Effect of Nd concentration on the laser performance of a new laser crystal: Nd : NaY(WO4)2

We have measured the transmission and emission spectra of a new crystal, Nd : NaY(WO₄)₂ (Nd : NYW). Using a Ti : sapphire laser as the pump source, the laser performances of Nd : NYW crystals with different concentrations are compared for the first time. The Nd³⁺ concentrations used are 1, 2, 4 and 5 at%. Our investigation shows that 2 at% is the optimum concentration. When the incident pump power is 575 mW, the 1.06 μm output can reach 184 mW, corresponding to an optical-to-optical efficiency of 32%. We believe that our work is significant for the further research and actual application of this promising laser crystal.     

Effect of Nd3+ Concentration on the Laser Performance of a New Laser Crystal∶Nd∶NaY(WO4)2

The transmission and emission spectra of a new crystal, Nd∶NaY(WO4)2 (Nd∶NYW) have been measured. Using a Ti∶Sapphire laser as the pump source, the laser performances of Nd:NYW crystals with different concentrations are compared for the first time. The Nd3+ concentrations used are 1, 2, 4 and 5 at.-%. The experiments show that 2 at.-% is the optimum concentration. When the incident pump power is 575 mW, the 1.06 μm output can reach 184 mW, corresponding to an optical to optical efficiency of 32%. The experimental results show that the work is significant to the further research and praction application of this promising laser crystal.     

掺Er3+的NaY(WO4)2晶体的光谱特性

测量了Er:NaY(WO4)2晶体的吸收光谱、激发光谱、发射光谱以及上转换发光,并对测量的结果进行了详细分析,得出了Er:NaY(WO4)2晶体的光学特性.解释了离子间的能级跃迁过程 关键词： Er:NaY(WO4)2晶体 Er3+ 吸收光谱 激发光谱 发射光谱 上转换     

Er3+，Tm3+共掺的NaY(WO4)2晶体的光谱分析和上转换发光

在室温下，测量了Er:Tm:NaY(WO₄)₂晶体的吸收光谱、激发光谱、发射光谱以及上转换发光，并运用J-O理论对测量的结果进行了计算，得出了Er:Tm:NaY(WO₄)₂晶体的强度参数.报道了Tm，Er离子间特殊的能量传递和相关上转换，解释了离子间的能级跃迁过程.同时，对于Er增强Tm离子近红外发光的特性也作了充分研究. 关键词： 4)₂晶体')" href="#">Er:Tm:NaY(WO₄)₂晶体 吸收光谱 发射光谱 激发光谱 上转换     

钨酸钇钠晶体中Tm3+的光谱特性

测量了Tm3 :NaY(WO4 ) 2 晶体的吸收光谱、发射光谱和激发光谱 ,利用J_O理论计算了钨酸钇钠晶体的强度参数 :Ω2 =7 2 130 4× 10 - 2 0 cm2 ,Ω4 =0 5 0 4 76 6× 10 - 2 0 cm2 ,Ω6 =0 977784× 10 - 2 0 cm2 ,以及Tm3 的光学参数包括各能级的荧光寿命和荧光分支比、积分发射截面等 ,在计算了Tm3 的自发辐射概率时 ,同时考虑了电偶极跃迁和磁偶极跃迁 .研究了其发光特性和跃迁通道 ,发现存在1 D2 3H6 →1 G4 3F4 的交叉弛豫     

Ca8Mg(SiO4)4Cl2:Eu2+,Nd3+的近红外发光

用高温固相法制备了Ca<,8>Mg(SiO<,4>)<,4>Cl<,2>:Eu<'2+>,Nd<'3+>近红外发光材料,通过X射线衍射仪,近红外,可见发射光谱和激发光谱,荧光寿命等对样品进行了测试.研究了Eu<'2+>、Nd<'3+>的掺杂浓度对近红外发光性能的影响及相对强度变化的规律,结果表明,Ca<,8>Mg(Si...     

高压下Na5Tb(WO4)4单晶的光谱

研究了Na5Tb(WO4)4单晶的高压发光规律,化学计量的Na5Tb(WO4)4基质发光单晶的发光来源于基质中高浓度Tb3+.用金刚石对顶砧显微光谱系统在0-4GPa范围内研究了Na5Tb(WO4)4的室温高压光谱,确定了各发射谱线的高压移动率.对Tb3+的5D4→7Fj(j=0,1,2,3,4,5),测到18条谱线高压移动率中除一条(5D4→7F2,常压峰值15509cm-1)蓝移外,都红移,红移率最大为-19.5cm-1/GPa(对应谱线5D4→7F4,常压峰值16876cm-1),与Tb3+在其它基质中相比,此移动率很大.     

Intracavity Frequency Doubling of a New Low－threshold High－efficiency Crystal Nd：Sr_5（VO_4）_3F

ＩｎｔｒａｃａｖｉｔｙＦｒｅｑｕｅｎｃｙＤｏｕｂｌｉｎｇｏｆａＮｅｗＬｏｗ－ｔｈｒｅｓｈｏｌｄＨｉｇｈ－ｅｆｆｉｃｉｅｎｃｙＣｒｙｓｔａｌＮｄ：Ｓｒ＿５（ＶＯ＿４）＿３ＦＺＨＡＯＳｈｅｎｇｚｈｉ；ＷＡＮＧＱｉｎｇｐｕ；ＺＨＡＮＧＸｉｎｇｙｕ；ＷＡＮＧ...     

Nd3+:Er3+:KY(WO4)2激光晶体的生长和光谱特性

采用熔盐法从K2 WO4助熔剂体系生长出尺寸为 4 5mm的Nd3 :Er3 :KY(WO4) 2 透明晶体。从晶体中切割出Ф3× 11 9mm的激光器件 ,测量了晶体的紫外 -近红外的吸收光谱 ,从吸收光谱图上可以看到 ,晶体存在着 974 88nm ;80 1 0 (798 12 ,80 3 95 )nm ;74 8 5 (75 3 5 ,74 3 4 9)nm ;6 5 3 6 1nm ;5 86 6 5nm ;5 18 6(5 4 5 0 3,5 2 1 32 ,4 89 35 )nm ;4 5 2 80nm ;4 0 7 81nm ;36 7 2 2 (377 2 4 ,36 6 4 ,35 8 0 2 )nm九个吸收峰带 ,对各个吸收峰带按照Er3 和Nd3 离子的能级跃迁进行了归属。同时采用Edinburgh InstrumentF92 0荧光光谱仪在室温下对晶体进行了荧光测试研究。研究结果表明 ,共掺Nd3 离子可以增强Er3 :KY(WO4) 2 对半导体激光器泵浦源 (80 0nm)的吸收。     

Na5Eu(WO4)4单晶的光学性质研究

本文测定了Na5Eu(WO4)4单晶的吸收光谱,荧光寿命和荧光分支比,并计算了5D0→7FJ,的辐射跃迁几率、量子效率和发射截面。     

Nd∶NaR(WO_4)_2晶体生长(R=Bi,Y)

采用提拉法生长出了掺钕钨酸铋钠[Nd∶NaBi(WO4)2,简称Nd∶NBW]和掺钕钨酸钇钠[Nd∶NaY(WO4)2,简称Nd∶NYW]晶体,并给出了制备无开裂优质Nd∶NBW和Nd∶NYW晶体的最佳生长工艺参数。从XRD分析得到Nd∶NBW和Nd∶NYW晶体的晶胞参数,并分析了晶体的拉曼光谱,认为二者结构基本相同,为四方晶系、白钨矿结构、I41/a空间群。由吸收光谱可以看出,Nd∶NBW在802nm有较强的吸收峰,Nd∶NYW在804nm、752nm、586nm附近有较强、较宽的吸收峰,二者均适合于LD泵浦;计算了晶体中Nd3+的吸收截面积。     

Nd: Sr_5 (PO_4 )_3 F Crystal Laser Characteristics Using GaAs as Passive Q-switch

1 IntroductionQ- switching Of diode-pumped lasers iS an effective technique because they provideshort duration optical pulses required for laser ranging, nonlinear studies, medidne andother important applications[1--#]. It is obvious that the replacement of an organic dyewith a solid-state one makeS a laser more convenient tO use. Semiconductor materialsare attractive for saturable absorber because Of the large optical nonlinearities that can beobtained, particularly in quantum--well .t..t..…     

Laser-diode-pumped Passively Q-switched Nd:Sr5(VO4)3F Laser with Cr4+: YAG Saturable Absorber

Cr4+:YAG is a new saturable absorber for passive Q-switching. As a passive Q-switcher, it has several excellent properties, such as low saturation fluence, high damage threshold, good thermal conductivity, no degradation and so on. By using a laser-diode as pumping source and Cr4+ :YAG as passive Q switcher, the passive Q-switching run in Nd: Sr5(VO4)3F laser at 1. 065 μm is realized. The average output power, the single pulse energy, the pulse width and the repetition rate for different small-signal transmission of Cr4+:YAG and different pumping power were measured. Meanwhile, the coupling rate equations for Cr4+:YAG as passive Q-switcher were given and the experimental results agreed with the numerical solution of equations.     

595 nm激光抽运双钨酸钇钠晶体激光特性研究

利用脉冲调Q染料激光对掺钕双钨酸钇钠晶体（Nd:NYW)的短波长吸收带（595nm)进行抽运,实现了1．064μm激光运转,在抽运能量24．2mJ时,获得的激光输出能量为1．08mJ,阈值抽运能量小于5mJ。     

Nd∶KY(WO4)2和Nd∶KG(WO4)2晶体吸收光谱性能分析

通过研究分析钨酸盐晶体Nd∶KY(WO₄)₂和Nd∶KG(WO₄)₂在室温下的吸收光谱，发现这2种晶体具有作为激光晶体的优良特性。根据Judd-Ofelt理论和测试所得的吸收光谱及数据，用VC++编程计算出晶体的谱线强度、振子强度、吸收截面等，拟合得Nd³⁺离子的3个晶场调节参数Ω_λ(λ=2，4，6)的值，并从理论上计算了自发跃迁几率、能级寿命、荧光分支比和积分发射截面。从计算得出的荧光分支比β可以看出，Nd∶KY(WO₄)₂(β_1060nm=0.4380)和Nd∶KG(WO₄)₂(β_1060nm=0.4618)晶体荧光分支比都较大，计算了该晶体的X=Ω₄/Ω₆，并将其X值与其他晶体的X值加以比较，Nd∶KY(WO₄)₂和Nd∶KG(WO₄)₂均易于实现1.06μm激光输出，适合作为LD泵浦的钨酸盐晶体激光器。     

Efficient Lasing Demonstration of a New Crystal Nd: Sr_5 (PO_4)_3F

Ｅｆｆｉｃｉｅｎｔ　Ｌａｓｉｎｇ　Ｄｅｍｏｎｓｔｒａｔｉｏｎ　ｏｆ　ａ　Ｎｅｗ　Ｃｒｙｓｔａｌ　Ｎｄ：Ｓｒ_５（ＰＯ_４）_３ＦＥｆｆｉｃｉｅｎｔＬａｓｉｎｇＤｅｍｏｎｓｔｒａｔｉｏｎｏｆａＮｅｗＣｒｙｓｔａｌＮｄ：Ｓｒ_５（ＰＯ_４）_３Ｆ￥ＺＨＡＯＳｈ...     

Growth of high quality Ce~(3 ):YAP and (Ce~(3 ) Nd~(3 )): YAP single crystals

The effect of melt pretreatment of Ce~(3 ): YAP and (Ce~(3 ) Nd~(3 )): YAP and their growth ambient gases on the quality of the crystals are described. Firstly, a superheating pretreatment of YAP melt is adopted in a nitrogen atmosphere containing a little oxygen to eliminate carbon; then the YAP melt is superheated in a reduction atmosphere to fully reduce Ce~(4 ) ions into Ce~(3 ) ions in the melt. Finally, in a growth atmosphere of pure nitrogen, high quality Ce~(3 ): YAP and (Ce~(3 ) Nd~(3 )): YAP single crystals with high Ce~(3 ) concentration with only few light scattering centers were grown.     

Amplification of spontaneous emission in Nd~(3 )-doped fiber pumped by Ti: Al_2O_3 tunable laser

Amplification of spontaneous emission(ASE) in 4m Nd~(3 )-doped fiber pumped by Ti : Al~2O_3 tunable laser is studied theoretically and experimentally. The output of 2.64mW from ASE source pumped at 833 nm is obtained and the experimental results of ASE source are compared with that of Nd~(3 )-doped fiber ring laser.     

Nd: Sr5 (PO4) 3F Crystal Laser Characteristics Using GaAs as Passive Q-switch

It is investigated the properties of a diode-pumped Nd: Sr5 ( PO4 )3F laser that is passively Q-switched by a thin, single crystal GaAs wafer. The short high-peak-power pulses of the laser have been obtained. The pulse energies, pulse widths and pulse repetition rates for different conditions have been measured and the experimental results show that GaAs is an excellent passive Q-switch of the diode-pumped Nd: Sr5(PO4)3F lasers.     

ICP—AES法测定钒酸钇钕晶体中Nd,V和Y

本文用硫酸溶解样品，无需加内标元素，可以同时测定钒酸钇钕酸晶体中Ｎｄ，Ｖ和Ｙ含量，并取得满意结果，主含量Ｖ，Ｙ回收率为９９．５％－１００．６％，Ｎｄ回收率为９８．７％－１０２．４％相对标准偏差均小于１％。