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1.
CrystalStructuresofLn(NO_3)_3(Ln=La,Yb)Complexeswith12-crown-4MaoJiang-Gao;JinZhong-Sheng;YuFeng-Lan(LaboratoryofRareEarthChem... 相似文献
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SynthesisandCrystalStructureofNeodymiumComplex[Nd(C_6H_4OHCHNC_2H_4NCHC_6H_4OH)(NO_3)_3(CH_3SOCH_3)]ZHANGMin;KONGFan-Rong;ZHUHui-J... 相似文献
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ZHANG Quan-Zheng YU Ya-Qin CHEN Shu-Mei HE Xiang YANYing LIU Jiu-Hui CHEN Li-Juan XIA Chang-Kun XU Xin-Jiang WU Xiao-Yuan LU Can-Zhong② 《结构化学》2004,(11)
1 INTRODUCTION Polyoxometalates, a rich and remarkable classof inorganic cluster system[1], exhibit diverse appli-cation possibilities due to their topological and elec-tronic properties, ranging from their well-known roleas reagents in analytical, b… 相似文献
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SynthesisandCrystalStructureof[C_6H_5CH_2C_5H_4ErCl_2(THF)_3]·THFGaoFu-Xing;WeiGe-Cheng;JinZhong-Sheng;ChenWen-Qi(ChangchunInsti?.. 相似文献
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1 INTRODUCTION Great attention has currently been paid to com-pounds formed by the reaction between phosphineand metal alkynyl building blocks[1]. The ligand NP3contains one tertiary nitrogen atom as well as threephosphorous atoms and bonds to the metal ions as atetradentate ligand, affording tetrahedral[2] or triangle-bipyrimidal geometry[3, . In other coordination ca- 4]ses, one[5, , two[7], three P donors[8, 6] … 相似文献
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Ming Zhu Li‐Bei Zhang Ying‐Hua Chen Xi‐Geng Zhou Rui‐Fang Cai Lin‐Hong Weng 《中国化学》2004,22(9):935-940
Six new ethylthioethylcyclopentadienyl containing organolanthanide complexes CpLnCl [Ln=Gd (1), Dy (2)] and Cp2LnCpTh [Cp=C5H5, Ln=Yb (3), Sm (4), Dy (5), Y (6)] were synthesized by the reaction of ethylthioethyl‐cyclopentadienyl (CpTh) sodium salt with LnCl3 or Cp2LnCl in THF. Complexes 1–6 were characterized by elemental analyses, infrared and mass spectroscopies. The molecular structures of complexes 1–3 were also determined by the X‐ray single crystal diffraction. The results show that the side‐chain sulfur atom on the ethylthioethylcyclopentadienyl ring can form intramolecular chelating coordination to the central lanthanide ion, improving the stability of organolanthanide complexes and reducing the number of coordinated THF molecules. 相似文献
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合成了标题配合物Cd[CH3O(OH)C6H3CH =N(CH2 ) 2 OH]2 Br2 ,对其进行了元素分析、红外和X射线结构分析。该配合物单晶的分子式为 :CdC2 0 H2 6N2 O6Br2 ,Mr=662 .66属于单斜晶系 ,P2 1 /n空间群 ,晶胞参数a =7.851 2 (2 ) ,b =1 7.391 (3) ,c=1 7.575(4) ,β =90 .86(3)°,V =2 392 (1 ) 3,Z =4,Dc=1 .834g·cm- 3,μ(MoKα) =4.2 4 1 9mm- 1 ,F(0 0 0 ) =1 30 4。用直接法解得结构 .R =0 .0 74,Rw=0 .0 84.在 2 99± 1K的温度下收集到 3744个独立衍射点 ,其中 2 4 70个为可观察的衍射点 [I≥ 3σ(I) ]。同时在 1 .0 64μm的Nd :YAG激光器上对配合物进行了粉末SHG实验 ,并用MOPAC软件包采用PM 3方法解得其分子的微观二阶极化率为 3.341× 1 0 - 30 esu。进一步讨论了微观二阶非线性极化率、宏观激光倍频效应和分子结构、晶体结构之间的关系。 相似文献
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Two new nonmetal borates, [(C2H10N2)]2[B14O20(OH)6] 1 and [C8H22N4][B5O6(OH)4]2 2, have been synthesized under mild conditions and characterized by single-crystal X-ray diffraction, FTIR, elemental analysis and thermogravimetric analysis. Crystal data for compound 1: triclinic, space group P^-1, a = 8.4979(17), b = 8.8498(18), c = 10.065(2)A^°, α = 95.01(3), β = 96.99(3), γ = 116.82(3)°, V= 661.8(3)A^°^3, Z= 1, Mr = 697.63, Dc = 1.751 g/cm^3,μ = 0.163 mm^-1, F(000) = 356, the final R = 0.0372 and wR = 0.0968 (I 〉 2σ(I)); and those for compound 2: monoclinic, space group P21/c, a = 9.1867(18), b= 14.118(3), c = 10.334(2)A^°, β = 91.48(3)°, V = 1339.8(5)A^°^3, Z = 2, Mr = 610.46, Dc = 1.513 g/cm^3,μ = 0.135 mm^-1, F(000) = 632, the final R = 0.0350 and wR = 0.0912 (I 〉 2σ(I)). For both 1 and 2, the anionic units are interlinked via O-H…O hydrogen bonds to form a 3D supramolecular network, while the protonated cations are located in the free space of the inorganic borate framework and interact with the anions by electrostatic attraction and extensive N-H…O hydrogen bonds. 相似文献
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Synthesis and Characterization of Diorganotin Compounds {[R2Sn(ON =CHC6H5)]2O}2 and Crystal Structure of {[(C6H5CH2)2Sn(ON=CHC6H5)]2O}2 总被引:1,自引:0,他引:1
Introduction Dimeric tetraorganodistannoxanes are a kind of in-teresting organotin oxo clusters and have attracted con-siderable attention during the last several decades, in view of their unique structural features1-5 as well as their applications as biocides6,7 and in homogenous cataly-sis.8,9 In the solid state, they contain characteristic Sn4O2X2Y2 structural motifts with staircase or ladder arrangements, a planar four-membered Sn2O2 ring and, generally, penta-coordination around the tin… 相似文献
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X射线单晶衍射结果表明,三核镉配合物Cd3[CH3O(O)C6H3CH=NNHC(S)NH2]4·[CH3COO]2·1/2[CH3S(O)CH3]·2H2O为单斜晶系,空间群为C2/c,a=3.4214(4),b=1.1581(2),c=1.7932(5)nm,β=119.76(1)°,V=6.168nm3,Mr=1427.43,Z=4,Dc=1.54g/cm3,μ=12.48cm(-1),F(000)=2860,最后偏离因子R=0.066. 相似文献
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CrystalandMolecularStructuresof[Cu_2(OAc)_4(Ur)_2].2H_2Oand{[Cu(H_2Y)].Ur·H_2O}_n(Ur=urea;H_4Y=EDTA)¥ZhangHan-Hui;YeZhao;YangRong... 相似文献
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(C5H4SiMe2tBu)2LnnBu reacted with 1 equiv. of elemental sulfur in toluene at ambient temperature to yield the corresponding lanthanocene thiolates [(C5H4SiMe2tBu)2Ln(m-SnBu)]2 (Ln = Y (1), Er (2)). Complexes 1 and 2 have been characterized by elemental analysis, IR, mass spectros- copy and X-ray single-crystal diffraction analysis. Both complexes are of monoclinic with space group P21/c, formula C52H94S2Si4Y2 1 (C52H94S2Si4Er2 2) Mr = 1073.57 (1230.27), a = 8.495(2) (8.41(2)), b = 26.913(8) (26.67(7)), c = 13.756(4) (13.68(4)) (A), α = 90(90), β = 101.184(5) (101.57(4)), γ = 90 (90)°, V = 3085.1(15) (3007(14))(A)3, Dc = 1.156 (1.359) g·cm-3, Z = 2 (2), F(000) = 1144 (1260), μ = 2.046 (2.951) cm-1, R = 0.0687 (0.0749) and wR = 0.1306 (0.1507) for observed reflections with I > 2σ(I). X-ray structures of 1 and 2 definitively prove that only one sulfur atom is inserted into the Ln-C(nBu) bond, forming a thiolate ligand. 相似文献
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报道2,4-Br2C6H3OCH(CN3)CO2Sn(C6H11)2CU3(1)和2-OCH3-4-CH3CH=CHC6H3OCH2CO2Sn(C6H11)2CH3(H2O)(Ⅱ)的晶体结构和分子结构。(Ⅰ)单斜晶系,空间群P21/c,a=13.067(3),b=10.594(3),c=18.157(4),β=106.99(2)°,Z=4,Dc=1.672g/cm3,V=2403.73,μ=43.731cm-1,Mr=622.99,F(000)=1232;(Ⅱ)单斜晶系,空间群P21/n,a=10.409(1),b= 12.570(2),c=20.664(2),β=83.51(1)°,Z=4,Dc=1.281g/cm3,V=2686.4A3,μ=9.761cm-1,Mr=539.28,F(000)=1120.最后的偏离因子,化合物(Ⅰ)R=0.046,Rω=0.046;化合物(Ⅱ)R=0.049,Rω=0.047。晶体结构解析表明,化合物(Ⅰ)和(Ⅱ)中的锡均被配体的3个碳和2个氧原子配位,配位原子呈畸变三角双锥构型;化合物中的环己基均为椅式构象;化合物(Ⅱ)中,配位水分子和另一分子的羰基氧与芳环上的甲基氧? 相似文献
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中性均配型稀土胺化物Yb(NPh_2)_3(THF)_2的合成、表征及晶体结构 总被引:1,自引:0,他引:1
无水YbCl3与三倍量的LiNPh2 在四氢呋喃 (THF)中反应 ,合成了中性均配型稀土胺化物Yb(NPh2 ) 3(THF) 2 。产物经元素分析、红外光谱表征 ,并测定了其晶体结构。配合物属单斜晶系 ,P2 1 /n空间群 ,晶胞参数为a =1 2 0 5 2 ( 2 )nm ,b =1 9369( 3)nm ,c =1 65 2 3( 2 )nm ,β =92 79( 1)°,V =3 85 2 4( 9)nm3,Z =4,Dc=1 417g·cm- 3,μ =2 4 67cm- 1 (MoKα) ,F( 0 0 0 ) =1668,R =0 0 36,Rw=0 0 39。3个二苯胺基的氮原子和两个THF的氧原子与金属镱配位 ,形成五配位的扭曲的三角双锥几何构型。平均的Yb—N键长为 0 2 2 19( 6)nm。 相似文献
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1INTRODUCTIONAlthoughseveralhundredpolyhedralmetallaboraneshavebeencharacterized,theincidenceofruthenaboranesisparticularlysurprising.(hThefirstpolyhedralruthenaboraneisstructurallytypifiedbythecompound[(PPh,)2RuB,,HS(OEt),j,whichisobtainedin40%yieldsfromthereactionbetweentRuCI,(PPh,),jandcloso-tB,,H,,j'--inCHCI,/EtOH.tZiWithCH,COOH/THFt'iandC,H,COOH/CH,CI,">insteadofCHCI,/EtOH,twocompoundsF{(PPh,)2Ru}~(p-MeCO,)3--(pH)z-{RuB,,H,}jand[(PPh,)2(PhCOO)RuB,,HSCljhav… 相似文献
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1INTRODUCTIONThepseudoliquidcharacterofheteropolycompoundsascatalystisdeterminedbytheircrystallographicproperties"3.Thedeterminationofthecrystalstructureofhet-eropolycompoundhasbecomeanimportantmethodtocharacterizeandidentifythesecompounds,atthesametimeitalsoprovidesinterestinginformationtoenrichhet-eropolyacidandcatalyticchemistry.Inthispaper,wereportthesynthesisandcrys-talstructureof[(CH,).Nj.H,[ZnW,,SnO,,j.gH,O.2EXPERIMENTAL2.1SynthesisNa,WO..ZH,O(18.2g,55mmol)wasdissolvedin… 相似文献
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<正> (C6H5COCHCOC6H5)SmI2(THF)3,Mr= 843. 75,triclinic space group P1,a=13. 274(3),b=9. 886(3),c= 12. 526(4)A,a= 110. 89(3),B=93. 98(2),y=85. 16(2) ,V=1528. 9(8)A3,Z=2,Dc=1. 83g/cm3, (MoKa) = 0. 71069A,u= 40. 3cm-1,F(000) - 810. The structure was solved by Patterson and Fourier techniques and refined by least-squares method to a final conventional R value of 0.082(Rw= 0. 083). The central Sm(III) ion is coordinated by two iodine ions, two oxygen atoms from C6H5COCHCOC6H5 and three oxygen atoms from three THF molecules to form a distorted pentagonal bipyramid. The Sm-I distances are 3. 103 and 3. 092 A ,The Sm-O (O atom from C6H5COCHCOC6H5) distances are 2. 273 and 2. 307 A and the average Sm -O(THF) distance is 2. 500A. 相似文献
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SynthesisandCrystalStructureof[Lu(NO_3)_3(H_2O)_2(CH_3CN)](Benzo-15-C-5)·CH_3CNWangRui-Yao;JinZhong-Sheng;NiJia-Zuan(Laboratoryo... 相似文献
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(C5H4CH3)3Ho和(C5H4CH3)2Ho(C5H5)与5-苯基四唑(HN4CPh)在THF中反应,得到复合产物[(C5H4CH3)2HoN4CPh]2·[(C5H4CH3)(C5H5)HoN4CPh]2,该晶体属三斜晶系,P1空间群,晶胞参数为a=9.386(3),b=13.071(3),c=16.571(2)A,a=86.90(1),β=74.61(2),γ=77.30(2)°,V=1912.2(8)A3,Z=1,Dc=1.602g/cm3,Mr=922.61,μ=41.92cm-1,F(000)=896,最终偏离因子R=0.041,Rw=0.056.晶体数据显示,在同一个晶胞里有两个组成不同的分子,每一个分子都是具有对称中心的四唑基桥二聚体结构,其桥环单元-HoN3HoN3-是平面型的。每个钬原子分别被两个茂基和3个四唑基氮原子配位,形成1个边桥变形四面体构型。 相似文献