共查询到20条相似文献,搜索用时 140 毫秒
1.
2.
在室温下测量了GdoBr:Eu的常压和高压荧光谱,光谱范围在13 000~21 500 cm-1之间,压力至12 GPa。由光谱数据得到了Eu3+晶场能级随压力的变化曲线。7F0~5能级随压力的变化规律比较复杂,而5D0~2各能均随压力的升高几乎线性地降低。在基态谱项7F的49个状态上进行了晶场拟合计算,所得常压下的5个非零晶场参数分别为:B02=-1 124.0 cm-1,B04=-969.6 cm-1,B44=827.9 cm-1,B06=889.6 cm-1,B46=377.0 cm-1。高压下的计算结果表明,B04、B06这两个晶场参数随压力的增加而增大,B46随压力的增加而减小,而B02、B44随压力的变化有些起伏。晶场强度在8 GPa以下随压力增加而减小,其后开始变强。 相似文献
3.
在1.0~4.0 GPa压力、1 073~1 573 K温度和10-1~107 Hz频率条件下,利用SARLTON-1260阻抗-增益/相位分析仪,就位测定了二辉橄榄岩的阻抗谱。实验结果表明:二辉橄榄岩的阻抗谱对频率具有很强的依赖性,并从阻抗谱的测试原理(颗粒内部、颗粒边缘、样品与电极间的导电机制)上做出了解释;温度是决定二辉橄榄岩电导率的一个重要物理参数,电导率随着温度的升高而增大,lg σ与1/T之间符合Arrenhius关系式;在高压实验中第一次将压力作为测量二辉橄榄岩电导率重要的约束因素,随着压力的增大,电阻率升高、电导率降低。 相似文献
4.
核物理研究室核化学组 《中国物理 C》1978,2(4)
在12C离子引起的209Bi和238U的裂变中,用放射化学方法分别测量了15个和17个裂变产物的产额.根据这些数据,用三种电荷分布假设计算了裂变碎片的质量分布.计算表明,等电荷位移假设得到的结果一般和裂变碎片高斯质量分布曲线拟合得最好.比较了209Bi(12C,f),238U(12C,f)以及我们较早测量得到的(197Au(12C,f)的质量分布曲线,指出当裂变参数Z2/A>37时,质量分布宽度随Z2/A的增加而迅速增加. 相似文献
5.
6.
7.
讨论了PDC材料烧结过程中钴在金刚石层中的固相扩散、钴液熔渗、两次钴高浓度峰的“波浪”式迁移过程中的运动规律及其作用机制,并根据实验观测的数据进行了有关计算。结果表明:在5.8 GPa、1 300 ℃条件下,钴的扩散系数D≈1.6×10-7 cm2/s,是一般常压及相同温度条件下钴固相扩散系数(3×10-10 cm2/s)和相同压力条件下钴的液相扩散系数(5×10-5 cm2/s)的中间值;对于粒度W≥10 μm的金刚石烧结体系,钴液熔渗作用时间非常短暂,略大于0.5 s,而对于W≤1 μm的超细金刚石烧结体系而言,钴熔渗作用时间为28 s,比粒度W≥10 μm的金刚石烧结要长得多;两次钴高浓度峰的迁移速度分别约为50 μm/s和100 μm/s。 相似文献
8.
9.
10.
采用压力光谱技术在低温下观测到了Mn2+离子的4T1→6A1跃迁,该谱线在Zn0.83Mn0.17Se和ZnSe/Zn0.84Mn0.16Se超晶格样品中有不同的压力行为,体材料中其压力系数为-42.4 peV/Pa,超晶格中为-29.5 peV/Pa。用晶体场理论计算得到体材料Zn0.83Mn0.17Se中Mn2+离子4T1→6A1谱线的压力系数为-38.3 peV/Pa,与实验结果基本一致。结合材料中发光峰积分强度随压力的变化关系进行分析,证实Mn2+离子的发光性质主要与其近邻的晶体场环境有关。 相似文献
11.
The electrochemical behaviour of polypyrrole films doped with dodecyl benzene sulfonate (PPy/DBS) in LiCl aqueous electrolytes has been investigated in order to find the electrolyte concentration suitable for the operation of PPy/DBS-based soft actuators. For this investigation, PPy/DBS films deposited on gold-coated quartz crystals by electropolymerization and simultaneous cyclic voltammetry and electrochemical quartz crystal microbalance techniques were used. During the first redox cycle, while large water movement is observed along with the counter ions in dilute electrolytes, such water transport in concentrated electrolytes is found to be very low. In dilute electrolytes, water molecules accompany counter ions as solvated molecules and due to osmotic effect. In concentrated electrolytes, water movement is less due to limited availability of free water as well as a smaller osmotic pressure difference. In highly concentrated aqueous electrolytes, the mass of the PPy/DBS film at the end of each redox cycle is found to drift, which can be controlled by changing the concentration of the electrolyte. The PPy/DBS films were also cycled at different scan rates in various alkali halide aqueous electrolytes of concentrations 0.1 and 1 M to determine the effective diffusion coefficients of alkali ions in the films. The effective diffusion coefficients were found to increase with the concentration of the electrolytes and decrease with the increase in size of cations. 相似文献
12.
Based on a glow discharge model of analytic form developed recently and by using the available data for the diffusion coefficients and mobilities of electrons and positive ions, the pressure effects on the spatial distribution of the electron density n have been systematically calculated and analyzed, The gas employed in the study was pure argon and the pressure range was from 0.1 to 1Torr. Theoretical results were found to be consistent with the experimental observations. 相似文献
13.
1引言在现代工业特别是化学工业和石油工业中,广泛涉及到物质传热过程。因此,作为表征物质热传导强弱的导热率是科研与生产必不可少的重要物性数据之一。作为物质导热率研究的一个方面,液体导热率的研究一直受到人们的关注。现在已有许多液体导热率关联方程发表,但这些方程往往适用范围较窄,是纯经验或半经验的,其理论性不强。只有Enskog公式*中各参数的物理意义明确,所以此公式的实际应用有待进一步研究。本文用热压代替znsx。g公式中的体系压力,其中热压用un状态方程回来计算,找出正构烷烃分子硬球直径的变化规律,对正构烷烃… 相似文献
14.
We present a method to calculate ionic conductivities of complex fluids from ab initio simulations. This is achieved by combining density functional theory molecular dynamics simulations with polarization theory. Conductivities are then obtained via a Green-Kubo formula using time-dependent effective charges of electronically screened ions. The method is applied to two different phases of warm dense water. We observe large fluctuations in the effective charges; protons can transport effective charges greater than +e for ultrashort time scales. Furthermore, we compare our results with a simpler model of ionic conductivity in water that is based on diffusion coefficients. Our approach can be directly applied to study ionic conductivities of electronically insulating materials of arbitrary composition, e.g., complex molecular mixtures under such extreme conditions that occur deep inside giant planets. 相似文献
15.
V. Klepko S. Ryabov Yu. Kercha L. Bulavin R. Bila V. Slisenko O. Vasilkevich V. Krotenko 《Journal of Molecular Liquids》2005,120(1-3):67-69
Water molecule mobility in ion-containing and nonionic aqueous solutions of β-cyclodextrin was studied by quasielastic neutron scattering (QENS). The total self-diffusion coefficients and their components corresponding to the contributions from collective (Lagrange type) and single-particle (jump diffusion) parts of molecular motions were determined. From the data obtained, one can conclude that the molecular mobility of free water in nonionic aqueous solutions of β-cyclodextrin with guest molecules (2-aminopyridine) proceeds by a single-particle mechanism. The addition of Pb2+ ions into the solution leads to increase in self-diffusion coefficients and growth of a bound water fraction. 相似文献
16.
Ana C.F. Ribeiro Victor M.M. Lobo Hugh D. Burrows Artur J.M. Valente Ana M. Amado Abílio J.F.N. Sobral Ana S.N. Teles Cecília I.A.V. Santos Miguel A. Esteso 《Journal of Molecular Liquids》2008,140(1-3):73-77
Numerical values for the mean distance of closest approach of ions, “a”, for lithium salts in aqueous solutions are presented and discussed. These values were obtained from both experimental activity and diffusion coefficients, and estimated by using different theoretical approaches. 相似文献
17.
18.
19.
G. Nägele M. Heinen A. J. Banchio C. Contreras-Aburto 《The European physical journal. Special topics》2013,222(11):2855-2872
Dynamic processes in dispersions of charged spherical particles are of importance both in fundamental science, and in technical and bio-medical applications. There exists a large variety of charged-particles systems, ranging from nanometer-sized electrolyte ions to micron-sized charge-stabilized colloids. We review recent advances in theoretical methods for the calculation of linear transport coefficients in concentrated particulate systems, with the focus on hydrodynamic interactions and electrokinetic effects. Considered transport properties are the dispersion viscosity, self- and collective diffusion coefficients, sedimentation coefficients, and electrophoretic mobilities and conductivities of ionic particle species in an external electric field. Advances by our group are also discussed, including a novel mode-coupling-theory method for conduction-diffusion and viscoelastic properties of strong electrolyte solutions. Furthermore, results are presented for dispersions of solvent-permeable particles, and particles with non-zero hydrodynamic surface slip. The concentration-dependent swelling of ionic microgels is discussed, as well as a far-reaching dynamic scaling behavior relating colloidal long- to short-time dynamics. 相似文献
20.
《Solid State Ionics》2006,177(5-6):595-600
Oxygen permeation fluxes across the dense Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCFO) membrane disks were measured under an air/helium oxygen partial pressure gradient at high pressures (up to 10 atm) and various temperatures (973–1123 K). The fabricated BSCFO membrane exhibited good oxygen permeability with a high oxygen permeation flux of 2.01 ml min− 1cm− 2 (thickness: 1.37 mm) at 1123 K and 10 atm. Oxygen permeation results were analyzed theoretically using the surface exchange current model. The dependences of the oxygen permeation fluxes on the oxygen partial pressure gradient, suggested that the bulk oxygen ionic diffusion was the rate-limiting step for the overall oxygen permeation process across the BSCFO membrane. The ambipolar diffusion coefficients (Da), the oxygen vacancy diffusion coefficients (Dv) and the oxygen ionic conductivities (σi) of the BSCFO material at different temperatures (973–1123 K) were calculated. It was found that BSCFO possessed high oxygen diffusion coefficients and ionic conductivities, which resulted in the good oxygen permeability of BSCFO. In addition, the BSCFO membrane exhibited good stability of oxygen permeation at 1123 K, while the deterioration of oxygen permeation stability was observed at 1098 K due to structural changes occurring at the surface of the BSCFO membrane disk as demonstrated by XRD. 相似文献