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Dr. Christopher Batchelor-McAuley Dr. Enno Kätelhön Dr. Edward O. Barnes Prof. Richard G. Compton Dr. Eduardo Laborda Prof. Angela Molina 《ChemistryOpen》2015,4(3):224-260
Recent progress in the theory and practice of voltammetry is surveyed and evaluated. The transformation over the last decade of the level of modelling and simulation of experiments has realised major advances such that electrochemical techniques can be fully developed and applied to real chemical problems of distinct complexity. This review focuses on the topic areas of: multistep electrochemical processes, voltammetry in ionic liquids, the development and interpretation of theories of electron transfer (Butler–Volmer and Marcus–Hush), advances in voltammetric pulse techniques, stochastic random walk models of diffusion, the influence of migration under conditions of low support, voltammetry at rough and porous electrodes, and nanoparticle electrochemistry. The review of the latter field encompasses both the study of nanoparticle-modified electrodes, including stripping voltammetry and the new technique of ‘nano-impacts’. 相似文献
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唾液酸是一类重要的具有多种生物学功能的糖酸化合物. 唾液酸糖苷化反应条件较一般糖苷化反应苛刻, 立体选择性通常较差, 端基碳的立体构型较难控制. 在唾液酸糖苷化反应中能否高效地得到α糖苷键是评价该反应优劣的重要标志之一. 唾液酸苷化方法的研究一般涉及以下几个方面: C-2上的离去基团的运用, C-1, C-3上辅助基团的参与作用, C-5上氨基保护基团的修饰, 以及一些新的糖苷化反应催化剂的发展. 近些年来, 这些研究领域, 尤其是C-5上氨基保护基团的研究, 取得了重要进展. 将着重对唾液酸糖苷化方法的新进展做一总结和评述. 相似文献
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Samuel C. Temin 《高分子科学杂志,C辑:聚合物评论》2013,53(1):131-167
Abstract The topics of cross-linking methods and network polymers encompass an enormous literature covering many facets of polymer science. This review selects several areas from the broad field of cross-linking which represent more recent technology, particularly that not covered in earlier reviews [1]. 相似文献
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代谢组学及其研究进展 总被引:36,自引:0,他引:36
1 代谢组学的定义和特点 近年来,随着人类基因组测序工作的完成,人们对生命过程的理解有了很大的提高,研究的热点转移到基因的功能和几个“组学”研究,包括研究核糖核酸(RNA)转录过程的转录组学、研究某个过程中所有蛋白及其功能的蛋白组学、研究代谢产物的变化及代谢途径的代谢组学。 代谢组学作为一门新发展的技术,它是通过考察生物体系受刺激或扰动后(如将某个特定的基因变异或环境变化后)其代谢产物的变化或其随时间的变化,来研究生物体系的代谢途径的一种技术[1];它所关注的是相对分子质量为1000以下的小分子。代谢组学的代表… 相似文献
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Xing Wei Meng-Jiao Zhu Prof. Dr. Hong Yan Dr. Changsheng Lu Prof. Dr. Jing-Juan Xu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(55):12671-12683
The emergence of the rising alliance between aggregation-induced emission (AIE) and electrochemiluminescence (ECL) is defined as aggregation-induced electrochemiluminescence (AIECL). The booming science of AIE has proved to be not only distinguished in luminescent materials but could also inject new possibility into ECL analysis. Especially in the aqueous phase and solid state for hydrophobic materials, AIE helps ECL circumvent the dilemma between substantial emission intensity and biocompatible media. The wide range of analytes makes ECL an overwhelmingly interesting analytical technique. Therefore, AIECL has gained potential in clinical diagnostics, environmental assays, and biomarker detections. This review will focus on introduction of the novel concept of AIECL, current applied luminophores, and related applications developed in recent years. 相似文献
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稀土-钛氧簇合物作为团簇化学的一个新分支,不但结合了稀土和钛离子的特性,而且由于二者的协同效应而表现出优异的光、电、磁和催化性能.本文综合评述了不同配体稀土-钛氧簇合物的合成与结构,介绍了稀土-钛氧簇合物的代表性成果,并对其合成策略和发展前景进行了总结和展望. 相似文献
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Anne Robert Odile Dechy‐Cabaret JR
Me Cazelles Franoise Benoit‐Vical Bernard Meunier 《中国化学会会志》2002,49(3):301-310
A short review of the currently used antimalarial drugs is reported. The molecular aspects of the different possible mechanisms of action of artemisinin is documented, including recent data on heme alkylation. The preparation and the in vitro antimalarial activity of new modular molecules named “trioxaquines” is also presented. 相似文献
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ZHANG Tian-You 《高等学校化学学报》1999,20(Z1):217
Countercurrent Chromatography (CCC) is a special form liquid-liquid partition chromatography which entirely eliminates the use of solid support matrix. Its development began in the mid-1960s and first introduction of CCC is in 1970. In its early stage of development, the method was hindered by a limited mobile flow rate since the application of higher flow rates resulted in excessive loss of the stationary phase from the column. 相似文献
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分析化学学科发展趋势 总被引:1,自引:0,他引:1
本文对近年分析化学发展的新动向进行了简要的综述,包括痕量危险污染物和生物活性化合物分析方法的新进展。质谱法在分析生物样品中极性和荷电分子方面有着明显的长处。本文还评述了毛细管电泳、电分析、流动注射分析以及计算机在现代分析中的应用。 相似文献
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Bingyang Han Prof. Dr. Zhaofeng Wang Prof. Dr. Yong Huang 《Chemical record (New York, N.Y.)》2023,23(7):e202300099
Enamines are formed by reacting a carbonyl compound with an amine under dehydration conditions. A vast array of transformations has been achieved via preformed enamine chemistry. Recently, by introducing conjugating double bonds to the enamine functionality, dienamines, and trienamines have propelled the discovery of several previously unattainable remote-site functionalization reactions of carbonyl compounds. Comparatively, alkyne-conjugating enamine analogues have recently shown high potential in multifunctionalization reactions while remaining underexplored. In this account, we systematically summarized and discussed recent advances in synthetic transformations based on ynenamine-containing compounds. 相似文献
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电光高分子材料由于其在光电子信息领域的潜在应用前景已得到了广泛关注和深入研究.本文在简要介绍电光效应及其材料等相关知识的基础上,综述了最近几年来电光高分子材料的研究进展,主要包括生色团的设计与合成,以及掺杂型、侧链型、主链型、交联型、互穿网络型和树枝型等聚合物材料体系的设计与合成. 相似文献
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综述了具有 MWW 结构钛硅分子筛的制备方法、孔道和晶体结构的调变和修饰以及催化应用三个方面的研究进展. 与 TS-1 相比, 具有 MWW 结构钛硅分子筛的制备方法多种多样; 其孔道结构可塑性强, 通过采用层间剥离、柱撑以及分子水平硅烷化插硅扩孔技术, 可以增大和暴露孔道和外表面, 满足不同选择氧化反应的要求. 由于 MWW 结构钛硅分子筛拥有复杂而独特的孔道结构, 所以在小分子 (如直链烯烃等) 的环氧化反应, 和大分子 (环状烯烃, 二苯并噻吩等) 氧化反应中都表现出优异的催化性能. 此外, 该钛硅分子筛表现出与 TS-1 完全不同的溶剂效应, 用于烯丙基氯液相环氧化与酮类氨氧化反应主产物选择性更高. 相似文献
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含偶氮苯生色团的树枝状大分子的研究进展 总被引:4,自引:0,他引:4
含偶氮苯生色团的树枝状大分子是一类新型的功能化大分子,是目前功能大分子研究中最为活跃的方向之一。本文分类综述了含偶氮苯生色团的树枝状大分子的合成方法,结构及主要性能,并对其光响应性能进行了重点讨论。 相似文献