Reactive pulsed laser deposition and laser induced crystallization of SnO2 transparent conducting thin films

Transparent conducting SnO₂ thin films with a thickness between 1000–2000 Å were deposited on glass, quartz and silicon substrates using standard pulsed laser deposition techniques with two different targets (Sri and SnO₂) and with three different laser wavelengths (1.06, 0.532 and 0.266 ) from a Q-switched Nd: YAG laser. Tin dioxide films with optical transmission over most of the visible spectrum exceeding 80% were obtained using a Sn target and a background oxygen pressure of 20 Pa. The electrical resistivity () depended strongly on the substrate temperature during deposition, with the lowest values of of about 10^–2 -cm obtained when the substrate was maintained at 400°C during deposition. Using SnO₂ targets, predominantly amorphous phase SnO₂ films were deposited on Si substrates and then transformed into polycrystalline Sn₃O₄ by laser induced crystallization ( = 1.06 m). Whereas these later films were essentially non-conducting as deposited ( > 400 -cm), the electrical resistivity was permanently reduced after laser induced crystallization by a factor greater than 1000 to a value of approximately 4 × 10^–1 -cm.     

ВЛИЯНИЕ СПЕКТРАЛЬНО ГО ПРОФИЛЯ ДУБЛЕТАKα 1 α 2 И ДИФРАКЦИОННОГО РАС ШИРЕНИЯ НА ИНТЕГРАЛЬ НУЮ ИНТЕНСИВНОСТЬ ДИФРА КЦИЙ ПРИ ВЫСОКИХ УГЛА Х БРЭГГА

, K _{1 2} LP . 75°85° K , . , <80°. ( , ) <83°. , 90° , , , . >83° , , .

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The influence of the spectral profile of theK₁₂ doublet and diffraction broadening on the integrated intensities of high angle diffractions

Relations are derived giving the influence of the spectral profile of theK _{1 2} doublet and the influence of diffraction broadening on the productLP of the Lorentz and polarization factor. The relations are used to calculate the numerical values of the corresponding corrections for the theoretical values of the integrated intensities of diffractions in the angular region 75°85° and for the most frequently usedK radiation of copper, cobalt and iron.It follows from the calculated values of the corrections that, due to the accuracy at present attainable in experimental measurements, the influence of the spectral profile in diffractions with an angle<80° can be neglected when calculating the theoretical values of the integrated intensities. The influence of diffraction broadening need not be taken into account in diffractions with an angle<83° even when the broadening is large (e. g. five-fold). As the angle approaches 90°, of eourse, the corrections for both above influences suddenly increase, particularly those for diffraction broadening, and their limitation becomes difficult and is not single-valued. For this reason the use of diffractions with angles>83° does not appear very suitable for solving problems based on exact measurement of the integrated intensities and their comparison with the corresponding theoretical values.

     

Investigation of laser-induced plasma deposition of boron nitride

Laser ionization mass spectrometry (LIMS) was applied to the investigation of the composition of laser plasmas of three different boron nitride modifications (hexagonal -boron nitride with graphite structure, cubic -boron nitride with diamond structure and hexagonal -boron nitride resembling the wurtzite type). Thin films in the 10 nm range were produced in the ion source of the laser mass spectrograph by laser-induced plasma deposition. So we could carry out the plasma diagnostic and the preparation of thin films under the same condition. The cluster distribution in laser plasma is independent of the structure of the BN target. An explanation of laser-induced plasma deposition of boron nitride from the results of mass spectrometric analysis of laser plasmas and of the analysis of deposited thin films (TEM, EELS) was derived.     

Nano-structured oriented carbon films grown by PLD and CVD methods

PLD and CVD methods, plasma or bias assisted, have been used to prepare thin films of nano-clustered graphite. The experimental conditions (vz. deposition apparatus, substrate temperature, working pressure, inert sustaining gases, parent species, and applied voltage) have been changed with the final aim of obtaining small graphene particles with the basal planes oriented along the growth vector and perpendicular to the n-Si100 substrate. Pulsed laser ablation (Nd:YAG, 2nd harmonic: =532 nm, h=2.33 eV, =7 ns, =10 Hz, 7 J/cm²), assisted by an RF-plasma, of a pyrolytic graphite target gave good results for nano-structure formation, provided high substrate temperature and high inert gas pressure are maintained. CVD methods, in the presence of high substrate temperature and a DC bias, showed a good attitude to drive a longitudinal growth of graphene layers and nano-wires from a reactive gas flow of Argon/Hydrogen and Methane. The morphology of the films grown at different conditions have been characterised by scanning electron microscopy (SEM). Film quality and nano-particle dimensions have been estimated by Raman spectroscopy. PACS 81.07.-b; 81.15.-z; 78.30.-j; 68.37.-d     

К ТЕОРИИ ГРАВИТАЦИОННОГО ИЗЛУЧЕНИЯ

. , , , . , . . . . , , . ; , .

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On the theory of gravitational radiation

The equations of motion of weakly radiating particles are investigated in a linear approximation in which the pseudo-Euclidian metric remains valid but energy changes caused by gravitational radiation are considered. The classical relativistic equations of motion with variable rest mass are applied. An elementary theory of the gravitational radiation of a rotator is formulated. The results are applied for particles in circular accelerators. It is found that a rotator with non-zero rest mass cannot exist for an unlimited period and that it cannot exceed the velocity of light. This explains why particles with non-zero rest mass cannot attain the velocity of light in circular accelerators; it is also shown that the gravitational radiation of particles in circular accelerators does not exist in practice.

     

The temperature vibrations of urea molecules

The structural and dynamic parameters of urea at 112°K and 295°K were determined by the least squares method. The characteristic temperature of the torsional optical vibrations of a molecule about a C-O bond was determined and is in good agreement with the value determined by Raman scattering. The fractional X-coordinate of the nitrogen atom corrected for torsional vibrations was determined and it was found that the magnitude of the projection of the C-N bond in the given temperature range changes only within the limits of observational errors. A new method, called temperature difference synthesis, is described and it is shown that it is suitable for rapid qualitative determination of the thermal anisotropy of the vibrations of atoms in a crystal lattice.

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112°K 295°K. C-O , , . X- , C-N . , , , .

     

КОРРЕКЦИОННЫЕ ФАКТО РЫ ПРИ АБСОЛЮТНОЙ ДОЗ ИМЕТРИИ ПЛОСКИХ ИСТОЧНИКОВβ-ИЗЛУЧЕНИЯ С ПОМОЩЬЮ СЧЕТЧИКА ГЕЙГЕРА-МЮЛ ЛЕРА

n n, n , .     

The effect of microsegregation on the generation of dislocations in zinc single crystals

The applicability of Tiller's considerations on the production of dislocations is proved. The density of dislocations appearing during impurity microsegregation increases with increasing rate of growth as a consequence of the corresponding change in the effective distribution coefficient. The real value of C at the microsegregation boundaries is at least twice as great as the average value of the concentration of impurities in the crystal in question.

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. , , . C , .

     

К ОПРЕДЕЛЕНИЮ ПОСТОЯ ННЫХ РЕШЕТКИ МЕТОДОМ ДЕБАЯ-ШЕРРЕР А

, , , .     

КОГЕРЕНТНОЕ ИЗЛУЧЕН ИЕ СИНХРОТРОННЫХ СГУ СТКОВ ЭЛЕКТРОНОВ В ЗАМКНУТ ОМ РЕЗОНАТОРЕ

. , .

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The coherent radiation of synchrotron electron clusters in a closed resonator

A study is made of the electromagnetic interaction of electrons in thin relativistic clusters during coherent radiation in a synchrotron. The magnitude and form of the tangential component of the force, acting on an isolated electron of a cluster of electrons, is expressed.

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The crystal structure of copper dipyridine dibromide Cu(C5H5N)2Br2

The X-ray structural analysis of copper dipyridine dibromide was carried out. The substance is monoclinic, its space group isP2₁/n, having the lattice constantsa=8.30 kXU,b=17.72 kXU,c=4.04 kXU,=96°,Z=2. The localization of the heavy atoms was carried out by means of the projections of the Patterson functionsP(u, v) andP(v, w), which provided the bases for determining the signs of the majority of structure factors. The projections of the electron density(x, y) and(y, z) were calculated on the basis of these data. The positions of the atoms were refined three times by methods of differential syntheses and by geometrical analysis. The structure of CuPy₂Br₂ is very close to that of CuPy₂Cl₂ [1], [2], differing from it primarily in the orientation of the symmetry elements with respect to the crystallographic axes. In both structures the copper atom is octahedrally coordinated with four halogen and two nitrogen atoms. The nitrogen atoms and two bromine atoms are bound to the copper covalently in the structure of the bromine derivative, as follows from the length of the bonds (Cu-N 1.99 kXU, Cu-Br, 2.46 kXU), while the remaining two bromine atoms are bound to the copper by weaker bonds and mediate the chain formation of molecules in the direction of thec axis.

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Cu(C₅H₅N)₂Br₂

. , 2₁/ ==8,30 kX,b=17,72 kX,=4,04 kX,=96°,z=2. (, v) P(v, w), . (, ) (, z). . CuPy₂Br₂ u₂1₂, . . , (-N 1,99 kX, u-r 2,46 kX), .

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The authors thank M. Serátor for supplying the crystal samples and for initiating the work, the management of the Institute of Technical Physics, Czechoslovak Academy of Sciences, in Prague and especially Dr. A. Línek for making it possible to calculate some of the Fourier maps on the special computer Elika and finally A. lechtová for carefully calculating the Fourier maps and structure factors.

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The first stage of this work was reported on at the 3rd State Conference on Inorganic Chemistry, held in Bratislava from June 29th to July 4th, 1959.     

К ВОПРОСУ O КРИТИЧЕСКО Й ЧАСТОТЕ ПРИ ПРЕРЫВИСТОМ ОСВЕ ЩЕНИИ

c , c n , n AgBr. .     

On the problem of the phase shifts of reflected light

. , . , . .

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On the problem of the phase shifts of reflected light

The paper solves the topical question of phase shifts when light is reflected. By introducing the reflection tensor and its transformation it was found that all phase shifts hitherto given in the literature can be used. It was proved that when different phase shifts are used the corresponding unit vectors must be oriented. If an arbitrary coordinate system and the relations pertaining to it are used consistently it is not possible by calculation or experiment to arrive at contradictory results.

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. , , . .: , 1961. . 45–49 . . , .. . , .     

Studium der photodielektrischen Erscheinung an lumineszierenden Zinkkadmiumsulfiden

Zusammenfassung Die spektrale Abhägigkeit der photodielektrischen Eigenschaften der lumineszierenden Zinkkadmiumsulfide verschiedener Zusammensetzung zeigt, da eine Beimengung von Kupfer das Eintreten von Zuständen mit groer Polarisierbarkeit hervorruft, die eine Änderung der realen Komponente der Dielektrizitätskonstanten zur Folge haben. Die Kupferkonzentration kann dabei so gering sein, da sie in der Lumineszenzemission gar nicht zur Geltung kommt. Die Infrarotmaxima der Verluste entsprechen Niveaus, die von anderen Autoren und mit anderen Methoden festgestellt wurden. Das Maximum des Exzitationsspektrums im Bereiche des Ausläufers der Absorptionskante hängt mit dem Maximum der Änderung der realen Komponente der Dielektrizitätskonstante zusammen.

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- , , . , . , . .

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Nunmehr im Physikalischen Institut der Karlsuniversität, Prag.     

Усовершенствование рентгенометрическо го метода определения дефекто в решетки третьего ро да в поликристаллическ их и порошкообразных материалах

, . .     

The rotation of bloch walls

A Bloch wall has an integral magnetic moment which is due to the spatial distribution of the magnetic moments of the spin. The external magnetic field thus acts on the wall with a torque, which leads to the rotation of the sub-domains and therefore to deformation of the walls. A theory of this rotation is given and from it a microphysical model of the undulatory surface structure in uniaxial ferromagnets is derived. Experiments performed on magnetoplumbite single crystals fully confirm the theoretical assumptions.

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. , , . , . , , .

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Our thanks go to J. Fousek and Z. Málek who by reading this paper contributed greatly to the clarity of its presentation.     

ПОТОК ЭНЕРГИИ ЧЕРЕЗ Д ИЭЛЕКТРИЧЕСКИЙ ТОНК ИЙ СЛОЙ ПРИ НАРУШЕННОМ ПОЛНО М ОТРАЖЕНИИ

, .

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Energy flux through thin dielectric film when total reflection is disturbed

It is shown that the energy flux through a thin dielectric film when total reflection is disturbed is brought about by the interference Poynting vector.

     

On the energy balance in the optics of metals

On the basis of the boundary conditions of the electromagnetic theory an explicit calculation of the absorption in a thin metallic film was carried out with the result that transport and interference components were found to exist. By applying the method to a simple metal-dielectric boundary the physical interpretation was given of the energy balance, which had hitherto been regarded as unclear. It was also explained why the reversibility principle fails when applied to a metal-dielectric boundary.

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, . - , . , - .

     

ЗАВИСИМОСТЬ ПОЧЕРНЕ НИЯ ФОТОГРАФИЧЕСКОЙ ЭМУЛЬСИИ ОТ ЭНЕРГИИβ-ИЗЛУЧЕНИЯ

, - - . , - , , :³²P,³⁵S ⁹⁰Sr+⁹⁰Y.     

Металлографические методы определепия нлотности дислокаци й В монокристаллах германия

, , . , .1) . .