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1.
1 INTRODUCTIONPolymolybdateanionshavebeenstudiedformanyyearsbecauseoftheirapplica tionincatalysischemistry〔1〕.Inthesynthesisoforganicpolymolybdatederivativesusingacetoneassolvent,wefoundthatthecondensationreactionofacetoneoccurredandthecondensationprod…  相似文献   

2.
<正> {Ni C(C4H9O)2PS2] (C12H8N2)2} [C(C4H9O)2PS2], Mr= 795. 60, Monocinic,P2,/n,a=16. 806(2), b=12. 720(2), c=21. 248(2) A. β=98. 454(7)°, V = 4493A3,Z=4,Dc= 1. 18g·cm-3,Mo Ka radiation,A=0. 71069A ,F(000) = 1664, R=0. 102 for 4154 reflections with I≥3σ(I).The crystal structure consists of complex cation {NiC(C4H9O)2PS2](C12H8N2)2}+ and complex anion C(C4H9O)2PS2]-. In the cation, nickel (Ⅱ) atom is coordinated by four nitrogen atoms and two sulfur atoms to form a distorted octahedron.  相似文献   

3.
SynthesisandStructureof[(C_2H_5)_4N][Mo_3(μ_3-O)(μ-Cl)_3(μ-CH_3CH_2COO)_3Cl_3]ZhuangHong-Hui;WuDing-Ming;HuangJian-Quan;HuangJin-L...  相似文献   

4.
[C_5H_7S_2]_2[(SbCl_3)_2S]的晶体结构   总被引:1,自引:1,他引:1  
[C_5H_7S_2]_2[(SbC1_3)_2S]的晶体结构采用x射线衍射法测定。晶体属于卑斜晶系,空间群C2/c,a=14.531(2),b=11.265(2),c=15.364(3),B=112.72(1)°,Z=4。在CAD-4四圆衍射仪上收集数据,用重原子法解出结构并经全矩阵最小二乘法修正。R=0.067。研究表明,该离子晶体中,[C_5H_7S_2]~+的C、S骨架具有平面构型,而[(SbCl_3)_2S]~(2-)的构型是:Sb原子周围形成缺位的准三角双锥构型,两个Sb准三角双锥通过共用S桥形成二聚体,∠Sb-S-Sb=98°,整个阴离子具有C_2对称性。  相似文献   

5.
胡宁海  徐吉庆 《结构化学》1991,10(2):117-120
<正> Fe_4S_4[SC(CH_3)_3]_4[(C1H_9)_2,Mr=1193. 23,tetragonal,142d,a = 23. 272(2), c= 13. 080(5) A ,V=7084(3) A3,Z=4,DC=1. 12g·cm-3,UUUU(MoKa) = 10. 8cm-1,F(000) = 2568,R=0. 058 for 1005 observed reflections. The cluster anion contains a cubane-type Fe4S4 core compressed along the 4 axis which is crystallographically imposed. Compared to other salts with different cations ,the core is subject to slight structural distortions in different crystalline environments and crystallographic symmetry of the anion is related to that of the cation.  相似文献   

6.
1INTRODUCTIONFromreactionsof[RuCl,(PPh,),jwithcloso-[B,,H,,j'-respectivelyinEtOH/CH,Cl,t'i,CH,COOH/THF"'andC,H,COOH/CH,Cl,">solution,itcanbefoundthatbothalcoholandorganicacidcanreplacehydrogenatomsinborane.Further-more,accordingtotheirdifferentreactiontime(3h,1OOhand113hrespectively),wecanknowthatalcoholismoreactivetoreplacehydrogenatomsinborane.NowinordertoconfirmthisrulefurtherweusePhCH(OH)COOH/(CH3)2CHOHsolutioninsteadofabove-mentionedsolutions.Newcompounds(I)and(II…  相似文献   

7.
1INTRODUCTIoNFerrocenecontainingtransitionmeta1complexeshasarousedtheinterestofchemistsbecauseofitsnovelstructureandproperties"',Huangetal[2'3isynthesizedsomechainandbridgeformcomplexesandstudiedtheirIRandCV.Linetal[4isyn-thesizedthecrystalof[(dppf)PdCl,jO.5[(CH3),COj(dppf=1,11-(diphenylphosphine)-ferrocene)anddeterminedthestructurebyX-raydiffraction.Inthisarticlewereportthesynthesisandcrystalstructureof[(dppf),Pd,(ll)(p-Cl),j[PF,j2.2EXPERIMENTAL2.1PreparationAsolutionofO.86mm…  相似文献   

8.
(C5H4CH3)3Ho和(C5H4CH3)2Ho(C5H5)与5-苯基四唑(HN4CPh)在THF中反应,得到复合产物[(C5H4CH3)2HoN4CPh]2·[(C5H4CH3)(C5H5)HoN4CPh]2,该晶体属三斜晶系,P1空间群,晶胞参数为a=9.386(3),b=13.071(3),c=16.571(2)A,a=86.90(1),β=74.61(2),γ=77.30(2)°,V=1912.2(8)A3,Z=1,Dc=1.602g/cm3,Mr=922.61,μ=41.92cm-1,F(000)=896,最终偏离因子R=0.041,Rw=0.056.晶体数据显示,在同一个晶胞里有两个组成不同的分子,每一个分子都是具有对称中心的四唑基桥二聚体结构,其桥环单元-HoN3HoN3-是平面型的。每个钬原子分别被两个茂基和3个四唑基氮原子配位,形成1个边桥变形四面体构型。  相似文献   

9.
ComplexationofMolybdenum(Ⅵ)withR-andS-malicAcid,TheCrystalStructureof(NH_4)_4[(MoO_2)_4O_3(R-mal)_2]·6H_2OZhouZhao-Hui;YanWen-Bi?..  相似文献   

10.
1 INTRODUCTION Azole derivatives, such as the derivatives of pyra- zole, imidazole, triazole including benzotriazole, te- trazole and indole, have extensive biological activi- ties. They have become the central focus of studies of agricultural chemicals, medicines, plant growth regulating agents and so on[1, 2]. Schiff bases also constitute a good type of biologically active sub- structures. Studies on pyrazole Schiff base-type fun- gicides have been reported[3, 4]. However, some struc- …  相似文献   

11.
1INTRODUCTIONIntherecentyears,organolanthanideamideshaveattractedagreatdealofat-tention.Forexample,theyareabletoreactwithCOtogiveinsertionproduct[(C,Me,)2SinjZt(PhN)OCCO(NPh)jti},withaminoolefinstoyieldcorrespondingheterocyclestZ),withmethylmethacrylate(MMA)toleadtoMMApolymeriza-tiont3'43.Inordertoexplorefurthertheirchemistry,wesynthesizedsomeanionicandneutrallanthanoceneamidestoinvestigatetheirchemicalreactivities(5--7).Inthispaper,wewouldliketodescribethepreparationofanotheranio…  相似文献   

12.
<正> The title compound has been synthesized by the reaction of (Bu4N)2MoS4, CuCl and (C6H5CS2)(Bu4N) in DMF and recrystallized from DMF/ Et2O. The red black crystal belongs to the triclinic space group P1 with a = 12. 021 (6), b = 17.045(8), c=17. 136(7)(?) , α=110.05(3), β=108.64(4), γ=103.87 (4)°, V = 2873(3)(?)3, Dc=1. 321gcm-3, Z = 2. The structure was refined to R = 0. 065 for .4783 reflections. The anion of the title compound can be described as a MoS42- tetrahedron coordinated by two [Cu(C6H5CS2)] units with the three metal atoms lying on a line. The coordination number of each Cu atom is three.  相似文献   

13.
A novel coordination polymer [(C10H16N)2(Pb2I6)·2DMF·H2O]n (C10H16N=N-butyl-2-Methy-Pyridinium) was synthesized by the reaction of Pb(NO3)2 with C6H10NI at room temperature in DMF solvent and structurally characterized by means of X-ray single diffraction. The title compound crystallizes in triclinic system, space group P1 with a=1.1237(2) nm, b=1.25330(16) nm, c=0.808 00(12) nm, α=102.523(4)°, β=92.475(5)°, γ=95.712(10)°, V=1.102 9(3) nm3, Z=1, Dc=2.470 Mg·m-3, F(000)=738, chemical formula C26H48N4O3Pb2I6 and Mr=1 640.46, μ(Mo)=11.849 mm-1, the final R=0.057 8 and wR=0.166 5 for 3716 observed reflections with I > 2σ(I). The title compound consists of cations ([(C10H16N)+] and anion chain(PbI3-),they are combined by static attracting forces in the crystal. DMF and H2O locate between the organic and inorganic moiety. CCDC: 210812.  相似文献   

14.
The title compound,C 12 N 2 O 4 H 14 (M r=250.3),crystallizes in triclinic P1 space group with a=7.7709(9),b=8.7534(11),c=9.6958(12),α=77.103(2),β=80.496(2),γ=86.726(2)o,V=633.9(1) 3,Z=2,F(000)=264,D c=1.311 Mg/m 3,μ(MoKα)=0.1 mm-1,the final R=0.056,and wR=0.15 for 2239 observed reflections (I > 2σ(Ⅰ)).The molecules in the crystal are linked through O-H···O type of hydrogen bonding interaction forming an infinite chainlike structure.The phenylhydrazone ring and oxobutanoate groups are almost planar.The keto hydrazo group adopts a Z-configuration in the molecule and the torsion angle is-177.6(2)°.  相似文献   

15.
<正> The title compound was synthesized and its structure solved. The formula is [Et4N]3[Fe3(SPh)3Br3Cl3]. M=1231.95, monoclinic, space group C2/c, a=24.569(4), b=13.504(2), c=18.348.(3)A, β=110.78(1)°, V=5691(3)A3, Z=4, Dm= 1.41, Dc=1.44-g/cm3. The flat structure of the anion has. a planar [Fe3S3] ring and three phenyl groups. Statistical distribution of chlorine and bromine atoms on two sides of the [Fe3S3] plane results in a C2 symmetry of the anion.  相似文献   

16.
<正> The title compounds were prepared from the reation of (NH4)2MS4 (M=W,Mo),AgNO3,NadtcEt2 and Et4NBr in CH3CN-H2O solution. The isomorphous compounds [Bu4N]2[W2Ag3S8Et2du] ( I ) and [Bu4N]2[Mo2Ag3S8Et2dtc] (Ⅱ) crystallize in triclinic space qroup Pi with the following crystal parameters:α=13. 043(4),b = 21. 640(6),c=10. 757(6)A ,α=95. 09(5),β = 91. 90(4),γ = 98. 57(3)°,Z = 2,V = 2987A3,Dc=1. 76g/cm3 for I 5;a= 12. 989(2) ,b=21. 574 (9) ,c= 10. 7/1(1) A .α= 95. 06(7), β=91. 61(4), γ=98. 52(2)°, Z = 2,V = 2961 A3.Dc= 1. 58g/cm3 for Ⅱ . The final R and Rw values are 0. 061 and 0. 072 for Ⅰ ,and 0. 062 and 0. 076 for Ⅱ The M2Ag3 (M = W, Mo) unit in anion M2Ag3S8Et2dtc forms a five-membered ring.  相似文献   

17.
<正> Crystal of the title complex [(n-C4H9)4N]3[Mo6O18(N2C6H3-2,4-(NO2)2](Mr= 1710. 5) is orthorhombic with space group P21cn (Pna21), a = 17. 304(3), b = 17.580(2), c=24. 355(4) (?), V = 7409(2)(?)3, Z = 4, Dc=1. 60g/ cm3, μ=10. 29cm-1, F (000) = 3647. The structural solutions and refinements based on 3900 reflections (I≥3σ(I)) converged at R = 0. 0575, Rw =0. 0498. The atoms of Mo(3), Mo(4), O(1), O(5), O(9), O(11) and the [N2C6H3-2,4-(NO2)2] unit in the complex anion locate approximately in a plane about which the complex anion is nearly symmetrical.  相似文献   

18.
1INTRODUCTIONThepseudoliquidcharacterofheteropolycompoundsascatalystisdeterminedbytheircrystallographicproperties"3.Thedeterminationofthecrystalstructureofhet-eropolycompoundhasbecomeanimportantmethodtocharacterizeandidentifythesecompounds,atthesametimeitalsoprovidesinterestinginformationtoenrichhet-eropolyacidandcatalyticchemistry.Inthispaper,wereportthesynthesisandcrys-talstructureof[(CH,).Nj.H,[ZnW,,SnO,,j.gH,O.2EXPERIMENTAL2.1SynthesisNa,WO..ZH,O(18.2g,55mmol)wasdissolvedin…  相似文献   

19.
<正> C12H16N2O5S, Mr = 300. 34, monbclinic, P21, a = 12. 748(4), b = 5. 240(1), c=21. 356(4)(?); β=93. 28(2)°, V = 1428. 1(7) (?)3. Z = 4, Dc = 1. 397gcm-3, λ=0. 71073(?). Full matrix least-squares refinement, final R = 0. 042, Rw = 0. 045 for 2050 unique reflexions with I≥3σ(I). The two molecules in the asymmetric unit are connected by two hydrogen bonds to form a dimer.  相似文献   

20.
<正> [YC12(THF)5][YC14(THF)2], MT = 895. 2, monoclinic, space group C2/c, a = 12. 568(4), b = 11. 538(3), c=27. 354(3)A,β=91. 46(2)°, V = 3965. 3A3, Z = 4, Dc= 1. 500gcm-3,λ(MoKa) = 0. 71073A , F(000) = 3680, R = 0. 057 for 1663 observed reflections. The average Cl-O distance is 2. 570 A in the cation, 2. 607A in the anion. The average Y-O distance of 2. 391A in the cation is slightly longer than that of 2. 318 A in the anion.  相似文献   

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