Role of Activator and Vacancy Centers in the Decay of the Gamma Scintillators of CsI–Na Crystals

The influence of the concentration of an activator (C _NaI) and of plastic deformation on a change in the contribution of a slow component to the decay of the -scintillations of CsI–Na crystals was investigated, as well as the influence of C _NaI on a change in the shape of the luminescence excitation spectrum in the region of absorption of activator centers (AC) and of vacancy-related centers (VRC) and also on a change in the intercenter time of deexcitation of the centers indicated. It is shown that AC and VRC participate in the photoluminescence and -scintillations of CsI–Na crystals. In the -scintillations, AC are responsible for the component ₁ = 370 nsec, whereas the components ₁ = 460 nsec and ₂ 2 sec are associated with VRC. The reduction of ₁ from 770 to 560 nsec with an increase in C _NaI from 2·10^–3 to 3·10^–2 mole% and from 570 to 470 nsec after plastic deformation of the crystals ( = 5%) along the 111 axis is caused by a decrease in the number of VRC. The mechanisms underlying the -scintillations of the CaI–Na crystals containing AC and VRC and also the decrease in the number of VRC are discussed.     

An investigation of finite-size scaling for systems with long-range interaction: The spherical model

A method is suggested for the derivation of finite-size corrections in the thermodynamic functions of systems with pair interaction potential decaying at large distancesr asr ^{–d –} , whered is the space dimensionality and>0. It allows for a unified treatment of short-range (=2) and long-range (<2) interaction. The asymptotic analysis is illustrated by the mean spherical model of general geometryL ^d–d× ^d subject to periodic boundary conditions. The Fisher-Privman equation of state is generalized to arbitrary real values ofd, 0d. It is shown that the-expansion may be used to study the breakdown of standard finite-size scaling at the borderline dimensionalities.     

Statistical mechanics of polymer networks of any topology

The statistical mechanics is considered of any polymer network with a prescribed topology, in dimensiond, which was introduced previously. The basic direct renormalization theory of the associated continuum model is established. It has a very simple multiplicative structure in terms of the partition functions of the star polymers constituting the vertices of the network. A calculation is made toO(²), whered=4–, of the basic critical dimensions _L associated with anyL-leg vertex (L1). From this infinite series of critical exponents, any topology-dependent critical exponent can be derived. This is applied to the configuration exponent _G of any networkG toO(²), includingL-leg star polymers. The infinite sets of contact critical exponents between multiple points of polymers or between the cores of several star polymers are also deduced. As a particular case, the three exponents ₀, ₁, ₂ calculated by des Cloizeaux by field-theoretic methods are recovered. The limiting exact logarithmic laws are derived at the upper critical dimensiond=4. The results are generalized to the series of topological exponents of polymer networks near a surface and of tricritical polymers at the-point. Intersection properties of networks of random walks can be studied similarly. The above factorization theory of the partition function of any polymer network over its constitutingL-vertices also applies to two dimensions, where it can be related to conformal invariance. The basic critical exponents _L and thus any topological polymer exponents are then exactly known. Principal results published elsewhere are recalled.     

Direction-direction correlations of oriented polymers

We calculate the direction-direction correlations between the tangent vectors of an oriented self-avoiding walk (SAW). LetJ (x) andJ ^v (0) be components of unit-length tangent vectors of an oriented SAW, at the spatial pointsx and 0, respectively. Then for distances |x| much less than the average distance between the endpoints of the walk, the correlation function ofJ (x) withJ ^v (0) has, ind dimensions, the form . The dimensionless amplitudek(d) is universal, and can be calculated exactly in two dimensions by using Coulomb gas techniques, where it is found to bek(2)=12/25 ². In three dimensions, the -expansion to second order in together with the exact value ofk(2)in two dimensions allows the estimatek(3)=0.0178±0.0005. In dimensionsd4, the universal amplitudek(d) of the direction-direction correlation functions of an oriented SAW is the same as the universal amplitude of the direction-direction correlation functions of an oriented random walk, and is given byk(d)= ²(d/2)/(d–2) ^d .     

Photophysical Behavior of β-Carboline-3-Carboxylic Acid N-Methylamide

The solvent and temperature effect of fluorescence and phosphorescence and its polarization characteristics for -carboline-3-carboxylic acid N-methylamide were studied. From the results obtained it is concluded that the first excited singlet state changes from the * type in a polar solvent (EPA) to the n* type in a nonpolar solvent (MC) and that the lowest singlet excited states (* type and n* type) interact by vibronic coupling. In the nonpolar solvent (MC) the lowest singlet excited states are very close in energy and consequently the vibronic coupling is stronger. It has been found that the 0–0 band of the phosphorescence emission in EPA is polarized out of plane, using the excitations corresponding to absorptions into the first and second excited * singlet states. This fact and the order of lifetime measured indicate an emitting triplet that is *. The origin of this polarization is very likely mixing as a result of spin–orbit coupling. However, the vibrational structures and changing polarization outside the 0–0 band indicate that second-order effects involving spin–orbit coupling and vibronic interactions are important and the mixing scheme appears to be and . The proximity effect can qualitatively explain the absence of phosphorescence and the stronger vibronic interaction between the n* and the * states of -carboline-3-carboxylic acid .N-methylamide in a hydrocarbon solvent (MC).     

Collective structures of the <Superscript>131</Superscript>Cs nucleus

The collective structures of ¹³¹Cs have been investigated by in-beam -ray spectroscopic techniques following the ¹²⁴Sn (^11B , 4n) reaction at a beam energy E_lab = 57MeV. The previously established rotational bands, built on g_7/2, d_5/2 and the unique-parity h_11/2 orbitals, have been extended and evolve into new bands involving rotationally aligned (h_11/2)² and (h_11/2)² quasiparticles. In addition, a new multiquasiparticle band based on the g_7/2 g_7/2 h_11/2 configuration has also been observed. Theoretical interpretations for the assigned configurations are discussed in the framework of Total Routhian Surface (TRS) and Tilted Axis Cranking (TAC) model calculations. TAC model calculations predict a decrease in the B(M1) values with increasing rotational frequency for the g_7/2/d_5/2 (h_11/2)² and h_11/2 (h_11/2)² bands, thus indicating a magnetic rotation character for these bands.     

Manifestation of Extracoordination in the Resonance Raman Spectra of Water‐Soluble Cation Co‐Porphyrins

Resonance Raman spectra (RRS) of Co(II) and Co(III)5,10,15,20tetrakis(4Nmethylpyridinium)porphyrin ((Co^II(TmpyP4), and Co^III(TMPyP4)) in aqueous solutions at different pH as well as in organic solvents (methanol, ethanol, DMSO, DMF) are obtained. The increased sensitivity of the oscillation frequencies ₂, ₄, ₈, and ₆ — the markers of the oxidation state of a metal — to the nature of an axial ligand has been revealed. For Co^III(TmpyP4), the shifts of the indicated frequencies in extracoordination have turned out to be twofold larger than those for Co^II(TmpyP4). The spectral effects observed are related to different electron influence of the extraligands on the system of the porphyrin ring. In the case of Co(III)porphyrin, interaction of the d orbitals of the metal and the e _g ^*orbitals of the macrocycle is more efficient since its ionic radius is smaller than for the Co(II)complex. For Co^III(TmpyP4), a linear correlation between the oscillation frequencies ₂, ₄, ₈, and ₆ and the experimental Gutmann parameters characterizing the electronacceptor properties of solvents is found.     

Intrinsical Randomness of Kolmogorov ℤd-Actions on a Lebesgue Space

We introduce a concept of an intrinsically weak and strong randomness of a ^d -action on a Lebesgue space and we show that Kolmogorov ^d -actions are intrinsically weak random, and Bernoulli ^d -actions are intrinsically strong random.     

Measurements of 110Xe and 106Te decay half-lives

The -decays of ¹¹⁰Xe and ¹⁰⁶Te were studied at the GSI on-line mass separator. By using the grow-in and decay of the activity, observed in pulsed-beam measurement, the half-life of ¹¹⁰Xe was found to be T_1/2 = 105⁺³⁵_-25ms. The lifetime of ¹⁰⁶Te was determined to be T_1/2 = 70⁺²⁰_-10s by measuring the time between two successive ¹¹⁰Xe ^{106} Te ^{102} Sn -decays. The newly determined half-lives were used to calculate reduced -decay widths for ¹⁰⁶Te and ¹¹⁰Xe. Universal systematics of reduced widths are proposed to search for the evidence of enhancement of the formation amplitude in the emitters above ¹⁰⁰Sn.     

The slow passage through a steady bifurcation: Delay and memory effects

We consider the following problem as a model for the slow passage through a steady bifurcation: dy/dt = (t) y – y³ +, where is a slowly increasing function oft given by= _i + t ( ⁱ,<0). Both and are small parameters. This problem is motivated by laser experiments as well as theoretical studies of laser problems. In addition, this equation is a typical amplitude equation for imperfect steady bifurcations with cubic nonlinearities. When=0, we have found that=0 is not the point where the bifurcation transition is observed. This transition appears at a value = ^j > 0. We call ^j the delay of the bifurcation transition. We study this delay as a function of ⁱ, the initial position of, and, the imperfection parameter. To this end, we propose an asymptotic study of this equation as 0, small but fixed. Our main objective is to describe this delay in terms of the relative magnitude of and. Since time-dependent imperfections are always present in experiments, we analyze in the second part of the paper the effect of a small-amplitude but time-periodic imperfection given by (t) = cos(t).     

Photometric and fluorimetric study of the acid-base behavior of 2,2′-diquinolyl and 2,2′,2″-terpyridyl

A photometric and fluorimetric study of the acid-base behavior of 2,2-diquinolyl and 2,2,2-terpyridyl was performed. In sulfuric acid medium, the doubly charged 2,2-diquinolynium ion undergoes the first dissociation atH ₀=0.20±0.09, as determined by fluorimetry (_ex=336 nm, _em=424 nm). Photometric titration is less accurate because of the overlapping of the absorption spectra. The second dissociation constant of 2,2-diquinolyl was determined by fluorimetric titration (_ex=336 nm, _em=420 nm), obtaining a value of 3.67±0.03. The triply charged 2,2,2-terpyridyl molecule was found to undergo the first dissociation atH ₀=–7.17±0.04, as determined by fluorimetric titration (_ex=316 nm, _em=350 nm), in aqueous sulfuric acid medium. Photometric titration (=335 nm) was performed in the presence of 6.5% ethanol because of the low solubility of the compound in water. In this ethanolicwater medium, a value of the dissociation constant atH ₀=–7.39±0.03 was calculated. The second dissociation constant was determined to be 2.81±0.12 by photometric titration at 285 nm, and values of 4.03±0.26 and 4.16±0.20 were found for the third dissociation constant by photometric titrations at 320 and 295 nm, in 10% ethanol, in close agreement with previously reported values. The fluorimetric titration profile obtained by exciting at 274 nm and measuring the fluorescence emission at 350 nm, in the zone betweenH ₀=–3 and pH=10, is complicated by the several equilibria involved.     

Bounded perturbations of dynamics

If and are one-parameter automorphism groups of a von Neumann algebraM is said to be a bounded perturbation of if _t – _t 0 ast0. We give a complete characterization of the bounded perturbations of . In particular, we show that if can be implemented by a strongly continuous one-parameter group with self-adjoint generator (Hamiltonian)H, then can be implemented in the same way and the corresponding HamiltonianH can be chosen to be of the formH=VHV ^–1+h, whereV is a unitary ofM andh=h*M.On leave of absence from II. Institut für Theoretische Physik, Universität Hamburg, D-2000 Hamburg 50, Federal Republic of Germany     

Far-infrared laser stark spectroscopy of CH3OH and13CH3OH

The high resolution laser Stark spectra of methanol and¹³C-substituted methanol have been studied up to Stark fields of about 60 000V/cm with the HCN and DCN lasers. Numerous families of absorption lines have been observed in both parallel and perpendicular polarizations. For methanol, the transitions J _k =7₅ 6₄ A, _t=0; J _k =11₄ 10₃ E _l , _t=0; and J _k =17₃ 16₂ E₂, _t=0 have been identified while the assignments for¹³C-substituted methanol are J _k =14₈ 15₇ A, _t=0; J _k =15₃ 14₂ A⁺, _t=0; J _k =10₇ 9₆ A, _t=0; and J _k =27₉ 27₈ E₁, _t=0. Zero-field frequencies for the assigned transitions are given with improved accuracy over those calculated from available molecular constants, especially for¹³CH₃OH.     

Singular Perturbations of Self-Adjoint Operators

Singular finite rank perturbations of an unbounded self-adjoint operator A ₀ in a Hilbert space ₀ are defined formally as A ₍₎=A ₀+GG ^*, where G is an injective linear mapping from = ^d to the scale space _-k(A₀)k , kN, of generalized elements associated with the self-adjoint operator A ₀, and where is a self-adjoint operator in . The cases k=1 and k=2 have been studied extensively in the literature with applications to problems involving point interactions or zero range potentials. The scalar case with k=2n>1 has been considered recently by various authors from a mathematical point of view. In this paper, singular finite rank perturbations A ₍₎ in the general setting ran G – _k (A ₀), kN, are studied by means of a recent operator model induced by a class of matrix polynomials. As an application, singular perturbations of the Dirac operator are considered.     

Characters of Finite-Dimensional Irreducible q(n) -Modules

The solution of the Kac character problem for thequeer series of Lie superalgebras q(n) is announced. An explicit algorithm which computes the character of an arbitrary finite-dimensional irreducible q(n)-module is presented. As an illustration, the correction terms to the generic character formula of Penkov (Monatsh. Math.118 (1994), 419) are written down for all finite-dimensional irreducible representations of q(n), for n4, with nongeneric character.     

A GaAs–InGaAs optoelectronic switch with multiple operation states

An optoelectronic switch with both n- and p-type delta-doped (-doped) quantum wells was investigated. The -doped structures formed potential wells for the carrier accumulation and potential barriers for the carrier injection. Being possessed of -doped sheets with different doping levels, the potential barriers were sequentially collapsed to produce a double negative-differential-resistance (NDR) phenomenon in the current–voltage (I–V) characteristics of the device, due to the carrier accumulation in the potential wells. The device also showed an optical function related to the barrier heights controllable by incident light.     

The correlation function in Wilson's theory of phase transitions: Above and below the transition

The correlation function and the correlation length are discussed in the theoretical framework of the Wilson-Feynman diagram expansion for small =4–d. It is shown explicitly that to order ² the scaling relation = (2–) is satisfied and that the correlation function is a homogeneous function ofk and . The explicit form of the scaled correlation function is exhibited.     

Investigation of Rust Formed on Steel Surfaces and Related Oxyhydroxides

In order to indentity the corrosion products formed on steel surfaces from ⁵⁷Fe Mössbauer spectroscopy, detailed Mössbauer parameters have been determined for various kinds of iron-oxyhydroxides: -FeOOH, -FeOOH, -FeOOH and -FeOOH. ⁵⁷Fe Mössbauer measurements of the iron oxyhydroxides indicate the following results. Fe occupies a single site in -FeOOH, but below the Néel temperature as at e.g., 300 K the Mössbauer spectrum is always broad, showing a distribution of the strength of the magnetic exchange interactions. Its shape depends on the grain-size and synthetic methods of the specimen. Fe occupies 3 sites in -FeOOH. High-purity reagents of -FeOOH always contain small amounts of -FeOOH and their Néel temperatures depend on the synthetic methods of the specimen. Mössbauer spectroscopy of the synthetic -FeOOH shows very broad distribution of the hyperfine magnetic fields.     

α-Particle Loss from Cylindrical Magnetized DT Plasma

-particles from fusion reactions in a DT magnetized plasma are confined inside the plasma not only by magnetic fields but also by induced electric fields which are due to the different mobilities of -particles and electrons. Criteria are derived for the -confinement in a cylindrical plasma, inertially confined by a heavy liner. It is observed that the suprathermal population in the DT plasma will influence the overall dynamics.     

Alpha-decay of neutron-deficient 200Fr and heavier neighbours

A new measurement of the ²⁰⁰Fr -decay half-life, with improved accuracy compared to previous measurements, has been carried out at the Isolde-CERN on-line mass separator. A half-life of 49(4) ms has been obtained, which is substantially different from earlier literature values. For the ¹⁹⁶At daughter decay, a half-life of 389(54) ms and an branching ratio b = 94(5)% were measured. In addition, the half-lives of ^{201, 203, 205}Fr and ^197,199At are reported.