共查询到19条相似文献,搜索用时 62 毫秒
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在Dirac-Slater相对论理论框架下,研究了HCI(高离化态离子)的基本性质及其光电离过程的基本特征. 通常HCI的电场非常强,其电子波函数沿靠近核的径向空间被压缩,这极大地改变了相应的物质的性质,使HCI的光电离过程与一般的原子(离子)的相比较有很大的不同:原子核的尺寸效应和相对论效应变得更加重要,而多极效应对光电离截面的影响却趋于减弱. 相似文献
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在Dirac-Slater相对论理论框架下,研究了HCI(高离化态离子)的基本性质及其光电离过程的基本特征.通常HCI的电场非常强,其电子波函数沿靠近核的径向空间被压缩,这极大地改变了相应的物质的性质,使HCI的光电离过程与一般的原子(离子)的相比较有很大的不同:原子核的尺寸效应和相对论效应变得更加重要,而多极效应对光电离截面的影响却趋于减弱. 相似文献
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在考虑组态相互作用的基础上,利用包含相对论修正的Hartree-Fock(HFR)理论对S8+-S13+离子的谱线波长及加权振子强度等有关原子参数进行了系统计算,并与最新的实验观测和其它理论计算结果进行了比较。计算结果表明:S8+-S11+的各个原子态在LS耦合下纯度很高,随着离化度的增大,S12+和S13+离子的部分原子态能级出现混合,组态相互作用逐渐增强。通过对实验结果的分析,识别出32条实验谱线,其中大多数谱线来自S8+-S13+离子的2s22pk-2s2pk+1和2s2pk+1-2s2pk+2(k=0,1,2,3,4)之间的跃迁,理论计算结果与实验谱线波长之间的绝对误差大多数都在实验的有效分辨力以内。 相似文献
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高离化态氖的类H、类He离子激发光谱的研究 总被引:1,自引:0,他引:1
利用束箔技术研究由重离子加速器提供的47MeV能量的Ne离子,穿过厚度为39μg/cm2的碳箔而产生高离化态类H(NeX)、类He(NeⅨ)离子激发谱的情况。 相似文献
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在加速器上利用束箔光谱方法,测量了Ti离子的高电离态光谱。 相似文献
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报道用 15 0keV的高电荷态离子1 2 6 Xeq + (6≤q≤ 30 )轰击Ti固体表面产生 2 0 0— 10 0 0nm波段发射光谱的实验结果 .结果显示 ,用电荷态足够高的离子作光谱激发源 ,无需很强的束流强度 (nA量级 ) ,便可激发起样品表面的原子和离子在可见光波段的特征谱线 .当入射离子剥离度q >qc≈ 2 0时 ,Ti原子及其离子的特征谱线强度突然显著增强 ;不同金属靶 ,特征谱线突然增强的qc值不同 .理论分析表明 ,这与q大于此临界值后 ,单电子转移释放能量激发靶材料传导电子气体的表面等离激元密切相关 . 相似文献
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An analysis is presented of the extremum properties of energy functionals for the excited states of many-electron systems, in particular, atoms, in the case when there exist low-lying states of the same symmetry as the excited state under consideration. Two theorems are proved concerning the relationship between the upper bound on the eigenvalues corresponding to the excited states and the extremum properties of the energy functional determined by variational test functions which depend on parameters. In this context, different variants of the one-electron approximation used in the excited-state calculations are considered: the method of obtaining self-consistent solutions with one-electron functions orthogonal within the configurations (the Hartree-Fock method for configurations); the frozen atomic core approximation for the excited configuration; the method of nonorthogonal orbitals in the excited configuration; and the approximation of the frozen ionic core. Cases are identified and reasons given for the possible collapse of the excited state energy level to an unjustifiably low value of the energy.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 18–33, August, 1990. 相似文献
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M. Cacciatore M. Capitelli 《Journal of Quantitative Spectroscopy & Radiative Transfer》1976,16(4):325-334
Population densities of transient oxygen plasmas have been calculated solving a system of differential equations, which describes the temporal evolution of the considered quantum levels. The results, which refer to a temperature of 1 eV and to electron number densities ranging from 108 to 1014 cm-3, show the strong importance of the metastable 3s5S state in determining the evolution of these plasmas. The present results are then applied to the calculation of relaxation times of selected quantum levels and to the definition of quasistationary conditions of plasmas having low lying excited states (i.e. states belonging to the same principal quantum number as the ground state). 相似文献
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Ambartzumian R. V. Furzikov N. P. Letokhov V. S. Puretsky A. A. 《Applied Physics A: Materials Science & Processing》1976,9(4):335-337
A new method of photoionization cross-section measurement based on the observation of saturation in the ion yield as a function
of radiation intensity has been proposed. The photoionization cross-sections for the 62P1/2 and 62P3/2 levels of Rb atoms of the fundamental and second harmonics of ruby laser radiation are measured, with a tunable pulsed dye
laser used for excitation. The following values of cross-sections are obtained: (1.7±0.4)·10−17 cm2 and (1.5±0.4)·10−17 cm2 for the levels 62P3/2 and 62P1/2, respectively, ionized by radiation of v2=14403 cm−1, and (1.9±0.5)·10−17 cm2 for the 62P3/2 level ionized by v2=28806 cm−1 radiation. 相似文献
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采用双色三步激发和光电离过程,对Sm原子的偶宇称高激发态的光谱进行了研究.先采用两条激发路线分别将Sm原子两步共振激发至待测的高激发态,然后利用光电离技术对其进行探测.分别将第一束激光的波长固定在627.50nm和624.41nm上,以便将Sm原子从亚稳态共振激发到由4f66s6p电子组态所构成的两个原子状态上.第二束激光在440-700nm的波段范围内扫描,不仅使Sm原子在30040-38065cm-1能域内的偶宇称高激发态上布居,将其进一步光电离,测量了其光谱.通过光谱定标和选择定则等分析手段,本工作不仅精确获得了136个态的能级位置,而且也唯一确定了其总角动量,并且给出了相关跃迁的相对谱线强度. 相似文献
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James A.R. Samson V.E. Petrosky 《Journal of Electron Spectroscopy and Related Phenomena》1974,3(6):461-465
The Rydberg states 3d′ 3P2,o1, 0 and 3s″ 3P2,o1, 0 and the inter-shell transition 2sp53P2,01, 0, which are forbidden to autoionize on the basis of LS coupling, have been observed in emission spectroscopy and in autoionization spectra produced in the photoelectron spectrum of atomic oxygen. 相似文献
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A one-configuration approximation is used to analyze the possibility of employing the frozen ion core model to calculate excited states with low-lying configurations of the same symmetry when the wave functions of the excited states are orthogonal to the function of the ground state. The nonorthogonality of the wave functions of different excited configurations is then weak. A calculation is made for certain Isns1S and 1s22sns1S terms of two-and four-electron ions, respectively, and the relaxation effects in the core are investigated for these excited states. This approximation is employed to obtain a variational equation for virtual orbitals allowing for the core relaxation.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 71–77, June, 1980. 相似文献
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Transitions from autoionizing states in the spectrum of Sn IV in the range 200–630 Å, occurring due to the excitation of electrons from the inner 4d 10 shell, are investigated with high resolution. The transitions from the 4d 95p 2, 4d 95s6p, and 4d 95snf (up to n = 9) configurations are identified and their autoionization widths are measured. Transitions from the highly excited 4d 10 ns (n = 8–10), 4d 106p, and 4d 107d configurations are also revealed and the ionization potential of Sn IV is refined. The data obtained are compared with the results of calculations by the Hartree-Fock and semiempirical methods. 相似文献
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V. I. Yakovleva V. E. Yakhontova A. B. Tsyganov I. E. Kozlov 《Optics and Spectroscopy》2003,95(4):511-514
The processes of population of excited levels of a krypton atomic ion via electron-stimulated desorption are studied. The radiation yield per single exciting electron in the corresponding krypton spectral lines is measured by the optical time-of-flight mass spectrometric method. The efficiency of the processes studied is compared with that of electron-impact excitation of the same levels. 相似文献