Light scattering spectra at the wavelength of excitation and fluorescence spectra of water and highly diluted aqueous media
were measured. Long-term (several hours and/or days) changes in the spectral parameters after shaking, ultraviolet irradiation,
and other actions on the aqueous medium were detected. It was found that melt water is significantly more sensitive to physical
actions and adding various compounds. 相似文献
The effect of celluloses microfibers (CMF) reinforcement in ethylene-vinyl acetate (EVA) on its barrier properties was evaluated using xylene, toluene, and benzene as penetrant molecule. CMF were obtained from Hibiscus sabdariffa by steam explosion technique and was reinforced in EVA by melt extrusion. The barrier properties of the composites were found to be improved with CMF loading. This has been attributed to good interfacial interaction between CMF and EVA which is further confirmed using Kraus equation. Arrhenius activation parameters for the diffusion, permeation, and thermodynamic parameters were also estimated from the sorption data. The mode of the transport was found to follow regular Fickian trend. 相似文献
The critical conditions of a thermal explosion in a cylindrical chemical reactor with several symmetrically positioned agitators for creating a forced convection of the reaction mixture are examined. The analysis is carried out for an arbitrary Peclet number on the assumption that the flow of the fluid is laminar. The critical value of the thermal explosion parameter (Frank-Kamenetskii parameter) is determined as a function of the number of agitators, Peclet number, and the distances between the axes of the agitators and the reactor axis. In contrast to the previous studies, the dependence of the thermal explosion parameter on the rate of stirring of the medium is considered. Calculations show that, as the number of agitators and mixing rate increases, the thermal explosion probability decreases, so that the critical value of the thermal explosion parameter can be several times greater than its classical value. It is demonstrated that, depending on the values of the parameters, the problem can have four stationary solutions, two of which are stable. 相似文献
The kinetics of the electrical explosion of foils has been investigated and the parameters of the plasma jet, the radius of
the plasma-affected zone, the pressure and temperature of the plasma in the shock-compressed layer near the irradiated surface,
and the accepted power density at the jet axis have been calculated in relation to the dimensions of the plasma accelerator,
the distance from the nozzle exit section to the irradiated surface, and the charge voltage of the energy store. Modes of
electrical explosion alloying of metals have been determined experimentally which are associated with surface melting, splashing
of melt, effects of convective heat and mass transfer, aftereffect, and also with physicochemical and physicomechanical features
of the materials used. Methods of optical, scanning, and transmission electron diffraction microscopy have been used to examine
the relief, phase composition, and defect substructure of the surface layers of metals after various types of one-and two-component
electrical explosion alloying. A multilayer structure has been revealed which is characterized by the degree of variation
of the phase-structure state and of the material mechanical characteristics. Based on the features of the multiphase jet that
serves as a tool for affecting the surface, some propositions have been made on the physical nature of the processes occurring
in a material subject to electrical explosion alloying.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 71–83, May, 2008. 相似文献
The electrical explosion of aluminum wires is numerically simulated in the magnetohydrodynamic approximation for the current density ranging from 107 to 1010 A/cm2 and times to explosion varying from 10?10 to 10?6 s. It is shown that, at current densities of 108?109 A/cm2, low-temperature explosion conditions change to high-temperature ones, when inertial forces preventing the wire dispersion play a decisive role. This transition is accompanied by a sharp change in the thermodynamic parameters (the temperature and the energy deposited into the wire by the instant of explosion increase by several times), and the action integral for this transition increases smoothly approximately threefold as the explosion characteristics (current density and time to explosion) change by two orders of magnitude. The instant of transition from the low-temperature explosion to the high-temperature one depends on the radial dimensions of an exploding wire and does not depend on the properties of the environment. 相似文献
Formation of an adhesive contact between a polymer melt (or solution) and reinforcing fibers is considered from the viewpoint of kinetics. A two-stage model of this process has been proposed, and an expression for the interfacial bond strength as a function of time and temperature is derived. Experimental data on bond strength in adhesive joints between thermoplastic polymers and reinforcing fibers formed under various conditions were obtained, and the concept of activation energy was used to analyze them. Since the process is controlled by the stage having the larger activation energy, the adhesive contact formation between fibers and polymer solutions is governed by the rate of adhesive bonding, whereas that between fibers and polymer melts is governed by the rate of the melt spreading. 相似文献
Contact melting has been examined for several alkali halide crystals with some refractory compounds via the formation of a contact melt and subsequent crystallization as eutectic structures or dendrites. Mutual solusolubility occurs during contact melting, the low-melting component being highly soluble in the high-melting one.The authors wish to thank D. D. Saratovkin and V. N. Zhdanova for discussions. 相似文献
The eutectic alloy of BiInSn was ablated in water by UV pulsed radiation. Electron microscopy of the ablated material shows spherical particles that fall into three size regimes: those with diameters of ~0.5 μm, crystalline and amorphous particles with dimensions of ~30 nm, and amorphous particles that are approximately 1 nm across. The 30-nm amorphous particles are homogeneous, while there are two types of 30-nm crystalline particles, those that separate into three phases and those that are homogeneous. The existence of different characteristic sizes is explained by two mechanisms: phase explosion and Rayleigh instability of the ejected melt. 相似文献
The kinetic equations of planar multi-body systems with friction-affected sliding joints are reformulated for the computation of closed-form solutions for the kinetic parameters. The state of such systems is characterized not only by the position parameters and velocities, but in addition, the modes of contact in the sliding joints must be specified. Then the cases with one or several sets of solutions, obtained for the same position parameters, velocities, active forces and friction parameters, can be related to positions of the system with different modes of contact between sliders and guiding surfaces. They are physical unequivocal states and can be interpreted as unique solutions for the kinetic problem with specified configuration of the system. If no solutions exist, then the friction parameters considered are too large and exceed limiting values, for which friction locking occurs. 相似文献
The validity of the “bubble method” is discussed for the measurements of contact angles between a crystal and its own melt and for the observations of interface morphology. Experiments were done on KCl crystals pulled in various directions. Gold decoration technique was employed to observe the surface morphology. The measurement of the contact angle a is valid for the 〈100〉 axis of pulling but lacks accuracy for the other directions. The {100} interface shows two dimensional nucleation, curved growth fronts and no trace of a liquid layer. The {110}, {310}and {111} interfaces show steps and pyramids constituted by {100} facets, completely stripped of the melt, and “structureless” regions resulting from freely frozen liquid surface. 相似文献
The wetting phenomenon of water droplets coexisting with the ordered water monolayer termed an unexpected phenomenon of "water that does not wet a water monolayer" at room temperature has been found on several solid surfaces.Although the hydrogen bond saturation inside the monolayer can qualitatively describe this phenomenon, whether the Young–Dupré equation still holds under this unconventional wetting framework is still not answered. In this work, we have calculated the contact angle values of the droplets as well as the work of adhesion between the droplets and the monolayer based on an extended phantom-wall method. The results show that similar to the conventional solid–liquid interface,classical Young–Dupré equation is also applicable for the interface of liquid water and ordered water monolayer. 相似文献
The reduction of void formation in local Al contact structures is of high interest in studies dealing with passivated emitter and rear contact (PERC) solar cells. So far, several processing parameters and their impact on local contact formation were investigated in detail. However, up to now density variation of Al in dependence on temperature and Si content in the melt were not taken into account as a principal reason for void formation. In this context the current assumption of a constant volume of the Al paste particles is discussed in more detail. Based on the results of energy dispersive X‐ray spectroscopy, void formation implies either an expansion of paste particles or their burst during contact formation.
Heating and explosive destruction of the near surface volume of metal with initial micro-porosity under nanosecond laser pulse is simulated. It is shown that presence of initial micro-porosity may influence and modify the ejection mechanisms from melt and from solid phase. Thermal and gas dynamic processes in a gas bubble growing in laser irradiated melt are analysed. Experiments show rather different surface morphology defined by micro-explosions and melt ejection for different metals. Possible explosion of micro-pores and solid particles release under nanosecond laser irradiation is analysed for metals with high melting point. It is shown that the stress attains the values that are close to the damage threshold. 相似文献
Experimental studies of the mechanism of negative ion and cluster ion emission from surfaces of ferroelectrics are described. The emission was produced by negative voltage pulses with the amplitude of about 400 V, with a rapid rise-time (below 10 ns) and a slow decay‐time (several μs). The pulses were applied between the back side of the ferroelectric sample and the metal tip touching the front emitting side. The surface of the ferroelectrics could be cleaned in situ by 1 keV Ar+ bombardment. The morphologic changes around the tip were observed with an atomic force microscope (AFM). Mostly negative ions and cluster ions were emitted and studied in our experiments. Positive ions were detected with much lower probability and are produced by an entirely different microscopic process than negative ions. Masses as well as energies of emitted ions were measured with a time-of-flight (TOF) spectrometer and compared with available spontaneous desorption (SD) spectra and Cs‐SIMS spectra in order to clarify the mechanism of the emission. The trajectory of ions emitted from the sample was studied by computer simulation. The conclusion of these studies is that the negative ion emission is caused by the Coulomb explosion of a polarization cloud rapidly formed at the front edge of the pulse. The explosion takes place in the vicinity of the tip-sample contact at distances several tens of μm from the contact where the stabilizing effect of the positively charged tip is already small. 相似文献
We investigate the collapse dynamics of a dipolar condensate of 52Cr atoms when the s-wave scattering length characterizing the contact interaction is reduced below a critical value. A complex dynamics, involving an anisotropic, d-wave symmetric explosion of the condensate, is observed. The atom number decreases abruptly during the collapse. We find good agreement between our experimental results and those of a numerical simulation of the three-dimensional Gross-Pitaevskii equation, including contact and dipolar interactions as well as three-body losses. The simulation indicates that the collapse induces the formation of two vortex rings with opposite circulations. 相似文献
The interaction between a Mg-containing melt and B under conditions of partial and complete wetting of Al/Al grain boundaries
by Al-Mg melt has been investigated. The study was performed on Al polycrystals with Mg contents of 5, 10, 15, 18, and 25
wt %. Correspondingly, the Mg content in the melt was determined by the liquidus line and was in the range from 5 to 30 wt
%. The obtained metal-matrix composites were investigated by light and scanning electron microscopy, electron-probe microanalysis,
and X-ray diffraction. The possibility of synthesizing MgB2 in the contact with a melt having a relatively low Mg content (from 15 to 30 wt %) has been demonstrated. 相似文献