共查询到20条相似文献,搜索用时 375 毫秒
1.
2.
对二元荧光配合物作为动力学反应指示剂的可行性进行了考察,以8-羟基喹啉-5-磺酸铝-高碘酸钠为指示反应,建立起流动注射光导纤维光谱技术测定痕量锰(Ⅱ)的动力学荧光分析新体系.此法线性范围为5~200ng/mL,检出限为1ng/mL,对50ng/mL锰(Ⅱ)进行11次测定的相对标准偏差为0.5%,分析速度为45样次/h. 相似文献
3.
在模拟人体生理条件下,利用紫外光谱法、荧光光谱法和同步荧光光谱法结合研究三种羟基蒽醌类药物(1,2-二羟基蒽醌、1,4-二羟基蒽醌和1,8-二羟基蒽醌)与溶菌酶(LYSO)相互作用机制,并探讨其构效关系。紫外结果初步显示,三种羟基蒽醌类药物与LYSO发生相互作用。荧光结果进一步证实三种羟基蒽醌类药物均与LYSO发生结合,且对LYSO的荧光猝灭机制均为静态猝灭并伴随有非辐射能量转移。三种羟基蒽醌类药物与LYSO均存在一个结合位点,它们与LYSO形成1∶1复合物,在303K下,结合常数K分别为8.47×105、4.88×105和5.43×105L·mol-1,结合距离r分别为5.83、5.12和5.14nm,与溶菌酶作用后焓变分别为-41.2、-87.6和-39.0 kJ·mol-1,熵变分别为-22.4、-180和-19.1 J·mol-1·K-1。三种羟基蒽醌类药物与LYSO的作用力均为范德华力和氢键,且作用强弱不同,其顺序为:1,2-二羟基蒽醌1,8-二羟基蒽醌1,4-二羟基蒽醌。同步荧光法结果表明三种羟基蒽醌类药物与LYSO相互作用后均导致LYSO构象发生改变。研究结果表明,蒽醌环上羟基位置的不同对羟基蒽醌类药物与溶菌酶结合强弱有较大程度的影响。 相似文献
4.
5.
吴诚 《理化检验(化学分册)》2006,42(8):692-692
答:茜素络合剂(Alizarin Complexan)为羟基蒽醌类显色剂,是茜素(1,2-二羟基蒽醌)的衍生物,其化学名为二羧基甲氨甲基-1,2-二羟基蒽醌,或3-氨基-甲基茜素-N,N-二乙酸。由于其分子中含具有络合作用的亚甲基二乙酸,故俗称为茜素络合剂,其化学结构式如下: 相似文献
6.
蒽醌丙烯酸酯、酰胺的合成 总被引:1,自引:0,他引:1
本文报道了3-羟基蒽醌-2-醛、1,6,8-三羟基蒽醌-3-醛、3-甲氧基蒽醌-2-醛、3-甲氧基蒽醌-2-丙烯酸及酯类、1,6,8-三羟基蒽醌-3-丙烯酸及蒽醌-2-丙烯酰胺类衍生物的合成,并报道有关化合物的紫外及红外吸收光谱数据。 相似文献
7.
1,8-二羟基-9,10-二氢蒽的合成 总被引:1,自引:0,他引:1
以1,8-二羟基蒽醌为原料,经甲醚化,锌粉和金属钠还原,去甲基等4步反应合成1,8-二羟基-9,10-二氢蒽,总产率为37.1,8-二甲氧基蒽醌用NaBH4/CF3COOH还原生成二聚产物,并测定了其单晶结构. 相似文献
8.
9.
基于HCl介质中和α,α-联吡啶存在下,As(V)可催化H2O2氧化2,3,4,9-四氢-9-羟基-1,10-蒽醌(R)转化无荧光化合物,导致体系荧光急剧猝灭,据此建立了催化H2O2氧化R荧光猝灭法测定痕量砷的新方法.在最佳条件下,As(V)含量在0.004 0~0.400 0 ng/mL范围内与荧光光强度的△If值符合比尔定律,工作曲线的回归方程△If=11.94 233.7 CAs(V)(ng/mL),n=7,相关系数r=0.9994,检出限为6.2×10-13g As(V)/mL,n=11.对0.004 0和0.400 0 ng/mL As(V)分别进行11次的测定,其RSD为2.6%与3.8%.该方法重现性好、灵敏、准确,用于实际中砷含量的测定,结果满意.还报道了R的合成,并借助核磁共振谱、红外光谱及质谱等谱学方法确定了其结构. 相似文献
10.
《理化检验(化学分册)》2010,(11)
预先制备了N,N′,N″-三(2-羟基-1-萘酚醛)胺作为配体(L),然后向含配体L的乙醇-二氯甲烷溶液中加入含稀土硝酸盐晶体RE(NO3)3.6 H2O(RE=La3+,Sm3+,Y3+,Tb3+,Ce3+,Eu3+)的乙醇溶液,合成稀土配合物。利用核磁共振法、元素分析法、摩尔电导法、红外光谱法及差热-热重法对稀土配合物的结构进行表征。结果表明:稀土配合物的结构为RE(NO3)3.L.4 H2O。采用荧光技术对稀土配合物的性能进行了研究,结果表明:在pH值约为7的介质中,以二甲亚砜(DMSO)为溶剂,稀土配合物浓度为1.0×10-4mol.L-1时,铽(Ⅲ)配合物有较强的特征荧光发射,铕(Ⅲ)配合物只表现了微弱的特征荧光发射,其他稀土配合物没有特征荧光发射。 相似文献
11.
Martin Sahlberg Yvonne Andersson 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(3):i7-i8
Scandium magnesium gallide, Sc2MgGa2, and yttrium magnesium gallide, Y2MgGa2, were synthesized from the corresponding elements by heating under an argon atmosphere in an induction furnace. These intermetallic compounds crystallize in the tetragonal Mo2FeB2‐type structure. All three crystallographically unique atoms occupy special positions and the site symmetries of (Sc/Y, Ga) and Mg are m2m and 4/m, respectively. The coordinations around Sc/Y, Mg and Ga are pentagonal (Sc/Y), tetragonal (Mg) and triangular (Ga) prisms, with four (Mg) or three (Ga) additional capping atoms leading to the coordination numbers [10], [8+4] and [6+3], respectively. The crystal structure of Sc2MgGa2 was determined from single‐crystal diffraction intensities and the isostructural Y2MgGa2 was identified from powder diffraction data. 相似文献
12.
13.
14.
Paul-Louis Fabre Dominique de Montauzon René Poilblanc 《Transition Metal Chemistry》1987,12(5):434-440
Summary The ability of [MoS4]2–, anions to be used as ligands for transition metal ions has been widely demonstrated, especially with Fe2+. The present study has been restricted to linear complexes such as (NEt4)2 [Cl2FeS2MoS2] and (NEt4)2[Cl2FeS2MoS2FeCl2]. Their electrochemical properties are described: upon electrochemical reduction, these compounds yield MoS2, as a black precipitate, and an iron complex in solution, assumed to be [SFeCl2]2–. The electrochemical reduction goes through two electron transfers, coupled with the breakdown of the molecular skeleton: a DISPl and an ECE mechanism. Depending on the solvent, the following equilibrium may be observed: [Cl4Fe2MoS4]2–[Cl2FeMoS4]2–+FeCl2. The equilibrium constant, KD, was evaluated by differential pulse polarography. KD is tightly related to the donor number of the solvent. 相似文献
15.
16.
Marina I. Naumova Natalia V. Kuratieva Nina V. Podberezskaya Dmitry Yu. Naumov 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(5):i53-i55
The structures of the hypophosphites KH2PO2 (potassium hypophosphite), RbH2PO2 (rubidium hypophosphite) and CsH2PO2 (caesium hypophosphite) have been determined by single‐crystal X‐ray diffraction. The structures consist of layers of alkali cations and hypophosphite anions, with the latter bridging four cations within the same layer. The Rb and Cs hypophosphites are isomorphous. 相似文献
17.
On Dialkali Metal Dichalcogenides β-Na2S2, K2S2, α-Rb2S2, β-Rb2S2, K2Se2, Rb2Se2, α-K2Te2, β-K2Te2 and Rb2Te2 The first presentation of pure samples of α- and β-Rb2S2, α- and β-K2Te2, and Rb2Te2 is described. Using single crystals of K2S2 and K2Se2, received by ammonothermal synthesis, the structure of the Na2O2 type and by using single crystals of β-Na2S2 and β-K2Te2 the Li2O2 type structure will be refined. By combined investigations with temperature-dependent Guinier-, neutron diffraction-, thermal analysis, and Raman-spectroscopy the nature of the monotropic phase transition from the Na2O2 type to the Li2O2 type will be explained by means of the examples α-/β-Na2S2 and α-/β-K2Te2. A further case of dimorphic condition as well as the monotropic phase transition of α- and β-Rb2S2 is presented. The existing areas of the structure fields of the dialkali metal dichalcogenides are limited by the model of the polar covalence. 相似文献
18.
[reaction: see text] Fluoranthene 2 and heptacycle 3 are easily accessible from the reaction of diyne 1 and norbornadiene (NBD) in the presence of the rhodium catalyst. The unusual [(2+2)+(2+2)] adduct 3 was confirmed by the X-ray crystal structure analysis. 相似文献
19.
[(n‐Bu)2Sn(O2PPh2)2] ( 1 ), and [Ph2Sn(O2PPh2)2] ( 2 ) have been synthesized by the reactions of R2SnCl2 (R=n‐Bu, Ph) with HO2PPh2 in Methanol. From the reaction of Ph2SnCl2 with diphenylphosphinic acid a third product [PhClSn(O2PPh2)OMe]2 ( 3 ) could be isolated. X‐ray diffraction studies show 1 to crystallize in the monoclinic space group P21/c with a = 1303.7(1) pm, b = 2286.9(2) pm, c = 1063.1(1) pm, β = 94.383(6)°, and Z = 4. 2 crystallizes triclinic in the space group , the cell parameters being a = 1293.2(2) pm, b = 1478.5(4) pm, c = 1507.2(3) pm, α = 98.86(3)°, β = 109.63(2)°, γ = 114.88(2)°, and Z = 2. Both compounds form arrays of eight‐membered rings (SnOPO)2 linked at the tin atoms to form chains of infinite length. The dimer 3 consists of a like ring, in which the tin atoms are bridged by methoxo groups. It crystallizes triclinic in space group with a = 946.4(1) pm, b = 963.7(1) pm, c = 1174.2(1) pm, α = 82.495(6)°, β = 66.451(6)°, γ = 74.922(6)°, and Z = 1 for the dimer. The Raman spectra of 2 and 3 are given and discussed. 相似文献
20.
Photoionization Mass Spectra of SCl2, S2Cl2, and S2Br2 Photoionization mass spectra of SCl2, S2Cl2, and S2Br2 have been measured. Heats of formation, bond energies, and ionization potentials of fragments have been calculated from appearance potentials. 相似文献