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1.
With the development of life science and environmental science, the increasing requirements on understanding the mechanism of trace element effects on ecology and human health become more and more obvious. The concept of "total amount of element" or its "valence" is not enough to give a satisfactory explanation about the events exactly happen in nature. As a result, metal compound speciation has become more and more important and challenging. 相似文献
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Lawrence NS 《Talanta》2006,69(2):385-392
The determination of methane is of strong interest to the analytical community due to its natural abundance, its potential to cause explosions and its known greenhouse effect. The current report gives a brief overview into the environmental significance of methane and an account of the existing detection protocols for methane in air and environmental samples. 相似文献
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Inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation ICP-MS (LA-ICP-MS) have been applied as the most important inorganic mass spectrometric techniques having multielemental capability for the characterization of solid samples in materials science. ICP-MS is used for the sensitive determination of trace and ultratrace elements in digested solutions of solid samples or of process chemicals (ultrapure water, acids and organic solutions) for the semiconductor industry with detection limits down to sub-picogram per liter levels. Whereas ICP-MS on solid samples (e.g. high-purity ceramics) sometimes requires time-consuming sample preparation for its application in materials science, and the risk of contamination is a serious drawback, a fast, direct determination of trace elements in solid materials without any sample preparation by LA-ICP-MS is possible. The detection limits for the direct analysis of solid samples by LA-ICP-MS have been determined for many elements down to the nanogram per gram range. A deterioration of detection limits was observed for elements where interferences with polyatomic ions occur. The inherent interference problem can often be solved by applying a double-focusing sector field mass spectrometer at higher mass resolution or by collision-induced reactions of polyatomic ions with a collision gas using an ICP-MS fitted with collision cell. The main problem of LA-ICP-MS is quantification if no suitable standard reference materials with a similar matrix composition are available. The calibration problem in LA-ICP-MS can be solved using on-line solution-based calibration, and different procedures, such as external calibration and standard addition, have been discussed with respect to their application in materials science. The application of isotope dilution in solution-based calibration for trace metal determination in small amounts of noble metals has been developed as a new calibration strategy. This review discusses new analytical developments and possible applications of ICP-MS and LA-ICP-MS for the quantitative determination of trace elements and in surface analysis for materials science. 相似文献
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Raúl A. Gil Pablo H. Pacheco Patricia Smichowski Roberto A. Olsina Luis D. Martinez 《Mikrochimica acta》2009,167(3-4):187-193
The enrichment ability of carbon nanotubes (CNTs) was investigated and a new method established for the determination of trace thallium species in environmental samples using electrothermal atomization-atomic absorption spectrometry (ETAAS). The CNTs were employed as sorbent substrate in a continuous flow system coupled to ETAAS. Parameters influencing the recoveries of thallium were optimized. Under optimal conditions, the detection limit and precision of the method were 0.009 µg L?1 and 3.9%, respectively. The method was applied to the determination of thallium in real environmental samples and the recoveries were in the range from 96 to 100%. This system was able to separate thallium (I) from the matrix, which allowed its selective determination. The total thallium content was then determined by reducing Tl(III) with hydroxylamine. All these experimental results indicated that this new procedure can be applied to the determination of trace thallium in drinking water samples. 相似文献
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W. A. Heidmann 《Chromatographia》1988,25(1):8-14
Summary A procedure has been developed which allows the determination of the concentration and composition of polychlorinated technical
mixtures in environmental samples avoiding the use of standard compounds as much as possible. A common MS response of the
congeners of each degree of chlorination is assumed and determined by comparison of the FID and MS response of the respective
congeners in a technical mixture. A measure for the variability of the assumed common MS response is derived so that its validity
is proved in an objective manner. The method presented here allows the isomer specific determination of those polychlorinated
technical mixtures in environmental samples which could not so far be determined in this way for lack of standards. The polychlorinated
naphthalenes are quoted as illustration and a few data of residues in environmental samples are given. 相似文献
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《Analytical letters》2012,45(12):1911-1922
Abstract A new chelating resin was prepared by coupling Amberlite XAD-4 with brilliant green through an azo spacer, and it has been used for preconcentration and separation of mercury(II) in environmental samples prior to its determination by spectrophotometry. The sorption capacity of functionalized resin is 4.12 mg g?1. Spectrophotometric determination of Hg(II), free from the interference of almost all cations and anions found in the environmental water samples, is a notable advantage of the method. The determination of Hg(II) in wastewater and seawater was carried out by the present method and cold vapor atomic absorption spectrometry (CVAAS). 相似文献
10.
Pyrzyńska K 《Talanta》1998,47(4):841-848
Increasing platinum concentrations have been detected in environmental samples since the introduction of catalytic converters used in cars. Also the intensive use of platinum-based anti-tumor drugs led to interest in the determination of trace amounts of platinum absorbed by the human body and of the physiological effect of its complexes on living organism. However, detection of Pt and Pd in environmental and biological samples with complex matrices, has to be generally preceded by a preconcentration/separation step. A brief overview of the application of solid sorbents for these procedures based on published data is presented. Attention is also paid to preparation of the samples and detection methods usually used for determination of platinum and palladium. 相似文献
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The pollution of organophosphorus pesticides in water, especially in drinking water source, is a vital threat to life. Therefore, great concern is being focused on the effects of pesticide residues on public health and wildlife. The detection of trace organophosphorus pesticide residues in water is a very important task. In the recent years, the immunoassay technique has been utilized in the determination of trace organophosphorus pesticide residues in various environmental samples. 相似文献
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Sherrod L. Maxwell Brian K. Culligan 《Journal of Radioanalytical and Nuclear Chemistry》2012,293(1):149-156
A new rapid method for the determination of 226Ra in environmental samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used for emergency response or routine sample analyses. The need for rapid analyses in the event of a Radiological Dispersive Device or Improvised Nuclear Device event is well-known. In addition, the recent accident at Fukushima Nuclear Power Plant in March, 2011 reinforces the need to have rapid analyses for radionuclides in environmental samples in the event of a nuclear accident. 226Ra (T1/2?=?1,620?years) is one of the most toxic of the long-lived alpha-emitters present in the environment due to its long life and its tendency to concentrate in bones, which increases the internal radiation dose of individuals. The new method to determine 226Ra in environmental samples utilizes a rapid sodium hydroxide fusion method for solid samples, calcium carbonate precipitation to preconcentrate Ra, and rapid column separation steps to remove interferences. The column separation process uses cation exchange resin to remove large amounts of calcium, Sr Resin to remove barium and Ln Resin as a final purification step to remove 225Ac and potential interferences. The purified 226Ra sample test sources are prepared using barium sulfate microprecipitation in the presence of isopropanol for counting by alpha spectrometry. The method showed good chemical recoveries and effective removal of interferences. The determination of 226Ra in environmental samples can be performed in less than 16?h for vegetation, concrete, brick, soil, and air filter samples with excellent quality for emergency or routine analyses. The sample preparation work takes less than 6?h. 225Ra (T1/2?=?14.9?day) tracer is used and the 225Ra progeny 217At is used to determine chemical yield via alpha spectrometry. The rapid fusion technique is a rugged sample digestion method that ensures that any refractory radium particles are effectively digested. The preconcentration and column separation steps can also be applied to aqueous samples with good results. 相似文献
14.
流动注射化学发光检测法的进展 总被引:11,自引:0,他引:11
评述近年来流动注射化学发光检测法及生物发光检测法的最新进展。内容涉及各类化学发光反应、生物发光和电致化学发光反应同流主射体系的耦合方式,仪器设计,多种无机、有机、生物大分子、生物活性的药物的分析方法及其在环境、生物医学客生命科学、化学及药物化学中的应用和发展方向。 相似文献
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Background
The rapid, simple determination of surfactants in environmental samples is essential because of the extensive use and its potential as contaminants. We describe a simple, rapid chemiluminescence method for the direct determination of the non-ionic surfactant Triton X-100 (polyethylene glycol tert-octylphenyl ether) in environmental water samples. The optimized experimental conditions were selected, and the mechanism of the Luminol-H2O2-Triton X-100 chemiluminesence system was also studied. 相似文献16.
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<Superscript>226</Superscript>Ra and <Superscript>228</Superscript>Ra determination in environmental samples by alpha-particle spectrometry 总被引:1,自引:1,他引:0
J. L. Aguado J. P. Bolivar R. García-Tenorio 《Journal of Radioanalytical and Nuclear Chemistry》2008,278(1):191-199
A complete methodology for 226Ra and 228Ra determination by alpha-particle spectrometry in environmental samples is being applied in our laboratory using 225Ra as an isotopic tracer. This methodology can be considered highly suitable for the determination of these nuclides when
very low absolute limits of detection need to be achieved. The 226Ra determination can be performed at any time after the isolation of the radium isotopes from the analyzed samples while the
228Ra determination needs to be carried out at least six months later through the measurement of one of its grand-daughters.
The method has been validated by its application to samples with known concentrations of these Ra nuclides, and by comparison
with other radiometric methods. 相似文献
18.
Aluminium speciation in environmental samples: a review 总被引:2,自引:0,他引:2
Because of its toxic effects on living beings, Al may represent an environmental hazard, particularly under increased acidic
conditions. Growing environmental concern over the presence of increased Al concentrations in soil solutions and fresh waters
resulted in the development of numerous analytical techniques for the determination of Al species. Al has a very complex chemistry
that is significantly influenced by pH. Different Al species are present in environmental solutions, and many of them are
unstable. Contamination of samples and reagents by extraneous Al represents an additional problem in speciation of Al at trace
concentrations. Due to these reasons quantitative determination of particular chemical forms of Al is still a very difficult
task for analytical chemists. The most important analytical methodologies of the last decade and new trends for the speciation
of Al in environmental samples are comprehensively reviewed here. 相似文献
19.
Two nuclear analytical techniques for determination of 210Pb-specific activity in solid environmental samples have been validated and compared. The first technique depends on determination
of 210Pb via its alpha emitting daughter 210Po using alpha-particle spectrometry, while the second technique is based on direct determination of 210Pb by measuring its activity at the 46-keV gamma line by low-energy gamma-ray spectrometry. Detection limits, repeatability,
reproducibility, and surrogate recovery were the main validation parameters. Measurement uncertainties were estimated and
compared for both techniques. Results of this study have shown that the expected activity of 210Pb in the environmental samples and the required measurement uncertainty are the main factors influencing a selection of the
appropriate method for the application. 相似文献
20.
Masahiko Fujita Wontae T. Jung Hiroko Tatematu Donghun H. Sohn Tsuneaki Maeda 《Journal of separation science》1991,14(2):83-90
An automated system employing a purge and trap technique with capillary gas chromatography and electron-capture detection (ECD) has been developed for the analysis of trace levels of volatile halogenated hydrocarbons and applied to the determination of the compounds in environmental samples such as rainwater and ambient air. The operation of the method, its application to environmental samples, and the results obtained are described. Use of the system ensured good chromatographic resolution and high accuracy, even with trace levels of the compounds. 相似文献