Sub-wavelength micromachining of silica glass by irradiation of CO<Subscript>2</Subscript> laser with Fresnel diffraction

We investigated a simple and productive micromachining method of silica glass by ablation using a TEA CO₂ laser (10.6 μm) with a spatial resolution down to sub-wavelength scale. The silica glass was irradiated by the TEA CO₂ laser light through a copper grid mask with square apertures of 20×20 μm² attached to the silica glass surface. After the irradiation, circular holes with a diameter of several μm were formed on the silica glass surface at the centers of the apertures due to the Fresnel diffraction effect. The minimum diameter of the holes was 3.4 μm. The characteristics of the micromachining are discussed based on the electric field distributions of the CO₂ laser light under the mask using a three-dimensional full-wave electromagnetic field simulation.     

High-efficiency mid-infrared laser from synchronous optical parametric oscillation and amplification based on a single MgO:PPLN crystal

This paper presents a specially designed optical parametric oscillator (OPO) which achieved high-efficiency mid-infrared laser of 2.83 μm. The cascaded nonlinear interactions of OPO and optical parametric amplifier (OPA) were simultaneously realized in a single MgO:PPLN crystal. The signal oscillation of 1.70 μm was used to pump a secondary parametric process that resulted in amplification of the idler laser of 2.83 μm. When the MgO:PPLN crystal with a grating period of 31.2 μm was pumped by a 1.064 μm laser and operated at 148°C, the quasi-phase-matching of both OPO and OPA could be simultaneously achieved. Average output power of 7.68 W at 2.83 μm was obtained for 25 W of pump at 7 kHz. The power conversion efficiency of 2.83 μm laser was 30.7%, which was evidently higher than common OPOs.     

Direct writing of conductive silver micropatterns on flexible polyimide film by laser-induced pyrolysis of silver nanoparticle-dispersed film

This article describes fabrication of Ag micropatterns on a flexible polyimide (PI) film by laser direct writing using an Ag nanoparticle-dispersed film as a precursor. Ag micropatterns are characterized by optical microscopy, atomic force microscopy (AFM), field emission scanning electron microscopy (FE-SEM), surface profilometry, and resistivity measurements. The line width of Ag micropatterns can be effectively controlled by altering the experimental parameters of laser direct writing especially laser intensity, objective lens, and laser beam scanning speed etc. Using an objective lens of 100× and laser intensity of 170.50 kW/cm², Ag micropatterns with a line width of about 6 μm have been achieved. The Ag micropatterns show strong adhesion to polyimide surface as evaluated by Scotch-tape test. The resistivity of the Ag micropatterns is determined to be 4.1 × 10⁻⁶ Ω cm using two-point probe method. This value is comparable with the resistivity of bulk Ag (1.6 × 10⁻⁶ Ω cm).     

Rapid fabrication of optical volume gratings in Foturan glass by femtosecond laser micromachining

We report on rapid fabrication of optical volume gratings in Foturan glass using a modulated femtosecond laser focused with cylindrical lenses. An optical volume grating with an area of 2 mm ×3 mm and ∼2 mm thickness can be achieved within 10 min by use of this method. Optical micrography confirms the volume nature of the gratings and shows that they consist of 10 μm-thickness planes with a period of 15 μm. The diffraction efficiency is examined to be ∼56%. The limitations and future implementations of the fabricated volume gratings are discussed.     

Modelling of a simple Dy<Superscript>3+</Superscript> doped chalcogenide glass fibre laser for mid-infrared light generation

A simple Dy³⁺-doped chalcogenide glass fibre laser design for mid-infrared light generation is studied using a one dimensional rate equation model. The fibre laser design employs the concept of cascade lasing. The results obtained demonstrate that efficient cascade lasing may be achieved in practice without the need for fibre grating fabrication, as a sufficient level of feedback for laser action is provided by Fresnel light reflection at chalcogenide glass fibre–air interfaces. Further enhancement of the laser efficiency can be achieved by terminating one of the fibre ends with a mirror. A numerical analysis of the effect of the Dy³⁺ doping concentration and fibre loss on the laser operation shows that with 5 W of pump power, at 1.71 μm wavelength, output powers above 100 mW at ∼ 4.5 μm wavelength can be achieved with Dy³⁺ ion concentrations as low as 3 × 10¹⁹ cm⁻³, when fibre loss is of the order 1dB/m.     

Occupational and consumer risk estimates for nanoparticles emitted by laser printers

Several studies have reported laser printers as significant sources of nanosized particles (<0.1 μm). Laser printers are used occupationally in office environments and by consumers in their homes. The current work combines existing epidemiological and toxicological evidence on particle-related health effects, measuring doses as mass, particle number and surface area, to estimate and compare the potential risks in occupational and consumer exposure scenarios related to the use of laser printers. The daily uptake of laser printer particles was estimated based on measured particle size distributions and lung deposition modelling. The obtained daily uptakes (particle mass 0.15–0.44 μg d⁻¹; particle number 1.1–3.1 × 10⁹ d⁻¹) were estimated to correspond to 4–13 (mass) or 12–34 (number) deaths per million persons exposed on the basis of epidemiological risk estimates for ambient particles. These risks are higher than the generally used definition of acceptable risk of 1 × 10⁻⁶, but substantially lower than the estimated risks due to ambient particles. Toxicological studies on ambient particles revealed consistent values for lowest observed effect levels (LOELs) which were converted into equivalent daily uptakes using allometric scaling. These LOEL uptakes were by a factor of about 330–1,000 (mass) and 1,000–2,500 (particle surface area) higher than estimated uptakes from printers. This toxicological assessment would indicate no significant health risks due to printer particles. Finally, our study suggests that particle number (not mass) and mass (not surface area) are the most conservative risk metrics for the epidemiological and toxicological risks presented here, respectively.     

Pulsed holmium laser ablation of tissue phantoms: correlation between bubble formation and acoustic transients

5 Pa served as tissue phantoms to evaluate such effects. Holmium laser pulses (wavelength: 2.12 μm, duration: 180 μs FWHM), were delivered through 400 and 600 μm diameter optical fibers inserted into cubes of clear gel. Bubble effects were investigated using simultaneous flash micro-videography and pressure recording for radiant exposures of 20–382 J/cm². Bubble formation and bubble collapse induced pressure transients were observed regardless of phantom stiffness. Bubbles of up to 4.2 mm in length were observed in gels with a Young’s modulus of 2.9×10⁵ Pa at a pulse energy of 650 mJ. An increase of Young’s modulus (reduction in water content) led to a monotonic reduction of bubble size. In the softest gels, bubble dimensions exceeded those observed in water. Pressure amplitudes at 3 mm decreased from 100±14 bars to 17±6 bars with increasing Young’s modulus over the studied range. Theoretical analysis suggested a major influence on bubble dynamics of the mass and energy transfer through the bubble boundary. Received: 26 August 1996/Revised version: 10 February 1997     

Table-top kHz hard X-ray source with ultrashort pulse duration for time-resolved X-ray diffraction

The interaction of ultrashort laser pulses with solid state targets is studied concerning the production of short X-ray pulses with photon energies up to about 10 keV. The influence of various parameters such as pulse energy, repetition rate of the laser system, focusing conditions, the application of prepulses, and the chirp of the laser pulses on the efficiency of this highly nonlinear process is examined. In order to increase the X-ray flux, the laser pulse energy is increased by a 2nd multipass amplifier from 750 μJ to 5 mJ. By applying up to 4 mJ of the pulse energy a X-ray flux of 4×10¹⁰ Fe K _α photons/s or 2.75×10¹⁰ Cu K _α photons/s are generated. The energy conversion efficiency is therefore calculated to η _Fe≈1.4×10⁻⁵ and η _Cu≈1.0×10⁻⁵. The X-ray source size is determined to 15×25 μm². By focusing the produced X-rays using a toroidally bent crystal a quasi-monochromatic X-ray point source with a diameter of 56 μm×70μm is produced containing ≈10⁴ Fe K _α1 photons/s which permits the investigation of lattice dynamics on a picosecond or even sub-picosecond time scale. The lattice movement of a GaAs(111) crystal is shown as a typical application.     

The Analysis of Scattering Effect for the Transmission of 1.06?μm Laser In Lower Altitude Atmosphere

On the basis of Mie’s scattering theory, the light scattering properties of atmospheric molecules and aerosol particles are analyzed and a forward-scattering model for atmospheric transmission in city outskirts is built. Through theoretical analysis and the numerical calculations to the irradiance distribution of the 1.06 μm pulse laser while transmitting in lower altitude atmosphere, we can draw some conclusions which provide usable information for the research and manufacture of off-axis scattering warning systems.     

Infrared steam laser cleaning

Steam Laser Cleaning with a pulsed infrared laser source is investigated. The infrared light is tuned to the absorption maximum of water (λ=2.94 μm, 10 ns), whereas the substrates used are transparent (glass, silicon). Thus a thin liquid water layer condensed on top of the contaminated substrate is rapidly heated. The pressure generated during the subsequent phase explosion generates a cleaning force which exceeds the adhesion of the particles. We examine the cleaning threshold in single shot experiments for particles sized from 1 μm down to 300 nm.     

Large-format fabrication by two-photon polymerization in SU-8

Microporous structures are central to many fields of science and engineering, but many of these systems are complex with little or no symmetry and are difficult to fabricate. We applied two-photon polymerization (2PP) and femtosecond laser direct-writing techniques to fabricate broad-area large-format 3D microporous structures (450 μm × 450 μm × 40 μm) in the epoxy-based photoresist SU-8. The appropriate exposure was determined by controlling average pulse energies and stage speeds to generate the exposure curves. Mechanical distortion exhibited in suspended walls fabricated by 2PP laser writing was studied by controlling wall lengths and widths. A simple thermal-expansion model is presented to explain the distortion caused by axial loadings of the walls.     

Amplification assisted optical parametric oscillator in the mid-infrared region

We demonstrate a high efficiency mid-infrared laser source based on optical parametric oscillator (OPO) assisted by an intracavity optical parametric amplification (OPA). The OPA-assisted-OPO scheme was realized in one piece of commensurable dual-periodic superlattice in which the signal light generated from the OPO process serves as the pump light for the OPA process. A maximum output power of 508 mW at 3.92 μm was achieved under a pump power of 2.85 W at 1.064 μm. The pump-to-idler conversion efficiency is 17.8% and the slope efficiency is 23.8%, and the enhancements of them are 58.9% and 67.6%, respectively, comparing with the standard OPO scheme.     

Near IR laser light visualizators using nonlinear GaSe and other layered crystallites

Two methods of preparation of the devices for visualization of pulsed and continuous near-IR (near infrared) are described and the results of conversion of pulsed and continuous IR (800–1360 nm) laser radiation into the visible range of spectra (400–680 nm) by using a transparent substrate covered with the particles (including nanoparticles) of effective nonlinear materials of GaSe _x S_{1 − x} (0.2 ≤ x ≤ 0.8) are presented. Converted light can be detected in transmission or reflection geometry as a visible spot corresponding to the real size of the incident laser beam. Developed device structures can be used for checking if the laser is working or not, for optical adjustment, for visualization of distribution of laser radiation over the cross of the beam and for investigation of the content of the laser radiation. Low energy (power density) limit for visualization of the IR laser pulses with 2–3 ps duration for these device structures are: between 4.6–2.1 μJ (3 × 10⁻⁴−1 × 10⁻⁴ W/cm²) at 1200 nm; between 8.4–2.6 μJ (4.7 × 10⁻⁴−1.5 × 10⁻⁴ W/cm²) at 1300 nm; between 14.4–8.1 μJ (8.2 × 10⁻⁴–4.6 × 10⁻⁴ W/cm²) at 1360 nm. Threshold damage density is more than 10 MW/cm² at λ = 1060 nm, pulse duration τ = 35 ps. The results are compared with commercially existing laser light visualizators.     

Stabilization method of an infrared two-wavelength laser

A simple method for stabilizing a He-Xe laser, which simultaneously operates at two wavelengths of 3.51 μm and 3.37 μm, is described. This stabilization method depends on the comparison of the light intensities of the two wavelengths, and has a possibility of realizing a stability of better than 1×10⁻⁸ with unmodulated output.     

Quantification of glucose levels in flowing blood using M-mode swept source optical coherence tomography

The increase of glucose levels in blood changes the viscosity of flowing fluids and shape of the erythrocytes. Both of these can affect the details of light scattering as can be quantified via decorrelation times measured by optical coherence tomography (OCT). The relative contributions of these competing effects have been studied by examining the motion dynamics of deformable asymmetrical (red blood cells, RBCs with ∼7 μm diameter and ∼2 μm thickness) and non deformable symmetrical (polystyrene microspheres, PSM with 1.4 μm diameter) flowing scattering particles. The fluid flow under the action of gravity was modulated by changing the glucose concentrations. Quantitative analysis of the OCT’s M-mode autocorrelation functions enabled the derivations of the translational diffusion coefficients. These systematic studies are aimed at eventual tissue imaging scenarios with speckle-variance OCT to obtain local glucose concentrations maps.     

Characterization of particulates accompanying laser ablation of pressed polytetrafluorethylene (PTFE) targets

We present observations of sub-micron- to micron-sized particles generated by high fluence (≈2 J/cm²) 248-nm laser ablation of pressed polytetrafluorethylene (PTFE) targets in air at atmospheric pressure. The original target material was hydrostatically compressed ≈7 μm PTFE powder, sintered at 275 °C. Collected ejecta due to laser irradiation consists of four basic particle morphologies ranging from small particles 50–200 nm in diameter to larger particles ≈10 μm in diameter. Many particles formed in air carry electric charge. Using charged electrodes we are able to collect charged particles to determine relative numbers of ± charge. We observe roughly equal numbers of positively and negatively charged particles except for the largest particles which were predominantly negative. For a range of particle sizes we are able to measure the sign and magnitude of this charge with a Millikan-oil-drop technique and determine surface charge densities. The implications of these observations with respect to pulsed laser deposition of PTFE thin films and coatings are discussed. Received: 15 January 1999 / Accepted: 18 January 1999 / Published online: 7 April 1999     

Effect of the uncertainty of the shape of a distribution on its parameters retrieval using the scattering matrix of quartz suspension

Scattering matrices of an aqueous suspension of quartz were measured at a wavelength of 0.63 μm in the scattering angle range of 10°–150°. The angular dependences of matrix elements were measured with a laser polarimeter the optical scheme of which contained two electro-optical modulators. The results of measurements were compared with the data of calculation for scatterers having the shape of prolate ellipsoids. It was shown that, under conditions of wide distribution of particles by size and at a dimensional parameter value of 2.1, the uncertainty of the shape of the distribution leads to an increase in the error of the retrieval of the parameters of the suspension particle distribution.     

Physical characteristics of polyimide films for flexible sensors

Physical characteristics of polyimide films, including optical, micro/nano mechanical, and thermophysical characteristics were investigated using a photometric, a nanoindentation, and a thermomechanical analyzer for applications in flexible sensors. Experimental results show that UV light cannot transmit into the polyimide films. The transmittances, with a maximum of about 86%, at VIS and near IR lights decrease with increasing PI film thicknesses. The mechanical characteristics were determined using tensile, bending moment, and nanoindentation testing. The stress–strain curve approximated bilinear characteristics, the load–unload bending moment exhibited hysteresis, and nanoindentation generated elastic energy dissipation in the loading–unloading region. Nanoindentation showed an almost uniform hardness and a reduced Young’s modulus of about 0.181±0.03 and 3.21±0.06 GPa, respectively, when the penetrating depth was more than about 2 μm. Thermophysical characteristics were greatly influenced on 8.3 and 25 μm specimens due to the higher relaxation of thin PI films. The thermal expansion remained steady when the thickness was over 50 μm. The results show that PI films have potential in flexible sensing and higher temperature fabrication.     

Femtosecond fiber laser based methane optical clock

An optical clock based on an Er³⁺ fiber femtosecond laser and a two-mode He–Ne/CH₄ optical frequency standard (λ=3.39 μm) is realized. Difference-frequency generation is used to down convert the 1.5-μm frequency comb of the Er³⁺ femtosecond laser to the 3.4-μm range. The generated infrared comb overlaps with the He–Ne/CH₄ laser wavelength and does not depend on the carrier–envelope offset frequency of the 1.5-μm comb. In this way a direct phase-coherent connection between the optical frequency of the He–Ne/CH₄ standard and the radio frequency pulse repetition rate of the fiber laser is established. The stability of the optical clock is measured against a commercial hydrogen maser. The measured relative instability is 1×10⁻¹² at 1 s and for averaging times less than 50 s it is determined by the microwave standard, while for longer times a drift of the He–Ne/CH₄ optical standard is dominant.     

Analysis of optical crosstalk within optoelectronic integrated circuits including lasers and photodetectors

Optical crosstalk from a 1.3 μm laser to a 1.55 μm photodiode on a single InP substrate, and its suppression within 1.3 μm/1.5 μm Y-junction transceiver OEICs, has been analyzed experimentally. The results indicate that the optical crosstalk suppression is limited by the accumulated light in the OEIC substrate coming mainly from the spontaneous emission of the integrated laser and from stray light at the laser–waveguide butt joint interface. For OEICs, integrating lasers and photodetectors, the achievable optical intra-chip crosstalk at present will be in the range of 30–40 dB at the required small die dimensions. Received: 16 May 2001 / / Published online: 23 October 2001