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1.
《中国化学》2018,36(6):487-490
Two‐electron oxidations of three 1,2‐di(bisphenylamino)‐benzenes afforded a class of nitrogen analogues of o‐quinodimethane. Their electronic structures in the ground state were studied by spectroscopic techniques including EPR and UV‐vis absorption spectroscopy. They have open‐shell singlet ground states with thermally accessible triplet states. One of them ( 1 2+) has been crystalized and isolated. SQUID measurements, single crystal X‐ray diffraction and theoretical calculations show 1 2+ has unexpected non‐Kekulé diradical character, sharply different from o‐quinodimethane.  相似文献   

2.
Although diradicals and azaacenes have been greatly attractive in fundamental chemistry and functional materials, the isolable diradical dianions of azaacenes are still unknown. Herein, we describe the first isolation of pyrene‐fused azaacene diradical dianion salts [(18‐c‐6)K(THF)2]+[(18‐c‐6)K]+? 1 2?.. and [(18‐c‐6)K(THF)]2+? 2 2?.. by reduction of the neutral pyrene‐fused azaacene derivatives 1 and 2 with excess potassium graphite in THF in the presence of 18‐crown‐6. Their electronic structures were investigated by various experiments, in conjunction with theoretical calculations. It was found that both dianions are open‐shell singlets in the ground state and their triplet states are thermally readily accessible owing to the small singlet–triplet energy gap. This work provides the first examples of crystalline diradical dianions of azaacenes with considerable diradical character.  相似文献   

3.
Peri‐acenes are good model compounds for zigzag graphene nanoribbons, but their synthesis is extremely challenging owing to their intrinsic open‐shell diradical character. Now, the successful synthesis and isolation of a stable peri‐tetracene derivative PT‐2ClPh is reported; four 2,6‐dichlorophenyl groups are attached onto the most reactive sites along the zigzag edges. The structure was confirmed by X‐ray crystallographic analysis and its electronic properties were systematically investigated by both experiments and theoretical calculations. It exhibits an open‐shell singlet ground state with a moderate diradical character (y0=51.5 % by calculation) and a small singlet–triplet gap (ΔES‐T=?2.5 kcal mol?1 by SQUID measurement). It displays global aromatic character, which is different from the smaller‐size bisanthene analogue BA‐CF3 .  相似文献   

4.
Chichibabin's and Müller's hydrocarbons are classical open‐shell singlet diradicaloids but they are highly reactive. Herein we report the successful synthesis of their respective stable analogues, OxR‐2 and OxR‐3 , based on the newly developed oxindolyl radical. X‐ray crystallographic analysis on OxR‐2 reveals a planar quinoidal backbone similar to Chichibabin's hydrocarbon, in accordance with its small diradical character (y0=11.1 %) and large singlet–triplet gap (ΔES‐T=−10.8 kcal mol−1). Variable‐temperature NMR studies on OxR‐2 disclose a slow cis/trans isomerization process in solution through a diradical transition state, with a moderate energy barrier (ΔG298K=15–16 kcal mol−1). OxR‐3 exhibits a much larger diradical character (y0=80.6 %) and a smaller singlet–triplet gap (ΔES‐T=−3.5 kcal mol−1), and thus can be easily populated to paramagnetic triplet diradical. Our studies provide a new type of stable carbon‐centered monoradical and diradicaloid.  相似文献   

5.

Abstract  

An electronic structure study of singlet and triplet states of two series of polyacenequinododimethides was performed using the B3LYP method. It was found that the ground state of all examined polyacenequinododimethides is a singlet with significant diradical character. The diradical character of the compounds under investigation was estimated using the unrestricted symmetry-broken and complete active space methods. It was shown that polyacene-2,3-quinododimethides have more pronounced diradical character than polyacene-2,x-quinododimethides. The diradical character of polyacene-2,x-quinododimethides monotonically increases with their increasing molecular size. Within the series of polyacene-2,3-quinododimethides the diradical character is not a monotonic function of the number of hexagons. It was found that pentacene-2,3-quinododimethide has the most pronounced diradical character in this series. It can be predicted on the basis of the singlet–triplet gap values that even higher polyacenequinododimethides will be singlet, but not triplet molecules.  相似文献   

6.
Trimethylenemethane (TMM) diradical is the simplest non‐Kekulé non‐disjoint molecule with the triplet ground state (ΔEST=+16.1 kcal mol?1) and is extremely reactive. It is a challenge to design and synthesize a stable TMM diradical with key properties, such as actual aliphatic TMM diradical centers and the triplet ground state with a large positive ΔEST value, since such species provide detailed information on the electronic structure of TMM diradical. Herein we report a TMM derivative, in which the TMM segment is fused with three NiII meso‐triarylporphyrins, that satisfies the above criteria. The diradical shows delocalized spin density on the propeller‐like porphyrin π‐network and the triplet ground state owing to the strong ferromagnetic interaction. Despite the apparent TMM structure, the diradical can be handled under ambient conditions and can be stored for months in the solid state, thus allowing its X‐ray diffraction structural analysis.  相似文献   

7.
Tetrakis(trimethylsilyl)cyclobuta‐1,3‐diene ( 1 ) was subjected to a temperature‐dependent EPR study to allow the first spectroscopic observation of a triplet diradical state of a cyclobutadiene ( 2 ). From the temperature dependent EPR absorption area we derive a singlet→triplet ( 1 → 2 ) energy gap, E ST, of 13.9 kcal mol−1, in agreement with calculated values. The zero‐field splitting parameters D =0.171 cm−1, E =0 cm−1 are accurately reproduced by DFT calculations. The triplet diradical 2 is thermally accessible at moderate temperatures. It is not an intermediate in the thermal cycloreversion of cyclobutadiene to two acetylene molecules.  相似文献   

8.
Transition-metal nitrides/nitrenes are highly promising reagents for catalytic nitrogen-atom-transfer reactivity. They are typically prepared in situ upon optically induced N2 elimination from azido precursors. A full exploitation of their catalytic potential, however, requires in-depth knowledge of the primary photo-induced processes and the structural/electronic factors mediating the N2 loss with birth of the terminal metal-nitrogen core. Using femtosecond infrared spectroscopy, we elucidate here the primary molecular-level mechanisms responsible for the formation of a unique platinum(II) nitrene with a triplet ground state from a closed-shell platinum(II) azide precursor. The spectroscopic data in combination with quantum-chemical calculations provide compelling evidence that product formation requires the initial occupation of a singlet excited state with an anionic azide diradical ligand that is bound to a low-spin d8-configured PtII ion. Subsequent intersystem crossing generates the Pt-bound triplet azide diradical, which smoothly evolves into the triplet nitrene via N2 loss in a near barrierless adiabatic dissociation. Our data highlight the importance of the productive, N2-releasing state possessing azide ππ* character as a design principle for accessing efficient N-atom-transfer catalysts.  相似文献   

9.
《化学:亚洲杂志》2017,12(17):2177-2182
We theoretically predicted that acetylene‐bridged benzo[1,2‐c ;4,5‐c ′]bis[1,2,5]thiadiazole (BBT) oligomers would show a quick increase of diradical character with the extension of chain length. To validate the hypothesis, six stable BBT‐based diradicaloids were synthesized and fully characterized by X‐ray crystallographic analysis and various spectroscopic measurements. Three of them showed prominent paramagnetic activity at elevated temperatures due to thermal population from the open‐shell singlet ground state to triplet excited state. It was also found that substitution by electron‐donating triphenylamine groups at the termini promoted the diradical character and reduced the singlet–triplet energy gap, and at the same time, resulted in intense near‐infrared absorption.  相似文献   

10.
A stable 5,10‐bis(9‐fluorenylidene)porphyrin (Por‐Fl) diradicaloid was synthesized. It shows a quinoidal, saddle‐shaped geometry in the single crystal but can be thermally populated to a triplet diradical both in solution and in the solid state. Coordination with the Ni2+ ion (Por‐Fl‐Ni) does not significantly change the contorted conformation but reduces the singlet–triplet gap. Heat‐induced geometric change can explain the observed paramagnetic properties as well as unusual hysteresis in SQUID measurements. On the other hand, protonation (Por‐Fl‐2H+) dramatically changes the conformation while maintains the closed‐shell electronic structure. Our studies demonstrate how heat, coordination, and protonation affect the geometry, diradical character, and physical properties of conformationally flexible open‐shell singlet diradicaloids.  相似文献   

11.
We report the first direct spectroscopic observation by electron paramagnetic resonance (EPR) spectroscopy of a triplet diradical that is formed in a thermally induced rotation around a main‐group π bond, that is, the Si?Si double bond of tetrakis(di‐tert‐butylmethylsilyl)disilene ( 1 ). The highly twisted ground‐state geometry of singlet 1 allows access to the perpendicular triplet diradical 2 at moderate temperatures of 350–410 K. DFT‐calculated zero‐field splitting (ZFS) parameters of 2 accurately reproduce the experimentally observed half‐field transition. Experiment and theory suggest a thermal equilibrium between 1 and 2 with a very low singlet–triplet energy gap of only 7.3 kcal mol?1.  相似文献   

12.
Thermolysis of thiirane oxide leads to production of highly reactive sulfur monoxide. The liberated SO can in turn be trapped with a diene scavenger forming dihydrothiophene oxide. Since the intermediate diatomic possesses a triplet ground state, the SO transfer can proceed on two spin-state surfaces. Here, we study the competition between singlet concerted and stepwise triplet diradical mechanisms utilizing the M06-2X density functional as well as CCSD(T) and MRCI+Q wavefunction theories. We find that the decomposition of thiirane oxide prefers to pass through a triplet diradical intermediate that becomes accessible from a nearby minimum energy crossing point (MECP). Hence, the thermolysis of thiirane oxide is expected to predominantly release triplet ground state sulfur monoxide in agreement with previous experimental reports. The addition of 3SO to 1,3-butadiene initially generates an allylic diradical, that ring-closes to a thiirane oxide through another MECP, and a subsequent rearrangement gives access to the final product.  相似文献   

13.
Although diradicals and azaacenes have been greatly attractive in fundamental chemistry and functional materials, the isolable diradical dianions of azaacenes are still unknown. Herein, we describe the first isolation of pyrene-fused azaacene diradical dianion salts [(18-c-6)K(THF)2]+[(18-c-6)K]+⋅ 1 2−.. and [(18-c-6)K(THF)]2+⋅ 2 2−.. by reduction of the neutral pyrene-fused azaacene derivatives 1 and 2 with excess potassium graphite in THF in the presence of 18-crown-6. Their electronic structures were investigated by various experiments, in conjunction with theoretical calculations. It was found that both dianions are open-shell singlets in the ground state and their triplet states are thermally readily accessible owing to the small singlet–triplet energy gap. This work provides the first examples of crystalline diradical dianions of azaacenes with considerable diradical character.  相似文献   

14.
The synthesis of a bithiophene‐bridged 34π conjugated aromatic expanded porphycene 1 and a cyclopentabithiophene bridged 32π conjugated anti‐aromatic expanded porphycene 2 by a McMurry coupling strategy is presented. Magnetic measurements and theoretical calculations reveal that both 1 and 2 exhibit an open‐shell singlet ground state with significant radical character (y0=0.63 for 1 ; y0=0.68, y1=0.18 for 2 ; y0: diradical character, y1: tetraradical character) and a small singlet–triplet energy gap (ΔES‐T=?3.25 kcal mol?1 for 1 and ΔES‐T=?0.92 kcal mol?1 for 2 ). Despite the open‐shell radical character, both compounds display exceptional stability under ambient air and light conditions owing to effective delocalization of unpaired electrons in the extended cyclic π‐conjugation pathway.  相似文献   

15.
The facile and tunable preparation of unique dinuclear [(L?)Pd?X?Pd(L?)] complexes (X=Cl or N3), bearing a ligand radical on each Pd, is disclosed, as well as their magnetochemistry in solution and solid state is reported. Chloride abstraction from [PdCl( NNOISQ )] ( NNOISQ =iminosemiquinonato) with TlPF6 results in an unusual monochlorido‐bridged dinuclear open‐shell diradical species, [{Pd( NNO ISQ)}2(μ‐Cl)]+, with an unusually small Pd‐Cl‐Pd angle (ca. 93°, determined by X‐ray). This suggests an intramolecular d8–d8 interaction, which is supported by DFT calculations. SQUID measurements indicate moderate antiferromagnetic spin exchange between the two ligand radicals and an overall singlet ground state in the solid state. VT EPR spectroscopy shows a transient signal corresponding to a triplet state between 20 and 60 K. Complex 2 reacts with PPh3 to generate [Pd(NNOISQ)(PPh3)]+ and one equivalent of [PdCl( NNOISQ )]. Reacting an 1:1 mixture of [PdCl( NNOISQ )] and [Pd(N3)( NNOI SQ)] furnishes the 1,1‐azido‐bridged dinuclear diradical [{Pd( NNO ISQ)}21‐N;μ‐N3]+, with a Pd‐N‐Pd angle close to 127° (X‐ray). Magnetic and EPR measurements indicate two independent S=1/2 spin carriers and no magnetic interaction in the solid state. The two diradical species both show no spin exchange in solution, likely because of unhindered rotation around the Pd?X?Pd core. This work demonstrates that a single bridging atom can induce subtle and tunable changes in structural and magnetic properties of novel dinuclear Pd complexes featuring two ligand‐based radicals.  相似文献   

16.
A series of 6π‐electron 4‐center species, E2N2 and E42+ (E=S, Se, Te) is studied by means of ab initio valence bond methods with the aims of settling some controversies on 1) the diradical character of these molecules and 2) the radical sites, E or N, of the preferred diradical structure. It was found that for all molecules, the cumulated weights of the two possible diradical structures are always important and close to 50 %, making these molecules comparable to ozone in terms of diradical character. While the two diradical structures are degenerate in the E42+ dications, they have on the contrary strongly unequal weights in the E2N2 neutral molecules. In these three molecules, the electronic structure is dominated by one diradical structure, in which the radical sites are the two nitrogen atoms, while the other diradical structure is much less important. The ordering of the various VB structures in terms of their calculated weights is confirmed by the relative energies of individual VB structures. In all cases, the major diradical structure (or both diradical structures when they are degenerate) is (are) the lowest one(s), while the covalent VB structures lie higher in energy. The vertical resonance energies are considerable in S2N2 and S42+, about 80 % of the estimated value for benzene, and diminish as one goes down the periodic table (S→Se→Te). This confirms the aromatic character of these species, as already demonstrated for S2N2 on the basis of magnetic criteria. This and the high weights and stabilities of one or both diradical structures in all systems indicates that aromaticity and diradical character do not exclude each other, contrary to what is usually claimed. Furthermore, it is shown that the diradical structures find their place in a collective electron flow responsible for the ring currents in the π system of these species.  相似文献   

17.
A tetracyano quinoidal tetrathiophene, having a central bi(thieno[3,4‐c]pyrrole‐4,6‐dione) acceptor, has been studied. The recovered aromaticity of the thiophenes produces a diradical species with cross‐conjugation between the inter‐dicyano and inter‐dione acceptor paths. A diradical character of y0=0.61 and a singlet–triplet gap of ?2.76 kcal mol?1 were determined. Competition between the two cross‐conjugated paths enhances the disjointed character of the SOMOs and results in the confinement of the diradical to the molecular center, enabling a thermodynamic diradical stabilization featuring a half‐life of 262 hours. Cross‐conjugation effects have been also addressed in the anionic species (up to a radical trianion).  相似文献   

18.
Geometry optimizations of several low-lying diradical states of the ring-opened oxirane (·CH2CH2O·) were performed by using the energy gradients of the UHF MINDO/3, STO-3G and 4-31G solutions. Both the STO-3G and 4-3 IG methods predict that the most stable form is the triplet state of the non-twisted σπ conformation in which the unpaired spins localized on the terminal carbon and oxygen atoms are oriented perpendicularly to each other. The singlet σσ diradical state in which both the radical-site p orbitals are coplanar with the molecular framework is only 2.3 (STO-3G) and 1.2 (4-31G) kcal/mol less stable than the triplet σπ diradical state. It is found that the geometry of the singlet σσ diradical is unique in that the C-C-O angle is noticeably small as compared with various other diradical states. Implications of these results to the mechanism of the oxirane-forming O(3P) + C2H4 reaction are discussed.  相似文献   

19.
Quinoidal azaacenes with almost pure diradical character (y=0.95 to y=0.99) were synthesized. All compounds exhibit paramagnetic behavior investigated by EPR and NMR spectroscopy, and SQUID measurements, revealing thermally populated triplet states with an extremely low‐energy gap ΔEST′ of 0.58 to 1.0 kcal mol?1. The species are persistent in solution (half‐life≈14–21 h) and in the solid state they are stable for weeks.  相似文献   

20.
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