Three-level phase modulator based on orthoconic antiferroelectric liquid crystals

Surface-stabilized orthoconic antiferroelectric liquid crystals (OAFLCs) have a director tilt of theta = 45 degrees and are, with no field applied, negatively uniaxial with the optic axis perpendicular to the cell substrates. We demonstrate that OAFLCs can be utilized to achieve lossless phase modulation with three almost equidistant phase levels. This turns out to be true also for polymer-stabilized OAFLCs, where the polymer network increases the switching speed of the device without affecting the phase modulation appreciably.     

Influence of a helical pitch on orthoconic antiferroelectric liquid crystals performance

Orthoconic antiferroelectric liquid crystals, whose half cone angle is 45°, are of interest in display technology because they are capable of providing greyscale in passively addressing waveform while exhibiting very good contrast. However, orthoconic antiferroelectrics having short pitch are difficult to be aligned, this makes surface stabilized alignment unfeasible. In this case, dynamic behaviour is usually poor, avoiding electronic addressing with standard electronics. In this work, we report the helical pitch measurements of OAFLC mixtures and we compare electrooptical performance of high and low pitch OAFLCs.     

Response times for a storage electrooptic effect in liquid crystals

By the optical storage effect in large pitch cholesterics, a relation of the type t_W (U_W-U_th)^-2 is established between the writing time t_W and the writing voltage U_W, revealing the existence of a threshold voltage U_th. Interpretations are given for the different erasure times observed at two selected scattering angles.     

Effect of fluorine groups and different terminal chains on the electro-isomerization of azobenzene liquid crystals

A series of azobenzene liquid crystals with one or two terminal acrylate groups were synthesized and their polymers were fabricated.The azobenzene liquid crystals and their polymers achieved the photoisomerization from the liquid crystalline trans-isomer to the isotropic cis-isomer with UV irradiation.Then,the cis to trans isomerization induced by an electric field was studied,the time required for electro-isomerization was measured,the texture change and absorption variation from cis to trans form induced by the electric field were observed clearly,and the time required for electro-isomerization was much shorter than that for thermal relaxation.The influence of the polar group(fluorine),terminal acrylate group,and flexible alkyl chain on the time of electro-isomerization was studied.The results show that the compounds with polar fluorine group require shorter time for electro-isomerization and the polymerization of terminal acrylate group delays the electro-isomerization.     

Synthesis and properties of high tilted antiferroelectric esters with partially fluorinated alkoxyalkoxy terminal chains

Novel chiral esters with partially fluorinated alkoxyalkoxy terminal chains are described. Their phase transition temperatures, enthalpies, and electrooptical properties are reported. A helical pitch in pure compounds and their mixtures based on selective reflection of light is also characterized.     

Investigation of electrooptic modulation from organic-inorganic crystals

Received: 28 September 1998     

Modifying electrooptics of orthoconic antiferroelectric liquid crystal cells by manufacturing procedures

Orthoconic antiferroelectric liquid crystals (AFLCs) having 45° tilt angle have been proposed to overcome the problem of reduced contrast usually exhibited by regular antiferroelectric displays. However, the pitch of the helix induced by chirality is customarily short in existing orthoconic materials, making it difficult to achieve surface stabilized configurations when the material’s pitch is smaller than the cell thickness. In this work, the influence of different manufacturing procedures on the electrooptical behaviour of orthoconic AFLCs is studied. Using the same orthoconic AFLC mixture, aligning surfaces and manufacturing protocol, we have observed two dissimilar responses, true orthoconic behaviour, and orthoconic V-shape response. The electrooptical response depends ultimately on the rubbing strategy adopted in either case.     

Dielectric and electrooptic properties of ADP crystals doped with chromate ions

The presence of impurity ions in ADP crystals grown in aquous solutions containing 5–10% (NH₄)₂ Cr₂O₇ causes a decrease of the dielectric constant ?₁₁ and ?₃₃ and an asymmetry of the electrooptical coefficient r₆₃. This assymmetry is equivalent to an effective small rotation of the axis.     

Dielectric measurements of new antiferroelectric liquid crystals

Three new pure antiferroelectric materials, synthesized at the Military University of Technology (MUT), were investigated by dielectric means. Clear relaxation modes were detected, i.e., Soft, Goldstone, low frequency in-phase (P_L) as well high frequency anti-phase (P_H) modes for paraelectric Sm A*phase, ferroelectric Sm C* phase and antiferroelectric Sm C_A* phase, respectively. Additionally, a high relaxation mode in Sm C_A* was found. The relaxation frequencies f_R of the observed modes were calculated from Cole-Cole diagrams.     

Study of optical parameters of two fluorinated isothiocyanato nematic liquid crystals exhibiting high birefringence

Optical studies have been carried out on two fluorinated isothiocyanato nematic liquid crystal (LC) compounds 4′-butylcyclohexyl-3, 5-difluoro-4-isothiocyanatobiphenyl and 4′-pentylcyclohexyl-3, 5-difluoro-4-isothiocynatobiphenyl. Transition temperatures of the two samples were confirmed using a polarizing microscope. The two LC compounds were found to exhibit fairly high clearing temperatures. Measurements of refractive indices of the two compounds were done by using thin prism method with He-Ne laser beam of wavelength 630 nm. Birefringence of the two LC compounds was calculated from the measured refractive indices. Both the compounds are found to display fairly high values of birefringence. Validation of a modified four-parameter model, based on Vuks equation describing the temperature dependence of refractive indices of the two liquid crystals, is also presented in this paper. The model is validated by fitting the experimentally measured values of refractive indices, birefringence and average refractive indices of the two nematic LCs with the theoretical values. In this paper, the calculation of order parameters of the LCs is presented by using two methods: direct extrapolation method based solely on the birefringence data and by using modified Vuks method based on Haller’s extrapolation. As observed from the obtained results, this procedure of calculating order parameter gives very reasonable results.     

Temperature dependence of ratio between dielectric anisotropy and order parameter in fluorinated nematic liquid crystals

Temperature dependence of ratio between dielectric anisotropy and order parameter of fluorinated nematic liquid crystal is investigated by using a semi-empirical molecular orbital package that can accurately calculate an angle between molecular dipole moment and long axis. We optimize the molecular conformations with three semi-empirical Hamiltonians AM1, PM3 and PM5, and then make a comparison between computational results and experimental measurements. It is shown that the results obtained from AM1 method are in good agreement with the measurements. The present study offers an applicable method to predict the dielectric properties of liquid crystal material.     

Temperature dependence of ratio between dielectric anisotropy and order parameter in fluorinated nematic liquid crystals

Temperature dependence of ratio between dielectric anisotropy and order parameter of fluorinated nematic liquid crystal is investigated by using a semi-empirical molecular orbital package that can accurately calculate an angle between molecular dipole moment and long axis. We optimize the molecular conformations with three semi-empirical Hamiltonians AM1, PM3 and PM5, and then make a comparison between computational results and experimental measurements. It is shown that the results obtained from AM1 method are in good agreement with the measurements. The present study offers an applicable method to predict the dielectric properties of liquid crystal material.     

Studies of errors in measurements of electrooptic coefficients in uniaxial crystals

The Jones calculus extended for optical waves that diverge and are modulated in electrooptic uniaxial crystals is applied to quadratic electrooptic coefficients. It is shown that in measurements of the coefficients the approach may be used to predict experimental errors that result from inaccuracies in the crystal cutting and alignment. The cases of static and sinusoidal modulating fields are considered.     

Electro-optical properties and(E,F) phase diagram of fluorinated chiral smectic liquid crystals

Fluorinated smectic liquid crystals each with a biphenyl benzoate rigid core are investigated. Molecular structures of the studied compounds have difference only in fluorine position and the length of the carbon chain. Dielectric relaxation study and electro-optical measurements are carried out with the classical SSFLC geometry. The field-induced phase transitions are studied and the(E,T) phase diagram is established.     

Electrical tuning of photonic crystals infilled with liquid crystals

In this paper we perform a complete study of electrical tuning in liquid crystal-infilled two-dimensional (2D) photonic crystals (PCs). The nematic liquid crystal (NLC) is characterized by a full range of bulk and surface elastic parameters. An essentially DC tuning field is applied in the axial direction. By minimizing the total (elastic plus electromagnetic) free energy, the configuration of the NLC directors, as a function of radial distance, is obtained. Three possible configurations are considered: escaped radial, planar radial, and axial. It is found that, in general, the escaped radial configuration is the preferred one. However, for sufficiently large applied fields, a phase transition occurs to the axial configuration. For example, in the case of the NLC 5CB, this transition is realized at about 14 V/μm provided that the cylinder radius is greater than about 50 nm. The configuration of the NLC directors determines the dielectric tensor as function of radial distance and this, in turn, leads to the eigenvalue equation for the PC. We present two such equations: one exact and the other approximate. The exact eigenvalue equation is based on the full anisotropy of the dielectric tensor and does not result in the usual separation of normal modes in a 2D PC. The approximate eigenvalue equation is derived from the average (over the cylinder cross-section) dielectric tensor and leads to modes that are polarized in the directions either parallel (E-mode) or perpendicular (H-mode) to the cylinders. Our calculations of the photonic band structure, by both methods, show that the approximate calculation works very well for the 5CB NLC cylinders in a silicon oxide (silica) host. This allows us to introduce the terminology quasi-E and quasi-H polarizations. We show how the partial photonic band gap in the [1 0 0] direction for these polarizations can be tuned and even completely closed. This behavior could be applied to the design of versatile, tunable polarization filters.     

A new method for characterizing ultrafast resonant-tunnelling diodes with electrooptic sampling

A new electrooptic sampling technique for characterizing ultrafast resonant-tunnelling diodes (RTD) is presented, in which the RTD is driven by the output of the photodiode irradiated by the same laser pulse that probes the output of the RTD. This method features a high time resolution, moderate slew rate and low heat load, which are the keys to characterizing RTD switching time. From the investigation of several factors, such as laser pulse width, interaction time between the probe pulse and electrical signal, and triggering jitter, the overall time resolution was found to be less than 1 ps. The measured switching times for In_0.53Ga_0.47As/AIAs RTDs were compared with the resistance-capacitance time constant for each device, and this confirmed that this driving method accurately measured RTD switching time at the order of 1 ps.     

Optimized Mueller polarimeter with liquid crystals

We demonstrate a Mueller polarimeter in which the polarization-state generator and analyzer are both composed of a linear polarizer and two liquid-crystal variable retarders. The polarimeter is designed to optimize the accuracy of the final results by minimization of the condition numbers of the modulation and analysis matrices. The polarimeter calibration, a difficult task by conventional procedures, is achieved easily by use of the eigenvalue method of Compain et al. [Appl. Opt. 38, 3490 (1999)]. The overall polarimeter performance is tested with a linear polarizer at various angles and a compensator at various retardations.     

A Monte Carlo simulation study of associated liquid crystals

We have performed a Monte Carlo simulation study of a system of ellipsoidal particles with donor—acceptor sites modelling complementary hydrogen-bonding groups in real molecules. We have considered elongated Gay—Berne particles with terminal interaction sites allowing particles to associate and form dimers. The changes in the phase transitions and in the molecular organization and the interplay between orientational ordering and dimer formation are discussed. Particle flip and dimer moves have been used to increase the convergency rate of the Monte Carlo (MC) Markov chain.     

A study on polymorphism of hydrogen-bonded thermotropic liquid crystals

A novel mesogenic homologous series comprising of eight hydrogen-bonded liquid crystalline complexes are isolated and analyzed by forming a hydrogen bond between p-n alkyloxy benzoic acids (where n represent alkyloxy carbon number which varies from 5 to 12) and mesaconic acid, respectively. Eight synthesized complexes are subjected to Fourier transform infra-red spectroscopy, polarizing optical microscopy and differential scanning calorimetry studies to meet the basic characterization. The variation of optical tilt angle with respect to temperature in various conventional and smectic X phases are investigated and analyzed. A phase diagram is constructed to elucidate the mesogenic behavior of novel liquid crystalline series. The Cox ratio that reveals the order of various mesophases and the stability factor, to invoke the thermal stability of mesophases, is studied under the results of DSC thermogram.