Anomalous temperature dependence of diffusion in crystals in time-periodic external fields

The features of the diffusion of particles under the action of an external periodic force in a crystal lattice have been studied using computer simulation. It has been shown that the temperature dependence of the diffusion coefficients is anomalous. Diffusion can increase with a decrease in the temperature in some temperature intervals. The positions and widths of these intervals depend on the frequency of the external field. It has been found that the diffusion coefficient in the presence of a periodic external field can be more than nine orders of magnitude larger than the usual diffusion coefficient at the same temperature. The physical reasons for this anomaly have been analyzed.     

Diffusion in flashing periodic potentials

The one-dimensional overdamped Brownian motion in a symmetric periodic potential modulated by external time-reversible noise is analyzed. The calculation of the effective diffusion coefficient is reduced to the mean first passage time problem. We derive general equations to calculate the effective diffusion coefficient of Brownian particles moving in arbitrary supersymmetric potential modulated by: (i) an external white Gaussian noise and (ii) a Markovian dichotomous noise. For both cases the exact expressions for the effective diffusion coefficient are derived. We obtain acceleration of diffusion in comparison with the free diffusion case for fast fluctuating potentials with arbitrary profile and for sawtooth potential in case (ii). In this case the parameter region where this effect can be observed is given. We obtain also a finite net diffusion in the absence of thermal noise. For rectangular potential the diffusion slows down, for all parameters of noise and of potential, in comparison with the case when particles diffuse freely.     

对利用动态光散射法测量颗粒粒径和液体黏度的改进

光散射技术通过测量悬浮液中布朗运动颗粒的平移扩散系数,得到颗粒流体力学直径或液体黏度.本文由单参数模型入手,建立了低颗粒浓度下,单颗粒平移扩散系数与颗粒集体平移扩散系数和颗粒浓度之间的线性依存关系并将其引入光散射法中,从而对现有的测量方法进行了改进.改进后的测量方法可实现纳米尺度球型颗粒标称直径的测量和液体黏度的绝对法测量.以聚苯乙烯颗粒+水和二氧化硅颗粒+乙醇两个分散系为参考样本,通过实验,验证了改进后方法的可行性.此外,还针对上述两个分散系,实验探讨了温度和颗粒浓度对颗粒集体平移扩散系数的影响规律,发现聚苯乙烯颗粒+水分散系中,颗粒间相互作用表现为引力;二氧化硅颗粒+乙醇分散系中,颗粒间相互作用表现为斥力.讨论了颗粒集体平移扩散系数随颗粒浓度变化规律与第二渗透维里系数的关系.     

外力作用下反馈耦合布朗棘轮的定向输运

本文研究了处于外力作用下双阱棘轮势中两个反馈耦合布朗粒子的定向输运性能. 通过对过阻尼朗之万方程的数值求解, 详细讨论了外力、热噪声与势阱的不对称参数等对耦合布朗粒子的平均速度、 有效扩散系数及Pe数的影响. 研究发现, 平均速度随外力呈周期性的变化规律. 同时耦合系统存在最优噪声强度会使定向输运达到最强. 值得指出的是棘轮系统可通过改变双阱势的结构来获得较强的定向流. 关键词： 耦合布朗棘轮 外力 双阱棘轮势 平均速度     

Diffusion in different models of active Brownian motion

Active Brownian particles (ABP) have served as phenomenological models of self-propelled motion in biology. We study the effective diffusion coefficient of two one-dimensional ABP models (simplified depot model and Rayleigh-Helmholtz model) differing in their nonlinear friction functions. Depending on the choice of the friction function the diffusion coefficient does or does not attain a minimum as a function of noise intensity. We furthermore discuss the case of an additional bias breaking the left-right symmetry of the system. We show that this bias induces a drift and that it generally reduces the diffusion coefficient. For a finite range of values of the bias, both models can exhibit a maximum in the diffusion coefficient vs. noise intensity.     

Extended Lagrangian formalisms for dyons and some applications to solid systems under external fields

We analyze the conditions of the electromagnetic potentials for systems with electric and magnetic charges and the Lagrangian theory with these potentials. The constructed Lagrangian function is valid for obtaining the field equations and the extended Lorentz force for dyonic charges for both relativistic particles in vacuum and non-relativistic entities in solids. In a second part, with the one-body Hamiltonian of independent particles in external fields, we explore some dual properties of the dyonic system under external fields. We analyze the possible diamagnetic (and ‘diaelectric’) response of magnetic monopoles under a weak and constant electromagnetic field and the theory of Landau levels in the case of magnetic charges under strong electromagnetic constant fields.     

Pore Stabilization in Cohesive Granular Systems

Cohesive powders tend to form porous aggregates which can be compacted by applying an external pressure. This process is modelled using the Contact Dynamics method supplemented with a cohesion law and rolling friction. Starting with ballistic deposits of varying density, we investigate how the porosity of the compacted sample depends on the cohesion strength and the friction coefficients. This allows to explain different pore stabilization mechanisms. The final porosity depends on the cohesion force scaled by the external pressure and on the lateral distance between branches of the ballistic deposit. Even if cohesion is switched off, pores can be stabilized by Coulomb friction alone. This effect is weak for round particles, as long as the friction coefficient is smaller than 1. However, for non-spherical particles the effect is much stronger.     

Manifestation of Arnol'd diffusion in quantum systems

We study an analog of the classical Arnol'd diffusion in a quantum system of two coupled nonlinear oscillators one of which is governed by an external periodic force with two frequencies. In a classical model this very weak diffusion happens in a narrow stochastic layer along the coupling resonance and leads to an increase of the total energy of the system. We show that quantum dynamics of wave packets mimics, up to some extent, global properties of the classical Arnol'd diffusion. This specific diffusion represents a new type of quantum dynamics and may be observed, for example, in 2D semiconductor structures (quantum billiards) perturbed by time-periodic external fields.     

Collective motion of polar active particles on a sphere

Collective motion of active particles with polar alignment is investigated on a sphere. We discussed the factors that affect particle swarm motion and define an order parameter that can show the degree of particle swarm motion. In the model, we added a polar alignment strength, along with Gaussian curvature, affecting particles swarm motion. We find that when the force exceeds a certain limit, the order parameter will decrease with the increase of the force. Combined with our definition of order parameter and observation of the model, the reason is that particles begin to move side by side under the influence of polar forces. In addition, the effects of velocity, rotational diffusion coefficient, and packing fraction on particle swarm motion are discussed. It is found that the rotational diffusion coefficient and the packing fraction have a great influence on the clustering motion of particles, while the velocity has little influence on the clustering motion of particles.     

Hopping on a zig-zag course

We study the diffusion coefficient of Active Brownian particles in two dimensions. In addition to usual attributes of active motion we let the particles turn in preferred directions over random times. This angular motion is modeled by an effective Lorentz force with time dependent frequency switching between two values at exponentially distributed random times. The diffusion coefficient is calculated by the Taylor-Kubo formula where distributions found from a Fokker-Planck equation or from a continuous time random walk approach have been inserted for averaging. Eventually properties of the diffusion coefficient will be discussed.     

Anomalous transport and diffusion phenomena induced by biharmonic forces in deformable potential systems

We study transport properties of an inertial Brownian motor which moves in a deformable Remoissenet-Peyrad periodic potential and is subjected to both a static bias force and time periodic driving biharmonic force. By modifying the shape of the potential, the anomalous transport is identified for a particular set of the system parameters. For a particular potential shape, the mean velocity of a particle is modified by going from negative to positive values according to the external bias force. These features also depend on both the biharmonic parameter and the phase-lag of two signals. A remarkable transition of the negative velocity depending on the shape of the potential is observed. We also focus on the efficiency of the motor and discuss velocity fluctuation. In addition, within selected system parameters, different types of diffusion particle such as subdiffusion, superdiffusion, normal diffusion, ballistic diffusion, hyperdiffusion and dispersionless transport phenomena are generated in the system.     

A nonlinear Fokker–Planck equation approach for interacting systems: Anomalous diffusion and Tsallis statistics

We investigate the solutions for a set of coupled nonlinear Fokker–Planck equations coupled by the diffusion coefficient in presence of external forces. The coupling by the diffusion coefficient implies that the diffusion of each species is influenced by the other and vice versa due to this term, which represents an interaction among them. The solutions for the stationary case are given in terms of the Tsallis distributions, when arbitrary external forces are considered. We also use the Tsallis distributions to obtain a time dependent solution for a linear external force. The results obtained from this analysis show a rich class of behavior related to anomalous diffusion, which can be characterized by compact or long-tailed distributions.     

One-Dimensional Steady Transport by Molecular Dynamics Simulation：Non-Boltzmann Position Distribution and Non-Arrhenius Dynamical Behavior

A non-equilibrium steady state can be characterized by a nonzero but stationary flux driven by a static external force. Under a weak external force, the drift velocity is difficult to detect because the drift motion is feeble and submerged in the intense thermal diffusion. In this article, we employ an accurate method in molecular dynamics simulation to determine the drift velocity of a particle driven by a weak external force in a one-dimensional periodic potential. With the calculated drift velocity, we found that the mobility and diffusion of the particle obey the Einstein relation, whereas their temperature dependences deviate from the Arrhenius law. A microscopic hopping mechanism was proposed to explain the non-Arrhenius behavior. Moreover, the position distribution of the particle in the potential well was found to deviate from the Boltzmann equation in a non-equilibrium steady state. The non-Boltzmann behavior may be attributed to the thermostat which introduces an effective "viscous" drag opposite to the drift direction of the particle.     

Effect of acceleration by internal and external force fields on particle motion in intermediate regimes between the hydrodynamic and free-molecular limits

The kinetic theory of gases is applied to analyze slow translational motion of low-concentration particles driven by an external force in a homogeneous gas. The analysis takes into account the diffusion due to the difference in acceleration between particles and molecules in internal and external force fields. A general expression is derived for the particle drag force in hydrodynamic, free-molecular, and intermediate regimes. This expression reduces to a simple relation between the drag force and its values in the hydrodynamic and free-molecular limits and the force of intermolecular interaction between particles and gas molecules. In the case of spherically symmetric potential of interaction between the particle and molecules, the drag force is the harmonic mean of its limit values.     

外场作用下铁电/铁磁双层膜的极化磁化性质

建立了铁电/铁磁双层膜模型,铁电层的电矩用连续标量描述,而铁磁层的自旋应用经典矢量描述.利用蒙特卡罗方法模拟了体系的热力学性质和极化、磁化行为.给出了零场下体系的内能、比热、极化和磁化随温度变化的关系,并分别研究了体系在外磁场和外电场下的极化和磁化行为.模拟结果表明,双层膜体系的内能、比热、极化和磁化性质因层间耦合系数的不同而明显不同,当界面耦合较弱时,双层膜表现出各自的热力学性质,当层间耦合增强到一定程度时,双层膜耦合为一个整体,表现出统一的热力学性质.该双层膜在外场中形成电滞回线和磁滞回线,并表现出偏置特性,界面耦合强度和温度影响滞后回线和偏置现象.     

Reversible quantum brownian heat engines for electrons

Brownian heat engines use local temperature gradients in asymmetric potentials to move particles against an external force. The energy efficiency of such machines is generally limited by irreversible heat flow carried by particles that make contact with different heat baths. Here we show that, by using a suitably chosen energy filter, electrons can be transferred reversibly between reservoirs that have different temperatures and electrochemical potentials. We apply this result to propose heat engines based on mesoscopic semiconductor ratchets, which can quasistatically operate arbitrarily close to Carnot efficiency.     

Thermodynamics and transport in an active Morse ring chain

We investigate the stochastic dynamics of an one-dimensional ring with N self-driven Brownian particles. In this model neighboring particles interact via conservative Morse potentials. The influence of the surrounding heat bath is modeled by Langevin-forces (white noise) and a constant viscous friction coefficient γ. The Brownian particles are provided with internal energy depots which may lead to active motions of the particles. The depots are realized by an additional nonlinearly velocity-dependent friction coefficient γ ₁(v) in the equations of motions. In the first part of the paper we study the partition functions of time averages and thermodynamical quantities (e.g. pressure) characterizing the stationary physical system. Numerically calculated non-equilibrium phase diagrams are represented. The last part is dedicated to transport phenomena by including a homogeneous external force field that breaks the symmetry of the model. Here we find enhanced mobility of the particles at low temperatures. Received 21 July 2001     

Noise-induced transport with low randomness

We study the transport of overdamped Brownian particles in periodic potentials subject to a spatially modulated Gaussian white noise. We derive an analytical expression for the diffusion coefficient of particles. By means of velocity, diffusion coefficient, and their ratio (Péclet number) we discuss (a) symmetric potential and modulation of noise intensity and (b) a ratchet profile with strong noise modulation. It is shown that state dependent fluctuations may not only induce directed transport, but also a pronounced coherence of transport if the potential exhibits a strong asymmetry.     

The rich phenomenology of Brownian particles in nonlinear potential landscapes

Non-interacting Brownian particles obey Langevin equations fulfilling a fluctuation–dissipation relation between friction and thermal noise. Under a linear potential (constant force) Einstein found a relation between diffusion and transport through mobility. In nonlinear potentials this prediction is only satisfied within the limits of very small and large constant external forces. Moreover, other more interesting behaviors do appear, such as: dispersionless transport, sorting, giant diffusion, subdiffusion, superdiffusion, subtransport, etc. All these phenomena depend on the characteristics of the nonlinear potential landscape: periodic or random, the symmetries and boundary conditions. Moreover, the presence of transport is the keystone of most of this phenomenology. In this review, we present numerical simulations illustrating these facts and theoretical analysis when possible.     

Thermal fluctuation electromagnetic field as a reason for the sensitivity of a condensed diamagnetic medium to weak actions

Interaction between the thermal fluctuation electromagnetic field of a condensed medium and a weak external factor, say, a weak effective magnetic field including an external magnetic field, rigid rotation of the medium, and Coriolis force, imparts a torque to any charged free or bound particles (atoms, molecules, etc.). which indicates that the medium is sensitive to weak actions. The torque is proportional to thermal energy kT and may increase substantially under the cyclotron resonance conditions. The so-called kT problem is solved, so that many observations having to do with the field of physics that can be called the physics of weak actions (?kT) can now be theoretically explained.