共查询到20条相似文献,搜索用时 31 毫秒
1.
ZHENG Ai-Xia LI Hong-Xi TANG Xiao-Yan LANG Jian-Ping 《结构化学》2009,28(9):1083-1086
In the presence of Et4NCl·H2O, reaction of AgCl with TabHPF6 in MeCN afforded the title complex {(Tab-Tab)[Ag2(μ-Cl)4]-2MeCN}n 1. 1 crystallizes in the orthorhombic space group Pbcn with a = 16.782(3), b = 6.8358(14), c = 26.194(5) A, V = 3004.9(10) A3, Z = 8,μ = 1.817 mm^-1, Dc = 1.711 g/cm3, T= 223 K, C1lH16AgCl2N2S, Mr= 387.10, F(000) = 1544, S= 1.160, R = 0.0528 and wR = 0.0896 for 2732 observed reflections with I 〉 2σ(I). 1 contains a 1D linear [Ag2Cl4]n^2n- chain coupled with the [Tab-Tab]2+ dications. Intermolecular hydrogen bonding interactions between the protons of methyl groups from the Tab-Tab dications and the chlorides result in the formation of a 2D hydrogen-bonded network. 相似文献
2.
The title compound(zifaxaban 2, C20H16ClN3O4 S, Mr = 429.87) was synthesized and its crystal structure was determined by single-crystal X-ray diffraction. Zifaxaban crystallizes in monoclinic, space group P21 with a = 5.7900(12), b = 13.086(3), c = 12.889(3) A, β = 100.86(3)°, V = 959.1(3) A3, Z = 2, Dc = 1.489 g/cm3, F(000) = 444, μ = 0.342 mm-1, the final R = 0.0320 and wR = 0.0640 for 2717 observed reflections(I 2σ(I)). The absolute configuration of the stereogenic center in the title compound was confirmed to be S by single-crystal X-ray diffraction. Four existing intermolecular hydrogen bonds help to stabilize the lattice and the molecule in the lattice to adopt an L-shape conformation. Zifaxaban was slightly more active than rivaroxaban 1 in in vitro assay against human FXa and therefore is promising as a drug candidate. 相似文献
3.
A new nickel(Ⅱ) complex, C34H38N8NiO4, has been prepared and characterized by X-ray diffraction analysis. It crystallizes in the monoclinic system, space group P21/c with a = 11.715(5), b = 12.328(5), c =11.113(5)A, β= 92.589(5)°, Z = 2, Dc = 1.411 g/cm^3,μ = 0.658 mml, the final R = 0.0427 and wR = 0.1099 for 2229 observed reflections with I 〉 2σ(I). The complex is a centrosymmetric plane in which nickel(Ⅱ) is coordinated in a regular octahedron to the ligand phenytoin through the nitrogen atoms of ethylenediamine, imine and amine. The complex was valued for its antimicrobial activity against bacterial strands using the agar diffusion method, and found to be active against the four test bacterial organisms. Preliminary screening for antimicrobial activities showed that the title complex is quite active against standard strains of Salmonella species, Staphylococcus aureus, Bacillus pumilus and Eschierichia coli. 相似文献
4.
ZHAO Xiao-Fan 《结构化学》2008,27(7):853-857
A novel end-to-end azido-bridged polynuclear Schiff-base copper(II) complex, [Cu(C12H15Br2N2O)(N3)]n, was prepared and characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. The crystal belongs to the orthorhombic system, space group Pbcn with a = 24.588(5), b = 10.377(2), c = 13.022(3) A, V= 3322.6(12) A^3, Z = 8, Dc = 1.874 g/cm^3, Mr = 468.65, λ(MoKa) = 0.71073 A,μ = 6.130 mm^-1, F(000) = 1832, R = 0.0637 and wR = 0.1176. The Cu atom in the complex is five-coordinated in a square pyramidal geometry by three donor atoms of the Schiff-base ligand, and two N atoms from two bridging azide ligands. The [2,4-dibromo-6-[(3-dimethylaminopropylimino)methyl]phenolato]copper(II) units are linked by the bridging azide ligands, giving zigzag polymeric chains with backbones of the [--Cu-N-N-N--Cu]n type running along the b axis. 相似文献
5.
The hydrothermal reaction of Cd(OAc)2.H2O with 1,2-benzenedicarboxylate (1,2-BDC), imidazole and H2O resulted in the formation of a binuclear polymeric Cd( Ⅱ ) complex {[Cd2(1,2-BDC)2(Im)4].(H2O)}n which was then characterized by elemental analyses and single-crystal X-ray diffraction analysis. The crystal is of monoclinic system, space group P21/c with a = 14.6455(3), b = 9.3530(2), c = 23.7838(5)A, β= 106.6290(10)°, Cl12H104CdgN32O36, Mr = 3373.47, V = 3121.64(11)A^3, Dc = 1.795 g/cm^3, F(000) = 1672,μ= 1.428 cm^-1 and Z = 1. The final R = 0.0316 and wR = 0.0687 for 5045 reflections with I 〉 2σ(I). In the title complex, the two Cd( Ⅱ) ions are in different coordination environments with distorted octahedral and pengonal bipyramidal geometries, respectively. Two Cd polyhedra are linked together through one μ2-η^1:η^1 and one μ2-η^1:η^1 carboxylate groups from different 1,2-BDC ligands, giving rise to a binuclear Cd( Ⅱ ) cluster, and such clusters are connected by bridged 1,2-BDC ligands to form a 2-D structure along the c axis. The inter- and intermolecular hydrogen bonds further connect the 2-D structures into a 3-D supramolecular network. 相似文献
6.
A new 4,5-diaryl-lH-imidazole was synthesized and characterized by 1H NMR, ESI-MS, elemental analysis and FT-IR. The crystal structure of the title compound (C19H16C12N202, Mr = 375.24) has been determined by single-crystal X-ray diffraction. Crystal parameters: mono- clinic system, space group P2/n, a = 14.349(3), b = 8.7918(18), c = 15.352(3) A, β = 108.56(3)°, V = 1836.1(6) A3, Z = 4, F(000) = 776, Dc = 1.357 g/cm3, p = 0.368 mm-1, the final R = 0.0502 and wR = 0.1066 for 2324 observed reflections with 1 〉 2 σ(/). A total of 16117 reflections were collected, of which 3615 were independent (Rint = 0.0595). The preliminary bioassay suggested that the title compound exhibits distinct effective inhibition on the proliferation of cancer cell lines. 相似文献
7.
The title compound 3-methyl-l-(4-methylphenyl)-4-(N-4-trifluoromethylphenyl) aminomethyl-5-(4-methoxyphenylthio)-lH-pyrazole has been synthesized via a four-step reaction and characterized by IR, 1H NMR, elemental analysis and X-ray crystallography. The compound crystallizes in monoclinic, space group P21/c with a = 8.7170(15), b = 18.355(3), c = 15.292(3) A, fl = 103.445(3)°, V= 2379.7(7) A3, Dc = 1.350 g/cm3, Z = 4, p = 0.184, F(000) = 1008, and the final R = 0.0491 and wR = 0.1339 for 4160 observed reflections (I 〉 2a(/)). The results demonstrate that there is a face-to-face π-π stacking interaction between one benzene ring (C(19)-C(24)) and another (C(I 3)-C(! 8)) at a plane-plane distance of 3.3539 A. The ring normal and vector between the ring centroids form an angle of 18.2° up to the centroid-to-centroid distance of 3.5273 A. The crystal structure is stabilized by the intermolecular hydrogen bond of N(3)-H(3A)...N(2) (symmetry code: A -x+l, -y+l, -z). The preliminary biological test shows that the title compound has a moderate antifungal activity. 相似文献
8.
DINGAi-Xiang JIAWen-Bin ZHANGGao-Bin PANJian-Ting ZHANGYu-Yang YANGJia-Xiang 《结构化学》2014,(8):1239-1244
Researches on a-cyanostilbene derivatives demonstrated them to be promising AIE or AIEE structural molecules and potential photoelectric materials. One novel a-cyanostilbene derivative, namely (E)-2-(4-butoxyphenyl)-3-(4-(diethylamino)phenyl)acrylonitrile (BPDPA), has been designed, synthesized and characterized. The crystalline structure of BPDPA has been studied in detail. The single-crystal X-ray diffraction revealed BPDPA crystallizes in triclinic space group Pi, with a = 12.860(5), b = 13.327(5), c = 15.016(5)А, a = 72.650(5), β = 66.969(5), Y = 62.897(5)°, Mr = 696.95, V= 2085.6(13) A3, Z = 2, Dc = 1.110 g/cm-3, p = 0.068 mm1, F(000) = 752, Rint = 0.0264, R(I〉 2σ(/)) = 0.0649, wR(l〉 2σ(/) = 0.1724, R(all data) = 0.1321, wR (all data) = 0.2158, completeness to theta = 25.00 is 99.4% and GOF = 1.067. Like most reported a-cyanostilbene derivatives, BPDPA possesses a somewhat twisted molecular structure. UV-Vis and FL measurements showed an obviously bathochromic effect of BPDPA with increasing the polarity of the solvents. 相似文献
9.
The title compound stachyose(C24H42O21),a biologicaly active tetrasaccharide,was characterized by X-ray diffraction analysis.It crystallizes in the orthorhombic system,space group P21212 with C24H42O21,a = 23.8760(3),b = 12.71028(12),c = 10.81279(11) ,V = 3281.36(6) 3,Z = 4,Dc = 1.511 g/cm3,Mr = 746.58,F(000) = 1576,and μ = 1.230 mm-1.The final R = 0.0666 and wR = 0.1797 for 6298 observed reflections(I 2σ(I)).The molecular crystal structure of stachyose shows absolute stereochemistry of β-D-fructofuranosyl α-D-galactopyranosyl-(1→6)-α-D-galactopyranosyl-(1→6)-α-D-glucopyranoside.The molecule is composed of two α-D-galactoses,one α-D-glucose,and one β-D-fructose and sequentially linked as α-Gal(1→6) α-Gal(1→6) α-Glc(1→2) β-Fru.The title compound is stacked into a 3D layer structure through hydrogen bonds.NMR spectra data are also assigned.In the crystal packing,X-ray analysis indicates that there are two intramolecular and eleven intermolecular hydrogen bonds in this compound. 相似文献
10.
A unique metal-organic framework [Cd2(L)1.5(μ3-OH)(H2 O)2 ]·2H2 O(1, H2 L = 2,5-dibenzoylterephthalic acid) has been synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffractions, elemental analyses, IR spectra and fluorescence spectrum. The compound is of triclinic system, space group P1, C33 H27 CdO14, Mr = 870.33, a = 12.2939(17), b = 12.5135(9), c = 13.2046(10), α = 115.3190(10), β = 96.9140(10), γ = 109.7950(10)°, V = 1641.6(3)3, Z = 2, Dc = 1.761 g/cm3, F(000) = 862, μ(MoK) = 1.366 mm-1, Rint = 0.0148, R = 0.0240 and wR = 0.0639 for 5995 observed reflections with I 2σ(I). X-ray analysis shows that the title complex exhibits a 3D framework with(412·63) topology, in which the tetra-nuclear [Cd4(μ3-OH)2 ] clusters act as 6-connected nodes, and the L ligands can be simplified to be linear connectors. Moreover, the thermal stability and fluorescence have been studied in detail. 相似文献
11.
The Schiff base organotin(IV) complex {[4-Et2NC6H3(O)C=NC6H3(O)-5-NO2](nBu2Sn)}2 has been synthesized via the reaction between 4-(diethylamino) salicylaldehyde-2-amino-4-nitrophenol Schiff base(H2L) and dibutyltin oxide. Complex C1 has been characterized by IR, 1H NMR, 13 C NMR spectra, and elemental analysis, and its crystal structure was determined by X-ray diffraction. It crystallizes in the monoclinic system, space group P21/n with a = 15.6559(8), b = 9.1657(5), c = 18.8351(10) , β = 107.3440(10)°, Z = 4, V = 2579.9(2) 3, Dc = 1.442 Mg·m-3, μ(MoKα) = 1.025 mm-1, F(000) = 1152, R = 0.0250 and wR = 0.0633. The central Sn atom is coordinated in a hexadentate manner to assume a distorted octahedral configuration. Complex C1 was studied by TGA analysis in air atmosphere. The interaction between complex C1 and the herring sperm DNA was realized through the intercalation of the complex based on the studies by EB fluorescent probe. 相似文献
12.
YANG Gao-Shan LIU Chong-Bo LI Heng-Nong CHEN Yuan HUANG De-He WEN Hui-Liang 《结构化学》2014,33(4):528-534
Two heterocyclic Schiff bases were synthesized via the condensation reactions of primary amines with carbonyl compounds. 2-[(4-pyridylmethylene)-amino] phenol(compound 1) was synthesized by the interaction of 4-pyridinecarboxaldehyde with o-aminophenol in ethanol solvent; N,N‘-bis(3-(furan-2-yl)allylidene)benzene-1,4-diamin(compound 2) was synthesized by the interaction of 3-(2-furyl)acrolein with p-phenylenediamine in ethanol medium. The compounds were characterized by elemental analysis, IR, MS and single-crystal X-ray diffraction. Compound 1(C12H10N2O) crystallizes in the monoclinic system, space group P21/c with a = 7.0771(7), b = 7.2820(7), c = 19.849(2),β= 96.3390(10)°, V = 1016.66(17) ?3, Z = 4, Mr = 198.22, Dc = 1.295 g/cm3, F(000) = 416, GOOF = 1.060, μ= 0.085 mm-1, the final R = 0.0371 and wR = 0.0929 for 1497 observed reflections with I 2σ(I). Compound 2(C20H16N2O2) crystallizes in the orthorhombic system, space group Fdd2 with a = 26.344(15), b = 48.50(3), c = 5.293(3), V = 6764(7) ?3, Z = 16, Mr = 316.35, Dc = 1.243 g/cm3, F(000) = 2656, GOOF = 1.043, = 0.081 mm-1, the final R = 0.0526 and wR = 0.1267 for 2059 observed reflections with I 2σ(I). 1 and 2 molecules are connected through hydrogen bonds to generate a 2D network and a 1D chain structure, respectively. The preliminary antibacterial activity results showed that the title compounds display excellent antibacterial activities to Escherichia coli, Staphylococcus aureus and Bacillus subtilis. 相似文献
13.
Using 3-amino-4-cyanopyrazole, salicylaldehyde and dialkylphosphite as materials, a series of a-aminophosphonates containing pyrazole and 2-hydroxybenzyl units were synthesized under microwave irradiation without solvents and catalysts. The structures of the compounds were verified by IR, 1H NMR, J3C NMR and elemental analysis. The crystal structure of diisobutyl {a-[3- (4-cyano-lH-pyrazol)amino)]-N-(2-hydroxylbenzyl)}phosphonate (4d, C19H27N404P) was deter- mined by single-crystal X-ray diffraction. Compound 4d crystallizes in the orthorhombic system, space group Pbcn with a = 17.329(4), b = 20.091(5), c = 12.433(3)/k, V = 4328.7(17) A3, M,. = 406.42, Dc = 1.247 g/cm3, Z = 8, F(000) = 1728,μ = 0.158 mm-1, MoKa radiation (2 = 0.71073 A), the final R = 0.064 and wR = 0.0169 for observed reflections with I 〉 2σ(I). X-ray diffraction analysis reveals that two planes lie in 4d, and the dihedral angle is 85.76°. Intermolecular O(1)-H(1B)-O(2), N(1)-H(1)-N(4), N(3)-H(3).-.N(2) and N(3)-H(3)...O(1) hydrogen bonds are found in the structure. All the compounds were evaluated for their antiviral and antitumor activities respectively. Among them, 4d and 4e showed moderate anti-TMV activities at 500 gg/mL, and 4e possessed excellent antitumor activity against PC3 cells at 10 gmol/L. 相似文献
14.
Efficient Synthesis,Crystal Structure and Antibacterial Activity of Two Novel 1,3-Oxazin Derivatives
Two new 1,3-oxazin derivatives, C22H24N2O5(3I) and C19H16N2O5(3II), have been synthesized via an unusual cascade reaction. The attractive aspect of this cascade reaction is that the novel construction of 1,3-oxazine and the direct C-N bond formation from C-C bond can be easily achieved via pyridine-mediated acylation in a one-pot operation. Both compounds have been synthesized and characterized by elemental analysis, IR, NMR spectra and X-ray single-crystal diffraction. Compound 3I crystallizes in monoclinic, space group P21/n with a = 16.282(4), b = 7.4117(18), c = 17.256(5) , β = 103.193(9)°, V = 2027.4(9) 3, Mr = 396.43, Z = 4, Dc = 1.299 g/cm3, F(000) = 840, MoKa radiation(λ = 0.71073 ), the final R = 0.0771 and wR = 0.1582 for 3662 were observed reflections with I 2σ(I). Compound 3II crystallizes in triclinic, space group P1 with a = 7.1265(9), b = 10.1071(13), c = 23.529(3), α = 97.463(9), β = 96.981(9), γ = 94.345(9)°, V = 1600.5(4) 3, Z = 4, Dc = 1.409 g/cm3, F(000) = 736, CuKa radiation(λ = 1.54186 ), the final R = 0.0515 and wR = 0.1241 for 4920 observed reflections with I 2σ(I). The preliminary antibacterial activities of 2 and 3 against E. coli and S. aureus were investigated. The results showed that the inhibiting effect of 3 was higher than that of 2. 相似文献
15.
A complex [NiL2] was synthesized, in which L, or to be exact, a Schiff base ligand(HL), was derived from the condensation of 1-phenyl-3-methyl-4-phenylacetyl-5-pyrazolone(PMPAP) with L-phenylalanine methyl ester. They were characterized by IR and single-crystal X-ray diffraction. Green block crystals of both ligand and its complex were grown at room temperature. The ligand, which consists of two individual fragments, crystalizes in the P1 space group(a = 5.6268(5), b = 10.6892(11) and c = 19.4869(18) ). The complex crystalizes in the P21 space group(a = 21.4076(18), b = 9.4792(8) and c = 25.287(2) ), which consists of a nickel six-coordinated compound. Every fragment is a distorted octahedron with four oxygen and two nitrogen atoms. The Schiff base ligand(HL) and its complex have been tested in vitro to evaluate their antibacterial activity against bacteria Escherichia Coli and Bacillus subtilis. It is found that the complex has higher activity than the corresponding free Schiff base ligand(HL) against the same bacterial. 相似文献
16.
A transition metal substituted polyoxotungstate, [Cu(en)2(H2O)]2{PW11.5Cu0.5O40[Cu(en)2] }·2H2O
1 based on Keggin frameworks, has bccn hydrothcrmally synthesized and characterized by IR, TGA and single-crystal X-ray structural analysis. It is interesting to find that the structure unit contains two different valence cations, narncly, one [Cu(1)(en)2(H2O)]^+ and one [Cu(2)(en)2(H2O)]^2+. Data for the crystal: orthorhombic system, space group Pbca, a = 21.585(2), b = 20.695(2), c = 26.137(3)A, V = 11675(2)A^3, Z = 8, Mr = 3428.23, Dc = 3.901 g/cm^3, F(000) = 12156,μ(MoKα) = 23.932 mm^-1, the final R = 0.0468 and wR = 0.0969 for 6927 observed reflections (I 〉 2σ(I)). 相似文献
1 based on Keggin frameworks, has bccn hydrothcrmally synthesized and characterized by IR, TGA and single-crystal X-ray structural analysis. It is interesting to find that the structure unit contains two different valence cations, narncly, one [Cu(1)(en)2(H2O)]^+ and one [Cu(2)(en)2(H2O)]^2+. Data for the crystal: orthorhombic system, space group Pbca, a = 21.585(2), b = 20.695(2), c = 26.137(3)A, V = 11675(2)A^3, Z = 8, Mr = 3428.23, Dc = 3.901 g/cm^3, F(000) = 12156,μ(MoKα) = 23.932 mm^-1, the final R = 0.0468 and wR = 0.0969 for 6927 observed reflections (I 〉 2σ(I)). 相似文献
17.
WANG Nonga② SHI Qib a 《结构化学》2008,27(2):191-194
A new Schiff base compound, 2-bromo-4-chloro-6-[(4-methylpyridin-2-ylimino)methyl]phenol (C13H10BrClN20), has been synthesized by the condensation of equimolar 3-bromo-5- chlorosalicylaldehyde and 4-methylpyridin-2-ylamine in a methanol solution. The compound was characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group P21 with a = 6.048(3), b = 14.063(7), c = 7.623(4) A,β = 97.703(7)°, Z = 2, V = 642.5(6)A3, Dc = 1.683 g/cm3, Mr=325.59, 2(MoKa) = 0.71073A,μ = 3.395 mm^-1, F(000) = 324, R = 0.0370 and wR = 0.0662. A total of 3879 reflections were collected, of which 1970 with I 〉 2σ(I) were observed. As expected, the molecule adopts a trans configuration about the C=N double bond. The benzene and pyridine rings are nearly coplanar (mean deviation from the combined plane is 0.031(3)A), with their dihedral angle of 3.3(3)°. The preliminary biological tests show that the compound has excellent antibacterial activities. 相似文献
18.
The supramolecular terbium complex, {[Tb(SIP)(H2O)5]2(bpy)3(H2O)}n (NaH2SIP = 5-sulfoisophthalic acid monosodium salt and bpy = 4,4'-bipyridyl), has been synthesized by the hydrothermal reaction of Tb4O7 with NaH2SIP and bpy at 165 ℃, and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectrum, powder X-ray diffraction and photoluminescence spectrum. It crystallizes in a monoclinic system, space group C2/c, with a = 30.6840(1), b = 10.9206(2), c = 17.4967(3) A, β= 111.931(1)°, V = 5438.65(14) A^3, Z = 4, C46H52N6O25S2Tb2, Mr = 1470.90, Dc = 1.796 g/cm^3, p = 2.747 mm^-1, F(000) = 2928, the final R = 0.0654 and wR = 0.1322 for 3806 observed reflections with I 〉 2σ(I). In the neutral [Tb(SIP)(H2O)5]2 motif, the Tb(III) ions are linked by the SIP ligands to form a one-dimensional zigzag chain propagating along the c axis. The zigzag chains are linked together by hydrogen bonds and π-π stacking interactions to form a two-dimensional supramolecular framework. The uncoordinated bpy molecules act as pillars to extend the two-dimensional sheets into a distinctive pillared three-dimensional supramolecular structure through O-H...N hydrogen bonds. The photoluminescence of the complex was investigated at room temperature in the solid state. 相似文献
19.
WANG Yue-Honga LIN Haib LIN Hua-Kuana② a 《结构化学》2008,27(2):163-166
The title compound, N-(1′-H-pyrrol-2′-ylcarbonyl)-5-amino-1,10-phenanthroline, was synthesized by the reaction of a-pyrrolyl carbonyl chloride and 5-amino-1,10-phenanthroline in pyridine. Determined by X-ray structure analysis, it crystallizes in triclinic system, space group P1 with the following crystallographic data: C20H21N5O3, Mr = 379.42, a = 7.8559(4), b = 9.1681(6), c = 14.6818(9) A, α= 73.254(10),β= 88.938(15), γ= 68.080(10)°, V= 934.66(10) A3, Z = 2, F(000) = 400, Dc = 1.348 g/cm^3 and p = 0.094 mm-1. The final R = 0.0680 and wR = 0.1419 for 2142 observed reflections with I 〉 2σ(/), and R = 0.1084 and wR = 0.1643 for all reflections. Two aromatic ring planes (pyrrole and phenanthroline rings) are connected by the amide plane. Two different types of intermolecular hydrogen bonds, O-H…N and N-H…O, exist in the crystal. The title complex molecules are connected through hydrogen bonds and weak π-π stacking interactions to generate a 3-D supramolecule. 相似文献
20.
The novel mixed-ligand neutral compound [Mo3O4(C2O4)2bipy-(H2O)3]·EtOH·2H2O(bipy = 2,2′-bipyridine) has been prepared by the reaction of oxalic acid elution of Mo(IV) and bipy, and characterized by single-crystal X-ray diffraction analysis and IR. The crystal is of triclinic, space groups P1^- with a = 9.5520(2), b = 10.3730(1), c = 13.5722(2)A, a = 74.940(12),β = 80.772(14),γ= 69.898(11)°, V = 1215.73(11)A^3, Z = 2, C16H24Mo3N2O18, Mr = 820.19, Dc = 2.241 g/cm^3,μ = 1.616 mm^-1, F(000) = 808, T = 293(2) K, the final R = 0.0424 and wR = 0.0939 for 4119 observed reflections with I 〉 2σ(I). The trinuclear unit is coordinated by mixed ligands of oxalate and bipy. The intermolecular hydrogen bonding interactions among adjacent [Mo3O4(C2O4)2·bipy(H2O)3] extend the compound into a three-dimensional supramolecular framework. The uncoordinated water molecules and ethal molecules act as space-fillers and consolidate the whole architecture through hydrogen bonding interactions. 相似文献