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A NEW METHOD TO ENHANCE THE MAGNETISM OF Fe OVERLAYER ON GaAs(100): SULFUR PASSIVATION USING CH3CSNH2 下载免费PDF全文
Ferromagnetic resonance (FMR) has been used to investigat the magnetism of Fe overlayer on S-passivated GaAs(lO0) pretreated by CH3CSNH2. Comparing with the magnetism of Fe overlayer on clean GaAs(100), we find that sulfur passivation can prevent Aa diffusion into Fe overlayer and weaken the interaction of As and Fe. It results in enhancing the magnetism of Fe overlayer on GaAs(100). We also investigate the effects of the pre-annealing of S- pasaivated GaAs(100) substrate on the magnetism of Fe overlayers. The results show that the maximum effective magnetization can be obtained at annealing temperature of 400℃. According to the experimental results of synchrotron radiation photoemission, it can be explained by the change of chemical composition and surface structure of the passivation layer on GaAs(100) surface after the annealing. 相似文献
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InP(100) surface treated with (NH4)2Sx has been investigated by using photolumines-cence(PL), Auger electron spectroscopy and X-ray photoelectron spectroscopy, It is found that PL intensity increased by a factor of 3.3 after (NH4)2Sx passivation and the sulfur remained on the surface only bonded to indium, not to phosphorus. This suggests that the sulfur atoms replace the phosphorus atoms on the surface and occupy the phosphorus vacancies. 相似文献
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STUDY OF IRON OVERLAYER ON SULPHUR PASSIVATED GaAs(100) BY SYNCHROTRON RADIATION PHOTOEMISSION 下载免费PDF全文
We have studied the interface electronic structures and the chemical reaction of the Fe overlayer deposited on S-passivated GaAs(100). The chemical bond and electronic structure are different from Fe/GaAs, and the reaction between As and Fe is weakened by S atoms. This is beneficial to the magnetism in the interface. In the first stage of deposition, Fe clusters is form near S atoms due to the large electronegativity of S. The S atoms remain at the interface with Fe coverage. Magnetic ordering feature is found at a coverage higher than 0.6 nm. According to the large exchange splitting in valence band spectra, we suggest that Fe phase transition from bcc to fcc occurs with increasing coverage. 相似文献
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本文利用自由电子激光(FEL)纵模统一理论讨论了光学速调管自由电子激光相干谐波的输出情况。从物理上分析了非对称光学速调管的设计,得出了采用非对称的光学速调管可使FEL的相干谐波输出提高近30%。 相似文献
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本文使用AES-LEED联合装置研究了650—800℃温度范围内硫在镍(100)表面上的偏析动力学。结果表明,在较短退火时间内硫的表面浓度正比于退火时间的平方根,与McLean的动力学模型是一致的。扩散系数与温度的关系为D(cm2/s)=5×10-3exp(-44600/RT)。硫偏析在镍(100)表面达到饱和值,LEED观察指出形成了硫的c(2×2)结构。深度剖面分析,硫/镍俄歇峰高比随氩离子剥离时间指数降低。
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InP(100) surface treated with (NH4)2Sx has been investigated by using photolumines-cence(PL), Auger electron spectroscopy and X-ray photoelectron spectroscopy, It is found that PL intensity increased by a factor of 3.3 after (NH4)2Sx passivation and the sulfur remained on the surface only bonded to indium, not to phosphorus. This suggests that the sulfur atoms replace the phosphorus atoms on the surface and occupy the phosphorus vacancies. 相似文献
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现场测量声信号需要消除因声反射而产生的干扰。本文根据传声通道的响应特性,提出一种用倒频谱技术消除声反射影响的方法。计算机模拟和在消声室进行的自由场与人为设立一、两个反射面情况的对比实验都表明,该方法有效。 相似文献
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给出测量金属线胀系数的一种新方法。本文根据夫琅和费衍射原理,利用CCD来测量金属体随温度升高的伸长量,对黄铜的线胀系数进行了测量。 相似文献
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建立了一种硫钝化GaAs(100)表面的新方法,即CH3CSNH2/NH4OH溶液处理,应用同步辐射光电子能谱(SRPES)和X射线光电子能谱(XPS)表征了该钝化液处理的n-GaAs(100)表面的成键,特性和电子态.结果表明,经过处理的n-GaAs(100)表面,S既与As成键也与Ga成键,形成S与GaAs的新界面,并且Ga和As的氧化物被移走,这标志着CH3CSNH2/NH4关键词: 相似文献
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Laser projection-patterned etching of GaAs in a HCl and CH3Cl atmosphere performed using a pulsed KrF-excimer laser (=248 nm, =15 ns) and deep-UV projection optics (resolution 2 m) is reported. The etching process carried out in a vacuum system having a base pressure of 10–6 mbar is shown to result from a purely thermochemical reaction. Etching takes place in two steps: (i) between the laser pulses, the etchant gas reacts with the GaAs surface-atomic layer to form chlorination products (mainly As and Ga monochlorides), (ii) local laser surface heating results in the desorption of these products allowing further reaction of the gas with the surface. The influence of the etching parameters (laser energy density, gas pressure and pulse repetition rate) on the etch rate and the morphology of the etched features was studied. Etch rates up to 0.15 nm per pulse, corresponding to the removal of 0.5 GaAs molecular layer, are achieved. The spatial resolution of the etching process is shown to be controlled by the heat spread in the semiconductor and by the nonlinear dependence of the etch rate on the surface temperature. As a result, etched features smaller or larger than the projected features of the photomask are achieved depending on the laser energy density. Etched lines having a width of 1.3 m were obtained at low fluences by the projection of 2 m wide lines onto the GaAs surface. 相似文献
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建立了一种计算SQM力场标度因子的新方法,它具有简捷、精确、且不依赖于实验信息的特点,改善了SQM方法。将其在Abinitio水平上计算的力常数用于振动分析,所得计算频率与观测频率十分吻合。 相似文献
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金属氧化物对Ca(OH)_2脱硫影响的研究 总被引:15,自引:0,他引:15
1前言鉴于钙基吸收剂干法烟气脱硫技术在脱硫产物处理等方面的优势,本文开展了Ca(O)。中低温干燥状态下的反应特性、活化能及其影响因素的试验研究,以求进一步增强对其反应特性的了解并弄清金属氧化物的作用。2装置及样品试验装置如图1示,采用硫化床形式以强化吸收剂与气相反应物之间传质。床层温度由理入反应器内的热电偶测出并由温控仅控制。SOZ气体经稀释气体稀释并混合、预热后流入反应管进行反应,反应后气体由尾部的SOZ吸收水箱吸收后排入大气。冷却室可防止水蒸气进入气体分析仪。通过记录SOZ浓度随时间的变化规律即可得到… 相似文献