共查询到19条相似文献,搜索用时 173 毫秒
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微量热法研究黄嘌呤氧化酶反应 总被引:2,自引:0,他引:2
在热导工热量计双参数理论模型的基础上,建立了较快酶仲反应研究的双参数初始速度法的热动力学模型,用微量热法研究了黄嘌呤氧化酶催化氧化黄嘌呤的热动力学,该较快酶促反应遵循Michaelis-Menten这,在298.15K和PH=7.5时,其米氏常数为1.04×10^-3mol.L^-1,与文献结果相符。 相似文献
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本文建立了2-Ⅰ型可逆反应的热动力学对比进度方程和热动力学模型。用热导式自动热量计研究了一个2-Ⅰ型吸热反应体系,并对结果进行了讨论。 相似文献
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Cheng S.-Q. Huang Z. Meng X.-G. Zeng X.-C. 《Journal of Thermal Analysis and Calorimetry》2000,63(2):415-421
This paper presents a novel data processing method for thermokinetics of faster first-order reaction on the basis of the double-parameter
theoretical model of a conduction calorimeter, in which the rate constant of a first-order reaction can be calculated from
only four peak height data from the same thermoanalytical curve without using any peak-area. The saponifications of ethyl
acetate and methyl acetate in aqueous solution and ethyl benzoate in aqueous alcohol have been studied to test the validity
of this method. The rate constants calculated with this method are in fair agreement with those in literature; hence the validity
of this method is demonstrated.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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Chen Y. Xie J. Q. Zhang B. Zeng X. C. 《Journal of Thermal Analysis and Calorimetry》2004,75(3):847-855
A novel thermokinetic research method for determination of rate constants of simple-order reaction in batch conduction calorimeter
under isothermal condition, the characteristic parameter method, is proposed in this paper. Only needing the characteristic
time parameter tm obtained from the measured thermoanalytical curve, the kinetic parameters of reactions studied can be calculated
conveniently with this method. The saponifications of ethyl propionate and ethyl acetate in aqueous ethanol solvent, the polymerization
of acrylamide in aqueous solution, the ring opening reaction of epichlorohydrin with hydrobromic acid have been studied. The
experimental results indicate that the characteristic parameter method for simple-order reaction is correct.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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根据化学反应动力学和热动力学基本理论, 建立了简单级数反应的热动力学对比参量方程, 提出了一种新的热动力学研究法--对比参量法. 利用该法可以从一张热谱图上同时解析出化学反应的速率常数、半衰期和热动力学体系的冷却常数. 实验结果验证了方法的正确性. 相似文献
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热导式热量计特征热谱方程的建立 总被引:1,自引:0,他引:1
Based on the interfacial model of a conduction calorimeter, a characteristic thermogram equation is suggested in this paper. Measurements of only two quantities such as the maximum peak height △m and its time tm, enables us to calculate the peak height at any interval by using this model. Thermograms of alkaline hydrolysis of ethyl propionate and ethyl acetate have been measured at 25℃, respectively. The themographic data calculated by using the characteristic thermogram equation are in reasonable agreement with those read from the thermograms. 相似文献
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Characteristic parameter method for studying kinetics of opposing reactions in calorimeter 总被引:1,自引:0,他引:1
According to the theoretical basis of thermokinetics, the integral and differential thermokinetic equations of opposing reactions have been derived, and a novel thermokinetic research method, the characteristic parameter method for opposing reactions which taking place in a batch conduction calorimeter under isothermal condition, has been proposed in this paper. Only needing the characteristic thermoanalytical data corresponding to tm and 2tm from the same curve, the rate constants of forward and backward reactions and equilibrium constant can be calculated simultaneously with this method. In order to test the validity of this method, the proton-transfer reactions of nitroethane with ammonia at 15 and 25°C, and with trihydroxymethyl aminomethane (Tris) at 15 and 30°C have been studied, respectively. The results of rate constants and equilibrium constants calculated with this method are in agreement with those in the literature. Therefore, the characteristic parameter method for opposing reaction is believed to be correct.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
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The kinetic investigation of thermoanalytical curves for the ethyl acetate and alkaline hydrolysis, requires tedious calculations of several mathematical expressions, to establish the correlation between the thermochemical and kinetic parameters. Using the DSC measured data for the heat flow-temperature dependence of the studied reactions, we have obtained the kinetic bulk parameters and the dependencek=k(T) for the basic and acid hydrolysis of ethyl acetate. 相似文献
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Y.-Q. Zhang X.-C. Zeng Y. Chen X.-G. Meng A.-M. Tian 《Journal of Thermal Analysis and Calorimetry》1999,58(2):463-475
On the basis of the theory of thermokinetics proposed in the literature, a novel thermokinetic method for determination of the reaction rate, the characteristic parameter method, is proposed in this paper. Mathematical models were established to determine the kinetic parameters and rate constants. In order to test the validity of this method, the saponifications of ethyl benzoate, ethyl acetate and ethyl propionate, and the formation of hexamethylenetetramine were studied with this method. The rate constants calculated with this method are in agreement with those in the literature, and the characteristic parameter method is therefore believed to be correct.In the light of the characteristic parameter method, we have developed further two thermo-kinetic methods, the thermoanalytical single and multi-curve methods, which are convenient for simultaneous determination of the reaction order and the rate constant. The reaction orders and rate constants of the saponifications of ethyl acetate and ethyl butyrate and the ring-opening reaction of epichlorohydrin with hydrobromic acid were determined with these methods, and their validity was verified by the experimental results.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献