. The thermodynamic driving forces for precipitation and phase transformation are briefly reviewed. The use of emulsification as a primary step in producing small particle dispersions is described and illustrated with photographic and pharmaceutical applications. Precipitation driven by solvent shifting is illustrated and applications in preparing organic–inorganic composites and protein coacervation are described. Miscible solvent–nonsolvent induced precipitation is outlined, and followed by related applications using supercritical fluid technology. The special case of solvent shifting, pH shifting, is reviewed at length and illustrated to be effective for preparing nanoparticles of organics having weak acid functional groups. The first applications of organic particle precipitation in reverse microemulsion systems are described. The applicability of gas condensation methods is illustrated. Exciting new applications of precipitation in submicron hollow spheres and dye entrapment in submicron polymer gel networks are discussed. 相似文献
6.
假定二元液态混合物分子间的相互作用势能可以表示成多体相互作用势能的和,分子间的力为短程力,相互作用势能只与分子间的相对距离有关.利用分布函数理论导出了二元液态混合物的过剩内能和内压的公式.二元液态混合物的过剩内能和内压可以表示成体积的幂级数形式,其中的系数可以用多体相互作用势和多体径向分布函数表出.讨论了单元液体的内压和过剩内能的表达式,在两种特殊情形下,过剩内能和内压的表达式分别与Egelstaff的微扰论结果及Frank的实验结果具有相同的形式.讨论了二元混合物内压和内能的两个特例,其一,在特殊情形下,给出了混合液体过剩内能的混合规则的一个证明.其二,给出的二元混合物的过剩内能和内压的表达式与Frank的实验结果具有相同的形式. 相似文献
7.
M. Endo 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2007,81(9):1497-1501
Recent advances in chemical oxygen-iodine lasers (COIL) are reviewed. In this paper, developments of the COIL as a unique
chemical device, whose product is not a chemical substance but coherent photons is emphasized. The key component of a COIL
is the singlet oxygen generator (SOG). The unique principles of modern SOGs are reviewed. For high-efficiency operation, rapid
mixing of oxygen and iodine is of primarly importance. The latest mixing enhancement techniques are reviewed. Applications
of ultrahigh-power COILs are presented.
The text was submitted by the author in English. 相似文献
8.
The kinetic method is based on the catalytic effect of copper(II) on the oxidation of 4,4'-dihydroxybenzophenone thiosemicarbazone by hydrogen peroxide. The reaction is followed spectrophotometrically at 415 nm. The kinetic parameters of the reaction are reported and a rate equation is suggested. Three methods of rate measurement are compared. The calibration graphs are linear in the range 10–90 ng Cu ml-1. There are few interferences. The method is applied to the determination of copper in waters. 相似文献
9.
The main concepts of the nature of electronically excited states in polyatomic molecules and the intramolecular and intermolecular processes of their evolution are reported. The dependence of the probabilities of these processes on the electronic structure of the molecule is considered. Possible mechanisms of the dissociation of electronically excited molecules with bond cleavage are discussed, and the theoretical results of this consideration are given. The experimental data obtained by the authors are interpreted. In this case, attention is focused on C-H-bond photodissociation processes in a condensed phase, which are the best studied processes. The dissociation of other bonds is briefly discussed. 相似文献
10.
Experimental studies of supermolecular structures and localized flow birefringence in solutions of high-molecular weight polymer are described. Advantage is taken of poly(ethylene oxide) and polyisobutylene. Supermolecular structures are examined with the aid of optical microscopy using freeze-dried samples of the polymer solutions. Birefringence is investigated that arises in planar elongational flow in a cross-slot cell. Flow velocities at which the onset of the localized birefringence occurs are determined. Then these velocities are correlated with viscoelastic characteristics of the solutions. The presence of a liquid-crystalline fibrillar network in the polymer solutions exhibiting flow birefringence is ascertained. The fibrils are birefringent objects. The fibrils are birefringent objects. The localized birefringence phenomenon is explained in term of the orientation of the fibrils in elongational flow. It has been shown that the onset of localized birefringence occurs at a critical Weissenberg number, the value of which is close to unity. 相似文献
11.
Elena Kardash-Strochkova Yakov I. Tur’yan I. Kuselman Naphtali Brodsky 《Accreditation and quality assurance》2002,7(6):250-254
The results of two interlaboratory comparisons of acid number determinations in used motor oils are discussed. It is shown
that the comparability of the measurement results is not as good as that required by known standards for petroleum products.
The problem is motor oil contaminants which accumulated during use, and which are the source of a matrix effect in the acid
number determination. The standard methods’ drawbacks are analyzed and some improvements are proposed. Repeatability and accuracy
of the improved methods are evaluated.
Received: 11 December 2001 Accepted: 15 February 2002 相似文献
12.
Yu. H. Krieger 《Journal of Structural Chemistry》1999,40(4):594-619
Structural instability of one-dimensional conducting molecular systems is suggested as a physical principle underlying the
operation of molecular electronic devices, and its potential application in such devices is analyzed. The theoretical basis
of this effect is discussed. The conditions and parameters determining its characteristics are analyzed from the viewpoint
of molecular electronics. Data on one-dimensional molecular structures which are of interest for the design of electronic
devices are given. Peculiarities of structural instability are discussed, and potential static and dynamic control over the
conductivity of one-dimensional systems is analyzed. Molecular structures are given as examples of hypothetical electronic
devices. The possibilities and prospects of this approach in the development of molecular electronics are discussed. 相似文献
13.
低浓度三分子双曲型反应-扩散方程的非线性理论 总被引:2,自引:0,他引:2
建立了低浓度三分子模型双曲型反应-扩散的波动方程,研究了定态的稳定性,重点研究了Turing不稳定问题,指出双曲型方程的Turing不稳定不受扩散系数不相等(Dx≠Dy)这一条件的约束,进而对方程作近似的分支分析,讨论了出现极限环的条件,最后对极限环和定态不稳定作了数值研究. 相似文献
14.
《Thermochimica Acta》1986,103(2):341-351
As it is very often the first step of the process, heat transfer plays an important role, especially for systems heated in scanning mode. The problem is studied in the simple case when no reaction occurs. In the present case, heat is transferred through the cross-section of a cylinder heated on faces with a constant heating rate. The gradients of temperature through the sample when they are established are proportional to the heating rate on faces and to the square of the diameter of the cylinder. The shape of the gradients of temperature are obtained at different times when these gradients are not established and when they are constant. The heat flux emitted through the face-calorimeter interface are also determined. The value of heat flux is certainly the best parameter for testing the validity of the model. 相似文献
15.
钼、钨系过氧化物是非常重要的Sharpless烯烃环氧化催化剂,有着非常广泛的工业发展前景。本文综述了钼、钨系过氧化物的种类,结构,合成方法及催化活性,分析了各种钼、钨系过氧化物的特点以及在催化环氧化领域的发展现状。同时,本文还讨论了钼、钨系过氧化物催化烯烃环氧化反应的机理。评述了在催化环氧化领域中两种主要理论——Mimoun机理与Sharpless机理的争论焦点及发展现状,以及计算化学对两种理论中间过渡态的研究进展,并且重点分析了Sharpless机理的过渡态结构。此外,本文还综述了影响钼、钨系过氧化物催化剂反应活性的各种因素以及质子所产生的副反应。最后,本文对应用于催化环氧化领域的钼、钨系过氧化物未来的研究方向提出了建议。 相似文献
16.
Sambhu N. Datta 《Journal of Chemical Sciences》1994,106(2):445-466
A brief review of relativistic quantum chemistry is given here. Relativistic effects and their importance in chemistry are
discussed. An outline of different theoretical aspects is presented. Aspects of variation techniques relevant to relativistic
calculations are discussed in detail. These involve the derivation of min-max theorems for Dirac, Dirac-Hartree-Fock and Dirac-Coulomb
calculations. The consequence of relativistic Hamiltonians being unbounded are also discussed for other lines of investigation.
The upper bounds derived are physically interpreted. Sample Dirac-Hartree-Fock results for the Be atom, calculated using both
STO and GTO bases for the nonrelativistic orbitals and the upper components of the relativistic orbitals, are given. The inadequacy
of the so-called kinetically balanced basis set is discussed and illustrated with these results. The importance of the variational
or dynamical balance and hence the merit of the LCAS-MS scheme is pointed out. The possibility of calculating quantum electrodynamical
pair energy from relativistic configuration interaction calculations on a two-electron atom is discussed and exemplified.
The present status of relativistic molecular calculations is briefly reviewed. Conclusions on the aspects of variational analysis
and molecular calculations are enclosed. 相似文献
17.
18.
Klein SM Manoharan VN Pine DJ Lange FF 《Langmuir : the ACS journal of surfaces and colloids》2005,21(15):6669-6674
The fabrication of small structured spherical particles that are essentially small photonic crystals is described. The particles are 1-50 microm in diameter and are porous with nearly close-packed monodisperse pores whose size is comparable to the wavelength of light. The solid matrix of the particles is titania, which provides a large refractive index contrast between the particle matrix and pores. The particles are made by encapsulating polymer colloidal particles in emulsion droplets of hexanes in which a titanium alkoxide precursor is dissolved. Subsequent osmotic removal of the hexanes from the droplets and condensation of the alkoxide precursor leads to spherical aggregates of polymer spheres with titania filling the spaces between the polymer spheres. The polymer particles are then burned out leaving behind the desired porous titania particles. The size and structure of the pores and high refractive index of the titania matrix are expected to produce particles that are very efficient scatterers of light, making them useful as pigments. 相似文献
19.
溶剂萃取-火焰原子吸收法测定叠氮树脂中铜铁 总被引:7,自引:0,他引:7
提出用石油醚溶解样品,硝酸(1+99)萃取,火焰原子吸收法测定叠氮树脂中痕量铜和铁的方法,铜、铁的相对标准偏差均小于4.5%,回收率在97.0%~102.0%之间,测定结果满意。『 相似文献
20.
A novel scheme for pressure fluctuations in turbulent flows is developed. The pressure fluctuations are sensitive parameter in some of the fluid phenomena. In the computational methods and modeling turbulence flow, the pressure fluctuations are eliminated after averaging of the Navier-Stokes equations, and only average pressure could be calculated. In this research, the Reynolds-averaged Navier-Stokes equations are computed using SIMPLE method. The Reynolds stress transport model (RSTM) is used to determine the Reynolds stresses and the flow details. The velocity fluctuations are simulated using the Kraichnan model. The Poisson equation for the pressure fluctuations is obtained by taking the divergence of the incompressible momentum equation and algebraic operations, and this equation is numerically solved by finite difference method. The effects of Reynolds number on the pressure fluctuations are studied. 相似文献